scholarly journals Carbonation Resistance Performance and Micro-Structure Analysis of Glazed Hollow Bead Insulation Concrete

2019 ◽  
Vol 4 (4) ◽  
pp. 63
Author(s):  
Huang ◽  
Yao ◽  
Pang

In this paper, the carbonation depths of glazed hollow bead insulation concrete (GHBC) and normal concrete (NC) at different carbonation ages are tested. The microstructure of GHBC and NC before and after carbonation were observed and compared by mercury intrusion porosimetry (MIP), energy dispersive spectrometer (EDS), and X-ray diffraction (XRD). The results showed that NC had better carbonation resistance than GHBC, and GHBC had a carbonation depth of 1.61 times than that of NC at 28 days accelerated carbonation experiment. The microstructural analysis showed that with the decrease of porosity of the samples, the carbon content and CaCO3 content increased after carbonation. The porosity of NC decreased from 14.36% to 13.53%, the carbon content increased from 4.42% to 5.94%, and the CaCO3 content increased from 18.5% to 56.0%. The porosity of GHBC decreased from 22.94% to 20.71%, the carbon content increased from 4.97% to 5.31%, and the CaCO3 content increased from 70.0% to 82.0%. The above results showed that carbon reacts with hydration products 3CaO·SiO2, 2CaO·SiO2, and Ca(OH)2 to produce a large amount of CaCO3 which causes a large amount of pores to be filled and refined hence the porosity and pore size were reduced leading to increase in the compactness of the material. From the results obtained, the carbonation depth prediction formula of glazed hollow bead insulation concrete was developed, and carbonation life was predicted.

Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 269
Author(s):  
Kailun Xia ◽  
Yue Gu ◽  
Linhua Jiang ◽  
Mingzhi Guo ◽  
Lei Chen ◽  
...  

To date, reinforcement concrete is the main construction material worldwide. As the concentration of atmospheric CO2 is steadily increasing, carbonation of the reinforcement concrete becomes a pressing concern. In this study, novel surface protective materials (SPMs) modified with hybrid nanoSiO2 (HNS), fly ash, and slag were developed to reduce CO2 emissions and extend the service life of the reinforcement concrete. The carbonation depths were measured by phenolphthalein to reflect the carbonation resistance. X-ray diffraction (XRD), fourier-transform infrared spectroscopy (FTIR), and thermal gravimetric analysis (TGA) were conducted to analyze the chemical components of the samples after carbonation. In addition, MIP was carried out to examine the microstructures of the samples prior to carbonation. Thermodynamic modeling was employed to calculate the changes in the phase assemblages of each blends in an ideal situation. The experimental results showed that the carbonation depth and CaCO3 content of the SPM modified with HNS decreased by 79.0% and 64.6% compared with the reference, respectively. The TGA results showed that after carbonation, the CaCO3 contents were 4.40% and 12.42% in the HNS modified samples and reference samples, respectively. MIP analysis demonstrated that the incorporation of HNS in SPM led to a 48.3% and 58.5% decrease in big pores and capillary pores, respectively. Overall, the SPMs modified with HNS in this study possessed better carbonation resistance and refined pore structures.


2019 ◽  
Vol 2019 ◽  
pp. 1-15 ◽  
Author(s):  
Mingjie Mao ◽  
Dongsheng Zhang ◽  
Qiuning Yang ◽  
Wenbo Zhang

To study the durability of concrete with fly ash as fine aggregate subjected to alternative attacks of freeze-thaw and carbonation, the appearance, mass loss, relative dynamic modulus of elasticity, relative compressive strength, and carbonation depth of the concrete are investigated using cyclic tests under single carbonation, single freeze-thaw, and alternation of freeze-thaw and carbonation. In addition, microstructural analysis techniques including scanning electron microscope and X-ray diffraction are adopted to reveal the deterioration mechanism of alternating freeze-thaw and carbonation. Results show that carbonation is beneficial for refining the pore structure and increasing concrete strength in the initial alternative cycle, which delays the damage from freeze-thaw cycles. Damage from freeze-thaw causes crack propagation in concrete, which leads to carbonation intensification. Compared with other test modes, concrete under alternative freeze-thaw and carbonation causes the greatest degree of deterioration during the initial freeze-thaw cycles. The carbonation depth under alternative freeze-thaw and carbonation is positively correlated with the carbonation time and the water-to-cement ratio. However, as the reactant is continuously consumed due to the expansion of crystalline ice and CaCO3, alternative cycles result in the appearance of many more new cracks in the concrete.


2017 ◽  
Vol 24 (Supp01) ◽  
pp. 1850015 ◽  
Author(s):  
QIONGYU ZHOU ◽  
WEI XIE ◽  
YADONG ZHANG ◽  
MINQI SHENG ◽  
ANWEI HU ◽  
...  

Ni–W–Al2O3 nanocomposite coatings were deposited on the low-carbon steel substrates from aqueous sulfate-citrate electrolytes containing various amounts of Al3O2 nanoparticles. Their surface morphology, element and phase composition were carried out using scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and X-ray diffraction (XRD). The corrosion resistance was carried out using the potentiodynamic polarization (Tafel) and electrochemical impedance spectroscopy (EIS). It is shown that incorporation of Al2O3 nano-particles into amorphous Ni–W coating would transform its structure to being crystalline and influence its properties. The hardness sharply increases and corrosion resistance performance significantly decreases even after few Al2O3 nanoparticles (2 g/L) were added into the bath. In addition, with increase of Al2O3 addition in the bath, a tendency of increase in hardness and corrosion resistance performance is observed.


Author(s):  
T. Gulik-Krzywicki ◽  
M.J. Costello

Freeze-etching electron microscopy is currently one of the best methods for studying molecular organization of biological materials. Its application, however, is still limited by our imprecise knowledge about the perturbations of the original organization which may occur during quenching and fracturing of the samples and during the replication of fractured surfaces. Although it is well known that the preservation of the molecular organization of biological materials is critically dependent on the rate of freezing of the samples, little information is presently available concerning the nature and the extent of freezing-rate dependent perturbations of the original organizations. In order to obtain this information, we have developed a method based on the comparison of x-ray diffraction patterns of samples before and after freezing, prior to fracturing and replication.Our experimental set-up is shown in Fig. 1. The sample to be quenched is placed on its holder which is then mounted on a small metal holder (O) fixed on a glass capillary (p), whose position is controlled by a micromanipulator.


2017 ◽  
Vol 13 (2) ◽  
pp. 4640-4647
Author(s):  
A. M. Abdelghany ◽  
M.S. Meikhail ◽  
S.I. Badr ◽  
A. S. Momen

Thin film samples of pristine polyvinyl chloride (PVC), poly vinyldine fluoride (PVDF) in combination with their blend in addition to samples containing factorial mass fraction of multi wall carbon nano-tubes (MWCNTs) in the dopant level were prepared via routine casting technique using tetrahydrofurane (THF) as a common solvent. X-ray diffraction and transmission electron microscopy (TEM) depict the nano-scale (15-25 nm) of functionalized MWCNTs with no surface damage results from functionalization process.X-ray diffraction (XRD) shows a semi-crystalline nature of PVDF with evidence for more than one phase namely a and b phases. The fraction of b phase was calculated and correlated to the dopant content. FTIR optical absorption spectra revels a preservation of the main vibrational bands before and after addition of MWCNTs in the doping level with a presence of new small band 1151 cm-1 assigned for the interaction and complexation between constituents.


2011 ◽  
Vol 314-316 ◽  
pp. 273-278
Author(s):  
Yu Hua Dong ◽  
Ke Ren ◽  
Qiong Zhou

Linear low density polyethylene (LLDPE) was chemically modified with grafting maleic anhydride (MAH) monomer on its backbone by melting blending. Nano-particles SiO2 was modified by cationic surfactant hexadecyl trimethyl ammonium bromide (CTAB) and anionic surfactant sulfosalicylic acid (SSA) and added to PE coating respectively. Measurement of membrane potential showed that the coating containing modified SiO2 nano-particles had characteristic of ion selectivity. The properties of the different coatings were investigated according to relative industrial standards. Experimental results indicated that PE coating with ion selectivity had better performances, such as adhesion strength, cathodic disbonding and anti-corrosion, than those of coating without ion selectivity. Crystal structure of the coatings before and after alkali corrosion was characterized by Fourier transform infrared spectra (FTIR) and X-ray diffraction (XRD). Structure of the coating without ion selectivity was damaged by NaOH alkali solution, causing mechanical properties being decreased. And the structure of the ion selective coatings was not affected.


Author(s):  
Ogün Baris Tapar ◽  
Jérémy Epp ◽  
Matthias Steinbacher ◽  
Jens Gibmeier

AbstractAn experimental heat treatment chamber and control system were developed to perform in-situ X-ray diffraction experiments during low-pressure carburizing (LPC) processes. Results from the experimental chamber and industrial furnace were compared, and it was proven that the built system is reliable for LPC experiments. In-situ X-ray diffraction investigations during LPC treatment were conducted at the German Electron Synchrotron Facility in Hamburg Germany. During the boost steps, carbon accumulation and carbide formation was observed at the surface. These accumulation and carbide formation decelerated the further carbon diffusion from atmosphere to the sample. In the early minutes of the diffusion steps, it is observed that cementite content continue to increase although there is no presence of gas. This effect is attributed to the high carbon accumulation at the surface during boost steps which acts as a carbon supply. During quenching, martensite at higher temperature had a lower c/a ratio than later formed ones. This difference is credited to the early transformation of austenite regions having lower carbon content. Also, it was noticed that the final carbon content dissolved in martensite reduced compared to carbon in austenite before quenching. This reduction was attributed to the auto-tempering effect.


Catalysts ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 678
Author(s):  
Stefano Alberti ◽  
Irene Basciu ◽  
Marco Vocciante ◽  
Maurizio Ferretti

In this contribution, the photoactivity upon activation by simulated sunlight of zinc oxide (ZnO) obtained from two different synthetic pathways (Acetate and Nitrate) is investigated for water purification. Different reagents and processes were exploited to obtain ZnO nanoparticles. Products have been characterized by means of X-Ray Diffraction, Scanning Electron Microscopy along with Energy Dispersive Spectrometer, Dynamic Light Scattering, and Diffuse Reflectance Measurements, to highlight the different outcomes ascribable to each synthesis. A comparison of characteristics and performances was also carried out with respect to commercial ZnO. Nanoparticles of this semiconductor can be obtained as aggregates with different degrees of purity, porosity, and shape, and their physical-chemical properties have been addressed to the specific use in wastewater treatment, testing their effectiveness on the photocatalytic degradation of methylene blue (MB) as a model pollutant. Excluding the commercial sample, experimental results evidenced a better photocatalytic behavior for the ZnO Nitrate sample annealed at 500 °C, which was found to be pure and stable in water, suggesting that ZnO could be effectively exploited as a heterogeneous photocatalyst for the degradation of emerging pollutants in water, provided that thermal treatment is included in the synthetic process.


2020 ◽  
Vol 9 (1) ◽  
pp. 998-1008
Author(s):  
Guo Li ◽  
Zheng Zhuang ◽  
Yajun Lv ◽  
Kejin Wang ◽  
David Hui

AbstractThree nano-CaCO3 (NC) replacement levels of 1, 2, and 3% (by weight of cement) were utilized in autoclaved concrete. The accelerated carbonation depth and Coulomb electric fluxes of the hardened concrete were tested periodically at the ages of 28, 90, 180, and 300 days. In addition, X-ray diffraction, thermogravimetry, and mercury intrusion porosimetry were also performed to study changes in the hydration products of cement and microscopic pore structure of concrete under autoclave curing. Results indicated that a suitable level of NC replacement exerts filling and accelerating effects, promotes the generation of cement hydration products, reduces porosity, and refines the micropores of autoclaved concrete. These effects substantially enhanced the carbonation and chloride resistance of the autoclaved concrete and endowed the material with resistances approaching or exceeding that of standard cured concrete. Among the three NC replacement ratios, the 3% NC replacement was the optimal dosage for improving the long-term carbonation and chloride resistance of concrete.


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