scholarly journals Structural, Spectroscopic, Thermal, and Magnetic Properties of a New Dinuclear Copper Coordination Compound with Tiglic Acid

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2148
Author(s):  
Marcin Świątkowski ◽  
Suneel Lanka ◽  
Agnieszka Czylkowska ◽  
Katarzyna Gas ◽  
Maciej Sawicki
Keyword(s):  
Magnetic Properties ◽  
Coordination Compound ◽  
Copper Ions ◽  
Water Solution ◽  
Antiferromagnetic Coupling ◽  
Diffraction Measurement ◽  
X Ray Diffraction ◽  
Tiglic Acid ◽  
Hirshfeld Analysis ◽  
Coordination System

The first coordination compound of copper and tiglic acid named tetrakis(μ-tiglato)bis(tiglic acid)dicopper(II) was synthesized and crystallized from water solution. Its structure was determined and analyzed based on X-ray diffraction measurement. The paddle-wheel coordination system of the investigated compound was compared with other similar copper structures known in the literature. The Hirshfeld analysis was used for the detailed analysis of intermolecular interaction. The new compound was also characterized in terms of infrared absorption, thermal, and magnetic properties. The antiferromagnetic coupling of copper ions was found.

Synthesis, structure, and magnetic properties of diphenylphosphinates of cobalt(II) and manganese(II). The crystal and molecular structures of the γ forms of poly-bis(μ-diphenylphosphinato)cobalt(II) and manganese(II)

1991 ◽  
Vol 69 (2) ◽  
pp. 277-285 ◽  
Author(s):  
Jing-Long Du ◽  
Steven J. Rettig ◽  
Robert C. Thompson ◽  
James Trotter
Keyword(s):  
Magnetic Properties ◽  
Heavy Atom ◽  
Molecular Structures ◽  
Antiferromagnetic Coupling ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Lattice Constants ◽  
Linear Chains

The synthesis of the β and γ forms of M(Ph2PO2)2 where M = Co and Mn are described and the compounds are characterized by infrared spectroscopy, differential scanning calorimetry, X-ray powder diffraction, and low-temperature (2–80 K) magnetic susceptibility studies. Single crystal X-ray diffraction studies are reported on the γ forms. Crystals of the γ forms of poly-bis(μ-diphenylphosphinato)cobalt(II) and poly-bis(μ-diphenylphosphinato)manganese(II) are isomorphous, crystallizing with 4 formula units per unit-cell in the monoclinic space group P21/c. Lattice constants are a = 8.080(2), 8.161(1), b = 23.550(6), 23.751(1), c = 11.726(3), 11.6946(6) Ǻ, and β = 92.88(2), 93.026(8)° for the Co and Mn derivatives respectively. The structures were solved by heavy atom methods and were refined by full-matrix least-squares procedures to R = 0.039 and 0.045 for 4041 and 2878 reflections with I ≥ 3σ(I), respectively. Both crystal structures consist of double phosphinate-bridged chain polymers containing tetrahedrally coordinated metal atoms: Co—O = 1.950(2)–1.963(2) Ǻ, O—Co—O = 104.81(8)–117.77(9)°, Mn—O = 2.016(3)–2.033(3) Ǻ, O—Mn—O = 103.2(1)–114.7(1)°. All four compounds exhibit antiferromagnetic coupling and magnetic susceptibilities have been analyzed according to two Heisenberg models for linear chains of metal ions with S = 3/2 for cobalt and S = 5/2 for manganese. The Weng model (with values for the Wagner and Friedberg model in parentheses) gives –J = 0.25 (0.26) cm−1 and 0.55 (0.60) cm−1 for the β and γ forms, respectively, of Co(Ph2PO2)2, and 0.34 (0.36) cm−1 and 0.17 (0.17) cm−1 for the β and γ forms, respectively, of Mn(Ph2PO2)2. Key words: crystal structure, diphenylphosphinates of cobalt(II) and manganese(II), magnetic properties.

scholarly journals Effect Of Co3+ Substitution on Electro-Magnetic Properties of Pr¬0.75¬Na¬0.25¬mno¬3 ¬and Nd¬0.75¬Na¬0.25¬mno¬3¬ Manganites

2018 ◽  
Vol 7 (4.30) ◽  
pp. 389
Author(s):  
Nurhabibah Nabilah Ab Mannan ◽  
Sufia Aqilah Razali ◽  
Suhadir Shamsuddin ◽  
Mohamad Zaky Noh ◽  
Zakiah Mohamed
Keyword(s):  
Magnetic Properties ◽  
Electrical Transport ◽  
Resistivity Measurement ◽  
Charge Order ◽  
Solid State Reaction Method ◽  
Diffraction Measurement ◽  
Ferromagnetic Transition ◽  
Antiferromagnetic Transition ◽  
X Ray Diffraction ◽  
Electro Magnetic

This paper reports influences of cobalt (Co) substituted at Mn-site of Pr­0.75­Na­0.25Mn1-xCo­x­O­3 and Nd0.75Na0.25Mn1-yCoyO3 on structure, electrical transport and magnetic properties. All of the samples were prepared via standard solid state reaction method. X-ray diffraction measurement indicates that all samples were crystallized in an orthorhombic structure (space group Pnma). Resistivity measurement displays the x = 0 sample manifests an insulator behavior while metal-insulator transition was found at 108 K and 84 K for x = 0.02 and 0.05 respectively for Pr­0.75­Na­0.25Mn1-xCo­x­O­3. On the other hand, all of the samples for Nd0.75Na0.25Mn1-yCoyO3 showed insulator behavior down to low temperature and analysis of the resistivity change with respect to temperature, dlnρ/dT-1 versus T reveals a slope changes of resistivity have been recorded. Two obvious peaks were recorded from the analysis for y = 0.02 and 0.05 which can be suggested to the existence of charge order transition at the vicinity. For magnetic properties, x = 0 sample showed a paramagnetic-antiferromagnetic transition and further substitution of Co, x = 0.02 and 0.05, induce the paramagnetic-ferromagnetic transition and antiferromagnetic arrangement respectively. Meanwhile, further substitution of Co, y = 0.02 and 0.05 indicate antiferromagnetic transition with increasing T­N­­­ as Co increased.

A three-dimensional cyanide-bridged heterometallic coordination polymer: poly[[diacetonitrilediaqua[μ2-3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine-κ4N1,N6:N3,N4]tetra-μ-cyanido-tetracyanidodimanganese(II)molybdate(IV)] dihydrate]

2014 ◽  
Vol 70 (11) ◽  
pp. 1029-1032 ◽  
Author(s):  
Xiao-Juan Xu
Keyword(s):  
Magnetic Properties ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Elemental Analysis ◽  
Room Temperature ◽  
Three Dimensional ◽  
Antiferromagnetic Coupling ◽  
X Ray Diffraction ◽  
X Ray ◽  
Magnetic Investigation

A metal coordination polymer, {[Mn2Mo(CN)8(C12H8N6)(CH3CN)2(H2O)2]·2H2O}n, has been synthesized by the reaction of Mn(ClO4)2·6H2O with 3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine (bptz) and (Bu3N)3[Mo(CN)8] at room temperature. The polymer was characterized by IR spectroscopy, elemental analysis and X-ray diffraction, and the magnetic properties were also investigated. The X-ray diffraction analysis reveals that the compound is a new three-dimensional coordination polymer with a PtS-type network. Magnetic investigation shows antiferromagnetic coupling between adjacent Mn2+cations.

scholarly journals Synthesis, structure and magnetic properties of tetrakis-μ-carboxylato-bis(dodecylnicotinato)dicopper(II) complexes; crystal and molecular structure of the decyl carboxylate derivative

2000 ◽  
Vol 56 (4) ◽  
pp. 666-672 ◽  
Author(s):  
Marcia Rusjan ◽  
Zulema Chaia ◽  
Oscar E. Piro ◽  
Daniel Guillon ◽  
Fabio D. Cukiernik
Keyword(s):  
Molecular Structure ◽  
Magnetic Properties ◽  
Copper Ions ◽  
Lone Pair ◽  
Magnetic Behavior ◽  
Coupling Constant ◽  
X Ray Diffraction ◽  
Carboxylate Groups ◽  
Lamellar Phases ◽  
Oxygen Lone Pair

Dodecylnicotinate bis-adducts of binuclear copper carboxylates, of the general formula Cu2(O2CC n − 1H2n − 1)4(C5H4NCOOC12H25)2, were synthesized for n = 10, 12, 14, 16, 18 and 20, and their crystal structure, thermal behavior and magnetic properties studied. The molecular structure of the decyl derivative has been determined from single-crystal X-ray diffraction data. The dimer is centrosymmetric with the CuII ions in a square-pyramidal coordination with four O-alkyl O atoms [average d(Cu—O) 1.960 (6) Å] in the basal plane and the nicotine N atom at apical positions [d(Cu—N) 2.183 (3)  Å]. The copper ions, 2.615 (1) Å apart, are bridged by four O-alkyl carboxylate groups. Both the n = 20 and n  =  18 homologues exhibit lamellar phases, which can be related to the supramolecular arrangement found in the n = 10 derivative. The magnetic behavior of the decyl and octadecyl dimers was studied in the 2–300 K temperature range. They exhibit a strong intramolecular antiferromagnetic interaction (Cu–Cu superexchange coupling constant J  = −347 cm−1 for the decyl derivative), which can be attributed to a large overlap of the metal 3d orbitals and the oxygen lone pair orbitals of the linking carboxylate groups.

Magnetic Properties of CdMoO4:Dy3+ Single Crystal

2016 ◽  
Vol 257 ◽  
pp. 107-110 ◽  
Author(s):  
Tadeusz Groń ◽  
Elzbieta Tomaszewicz ◽  
Marek Berkowski ◽  
Monika Oboz ◽  
Joachim Kusz ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Single Crystal ◽  
Diffraction Measurement ◽  
X Ray Diffraction ◽  
Weak Response ◽  
X Ray ◽  
Diamagnetic Transition ◽  
The Magnetic Field

X-ray diffraction measurement at 298 K of CdMoO4:Dy3+ showed that the molybdenum ions are tetrahedral coordinated and Cd/Dy – dodecahedral coordinated. The Dy3+ ions are randomly distributed in the unit cell, substituting the Cd2+ ones. The temperature dependence of ac and dc magnetic susceptibility showed a lack of the Curie-Weiss behaviour and a weak response to the magnetic field. The magnetization isotherms, M(H), showed a paramagnetic-diamagnetic transition at 17 K for 〈100〉 direction and at 35 K for 〈001〉 one in the magnetic field of 70 kOe. As the temperature increased this transition was moving toward smaller magnetic fields.

scholarly journals A New FeIII Substituted Arsenotungstate [FeIII2(AsIIIW6O23)2(AsIIIO3H)2]12−: Synthesis, Structure, Characterization and Magnetic Properties

2020 ◽  
Vol 6 (4) ◽  
pp. 54
Author(s):  
Masooma Ibrahim ◽  
Yan Peng ◽  
Christopher E. Anson
Keyword(s):  
Magnetic Properties ◽  
Fourier Transform ◽  
Structure Characterization ◽  
Basic Medium ◽  
Antiferromagnetic Coupling ◽  
X Ray Diffraction ◽  
One Pot ◽  
X Ray ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

The iron(III)-containing arsenotungstate [FeIII2(AsIIIW6O23)2(AsIIIO3H)2]12− (1) was prepared via a simple, one-pot reaction in aqueous basic medium. The compound was isolated as its sodium salt, and structurally-characterized by Single Crystal X-ray Diffraction (SCXRD), Powder X-ray Diffraction (PXRD), Fourier-Transform Infrared (FT-IR) spectroscopy, Thermogravimetric Analysis (TGA) and elemental analysis. Its magnetic properties are reported; the antiferromagnetic coupling between the two FeIII centers is unusually weak as a result of the bridging geometry imposed by the rigid arsenotungstate metalloligands.

Synthesis, crystal structure and magnetic characterization of a cyanide-bridged Mo–Ni nanosized molecular wheel

2015 ◽  
Vol 70 (8) ◽  
pp. 527-531 ◽  
Author(s):  
Daopeng Zhang ◽  
Lingqian Kong ◽  
Hongyan Zhang ◽  
Ping Wang
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Ir Spectroscopy ◽  
Structure Determination ◽  
Building Blocks ◽  
Antiferromagnetic Coupling ◽  
X Ray Diffraction ◽  
Magnetic Characterization ◽  
X Ray

AbstractBy using K4[Mo(CN)8] and [Ni(L)(H2O)2][ClO4]2 as reagents (L = 2,12-dimethyl-3,7,11,17-tetraazabicyclo [11.3.1]heptadeca-1(17),13,15-triene), a new cyanide-bridged Mo–Ni complex containing the building blocks [Ni(H2O)(L)]2+ and [Ni(L)]2+ bridged by [Mo(CN)8]4− units has been obtained. The complex with the formula {[Ni(H2O)(L)][Ni(L)][Mo(CN)8]}6 · 36H2O · 2CH3OH (1) was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The structure determination reveals an octadecanuclear cluster in the form of a 36-membered macrocycle, in which the largest intramolecular W···W and Ni···Ni distances are 16.5 and 14.4 Å, respectively, indicating that complex 1 is a nanosized molecular wheel. Investigation of its magnetic properties has shown weak antiferromagnetic coupling between the adjacent Ni(II) ions bridged by the diamagnetic [Mo(CN)8]4− ions.

Structural and Magnetic Hysteresis Properties of Co-Zr Substituted Hexagonal Barium Ferrites

2015 ◽  
Vol 7 (1) ◽  
pp. 1346-1351
Author(s):  
Ch.Gopal Reddy ◽  
Ch. Venkateshwarlu ◽  
P. Vijaya Bhasker Reddy
Keyword(s):  
Magnetic Properties ◽  
Single Phase ◽  
Magnetic Hysteresis ◽  
Grain Morphology ◽  
Hexagonal Structure ◽  
Ion Composition ◽  
X Ray Diffraction ◽  
Ceramic Method ◽  
Barium Ferrites ◽  
Xrd Patterns

Co-Zr substituted M-type hexagonal barium ferrites, with chemical formula BaCoxZrxFe12-2xO19 (where x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0), have been synthesized by double sintering ceramic method. The crystallographic properties, grain morphology and magnetic properties of these ferrites have been investigated by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Vibrating Sample Magnetometer (VSM). The XRD patterns confirm the single phase with hexagonal structure of prepared ferrites. The magnetic properties have been investigated as a function of Co and Zr ion composition at an applied field in the range of 20 KOe. These studies indicate that the saturation magnetization (Ms) in the samples increases initially up to the Co-Zr composition of x=0.6 and decreases thereafter. On the other hand, the coercivity (Hc) and Remanent magnetization (Mr) are found to decrease continuously with increasing Co-Zr content. This property is most useful in permanent magnetic recording. The observed results are explained on the basis of site occupation of Co and Zr ions in the samples.

Transformation of Structure, Magnetic Properties and Microwave Absorption Capability in Nd-Doped Strontium Hexaferrite

2020 ◽  
Vol 855 ◽  
pp. 255-260
Author(s):  
Mukhtar Effendi ◽  
Efi Solihah ◽  
Candra Kurniawan ◽  
Wahyu Tri Cahyanto ◽  
Wahyu Widanarto
Keyword(s):  
Magnetic Properties ◽  
Microwave Absorption ◽  
Solid State Reaction Method ◽  
Strontium Hexaferrite ◽  
Basic Material ◽  
X Ray Diffraction ◽  
Cell Parameters ◽  
Tetragonal Crystal ◽  
Capability Analysis ◽  
Natural Iron

The synthesize of Nd3+-strontium hexaferrite magnetic material by the solid-state reaction method has been successfully carried out. This study aims to determine the effect of Nd3+ on the structure, magnetic properties, and microwave absorption capability of the material. Preparation of (1-x)SrO:xNd2O3:6Fe2O3 where x = 0, 10, 20, and 30 mol% using basic material in the form of SrCO3 powder, Nd2O3 powder and Fe3O4 from natural iron sand. The characterization includes the X-Ray Diffraction (XRD) examination to determine the crystal structure, the Scanning Electron Microscope (SEM) for exploring the surface morphology, Vibrating Sample Magnetometer (VSM) for the magnetic properties investigation of material, and Vector Network Analyzer (VNA) for microwave absorption capability analysis. The XRD results show that the addition of Nd3+ doping increases the number of SrNdFeO4 phases. The phase has a tetragonal crystal system that has cell parameters a = b = 3.846 Å, and c = 12.594 Å. The magnetic properties of the material showed that the addition of Nd3+ decreased the saturation and remanence magnetization values, whereas the value of the coercivity field increased. Meanwhile, the best microwave absorption occurs in samples with the addition of Nd3+ as much as 0.3 mol, which results in a reflection loss value of -18.9 dB with a frequency bandwidth of 3.9 GHz.

scholarly journals Complex magnetic properties associated with competing local and itinerant magnetism in $${\text {Pr}}_2 {\text {Co}}_{0.86} {\text {Si}}_{2.88}$$

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mily Kundu ◽  
Santanu Pakhira ◽  
Renu Choudhary ◽  
Durga Paudyal ◽  
N. Lakshminarasimhan ◽  
...  
Keyword(s):  
Heat Capacity ◽  
Neutron Diffraction ◽  
Single Phase ◽  
Magnetic Transition ◽  
Muon Spin Rotation ◽  
Antiferromagnetic Coupling ◽  
Diffraction Measurement ◽  
Zero Field ◽  
Crystalline Electric Field ◽  
X Ray

AbstractTernary intermetallic compound $${\text {Pr}}_2 {\text {Co}}_{0.86} {\text {Si}}_{2.88}$$ Pr 2 Co 0.86 Si 2.88 has been synthesized in single phase and characterized by x-ray diffraction, scanning electron microscopy with energy dispersive x-ray spectroscopy (SEM-EDX) analysis, magnetization, heat capacity, neutron diffraction and muon spin rotation/relaxation ($$\mu$$ μ SR) measurements. The polycrystalline compound was synthesized in single phase by introducing necessary vacancies in Co/Si sites. Magnetic, heat capacity, and zero-field neutron diffraction studies reveal that the system undergoes magnetic transition below $$\sim$$ ∼ 4 K. Neutron diffraction measurement further reveals that the magnetic ordering is antiferromagnetic in nature with an weak ordered moment. The high temperature magnetic phase has been attributed to glassy in nature consisting of ferromagnetic clusters of itinerant (3d) Co moments as evident by the development of internal field in zero-field $$\mu$$ μ SR below 50 K. The density-functional theory (DFT) calculations suggest that the low temperature magnetic transition is associated with antiferromagnetic coupling between Pr 4f and Co 3d spins. Pr moments show spin fluctuation along with unconventional orbital moment quenching due to crystal field. The evolution of the symmetry and the crystalline electric field environment of Pr-ions are also studied and compared theoretically between the elemental Pr and when it is coupled with other elements such as Co. The localized moment of Pr 4f and itinerant moment of Co 3d compete with each other below $$\sim$$ ∼ 20 K resulting in an unusual temperature dependence of magnetic coercivity in the system.

Sign in / Sign up

Export Citation Format

Share Document