scholarly journals Morphological and Mechanical Characterization of DNA SAMs Combining Nanolithography with AFM and Optical Methods

Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 2888 ◽  
Author(s):  
Giulia Pinto ◽  
Paolo Canepa ◽  
Claudio Canale ◽  
Maurizio Canepa ◽  
Ornella Cavalleri
Keyword(s):  
Mechanical Properties ◽  
Ionic Strength ◽  
Photoelectron Spectroscopy ◽  
Quantitative Imaging ◽  
Quantitative Information ◽  
Optical Methods ◽  
Contact Mode ◽  
Young’S Moduli ◽  
Monomolecular Films ◽  
The Difference

The morphological and mechanical properties of thiolated ssDNA films self-assembled at different ionic strength on flat gold surfaces have been investigated using Atomic Force Microscopy (AFM). AFM nanoshaving experiments, performed in hard tapping mode, allowed selectively removing molecules from micro-sized regions. To image the shaved areas, in addition to the soft contact mode, we explored the use of the Quantitative Imaging (QI) mode. QI is a less perturbative imaging mode that allows obtaining quantitative information on both sample topography and mechanical properties. AFM analysis showed that DNA SAMs assembled at high ionic strength are thicker and less deformable than films prepared at low ionic strength. In the case of thicker films, the difference between film and substrate Young’s moduli could be assessed from the analysis of QI data. The AFM finding of thicker and denser films was confirmed by X-Ray Photoelectron Spectroscopy (XPS) and Spectroscopic Ellipsometry (SE) analysis. SE data allowed detecting the DNA UV absorption on dense monomolecular films. Moreover, feeding the SE analysis with the thickness data obtained by AFM, we could estimate the refractive index of dense DNA films.

Internal Oxidation and Mechanical Properties of Pt-IrO2 Thin Films

2003 ◽  
Vol 795 ◽  
Author(s):  
Richard R. Chromik ◽  
Thirumalesh Bannuru ◽  
Richard P. Vinci
Keyword(s):  
Mechanical Properties ◽  
Residual Stress ◽  
Photoelectron Spectroscopy ◽  
Thermal Cycle ◽  
Room Temperature ◽  
Sputter Deposition ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Difference ◽  
Pt Films

ABSTRACTPt-IrO2 films, approximately 200 nm thick, were fabricated by co-sputter deposition of Pt and Ir in an Ar-O2 mixture followed by annealing at 700°C in O2 for 4 hours. X-ray photoelectron spectroscopy and x-ray diffraction measurements indicate the presence of IrO2 throughout the thickness of the films. After a thermal cycle in vacuum to 700°C, the room temperature residual stress is significantly lower in the internally oxidized films than in pure Pt films of similar thickness subjected to identical cycling. Initial analysis of the behavior of the films during thermal cycling indicates that the primary cause for the difference in residual stress level is a decrease in the thermoelastic slope associated with the introduction of IrO2.

Effect of silver nitrate on some mechanical properties of heat polymerizing acrylic resins

2019 ◽  
Vol 14 (1) ◽  
pp. 110
Author(s):  
Assiss. Prof. Dr. Sabiha Mahdi Mahdi ◽  
Dr. Firas Abd K. Abd K.
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Silver Nitrate ◽  
Surface Hardness ◽  
Mechanical Tests ◽  
Hardness Tester ◽  
Acrylic Resins ◽  
The Difference

Aim: The aimed study was to evaluate the influence of silver nitrate on surfacehardness and tensile strength of acrylic resins.Materials and methods: A total of 60 specimens were made from heat polymerizingresins. Two mechanical tests were utilized (surface hardness and tensile strength)and 4 experimental groups according to the concentration of silver nitrate used.The specimens without the use of silver nitrate were considered as control. Fortensile strength, all specimens were subjected to force till fracture. For surfacehardness, the specimens were tested via a durometer hardness tester. Allspecimens data were analyzed via ANOVA and Tukey tests.Results: The addition of silver nitrate to acrylic resins reduced significantly thetensile strength. Statistically, highly significant differences were found among allgroups (P≤0.001). Also, the difference between control and experimental groupswas highly significant (P≤0.001). For surface hardness, the silver nitrate improvedthe surface hardness of acrylics. Highly significant differences were statisticallyobserved between control and 900 ppm group (P≤0.001); and among all groups(P≤0.001)with exception that no significant differences between control and150ppm; and between 150ppm and 900ppm groups(P>0.05).Conclusion: The addition of silver nitrate to acrylics reduced significantly the tensilestrength and improved slightly the surface hardness.

scholarly journals Goldmann Tonometry and Corneal Biomechanics

2021 ◽  
Vol 11 (9) ◽  
pp. 4025
Author(s):  
Dario Messenio ◽  
Marco Ferroni ◽  
Federica Boschetti
Keyword(s):  
Mechanical Properties ◽  
Anterior Chamber ◽  
Pressure Transducer ◽  
Pearson Correlation ◽  
Corneal Thickness ◽  
Applanation Tonometry ◽  
In Vitro Tests ◽  
Goldmann Tonometry ◽  
The Difference

Glaucoma is the second cause of irreversible blindness in the world. Intraocular pressure (IOP) is a recognized major risk factor for the development and progression of glaucomatous damage. Goldmann applanation tonometry (GAT) is internationally accepted as the gold standard for the measurement of IOP. The purpose of this study was to search for correlations between Goldmann tonometry and corneal mechanical properties and thickness by means of in vitro tests. IOP was measured by the Goldmann applanation tonometer (GIOP), and by a pressure transducer inserted in the anterior chamber of the eye (TIOP), at increasing pressure levels by addition of saline solution in the anterior chamber of enucleated pig eyes (n = 49). Mechanical properties were also determined by inflation tests. The GAT underestimated the real measurements made by the pressure transducer, with most common differences in the range 15–28 mmHg. The difference between the two instruments, highlighted by the Bland–Altman test, was confirmed by ANOVA, normality tests, and Mann–Whitney’s tests, both on the data arranged for infusions and for the data organized by pressure ranges. Pearson correlation tests revealed a negative correlation between (TIOP-GIOP) and both corneal stiffness and corneal thickness. In conclusion, data obtained showed a discrepancy between GIOP and TIOP more evident for softer and thinner corneas, that is very important for glaucoma detection.

scholarly journals Investigation of Color Reproduction on Linen Fabrics when Printing with Mimaki TX400-1800D Inkjet with Pigment TP250 Dyes

Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 354
Author(s):  
Tim Tofan ◽  
Rimantas Stonkus ◽  
Raimondas Jasevičius
Keyword(s):  
Mechanical Properties ◽  
Color Reproduction ◽  
Related Effect ◽  
Color Characteristics ◽  
Fabric Density ◽  
Different Types ◽  
The Difference ◽  
Printing Parameters ◽  
Linen Fabric

The aim of this research is to investigate related effect of dyeability to linen textiles related to different printing parameters. The study investigated the change in color characteristics when printing on linen fabrics with an inkjet MIMAKI Tx400-1800D printer with pigmented TP 250 inks. The dependence of color reproduction on linen fabrics on the number of print head passes, number of ink layers to be coated, linen fabric density, and different types of linen fabric was investigated. All this affects the quality of print and its mechanical properties. The change in color characteristics on different types of linen fabrics was determined experimentally. We determine at which print settings the most accurate color reproduction can be achieved on different linen fabrics. The difference between the highest and the lowest possible number of head passages was investigated. The possibilities of reproducing different linen fabric colors were determined.

scholarly journals The Mechanical Properties and Damage Evolution of UHPC Reinforced with Glass Fibers and High-Performance Polypropylene Fibers

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2455
Author(s):  
Jiayuan He ◽  
Weizhen Chen ◽  
Boshan Zhang ◽  
Jiangjiang Yu ◽  
Hang Liu
Keyword(s):  
Mechanical Properties ◽  
Glass Fiber ◽  
Damage Evolution ◽  
High Performance ◽  
High Performance Concrete ◽  
Glass Fibers ◽  
Ultra High Performance Concrete ◽  
Concrete Damaged Plasticity ◽  
The Difference ◽  
Experimental Values

Due to the sharp and corrosion-prone features of steel fibers, there is a demand for ultra-high-performance concrete (UHPC) reinforced with nonmetallic fibers. In this paper, glass fiber (GF) and the high-performance polypropylene (HPP) fiber were selected to prepare UHPC, and the effects of different fibers on the compressive, tensile and bending properties of UHPC were investigated, experimentally and numerically. Then, the damage evolution of UHPC was further studied numerically, adopting the concrete damaged plasticity (CDP) model. The difference between the simulation values and experimental values was within 5.0%, verifying the reliability of the numerical model. The results indicate that 2.0% fiber content in UHPC provides better mechanical properties. In addition, the glass fiber was more significant in strengthening the effect. Compared with HPP-UHPC, the compressive, tensile and flexural strength of GF-UHPC increased by about 20%, 30% and 40%, respectively. However, the flexural toughness indexes I5, I10 and I20 of HPP-UHPC were about 1.2, 2.0 and 3.8 times those of GF-UHPC, respectively, showing that the toughening effect of the HPP fiber is better.

Effect of toughened polyamide-coated carbon fiber fabric on the mechanical performance and fracture toughness of CFRP

2021 ◽  
pp. 002199832199945
Author(s):  
Jong H Eun ◽  
Bo K Choi ◽  
Sun M Sung ◽  
Min S Kim ◽  
Joon S Lee
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Photoelectron Spectroscopy ◽  
Mechanical Performance ◽  
Epoxy Composites ◽  
Scanning Calorimetry ◽  
Internal Damage ◽  
Impact Tests ◽  
Flexural Tests ◽  
The Impact

In this study, carbon/epoxy composites were manufactured by coating with a polyamide at different weight percentages (5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%) to improve their impact resistance and fracture toughness. The chemical reaction between the polyamide and epoxy resin were examined by fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray photoelectron spectroscopy. The mechanical properties and fracture toughness of the carbon/epoxy composites were analyzed. The mechanical properties of the carbon/epoxy composites, such as transverse flexural tests, longitudinal flexural tests, and impact tests, were investigated. After the impact tests, an ultrasonic C-scan was performed to reveal the internal damage area. The interlaminar fracture toughness of the carbon/epoxy composites was measured using a mode I test. The critical energy release rates were increased by 77% compared to the virgin carbon/epoxy composites. The surface morphology of the fractured surface was observed. The toughening mechanism of the carbon/epoxy composites was suggested based on the confirmed experimental data.

Transverse Young's Moduli and Cell Shapes in Coniferous Early Wood

Holzforschung ◽  
2002 ◽  
Vol 56 (1) ◽  
pp. 1-6 ◽  
Author(s):  
Ugai Watanabe ◽  
Minoru Fujita ◽  
Misato Norimoto
Keyword(s):  
Young’S Modulus ◽  
Young's Modulus ◽  
Bending Moment ◽  
Cell Models ◽  
Young’S Moduli ◽  
Cell Shapes ◽  
The Difference ◽  
Square Cells ◽  
Experimental Values ◽  
The Relationship

Summary The relationship between transverse Young's moduli and cell shapes in coniferous early wood was investigated using cell models constructed by two dimensional power spectrum analysis. The calculated values of tangential Young's modulus qualitatively explained the relationship between experimental values and density as well as the difference in experimental values among species. The calculated values of radial Young's modulus for the species having hexagonal cells agreed well with the experimental values, whereas, for the species having square cells, the calculated values were much larger than the experimental values. This result was ascribed to the fact that the bending moment on the radial cell wall of square cell models was calculated to be small. It is suggested that the asymmetrical shape of real wood cells or the behavior of nodes during ell deformation is an important factor in the mechanism of linear elastic deformation of wood cells.

Comparison of As-Cast Microstructures and Mechanical Properties for Mg-Ce-Mn-Sc and Mg-Ce-Mn-Zn Magnesium Alloys

2009 ◽  
Vol 610-613 ◽  
pp. 746-749 ◽  
Author(s):  
Jia Shen ◽  
Ming Bo Yang ◽  
Fu Sheng Pan ◽  
Ren Ju Cheng
Keyword(s):  
Mechanical Properties ◽  
Magnesium Alloys ◽  
Creep Properties ◽  
Microstructures And Mechanical Properties ◽  
The Difference ◽  
Cast Microstructure

The as-cast microstructures and mechanical properties of Mg-3Ce-1.2Mn-0.9Sc and Mg-3Ce-1.2Mn-1Zn magnesium alloys were investigated and compared. The results indicate that the as-cast microstructure of Mg-3Ce-1.2Mn-0.9Sc alloy was mainly composed of -Mg, Mg12Ce and Mn2Sc phases, and that the as-cast microstructure of Mg-3Ce-1.2Mn-1Zn alloy was mainly composed of -Mg, Mg12Ce and MgZn phases. In addition, the as-cast tensile and creep properties of Mg-3Ce-1.2Mn-0.9Sc alloy were higher than that of the Mg-3Ce-1.2Mn-1Zn alloy. The difference of the two alloys in as-cast tensile and creep properties may be related to the initial microstructures of the two alloys.

Measurements of Residual Stress in the Layers of Thin Film Micro-Gas Sensors

2000 ◽  
Vol 657 ◽  
Author(s):  
Youngman Kim ◽  
Sung-Ho Choo
Keyword(s):  
Thin Film ◽  
Mechanical Properties ◽  
Residual Stress ◽  
Gas Sensor ◽  
Gas Sensors ◽  
Micro Gas Sensor ◽  
Thin Film Layer ◽  
Film Layer ◽  
The Difference ◽  
Stress States

ABSTRACTThe mechanical properties of thin film materials are known to be different from those of bulk materials, which are generally overlooked in practice. The difference in mechanical properties can be misleading in the estimation of residual stress states in micro-gas sensors with multi-layer structures during manufacturing and in service.In this study the residual stress of each film layer in a micro-gas sensor was measured according to the five difference sets of film stacking structure used for the sensor. The Pt thin film layer was found to have the highest tensile residual stress, which may affect the reliability of the micro-gas sensor. For the Pt layer the changes in residual stress were measured as a function of processing variables and thermal cycling.

Mechanical Properties of Epoxy Adhesive Under Thermal Aging and Their Chemical Degradation Behavior

2021 ◽  
Vol 21 (8) ◽  
pp. 4444-4449
Author(s):  
Bongjin Chung ◽  
Shin Sungchul ◽  
Jaeho Shim ◽  
Seongwoo Ryu
Keyword(s):  
Mechanical Properties ◽  
Thermal Aging ◽  
Photoelectron Spectroscopy ◽  
Thermal Exposure ◽  
Chain Scission ◽  
Epoxy Adhesive ◽  
Chemical Degradation ◽  
Adhesive Properties ◽  
Noticeable Reduction

Epoxy adhesive was analyzed under long term thermal aging and mechanical properties and chemical degradation were observed by X-ray photoelectron spectroscopy (XPS). Long term thermal exposure of epoxy causes a noticeable reduction in adhesive properties. We developed a predictive model of temperature and time dependent aging. The temperature dependent aging behavior of epoxy adhesive shows good agreement with conventional Arrhenius equations. Using XPS analysis, we also discovered a correlation between chemical degradation and the adhesive properties. Decay of C–C bonding ratio induced chain-scission of epoxy adhesive; increase of total numbers of C–O and C═O induced oxidation of epoxy adhesive during thermal exposure.

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