scholarly journals Processing of Water Treatment Sludge by Bioleaching

Energies ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 6539
Author(s):  
Tomasz Kamizela ◽  
Malgorzata Worwag
Keyword(s):  
Water Treatment ◽  
Elemental Sulfur ◽  
High Efficiency ◽  
Incubation Temperature ◽  
Metal Leaching ◽  
Acidithiobacillus Thiooxidans ◽  
Water Treatment Sludge ◽  
Time Intervals ◽  
Experimental Conditions

Biological metal leaching is a technology used in the mining and biohydrometallurgy industries where microorganisms mediate the dissolution of metals and semi-metals from mineral ores and concentrates. The technology also has great potential for various types of metal-rich waste. In this study, bioleaching was used for sludge from water treatment. In addition to checking the applicability of the process to such a substrate, the influence of experimental conditions on the effectiveness of bioleaching of metals with sludge from water treatment was also determined, including sample acidification, addition of elemental sulfur, incubation temperature, and Acidithiobacillus thiooxidans-isolated strain. The measurement of metal concentration and, on this basis, the determination of bioleaching efficiency, as well as pH and oxygen redox potential (ORP), was carried out during the experiment at the following time intervals: 3, 6, 9, 12 days. After the experiment was completed, a mass balance was also prepared. After the experiment, high efficiency of the process was obtained for the tested substrate. The effectiveness of the process for most metals was high (Ca 96.8%, Cr 92.6%, Cu 80.6%, Fe 95.6%, Mg 91%, Mn 99.5%, Ni 89.7%, Pb 99.5%, Zn 93%). Only lower values were obtained for Al (58.6%) and Cd (68.4%).

scholarly journals Stabilization of High-Organic-Content Water Treatment Sludge by Pyrolysis

Energies ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 3292 ◽  
Author(s):  
Ye-Eun Lee ◽  
I-Tae Kim ◽  
Yeong-Seok Yoo
Keyword(s):  
Heavy Metal ◽  
Water Treatment ◽  
Algal Blooms ◽  
Xrd Analysis ◽  
Organic Content ◽  
Metal Leaching ◽  
Water Treatment Sludge ◽  
Heavy Metal Leaching ◽  
Inorganic Matter ◽  
High Organic Content

Water treatment sludge from algal blooms were analyzed and compared with general water treatment sludge as the pyrolysis temperature was varied from 300 °C to 900° C. Elemental analysis showed that the water treatment sludge in the eutrophication region has ~12% carbon content, higher than that (8.75%) of general water treatment sludge. X-ray diffraction (XRD) analysis of both types of sludge showed that amorphous silica changed to quartz and weak crystalline structures like kaolinite or montmorillonite were decomposed and changed into stronger crystalline forms like albite. Fourier transform infrared spectroscopy (FT-IR) peaks of humic/fulvic acid that indicated the affinity to combine with heavy metals disappeared above 700 °C. Toxicity characteristic leaching procedure (TCLP), conducted to determine the heavy metal leaching amount of pyrolyzed water treatment sludge, showed the lowest value of 5.7 mg/kg at 500 °C when the humic acid was not decomposed. At 500 °C, the heavy metal leaching ratio to the heavy metal content of high organic content water treatment sludge and low organic content water treatment sludge were 1.87% and 3.19%, respectively, and the water treatment sludge of higher organic content was more stable. In other words, pyrolysis of water treatment sludge with high organic content at 500 °C increases the inorganic matter crystallinity and heavy metal leaching stability.

scholarly journals Feasibility of Using Calcined Water Treatment Sludge in Rendering Mortars: A Technical and Sustainable Approach

2019 ◽  
Vol 11 (13) ◽  
pp. 3576 ◽  
Author(s):  
Jairo José de Oliveira Andrade ◽  
Edna Possan ◽  
Matheus Chiaradia Wenzel ◽  
Sérgio Roberto da Silva
Keyword(s):  
Water Treatment ◽  
Environmentally Friendly ◽  
Cementitious Materials ◽  
Strength Properties ◽  
Raw Material ◽  
Co2 Uptake ◽  
Water Treatment Sludge ◽  
Natural Sand ◽  
Natural Carbonation

Many current industrial processes, such as water treatment, produce large amounts of waste. The water treatment sludge (WTS) must be properly disposed of and/or used as raw material for application in other sectors, such as the construction industry. The rendering mortar production can be an environmentally friendly alternative to recycle the WTS, this being the object of this research. In this way, mortars were produced with 2.5%, 5%, 7.5%, and 10% calcined WTS to replace natural sand. The water absorption, compressive strength, bond strength, and flexural strength properties were evaluated. A natural carbonation was carried out for the determination of CO2 uptake due to carbonation. The results showed that the incorporation of calcined WTS has an influence on all the properties evaluated. Considering 50 years of service life, the CO2 uptake potential for mortar with 10% calcined sludge WTP is 111 kg CO2/t. In the sustainability approach, it was observed that CO2 uptake due to carbonation is higher in mortars with the addition of WTS, and could be an environmentally friendly alternative that compensates emissions from the cementitious materials production.

scholarly journals Determination of tea polysaccharides in Camellia sinensis by a modified phenol-sulfuric acid method

2010 ◽  
Vol 62 (3) ◽  
pp. 669-676 ◽  
Author(s):  
Xionggang Xi ◽  
Xinlin Wei ◽  
Yuanfeng Wang ◽  
Qinjie Chu ◽  
Jianbo Xiao
Keyword(s):  
Sulfuric Acid ◽  
Camellia Sinensis ◽  
Incubation Temperature ◽  
Experimental Conditions ◽  
Acid Method ◽  
Relative Standard ◽  
Sulfuric Acid Method ◽  
Concentrated Sulfuric Acid ◽  
Phenol Sulfuric Acid

A direct procedure for the determination of total polysaccharides (TPS) in Camellia sinensis was set up based on the modified phenol-sulfuric acid method. The monosaccharide composition of TPS was analyzed by GC. Based on the results of GC, model monosaccharide mixtures were made which provided an adequate standard for this procedure. Through single-factor and orthogonal (L934) experiments, the experimental conditions such as the volume of phenol, the volume of concentrated sulfuric acid, the reaction time, and the incubation temperature, were optimized. The highest sensitivity of absorbance was obtained when the volume of concentrated sulfuric acid, the volume of phenol (6%), and the incubation temperature were 2.5 ml, 0.2 ml, and 50?C, respectively. Under optimum conditions, the prepared samples were determined satisfactorily, with the recovery from 100.2% to 103.7%, and a relative standard deviation (RSD) of 2.1%. Overall, the modified method is easily operated, rapid, sensitive and accurate. A similar procedure can be applied to the determination of other plant polysaccharides as well. .

Antithrombin-mediated Inhibition of Factor Vlla-Tissue Factor Complex by the Synthetic Pentasaccharide Representing the Heparin Binding Site to Antithrombin

1996 ◽  
Vol 76 (01) ◽  
pp. 005-008 ◽  
Author(s):  
Jean Claude Lormeau ◽  
Jean Pascal Herault ◽  
Jean Marc Herbert
Keyword(s):  
Binding Site ◽  
Tissue Factor ◽  
Residual Activity ◽  
Coagulation Factors ◽  
Heparin Binding ◽  
Experimental Conditions ◽  
First Order ◽  
Heparin Binding Site ◽  
Coagulant Activity

SummaryWe examined the effect of the synthetic pentasaccharide representing the minimal binding site of heparin to antithrombin on the antithrombin-mediated inactivation of factor Vila bound to tissue factor. This effect was compared to the effect of unfractionated heparin. Using purified recombinant human coagulation factors and either a clotting or an amidolytic assay for the determination of the residual activity of factor Vila, we showed that the pentasaccharide was an efficient antithrombin-dependent inhibitor of the coagulant activity of tissue factor-factor Vila complex. In our experimental conditions, assuming a mean MW of 14,000 for heparin, the molar pseudo-first order rate constants for ATIII-mediated FVIIa inhibition by ATIII-binding heparin and by the synthetic pentasaccharide were found to be similar with respective values of 104,000 ± 10,500 min-1 and 112,000 ± 12,000 min-1 (mean ± s.e.m., n = 3)

Determination of alcohols in mixtures by 19F NMR spectroscopy using hexefluoroacetone reagent

1982 ◽  
Vol 47 (7) ◽  
pp. 1973-1978 ◽  
Author(s):  
Jiří Karhan ◽  
Zbyněk Ksandr ◽  
Jiřina Vlková ◽  
Věra Špatná
Keyword(s):  
Standard Deviation ◽  
Nmr Spectroscopy ◽  
Standard Method ◽  
Internal Standard ◽  
Internal Standard Method ◽  
Concentration Region ◽  
Experimental Conditions ◽  
Curve Method ◽  
Sample Preparation Procedure

The determination of alcohols by 19F NMR spectroscopy making use of their reaction with hexafluoroacetone giving rise to hemiacetals was studied on butanols. The calibration curve method and the internal standard method were used and the results were mutually compared. The effects of some experimental conditions, viz. the sample preparation procedure, concentration, spectrometer setting, and electronic integration, were investigated; the conditions, particularly the concentrations, proved to have a statistically significant effect on the results of determination. For the internal standard method, the standard deviation was 0.061 in the concentration region 0.032-0.74 mol l-1. The method was applied to a determination of alcohols in the distillation residue from an oxo synthesis.

scholarly journals Software-guided microscale flow calorimeter for efficient acquisition of thermokinetic data

2021 ◽  
Author(s):  
Timothy Aljoscha Frede ◽  
Marlene Dietz ◽  
Norbert Kockmann
Keyword(s):  
Design Of Experiments ◽  
Process Development ◽  
Reaction Conditions ◽  
Experimental Conditions ◽  
Flow Calorimeter ◽  
Microscale Flow ◽  
Increased Sensitivity ◽  
Important Time ◽  
Optimal Reaction

AbstractFast chemical process development is inevitably linked to an optimized determination of thermokinetic data of chemical reactions. A miniaturized flow calorimeter enables increased sensitivity when examining small amounts of reactants in a short time compared to traditional batch equipment. Therefore, a methodology to determine optimal reaction conditions for calorimetric measurement experiments was developed and is presented in this contribution. Within the methodology, short-cut calculations are supplemented by computational fluid dynamics (CFD) simulations for a better representation of the hydrodynamics within the microreactor. This approach leads to the effective design of experiments. Unfavourable experimental conditions for kinetics experiments are determined in advance and therefore, need not to be considered during design of experiments. The methodology is tested for an instantaneous acid-base reaction. Good agreement of simulations was obtained with experimental data. Thus, the prediction of the hydrodynamics is enabled and the first steps towards a digital twin of the calorimeter are performed. The flow rates proposed by the methodology are tested for the determination of reaction enthalpy and showed that reasonable experimental settings resulted. Graphical abstract A methodology is suggested to evaluate optimal reaction conditions for efficientacquisition of kinetic data. The experimental design space is limited by thestepwise determination of important time scales based on specified input data.

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