scholarly journals Ammonia Recovery from Digestate Using Gas-Permeable Membranes: A Pilot-Scale Study

Environments ◽  
2021 ◽  
Vol 8 (12) ◽  
pp. 133
Author(s):  
Berta Riaño ◽  
Beatriz Molinuevo-Salces ◽  
Matías B. Vanotti ◽  
María Cruz García-González
Keyword(s):  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Land Application ◽  
Frequent Change ◽  
Permeable Membrane ◽  
A Value ◽  
Trapping Solution ◽  
Ammonia Recovery ◽  
Total Ammonia ◽  
Eu Project

The reduction and recovery of nitrogen (N) from anaerobically digested manure (digestate) is desirable to mitigate N-related emissions, mainly ammonia and nitrate, derived from digestate land application in nutrient-saturated zones. This work reports the results of a gas-permeable membrane (GPM) pilot-scale plant to recover ammonia from digestate in the framework of the EU project Ammonia Trapping. The total ammonia nitrogen (TAN) concentration in digestate was reduced by 34.2% on average (range 9.4–57.4%). The recovery of TAN in the trapping solution in the form of a (NH4)2SO4 solution averaged 55.3% of the removed TAN, with a TAN recovery rate of 16.2 g N m−2 d−1 (range between 14.5 and 21.0 g N m−2 d−1). The TAN concentration in the trapping solution achieved a value of up to 35,000 mg N L−1. The frequent change of the trapping solution has been proven as an efficient strategy to improve the overall performance of the GPM technology.

Tilapia rearing with high rate algal pond effluent: ammonia surface loading rates and stocking densities effects

2018 ◽  
Vol 78 (1) ◽  
pp. 49-56
Author(s):  
I. A. Sánchez ◽  
R. K. X. Bastos ◽  
E. A. T. Lana
Keyword(s):  
Weight Gain ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
High Rate ◽  
Surface Loading ◽  
Loading Rates ◽  
Total Weight Gain ◽  
Low Weight ◽  
Total Ammonia

Abstract In two pilot-scale experiments, fingerlings and juvenile of tilapia were reared in high rate algal pond (HRAP) effluent. The combination of three different total ammonia nitrogen (TAN) surface loading rates (SLR1 = 0.6, SLR2 = 1.2; SLR3 = 2.4 kg TAN·ha−1·d−1) and two fish stocking densities (D1 = 4 and D2 = 8 fish per tank) was evaluated during two 12-week experiments. Fingerlings total weight gain varied from 4.9 to 18.9 g, with the highest value (equivalent to 0.225 g·d−1) being recorded in SLR2-D1 treatment; however, high mortality (up to 67%) was recorded, probably due to sensitivity to ammonia and wide daily temperature variations. At lower water temperatures, juvenile tilapia showed no mortality, but very low weight gain. The fish rearing tanks worked as wastewater polishing units, adding the following approximate average removal figures on top of those achieved at the HRAP: 63% of total Kjeldahl nitrogen; 54% of ammonia nitrogen; 42% of total phosphorus; 37% of chemical oxygen demand; 1.1 log units of Escherichia coli.

scholarly journals Application of Gas-Permeable Membranes For-Semi-Continuous Ammonia Recovery from Swine Manure

Environments ◽  
2019 ◽  
Vol 6 (3) ◽  
pp. 32 ◽  
Author(s):  
Berta Riaño ◽  
Beatriz Molinuevo-Salces ◽  
Matías B. Vanotti ◽  
María Cruz García-González
Keyword(s):  
Acidic Solution ◽  
Membrane Surface ◽  
Swine Manure ◽  
Ammonia Nitrogen ◽  
Nitrogen Loading ◽  
Membrane Technology ◽  
Continuous Mode ◽  
Permeable Membrane ◽  
Total Ammonia Nitrogen ◽  
Total Ammonia

Gas-permeable membrane technology is a new strategy to minimize ammonia losses from manure, reducing pollution and recovering N in the form of an ammonium salt fertilizer. In this work, a new operational configuration to recover N using the gas-permeable membrane technology from swine manure was tested in a semi-continuous mode. It treated swine manure with a total ammonia nitrogen (TAN) concentration of 3451 mg L−1. The system was operated with low aeration rate (to raise pH), and with hydraulic retention times (HRT) of seven days (Period I) and five days (Period II) that provided total ammonia nitrogen loading rate (ALR) treatments of 491 and 696 mg TAN per L of reactor per day, respectively. Results showed a uniform TAN recovery rate of 27 g per m2 of membrane surface per day regardless of the ALR applied and the manure TAN concentration in the reactor. TAN removal reached 79% for Period I and 56% for Period II, with 90% of recovery by the membrane in both periods. Water capture in the acidic solution was also uniform during the experimental period. An increase in temperature of 3 °C of the acidic solution relative to the wastewater reduced 34% the osmotic distillation and water dilution of the product. These results suggested that the gas-permeable membrane technology operating in a semi-continuous mode has a great potential for TAN recovery from manure.

scholarly journals Characteristics of Ammonia Removal and Nitrifying Microbial Communities in a Hybrid Biofloc-RAS for Intensive Litopenaeus vannamei Culture: A Pilot-Scale Study

Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3000
Author(s):  
Wujie Xu ◽  
Yu Xu ◽  
Haochang Su ◽  
Xiaojuan Hu ◽  
Keng Yang ◽  
...  
Keyword(s):  
Microbial Communities ◽  
Litopenaeus Vannamei ◽  
Removal Rate ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Ammonia Removal ◽  
Shrimp Culture ◽  
Recirculating Aquaculture ◽  
Total Ammonia ◽  
High Feed

Ammonia is the main pollution factor of the aquatic environment in marine shrimp culture systems. In order to demonstrate the feasibility of the combination of biofloc technology and nitrifying biofilter for the ammonia removal, a 70-day production trial was conducted in a simplified pilot-scale hybrid biofloc-based recirculating aquaculture system (biofloc-RAS) with the intensive culture of Litopenaeus vannamei. Nitrogen dynamics and nitrifying microbial communities were investigated in three replicated systems simultaneously under the conditions of high feed loading and zero water exchange. Along with biofloc development in the culture tank and biofilm formation in the nitrifying biofilter during the trial, nitrification could be fastly and effectively established in the system, which was indicated by the dynamics of total ammonia nitrogen (TAN), NO2–-N, NO3–-N, and total nitrogen (TN) concentrations. Meanwhile, similar nitrifying microorganisms could be found between biofloc and biofilm, despite some differences in abundance, diversity, and composition of ammonia-oxidizing archaea and bacteria and nitrite-oxidizing bacteria. High TAN removal rate could be achieved and was significantly and positively correlated with abundances of these nitrifying microbial communities in both biofloc and biofilm, further indicating that both biofloc and biofilm could contribute highly to nitrification performance of the biofloc-RAS. The results of this study indicate a potential application of the biofloc-RAS in coastal intensive aquaculture.

Reliability of an Ammonia Probe for Electrometric Determination of Total Ammonia Nitrogen in Fish Tanks

1973 ◽  
Vol 30 (9) ◽  
pp. 1389-1392 ◽  
Author(s):  
Jan Barica
Keyword(s):  
Ammonia Nitrogen ◽  
Ammonium Ion ◽  
Absolute Difference ◽  
Membrane Electrode ◽  
Permeable Membrane ◽  
Mean Absolute Difference ◽  
Total Ammonia ◽  
Subsequent Measurement ◽  
Fish Tanks

The method involves an alkalization of a sample to pH 12 and subsequent measurement of liberated un-ionized ammonia with a gas-permeable membrane electrode. Total ammonia is measured directly rather than ammonium ion. Tests on different samples of water from aquaria and fish tanks showed a mean absolute difference of ±8.3% as compared with the phenolhypochlorite method in the concentration range of 0.5–5.1 mg/liter NH3-N. The lowest level of detection was 0.1 mg/liter NH3-N.

scholarly journals Characterization of Microbial Communities in Pilot-Scale Constructed Wetlands with Salicornia for Treatment of Marine Aquaculture Effluents

Archaea ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Xiaona Ma ◽  
Xingqiang Song ◽  
Xian Li ◽  
Songzhe Fu ◽  
Meng Li ◽  
...  
Keyword(s):  
Microbial Communities ◽  
Constructed Wetlands ◽  
High Throughput Sequencing ◽  
Northern China ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Marine Aquaculture ◽  
Salicornia Bigelovii ◽  
Recirculating Aquaculture Systems ◽  
Total Ammonia

Microorganisms play an essential role in the performance of constructed wetlands (CWs) for wastewater treatment. However, there has been limited discussion on the characteristics of microbial communities in CWs for treatment of effluents from marine recirculating aquaculture systems (RAS). This study is aimed at characterizing the microbial communities of pilot-scale CWs with Salicornia bigelovii for treatment of saline wastewater from a land-based Atlantic salmon RAS plant located in Northern China. Illumina high-throughput sequencing was employed to identify the profile of microbial communities of three CWs receiving wastewater under different total ammonia nitrogen (TAN) concentrations. Results of this study showed remarkable spatial variations in diversity and composition of microbial communities between roots and substrates in three CWs, with distinct response to different TAN concentrations. In particular, Proteobacteria, Firmicutes, Cyanobacteria, and Bacteroidetes were predominant in roots, while Cyanobacteria, Proteobacteria, Firmicutes, Verrucomicrobia, and Bacteroidetes were prevalent in substrates. Moreover, redundancy analysis indicated that specific functional genera, such as Nitrosopumilus, Vibrio, Pseudoalteromonas, Nitrospina, and Planctomyces, played key roles in the removal of nitrogen/phosphorus pollutants and growth of wetland plants. From a microorganism perspective, the findings of this study could contribute to better understanding of contaminants’ removal mechanism and improved management of CWs for treatment of effluents from land-based marine aquaculture.

scholarly journals Effect of the Type of Gas-Permeable Membrane in Ammonia Recovery from Air

Environments ◽  
2019 ◽  
Vol 6 (6) ◽  
pp. 70 ◽  
Author(s):  
María Soto-Herranz ◽  
Mercedes Sánchez-Báscones ◽  
Juan Antolín-Rodríguez ◽  
Diego Conde-Cid ◽  
Matias Vanotti
Keyword(s):  
Surface Area ◽  
Acidic Solution ◽  
Membrane Surface ◽  
Fluid Velocity ◽  
Air Permeability ◽  
Gaseous Ammonia ◽  
Permeable Membrane ◽  
Trapping Solution ◽  
Ammonia Recovery ◽  
Synthetic Solution

Animal production is one of the largest contributors to ammonia emissions. A project, “Ammonia Trapping”, was designed to recover gaseous ammonia from animal barns in Spain. Laboratory experiments were conducted to select a type of membrane most suitable for gaseous ammonia trapping. Three types of gas-permeable membranes (GPM), all made of expanded polytetrafluoroethylene (ePTFE), but with different diameter (3.0 to 8.6 mm), polymer density (0.45 to 1.09), air permeability (2 to 40 L·min−1·cm2), and porosity (5.6 to 21.8%) were evaluated for their effectiveness to recover gas phase ammonia. The ammonia evolved from a synthetic solution (NH4Cl + NaHCO3 + allylthiourea), and an acidic solution (1 N H2SO4) was used as the ammonia trapping solution. Replicated tests were performed simultaneously during a period of 7 days with a constant flow of acidic solution circulating through the lumen of the tubular membrane. The ammonia recovery yields were higher with the use of membranes of greater diameter and corresponding surface area, but they were not affected by the large differences in material density, porosity, air permeability, and wall thickness in the range evaluated. A higher fluid velocity of the acidic solution significantly increased—approximately 3 times—the mass NH3–N recovered per unit of membrane surface area and time (N-flux), from 1.7 to 5.8 mg N·cm−2·d−1. Therefore, to optimize the effectiveness of GPM system to capture gaseous ammonia, the appropriate velocity of the circulating acidic solution should be an important design consideration.

scholarly journals Assessment of Protein-Rich Cheese Whey Waste Stream as a Nutrients Source for Low-Cost Mixed Microbial PHA Production

2018 ◽  
Vol 8 (10) ◽  
pp. 1817
Author(s):  
Catarina Oliveira ◽  
Marisa Silva ◽  
Carlos E. Silva ◽  
Gilda Carvalho ◽  
Maria A. M. Reis
Keyword(s):  
Nitrogen Source ◽  
Cheese Whey ◽  
Low Cost ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Nitrogen Supplementation ◽  
Protein Uptake ◽  
Pha Production ◽  
Eu Project ◽  
Protein Rich

The critical step in the mixed microbial cultures (MMC) polyhydroxyalkanoates (PHA) production process is the selection of an MMC enriched in an efficient PHA-accumulating organism, usually requiring growth-nutrients supplementation. This study aimed at assessing cheese whey (CW) proteins as a source of nitrogen for PHA-producing MMC, thus eliminating or reducing the need for nutrients supplementation. The selection reactor, operated with fermented CW, under a feast–famine regime, was initially supplemented with ammonia–nitrogen in a C/N ratio of 100/15 (Cmol/Nmmol), which was gradually reduced until eliminated, in order to select a culture capable of using CW proteins nitrogen. Decreasing nitrogen supplementation from a C/N ratio of 100/10 to 100/7.5 lead to significant microbial community changes, and reduced the MMC PHA-storing capacity, storage yield, and PHA productivity, decreasing by 30%, and over 45%, respectively. The PHA-storing capacity further deteriorated as nitrogen supplementation was reduced, despite increased protein-uptake. Results show that a culture enriched in PHA-accumulators capable of using proteins as sole nitrogen source could not be attained. In conclusion, this work reports for the first time that an easily bioavailable nitrogen source is required for efficiently selecting PHA-accumulating cultures. Based on the results obtained from this work, a pilot scale plant (two reactors of 100 L) fed with cheese whey for production of PHA is currently being successfully operated under the scope of the YPACK EU project, in which the selection reactor is supplemented with nitrogen (ammonia) from a total C/N ratio of 100/10.

scholarly journals Upgrading northern municipal lagoons: Total nitrogen removal and phosphorus assimilation at ultra-low temperatures

2021 ◽  
Author(s):  
Patrick M. D'Aoust ◽  
Simon Vincent ◽  
Guillaume Leblond ◽  
Raheleh Arabgol ◽  
Richard Hérard ◽  
...  
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Low Temperatures ◽  
Pilot Scale ◽  
Ammonia Nitrogen ◽  
Biofilm Reactor ◽  
Sulfide Toxicity ◽  
Total Ammonia ◽  
Treatment Train ◽  
Total Nitrogen Removal

In this study, a municipal lagoon with high wintertime effluent total ammonia nitrogen (TAN) concentrations was upgraded with a pilot-scale NIT-NIT-DENIT moving bed biofilm reactor (MBBR) treatment train to characterize its effluent over wintertime operation, investigate the feasibility of upgrading lagoons to achieve substantial biological total nitrogen removal across ultra-low temperatures (0.6 – 3.0°C) and investigate nitrification inhibition pathways in facultative lagoon systems at ultra-low temperatures. Throughout the study, it was observed that the system substantially reduced total nitrogen (TN) and total phosphorus (TP) effluent concentrations by an average of 69.0 ± 24.5% and 74.7 ± 20.1%, respectively, with average TN and TP concentrations exiting the treatment train of 7.60 ± 5.60 mg-N/L and 0.05 ± 0.02 mg-P/L, respectively, indicating the feasibility of upgrading municipal lagoons to meet increasing stringent effluent standards to ensure the perenniality of water resources. Furthermore, it was observed that sulfide toxicity may play an important role in the inhibition of nitrifying organisms in lagoons.

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