scholarly journals Electric Migration of Hydrogen Ion in Pore-Voltammetry Suppressed by Nafion Film

Electrochem ◽  
2020 ◽  
Vol 1 (4) ◽  
pp. 400-409
Author(s):  
Ling Liu ◽  
Koichi Jeremiah Aoki ◽  
Jingyuan Chen
Keyword(s):  
Hydrogen Ion ◽  
Hydrogen Ions ◽  
Cell Geometry ◽  
Grotthuss Mechanism ◽  
Cross Section Area ◽  
Section Area ◽  
Current Voltage ◽  
Micro Holes ◽  
Micro Hole ◽  
Nafion Film

Micro-hole voltammetry exhibiting rectified current-voltage curves was performed in hydrochloric acid by varying the lengths and the diameters of the micro-holes on one end of which a Nafion film was mounted. Some voltammetric properties were compared with those in NaCl solution. The voltammograms were composed of two line-segments, the slope of one segment being larger than the other. They were controlled by electric migration partly because of the linearity of the voltammograms and partly the independence of the scan rates. Since the low conductance which appeared in the current from the hole to the Nafion film was proportional to the cross section area of the hole and the inverse of the length of the hole, it should be controlled by the geometry of the hole. The conductance of the hydrogen ion in the Nafion film was observed to be smaller than that in the bulk, because the transport rate of hydrogen ion by the Grotthuss mechanism was hindered by the destruction of hydrogen bonds in the film. In contrast, the conductance for the current from the Nafion to the hole, enhancing by up to 30 times in magnitude from the opposite current, was controlled by the cell geometry rather than the hole geometry except for very small holes. A reason for the enhancement is a supply of hydrogen ions from the Nafion to increase the concentration in the hole. The concentration of the hydrogen ion was five times smaller than that of sodium ion because of the blocking of transport of the hydrogen ion in the Nafion film. However, the rectification ratio of H+ was twice as large as that of Na+.

scholarly journals Quantum consciousness in warm, wet and noisy brain

2016 ◽  
Vol 30 (28) ◽  
pp. 1650329 ◽  
Author(s):  
Valeriy I. Sbitnev
Keyword(s):  
Hydrogen Ion ◽  
Navier Stokes ◽  
Hydrogen Ions ◽  
Exclusion Zone ◽  
Superfluid State ◽  
Navier Stokes Equation ◽  
Ion Motion ◽  
Grotthuss Mechanism ◽  
Dynamic Flows ◽  
Quantum Consciousness

The emergence of quantum consciousness stems from dynamic flows of hydrogen ions in brain liquid. This liquid contains vast areas of the fourth phase of water with hexagonal packing of its molecules, the so-called exclusion zone (EZ) of water. The hydrogen ion motion on such hexagonal lattices shows as the hopping of the ions forward and the holes (vacant places) backward, caused by the Grotthuss mechanism. By supporting this motion using external infrasound sources, one may achieve the appearance of the superfluid state of the EZ water. Flows of the hydrogen ions are described by the modified Navier–Stokes equation. It, along with the continuity equation, yields the nonlinear Schrödinger equation, which describes the quantum effects of these flows, such as the tunneling at long distances or the interference on gap junctions.

EFFECT OF BEDLOAD SEDIMENT NATURAL COMPOSITION ON GEOMETRIC AND DINAMIC CHARACTERISTICS OF CHANNEL FORMS

2018 ◽  
pp. 36-39
Author(s):  
N Ikramov ◽  
T Majidov
Keyword(s):  
Research Work ◽  
Laboratory Data ◽  
Hydroelectric Station ◽  
Negative Consequences ◽  
Movement Velocity ◽  
Reservoir Volume ◽  
Pump Station ◽  
Cross Section Area ◽  
Section Area ◽  
Bedload Sediment

The article brings up data on sediment diversity at watercourse bed and on their movement in the form of ridges. The ridge form movement of sediment leads to the reduction of reservoir volume and canal cross section area, which has an effect on their carrying capacity, filling of pump station forechambers and hydroelectric station pressure basins with sediment. The presence of sediment in flow leads to abrasive deterioration of pumps, water motors and pressure pipes and to other negative consequences. Research work tasks on the study of these effects have been examined with the purpose of preventing such negative consequences. On the basis of laboratory data diagrams and relationships were obtained for ridge length, height and movement velocity vs. sediment hydraulic and geometric sizes.

Improvement of thread turning process using micro-hole textured solid-lubricant embedded tools

2021 ◽  
pp. 095440542110199
Author(s):  
Salman Khani ◽  
Seyedhamidreza Shahabi Haghighi ◽  
Mohammad Reza Razfar ◽  
Masoud Farahnakian
Keyword(s):  
Surface Roughness ◽  
Mechanical Strength ◽  
Solid Lubricant ◽  
Operating Cost ◽  
Contact Length ◽  
Solid Lubrication ◽  
Turning Process ◽  
Micro Holes ◽  
Micro Hole ◽  
Cutting Inserts

In this paper, the thread turning of aluminum 7075-T6 alloy is studied using micro-hole textured solid-lubricant embedded carbide inserts. The primary focus of this work is to enhance the performance of the thread turning process for producing high quality threaded parts. To achieve this, micro-holes were generated by laser micro-machining on the rake face of tools and then, MoS2 and CNT (carbon nanotube) solid-lubricants were embedded into micro-holes. The effects of micro-holes and solid-lubrication on the performance of the thread turning process were examined using traditional tool ( T0), micro-hole textured tool ( T1), micro-hole textured MoS2 embedded tool ( T2), and micro-hole textured CNT embedded tool ( T3). In this study, cutting forces, chip-tool contact length, built-up edge (BUE), surface roughness, and operating cost were investigated. The influence of micro-hole generation on the mechanical strength of cutting inserts was evaluated using the finite element method. The results showed that the fabrication of the micro-holes on the rake surface of cutting inserts has no significant effect on the mechanical strength of the tools. The comparisons of our method with traditional tools demonstrated that the cutting performance improved in the threading process. Our results reveal that the main cutting force, radial thrust force, surface roughness, built-up edge, and chip-tool contact length reduced 37.1%, 40.9%, 37.9%, 58.3%, and 38.2%, respectively, as T3 tools are applied in this process. A cost analysis, based on estimated tooling costs, showed that the T3 tool can yield an 18% reduction in overall operating cost.

scholarly journals Long-term evaluation of rootstock effects on cropping and tree parameters of selected sweet cherry cultivars

2020 ◽  
Vol 47 (No. 1) ◽  
pp. 13-20
Author(s):  
Jitka Blažková ◽  
František Paprštein ◽  
Lubor Zelený ◽  
Adéla Skřivanová ◽  
Pavol Suran
Keyword(s):  
Sweet Cherry ◽  
Cross Section Area ◽  
Section Area ◽  
Natural Tendency ◽  
Term Evaluation ◽  
The Mean ◽  
Sweet Cherry Cultivars ◽  
Tree Characteristics ◽  
Gisela 5

The cropping of six sweet cherry cultivars that originated in the Research and Breeding Institute of Pomology at Holovousy, and a standard one, ‘Burlat’, were evaluated on three rootstocks in the period of 2007–2017. Trees planted in a spacing of 1.5 m × 5.0 m were trained as tall spindle axes utilising their natural tendency to develop a central leader. On the standard rootstock, P-TU-2, ‘Tim’ was the most productive with a mean total harvest of 47.6 kg per tree. ‘Sandra’ yielded the most on the PHLC rootstock with 56.2 kg per tree and ‘Helga’ yielded the most on Gisela 5 with a mean total harvest of 55.9 kg per tree. The mean impact of the rootstock on the tree vigour, measured upon the trunk cross section area, ranged from 148.4 cm2 on the standard rootstock P-TU-2 to 114.1 cm2 on the PHLC and 125.2 cm2 on Gisela 5 . On the standard rootstock P-TU-2, the most vigorous one according to this criterion was ‘Jacinta’ (178.0 cm2) whereas ‘Justyna’ (109.7 cm2) was the least vigorous. On the PHLC, the most vigorous was ‘Sandra’ (147.2 cm2) and the least was ‘Amid’ (94.0 cm2). The other tree characteristics were mainly dependant on the cultivar and minimally, or not at all, influenced by the rootstock vigour.

Thermoacoustic Shape Optimization of a Subsonic Nozzle

2013 ◽  
Vol 135 (10) ◽  
Author(s):  
Alexis Giauque ◽  
Maxime Huet ◽  
Franck Clero ◽  
Sébastien Ducruix ◽  
Franck Richecoeur
Keyword(s):  
Acoustic Emission ◽  
Cross Section ◽  
Source Term ◽  
Combustion Noise ◽  
Noise Emission ◽  
Cross Section Area ◽  
Section Area ◽  
The Cross ◽  
Nozzle Flows ◽  
Subsonic Nozzle

Indirect combustion noise originates from the acceleration of nonuniform temperature or high vorticity regions when convected through a nozzle or a turbine. In a recent contribution (Giauque et al., 2012, “Analytical Analysis of Indirect Combustion Noise in Subcritical Nozzles,” ASME J. Eng. Gas Turbies Power, 134(11), p. 111202) the authors have presented an analytical thermoacoustic model providing the indirect combustion noise generated by a subcritical nozzle when forced with entropy waves. This model explicitly takes into account the effect of the local changes in the cross-section area along the configuration of interest. In this article, the authors introduce this model into an optimization procedure in order to minimize or maximize the thermoacoustic noise emitted by arbitrarily shaped nozzles operating under subsonic conditions. Each component of the complete algorithm is described in detail. The evolution of the cross-section changes are introduced using Bezier's splines, which provide the necessary freedom to actually achieve arbitrary shapes. Bezier's polar coordinates constitute the parameters defining the geometry of a given individual nozzle. Starting from a population of nozzles of random shapes, it is shown that a specifically designed genetic optimization algorithm coupled with the analytical model converges at will toward a quieter or noisier population. As already described by Bloy (Bloy, 1979, “The Pressure Waves Produced by the Convection of Temperature Disturbances in High Subsonic Nozzle Flows,” J. Fluid Mech., 94(3), pp. 465–475), the results therefore confirm the significant dependence of the indirect combustion noise with respect to the shape of the nozzle, even when the operating regime is kept constant. It appears that the quietest nozzle profile evolves almost linearly along its converging and diverging sections, leading to a square evolution of the cross-section area. Providing insight into the underlying physical reason leading to the difference in the noise emission between two extreme individuals, the integral value of the source term of the equation describing the behavior of the acoustic pressure of the nozzle is considered. It is shown that its evolution with the frequency can be related to the global acoustic emission. Strong evidence suggest that the noise emission increases as the source term in the converging and diverging parts less compensate each other. The main result of this article is the definition and proposition of an acoustic emission factor, which can be used as a surrogate to the complex determination of the exact acoustic levels in the nozzle for the thermoacoustic shape optimization of nozzle flows. This acoustic emission factor, which is much faster to compute, only involves the knowledge of the evolution of the cross-section area and the inlet thermodynamic and velocity characteristics to be computed.

Hydrogen Ion Beam Processing of Single Crystal Diamond Chips

1994 ◽  
Vol 354 ◽  
Author(s):  
Shuji Kiyohara ◽  
Iwao Miyamoto
Keyword(s):  
Surface Roughness ◽  
Single Crystal ◽  
Incidence Angle ◽  
Ion Beam ◽  
Etching Rate ◽  
Hydrogen Ion ◽  
Hydrogen Ions ◽  
Ion Beam Etching ◽  
Single Crystal Diamond ◽  
Before And After

AbstractIn order to apply ion beam etching with hydrogen ions to the ultra-precision processing of diamond tools, hydrogen ion beam etching characteristics of single crystal diamond chips with (100) face were investigated. The etching rate of diamond for 500 eV and 1000 eV hydrogen ions increases with the increase of the ion incidence angle, and eventually reaches a maximum at the ion incidence angle of approximately 50°, then may decrease with the increase of the ion incidence angle. The dependence of the etching rate on the ion incidence angle of hydrogen ions is fairly similar to that obtained with argon ions. Furthermore, the surface roughness of diamond chips before and after hydrogen ion beam etching was evaluated using an atomic force microscope. Consequently, the surface roughness after hydrogen ion beam etching decreases with the increase of the ion incidence angle within range of the ion incidence angle of 60°.

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