scholarly journals Eco-Friendly Protective Coating to Extend the Life of Art-Works and Structures Made in Porous Stone Materials

Coatings ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1270
Author(s):  
Mariateresa Lettieri ◽  
Maurizio Masieri ◽  
Marika Aquaro ◽  
Debora Dilorenzo ◽  
Mariaenrica Frigione
Keyword(s):  
Outdoor Exposure ◽  
Vapor Permeability ◽  
Hydrophobic Coating ◽  
Stone Materials ◽  
Art Works ◽  
Polymer Dispersed ◽  
Hydrophobic Treatment ◽  
Short Time ◽  
Proven Method

The application of hydrophobic treatments to stone surfaces is the most common proven method to prevent, or at least limit, the degradation of stone-made constructions and artworks brought about by the ingress and action of water, in particular in the case of very porous stone materials. To avoid the use of protective products containing harmful solvents, new green products have been proposed. In this paper, an eco-friendly hydrophobic coating, based on a fluorine polymer dispersed in water, was deeply analyzed to evaluate its protective properties, especially for very porous stone substrates. To this aim, a wide characterization of treated and untreated Lecce stone elements, i.e., a stone typical of the Apulia region, was carried out to assess the optimum required amount, the effectiveness and the protective capability, even against graffiti staining, of the green hydrophobic treatment, still allowing the stone to retain adequate vapor permeability. The efficacy of the eco-friendly product was analyzed also after a short time (four weeks) of outdoor exposure. Suitable performance and short-term durability of the green hydrophobic coating were found, comparable or even greater than those reported in the current literature for other widespread commercial products, confirming the capability of the product to preserve porous stone surfaces even in absence of solvents in its formulation. The study also allowed to experiment with the “contact sponge” test as an appropriate method for evaluating the water absorption properties of the stone.

Rapid, Refined, and Robust Method for Expression, Purification, and Characterization of Recombinant Human Amyloid-beta M1-42

2019 ◽  
Author(s):  
Priya Prakash ◽  
Travis Lantz ◽  
Krupal P. Jethava ◽  
Gaurav Chopra
Keyword(s):  
Amyloid Beta ◽  
Western Blots ◽  
Force Microscopy ◽  
E Coli ◽  
Atomic Force ◽  
Set Up ◽  
Short Time

Amyloid plaques found in the brains of Alzheimer’s disease (AD) patients primarily consists of amyloid beta 1-42 (Ab42). Commercially, Ab42 is synthetized using peptide synthesizers. We describe a robust methodology for expression of recombinant human Ab(M1-42) in Rosetta(DE3)pLysS and BL21(DE3)pLysS competent E. coli with refined and rapid analytical purification techniques. The peptide is isolated and purified from the transformed cells using an optimized set-up for reverse-phase HPLC protocol, using commonly available C18 columns, yielding high amounts of peptide (~15-20 mg per 1 L culture) in a short time. The recombinant Ab(M1-42) forms characteristic aggregates similar to synthetic Ab42 aggregates as verified by western blots and atomic force microscopy to warrant future biological use. Our rapid, refined, and robust technique to purify human Ab(M1-42) can be used to synthesize chemical probes for several downstream in vitro and in vivo assays to facilitate AD research.

scholarly journals Fabrication and characterization of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) modified with nano-montmorillonite biocomposite

e-Polymers ◽  
2020 ◽  
Vol 21 (1) ◽  
pp. 038-046
Author(s):  
Xu Yan ◽  
Wanru Zhou ◽  
Xiaojun Ma ◽  
Binqing Sun
Keyword(s):  
Thermal Stability ◽  
Oxygen Permeability ◽  
Water Vapor Permeability ◽  
Barrier Properties ◽  
Nucleating Agent ◽  
Vapor Permeability ◽  
Casting Method ◽  
Increasing Trend ◽  
Solution Casting Method

Abstract In this study, a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) modified with nano-montmorillonite biocomposite (MMT/PHBH) was fabricated by solution-casting method. The results showed that the addition of MMT increased the crystallinity and the number of spherulites, which indicated that MMT was an effective nucleating agent for PHBH. The maximum decomposition peak of the biocomposites moved to a high temperature and residue presented an increasing trend. The biocomposites showed the best thermal stability at 1 wt% MMT. Compared with PHBH, 182.5% and 111.2% improvement in elastic modulus and tensile strength were obtained, respectively. Moreover, the oxygen permeability coefficient and the water vapor permeability of MMT/PHBH biocomposites decreased by 43.9% and 6.9%, respectively. It was also found that the simultaneous enhancements on the crystallizing, thermal stability, mechanical, and barrier properties of biocomposites were mainly caused by the formation of intercalated structure between PHBH and MMT.

scholarly journals Synthesis and characterization of Cu(OH)2-NWs-PVA-AC Nano-composite and its use as an efficient adsorbent for removal of methylene blue

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sivarama Krishna Lakkaboyana ◽  
Khantong Soontarapa ◽  
Nabel Kalel Asmel ◽  
Vinay Kumar ◽  
Ravi Kumar Marella ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Kinetic Models ◽  
Batch Reactor ◽  
Maximum Adsorption Capacity ◽  
Nano Composite ◽  
Adsorption Processes ◽  
Intra Particle Diffusion ◽  
Short Time ◽  
Efficient Adsorbent

AbstractThe present study focused on the synthesis of copper hydroxide nanowires decorated on activated carbon (Cu(OH)2-NWs-PVA-AC). The obtained Cu(OH)2-NWs-PVA-AC Nano-composite was distinguished by XRD, SEM, EDX, BET, FTIR and XPS respectively. Besides, different variables such as solution pH, and initial dye concentration, contact time, and temperature were performed on the adsorption efficiency of MB in a small batch reactor. Further, the experimental results are analyzed by various kinetic models via PFO, PSO, intra-particle diffusion and Elovich models, and the results revealed that among the kinetic models, PSO shows more suitability. In addition, different adsorption isotherms were applied to the obtained experimental data and found that Langmuir–Freundlich and Langmuir isotherm were best fits with the maximum adsorption capacity of 139.9 and 107.6 mg/g, respectively. The Nano-composite has outstanding MB removal efficiency of 94–98.5% with a span of 10 min. and decent adsorption of about 98.5% at a pH of 10. Thermodynamic constants like Gibbs free energy, entropy, and enthalpy were analyzed from the temperature reliance. The results reveal the adsorption processes are spontaneous and exothermic in nature. The high negative value of ΔG° (− 44.11 to − 48.86 kJ/mol) and a low negative value of ΔH° (− 28.96 kJ/mol) show the feasibility and exothermic nature of the adsorption process. The synthesized dye was found to be an efficient adsorbent for the potential removal of cationic dye (methylene blue) from wastewater within a short time.

Electro-Optical Characterization of E48:PVP Polymer Dispersed Liquid Crystals

2001 ◽  
Vol 365 (1) ◽  
pp. 305-311
Author(s):  
Cheryll Lei E. Mahinay ◽  
Claire M. Macale ◽  
Fairland F. Amos ◽  
Zenaida B. Domingo ◽  
Leonorina G. Cada
Keyword(s):  
Liquid Crystals ◽  
Optical Characterization ◽  
Polymer Dispersed Liquid Crystals ◽  
Polymer Dispersed

scholarly journals Earthquake forecasting and its verification

2005 ◽  
Vol 12 (6) ◽  
pp. 965-977 ◽  
Author(s):  
J. R. Holliday ◽  
K. Z. Nanjo ◽  
K. F. Tiampo ◽  
J. B. Rundle ◽  
D. L. Turcotte
Keyword(s):  
Temporal Variations ◽  
Earthquake Forecasting ◽  
Earthquake Risk ◽  
Decision Threshold ◽  
New Approach ◽  
Pi Method ◽  
Time Prediction ◽  
Short Time ◽  
Large Earthquakes ◽  
Proven Method

Abstract. No proven method is currently available for the reliable short time prediction of earthquakes (minutes to months). However, it is possible to make probabilistic hazard assessments for earthquake risk. In this paper we discuss a new approach to earthquake forecasting based on a pattern informatics (PI) method which quantifies temporal variations in seismicity. The output, which is based on an association of small earthquakes with future large earthquakes, is a map of areas in a seismogenic region ("hotspots'') where earthquakes are forecast to occur in a future 10-year time span. This approach has been successfully applied to California, to Japan, and on a worldwide basis. Because a sharp decision threshold is used, these forecasts are binary--an earthquake is forecast either to occur or to not occur. The standard approach to the evaluation of a binary forecast is the use of the relative (or receiver) operating characteristic (ROC) diagram, which is a more restrictive test and less subject to bias than maximum likelihood tests. To test our PI method, we made two types of retrospective forecasts for California. The first is the PI method and the second is a relative intensity (RI) forecast based on the hypothesis that future large earthquakes will occur where most smaller earthquakes have occurred in the recent past. While both retrospective forecasts are for the ten year period 1 January 2000 to 31 December 2009, we performed an interim analysis 5 years into the forecast. The PI method out performs the RI method under most circumstances.

scholarly journals Study through Geant4, for Time Resolution characterization of different detectors arrays coupled with two SiPMs, as a function of: the scintillator plastic material, its volumetric dimensions and the location of the radiation emission source

2021 ◽  
Vol 8 (2) ◽  
pp. 211-217
Author(s):  
C. H. Zepeda Fernández ◽  
Hernández Aguilar Javier Efrén ◽  
E. Moreno-Barbosa
Keyword(s):  
Time Resolution ◽  
Plastic Material ◽  
High Time Resolution ◽  
Silicon Photomultipliers ◽  
Radiation Emission ◽  
Plastic Scintillators ◽  
Scintillator Material ◽  
Short Time ◽  
Lower Corner

The high time resolution detectors are relevant in those experiments or simulations were the particles to detect, have a very short time of flight (TOF), and due this it´s required that the detections times are ranged between ns. & ps.Using Geant4 software, it was made thirty simulations of coupled detectors to plastic scintillators with two silicon photomultipliers (SiPMs) located on the scintillator’s central sides. To characterize the time resolution, it was required to quantify the optical photons that reach the Score in a certain time, which are generated by muons on the surface of the plastic scintillator. Different configurations of muon beams were simulated at energy of 1 GeV, to interact with the configuration of the scintillator material of its corresponding arrangement. The simulations were made varying three parameters: the scintillator material “BC404 & BC422”, its size, and the location of the radiation source. Fifteen simulations correspond to BC404 material & fifteen simulations to BC422 material respectively. The first five simulations consisted in varying the scintillator’s volumetric size and collocate the muons beam guided randomly distributed over it, the next five simulations differentiate from setting up a directly centered beam, and the last five simulations for guide the beam on the left lower corner of each scintillator.The best time resolution achieved was σ= 8.67 +/− 0.26 ps., reported by the detector with BC422 scintillator material which has a volume of 20x20x3 mm3.

scholarly journals Characterization of Wave Fronts of Ultradistributions Using Directional Short-Time Fourier Transform

Axioms ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 240
Author(s):  
Sanja Atanasova ◽  
Snježana Maksimović ◽  
Stevan Pilipović
Keyword(s):  
Fourier Transform ◽  
Wave Front ◽  
Short Time Fourier Transform ◽  
Wave Fronts ◽  
Directional Wave ◽  
Tempered Ultradistributions ◽  
Short Time

In this paper we give a characterization of Sobolev k-directional wave front of order p∈[1,∞) of tempered ultradistributions via the directional short-time Fourier transform.

Structural, Textural and Thermal Characterization of Nano-Mg/Al Hydrotalcite before and after Cr (VI) Removal

2013 ◽  
Vol 755 ◽  
pp. 53-60
Author(s):  
Esthela Ramos Ramírez ◽  
Norma Leticia Gutiérrez Ortega ◽  
Cesar Augusto Contreras Soto ◽  
Gustavo Rangel Porras
Keyword(s):  
Crystalline Structure ◽  
Sol Gel ◽  
Textural Properties ◽  
Kinetic Studies ◽  
Thermal Characterization ◽  
Gel Method ◽  
Sol Gel Method ◽  
Before And After ◽  
Short Time

In this work there was studied the structural, textural and effect that has treat thermal on the removal of Cr (VI) of nanoMg/Al hydrotalcite (NHT) synthesized by the sol-gel method with a ratio of Mg/Al=3. These present the characterization of the nanoMg/Al hydrotalcite before and after Cr (VI) removal, as well as the kinetic studies and of balance. In agreement with the results, when the NHT are thermal treated to 350 °C the hydrotalcite crystalline structure remains but the textural properties are improved and structural. The NHT synthesized by the sol-gel method present a good capacity of removal with values of 91 mg of Cr (VI) removed / g of NHT. The above mentioned capacity of removal gets improved after thermal treating the material, reaching values of removal of 124 mg of Cr (VI) removed / g of NHT. The NHT with the Cr (VI) absorbed show decrease of the crystalline structure, as well as a saturation of the pores that annuls the porosity due to the fact that the Cr (VI) lodges both at the pores and at the intersheets. The time that him takes the HLM to remove the Cr (VI) of the watery solution is alone of 2 minutes, with which it is possible to conclude that the NHT have an excellent aptitude to remove Cr (VI) of watery solutions in an interval of very short time.

The versatility of the Bristow absorption tester – a review

2018 ◽  
Vol 33 (2) ◽  
pp. 279-296 ◽  
Author(s):  
Sami-Seppo Ovaska ◽  
Kaj Backfolk
Keyword(s):  
Special Focus ◽  
Print Quality ◽  
Substrate Roughness ◽  
Time Intervals ◽  
Absorption Properties ◽  
Liquid Absorption ◽  
Short Time ◽  
Printing Processes

Abstract This paper reviews the use of the Bristow Absorption Tester (known also as the Bristow wheel) in the characterization of fiber-based substrates. The Bristow wheel is a laboratory-scale instrument that has been designed for studying substrate wettability and dynamic liquid absorption properties in short time intervals, which are important in many converting and printing processes of paper and paperboard. The tester also gives information about substrate roughness. The Bristow wheel has shown great usefulness in predicting print quality especially in inkjet applications, in which a good correlation between print quality (letter area) and ink penetration rate has been found by several researchers. The apparatus is particularly useful in dynamic wetting studies, but it has also been successfully used in numerous other research purposes such as the determination of the degree of sizing, evaluation of material glueability, and various coatability studies. Modifications of both the testing principle and the tester structure have also been reported. These include e. g. equipping the apparatus with a corona unit that makes it possible to mimic a printing process on a relevant time-scale. This review summarizes the reported applications of Bristow wheel with a special focus on tester performance and versatility.

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