scholarly journals A Facile Way to Prolong Service Life of Double Base Propellant

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2236 ◽  
Author(s):  
Shixiong Sun ◽  
Song Ma ◽  
Benbo Zhao ◽  
Guangpu Zhang ◽  
Yunjun Luo

The safe storage time for double base propellant (DBP or DB propellant) with stabilizers could usually be calculated to be greater than 40 years. However, the actual service life is far below that, which is largely caused by the decline of propellant mechanical performance. In this work polytetrafluoroethylene (PTFE) was introduced into the double base propellant formula as an additive. The tensile properties of this propellant before and after artificial aging were determined. The evaporation and diffusion characteristics of nitroglycerin (NG) in propellant were evaluated by thermogravimetry analysis (TGA). The results showed that mechanical properties of propellant were improved due to PTFE, especially for elongation at −40 °C, which was greatly increased by 115%. Moreover, the results of TGA showed that NG migration was reduced due to PTFE, which delayed the decline of propellant mechanical performance during aging. The reduction in elongation at −40 °C caused by aging was decreased by 68.5% for PTFE modified DBP. Enhanced mechanical properties and reduced NG migration could potentially prolong propellant service life.

2020 ◽  
Vol 2020 ◽  
pp. 1-16
Author(s):  
Peng Liu ◽  
Ying Chen ◽  
Zhiwu Yu ◽  
Zhaohui Lu

The effects of erosion mode, erosion age, and concentration of sulfate solution on mechanical properties of concrete were investigated. The dimensionless relationship model of the stress-strain of concrete on the basis of randomness was proposed. The variation of the elasticity modulus and Poisson’s ratio of the concrete surface attacked by sulfate was studied, and a novel method of using a superficial parameter to characterize the performance change of the concrete surface was recommended. The results showed that the dimensionless relationship model of stress-strain of concrete could be used to represent the variations of mechanical properties of concrete. The differences of load-displacement of concrete before and after sulfate attack were reflected as the change of curve’s slope and ultimate bearing capacity, and the slope of a straight section of the lateral and longitudinal strain curves of concrete surface also varied. The increment rates of ultimate bearing capacity of concrete attacked by 1% and saturated sulfate solution were about 30% and 10%, respectively. However, the decreasing ratio of the ultimate bearing capacity of concrete attacked by saturated sulfate solution was approximately 25%. The damage factor of the elasticity modulus of the concrete surface of C20 and C40 was 0.185 and −0.19, respectively. The obtained results could provide a support for investigating the variations of stress-strain relationship and mechanical performance of concrete under a sulfate environment.


2013 ◽  
Vol 24 (6) ◽  
pp. 599-604 ◽  
Author(s):  
Andrea Candido dos Reis ◽  
Denise Tornavoi de Castro ◽  
Marco Antonio Schiavon ◽  
Leandro Jardel da Silva ◽  
Jose Augusto Marcondes Agnelli

The aim of this study was to investigate the influence of accelerated artificial aging (AAA) on the microstructure and mechanical properties of the Filtek Z250, Filtek Supreme, 4 Seasons, Herculite, P60, Tetric Ceram, Charisma and Filtek Z100. composite resins. The composites were characterized by Fourier-transform Infrared spectroscopy (FTIR) and thermal analyses (Differential Scanning Calorimetry - DSC and Thermogravimetry - TG). The microstructure of the materials was examined by scanning electron microscopy. Surface hardness and compressive strength data of the resins were recorded and the mean values were analyzed statistically by ANOVA and Tukey's test (α=0.05). The results showed significant differences among the commercial brands for surface hardness (F=86.74, p<0.0001) and compressive strength (F=40.31, p<0.0001), but AAA did not affect the properties (surface hardness: F=0.39, p=0.53; compressive strength: F=2.82, p=0.09) of any of the composite resins. FTIR, DSC and TG analyses showed that resin polymerization was complete, and there were no differences between the spectra and thermal curve profiles of the materials obtained before and after AAA. TG confirmed the absence of volatile compounds and evidenced good thermal stability up to 200 °C, and similar amounts of residues were found in all resins evaluated before and after AAA. The AAA treatment did not significantly affect resin surface. Therefore, regardless of the resin brand, AAA did not influence the microstructure or the mechanical properties.


2012 ◽  
Vol 529-530 ◽  
pp. 229-232
Author(s):  
Ryo Akatsuka ◽  
Ken Matsumura ◽  
Miyoko Noji ◽  
Chihiro Nishikawa ◽  
Kei Sato ◽  
...  

This study aimed to create a thick hydroxyapatite (HAp) film on the surface of a human tooth by using a newly developed powder jet deposition (PJD) device for dental handpieces, and sought to examine the microstructural and mechanical properties of the resulting HAp film. The film was evaluated on three-dimensional view, surface roughness, Vickers hardness, and bonding strength before and after artificial aging through thermal cycling (555°C) for 500 cycles (30 sec for each cycle, 20 sec of dwell time).The HAp particles in the deposited film were densely packed, and the HAp films three-dimensional microstructure and its rough surface were maintained after thermal cycling. There was no significant difference in either the HAp films Vickers hardness or the bonding strength between the film and the enamel substrate before and after thermal cycling. The HAp films created in this study demonstrated excellent microstructural and mechanical properties even after the application of thermal stress. We demonstrated the possibility of using a new type of powder jet deposition (PJD) method we developed to form a new type of interface between the tooth and biomaterials. Consequently, we propose the use of this method in new dental treatments.


Metals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 645 ◽  
Author(s):  
Sebastian Marian Zaharia ◽  
Lucia Antoneta Chicoș ◽  
Camil Lancea ◽  
Mihai Alin Pop

In this study, lightweight sandwich structures with honeycomb cores are proposed and their mechanical properties are investigated through experiments and FEA (finite element analysis) simulation. Sandwich structures were fabricated out of Inconel 718 using selective laser melting technique with two different topologies—sandwich structures with perforated skin (SSPS) and sandwich structures with perforated core (SSPC). In addition, the effect of the homogenization heat treatment on the mechanical properties of the sandwich samples subjected to compression and microhardness tests was analyzed. Results showed significant increases of mechanical performance before and after homogenization heat treatment of the Inconel 718 samples. Microstructure analysis was performed to compare the microstructures before and after homogenization heat treatment for Inconel 718 alloys manufactured by selective laser melting (SLM). The accuracy of experimental data were evaluated by modeling of sandwich samples in Ansys software at the end of this study.


Author(s):  
Cleiton André Comelli ◽  
Richard Davies ◽  
HenkJan van der Pol ◽  
Oana Ghita

AbstractThe heating and extrusion process in fused filament fabrication (FFF) is significantly shorter than the conventional extrusion process where longer heating times and significant pressure are applied. For this reason, it is important to understand whether the crystal history of the feedstock is fully erased through the FFF process and whether the FFF process can be tailored further by engineering the crystallization of the feedstock filaments. In this context, a methodology for evaluating the influence of morphology and mechanical properties on different feedstock and extruded filaments is proposed. Filaments with three different PEEK 450G crystalline structures (standard crystallinity, drawn filament and amorphous filament) were selected and evaluated, before and after free extrusion. The resulting morphology, crystallinity and mechanical properties of the extruded filaments were compared against the feedstock properties. X-ray diffraction (XRD), transmission electron microscopy (TEM), differential and fast scanning calorimetry (DSC/FDSC) and tensile test were the techniques used to evaluate the materials. The results showed clear differences in the properties of the feedstock materials, while the analysis of the extruded filaments points to a homogenization of the resulting material producing mostly similar mechanical properties. However, the use of the drawn filament highlighted a statistically significant improvement in crystallinity and mechanical performance, especially in strain values. This conclusion suggests the innovative possibility of improving the quality of manufactured parts by tailoring the microstructure of the feedstock material used in the FFF process. Graphical abstract


2010 ◽  
Vol 168-170 ◽  
pp. 408-411
Author(s):  
Xiao Yong Li

Corrosion is a negative contributor on the structural integrity of rock bolt and leads to degradation of the mechanical properties of steel rock bolt. Exposure to chloride, seawater, salt and saltwater and deicing chemical environments influences rock bolt and weakens it. In order to evaluate the influence of corrosion and the size of the steel on the mechanical properties of rock bolt, an experimental investigation was conducted on rock bolt whose rebar is 8, 12, 16, and 18 mm diameter, and which were artificially corroded for 10, 20, 30, 45, 60, 90, and 120 days. By the simulation corrosion test of loaded and unloaded bolts in Na2SO4 solution, the relation curves of the mechanical performance with the corrosive conditions and the corrosion time are given. The mechanical performance is compared between these two types of bolts. At the same time, the influential trend of the load on the mechanical performance of the corroded bolt is analyzed. The laboratory tests suggest that corrosion duration and rebar size had a significant impact on the strength and ductility degradation of the specimens. after being corroded in Na2SO4 solution, both the ultimate bearing capacity and the maximal tensility of loaded bolt decrease far more than those of unloaded bolt, and the endurance and service life of loaded bolt will also be shortened much more severely. The tensile mechanical properties before and after corrosion indicated progressive variation and drastic drop in their values.


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