scholarly journals The Influence of Silica Nanoparticles on the Thermal and Mechanical Properties of Crosslinked Hybrid Composites

Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7431
Author(s):  
Tomasz Klepka ◽  
Beata Podkościelna ◽  
Dariusz Czerwiński ◽  
Bronisław Samujło
Keyword(s):  
Mechanical Properties ◽  
Silica Nanoparticles ◽  
Hybrid Composites ◽  
Physicochemical Characterization ◽  
Weight Ratio ◽  
Polymeric Materials ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Thermal Stabilities ◽  
Constant Weight

This paper presents the synthesis and physicochemical characterization of a new hybrid composite. Its main goals are evaluating the structure and studying the thermal and mechanical properties of the crosslinked polymeric materials based on varying chemical properties of the compounds. As an organic crosslinking monomer, bisphenol A glycerolate diacrylate (BPA.GDA) was used. Trimethoxyvinylsilane (TMVS) and N-vinyl-2-pyrrolidone (NVP) were used as comonomers and active diluents. The inorganic fraction was the silica in the form of nanoparticles (NANOSiO2). The hybrid composites were obtained by the bulk polymerization method using the UV initiator Irqacure 651 with a constant weight ratio of the tetrafunctional monomer BPA.GDA to TMVS or NVP (7:3 wt.%) and different wt.% of silica nanoparticles (0, 1, 3%). The proper course of polymerization was confirmed by the ATR/FTIR spectroscopy and SEM EDAX analysis. In the composites spectra the signals correspond to the C=O groups from NVP at 1672–1675 cm−1, and the vibrations of Si–O–C and Si–O–Si groups at 1053–1100 cm−1 from TMVS and NANOSiO2 are visible. Thermal stabilities of the obtained composites were studied by a differential scanning calorimetry DSC. Compared to NVP the samples with TMVS degraded in one stage (422.6–425.3 °C). The NVP-derived materials decomposed in three stages (three endothermic effects on the DSC curves). The addition of NANOSiO2 increases the temperature of composites maximum degradation insignificantly. Additionally, the Shore D hardness test was carried out with original metrological measurements of changes in diameter after indentation in relation to the type of material. The accuracy analysis of the obtained test results was based on a comparative analysis of graphical curves obtained from experimental tests. The values of the changes course of similarity in the examined factors, represented by those of characteristic coefficients were determined based on the Fréchet’s theory.

Thermal and Mechanical Properties of Epoxy Resin Functionalized Copper and Graphene Hybrids using In-situ Polymerization Method

2020 ◽  
Vol 16 ◽  
Author(s):  
Nadia A. Ali ◽  
Alaa M. Abd-Elnaiem ◽  
Seenaa I. Hussein ◽  
Asmaa Sh. Khalil ◽  
Hatem R. Alamri ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Wear Resistance ◽  
Epoxy Resin ◽  
Hybrid Composite ◽  
Hybrid Composites ◽  
Weight Ratio ◽  
Epoxy Composites ◽  
Thermal And Mechanical Properties ◽  
Maximum Hardness

Objective: In this work, graphene (Gr) or/and Cu particles are used to improve the thermal and mechanical properties of epoxy resin. Methods: Various contents of Gr powder (0.1, 0.3, and 0.5 wt%), Cu powder (10, 30, and 50 wt%) were loaded to epoxy to form Gr/epoxy and Cu/epoxy composites, respectively. In addition, hybrids epoxy/Cu/Gr samples were prepared with a selection of lowest (0.1 and 10) and highest (0.5 and 50) ratios of Gr, and Cu, respectively. Results: The thermal conductivity increases with the increasing weight ratio of Gr and Cu as compared to the pure epoxy. The Thermogravimetric analysis (TGA) of epoxy composites and hybrid composites reveals an improvement in the thermal stability. In addition, the mechanical properties such as hardness shore D and the wear resistance are enhanced for both the epoxy composites and hybrids composites. However, the Ep+0.5wt%Gr+50wt%Cu hybrid composite has the maximum hardness 84, thermal conductivity of 3.84 W/m.K, it shows the lowest wear resistance 2.7×10-6 mm3/Nm at loading 10 N. Conclusion: The hybrid composite containing 0.5wt%Gr and 50wt%Cu shows the maximum hardness and thermal conductivity, as well as the lowest wear resistance when compared to other composites. The physical properties of the hybrid composite can be controlled by the host blend, and hence the morphology, and interfacial characteristics.

scholarly journals The research of the thermal and mechanical properties of materials produced by 3D printing method

2019 ◽  
Vol 23 (Suppl. 4) ◽  
pp. 1211-1216
Author(s):  
Adam Gnatowski ◽  
Agnieszka Kijo-Kleczkowska ◽  
Henryk Otwinowski ◽  
Piotr Sikora
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
3D Printing ◽  
Thermoplastic Polyurethane ◽  
Polymeric Materials ◽  
Poly Lactic Acid ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Properties Of Materials ◽  
Butadiene Styrene

A comparative analysis of thermal properties of semi-crystalline and amorphous polymeric materials was carried out. Samples were produced using 3D printing technology on the SIGNAL-ATMAT printer. The following polymeric materials were used to make the samples: thermoplastic polyurethane elastomer, acryloni-trile-butadiene-styrene copolymer, Laywood, ethylene terephthalate, poly (lactic acid). The materials were tested for their thermal and mechanical properties. The research included the analysis of thermal properties by differential scanning calorimetry of manufactured materials. The tensile strength also was determined.

Effect of silica nanoparticles on mechanical properties of Kevlar/epoxy hybrid composites

2018 ◽  
Vol 110 (4) ◽  
pp. 606-613 ◽  
Author(s):  
Madeha Jabbar ◽  
Mehmet Karahan ◽  
Yasir Nawab ◽  
Munir Ashraf ◽  
Tanveer Hussain
Keyword(s):  
Mechanical Properties ◽  
Silica Nanoparticles ◽  
Hybrid Composites

Effects of walnut shell powders on the morphology and the thermal and mechanical properties of poly(lactic acid)

2019 ◽  
Vol 33 (10) ◽  
pp. 1383-1395
Author(s):  
Hongjuan Zheng ◽  
Zhengqian Sun ◽  
Hongjuan Zhang
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Property Testing ◽  
Walnut Shell ◽  
Poly Lactic Acid ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Elongation At Break ◽  
Heat Distortion Temperature ◽  
Testing Techniques

Poly(lactic acid) (PLA) has good environmental compatibility, however, its high brittleness, slow rate of crystallization, and low heat distortion temperature restrict its widespread use. To overcome these limitations, in this study, PLA was mixed with walnut shell (WS) powders. The effects of WS powders on the morphology and the thermal and mechanical properties of PLA were investigated. The products were characterized by differential scanning calorimetry (DSC), infrared (IR) spectroscopy, polarizing optical microscopy (POM), and various mechanical property testing techniques. The results showed that WS powders had a significant effect on the morphology and the thermal and mechanical properties of PLA. The tensile strength, impact strength, and elongation at break of the PLA/WS composites first increased and then decreased with the increasing addition of WS powders. When the addition of WS powders was about 0.5 wt%, they reached maximum values of 51.2 MPa, 23.3 MPa, and 19.0%, respectively. Compared with neat PLA, the spherulite grain size of the composites could be reduced and many irregular polygons were formed during crystallization. The melting, cold crystallization, and glass-transition temperatures of the composites were lower than those of neat PLA.

Weldability of pipe grade polyethylenes as realized from thermal and mechanical properties assessments

2016 ◽  
Vol 36 (8) ◽  
pp. 853-860 ◽  
Author(s):  
Vahabodin Goodarzi ◽  
Zahed Ahmadi ◽  
Mohammad Reza Saeb ◽  
Farkhondeh Hemmati ◽  
Mehdi Ghaffari ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Analysis ◽  
Molecular Weight ◽  
Aging Process ◽  
Pipe Production ◽  
Lamellar Thickness ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Injection Molded ◽  
The One

Abstract Since polyethylene (PE) has been widely accepted for the production of high-pressure fluid conveying pipelines, studies devoted to weldability of PE connections were always of major importance. In this study, two industrial PE grades designed for pipe production, namely PE80 and PE100, were injection molded, cut, and then welded as PE100-PE100, PE100-PE80, and PE80-PE80. The heat-welded joints were assessed by differential scanning calorimetry and tensile measurements. The results obtained from thermal and mechanical analyses were compared with equivalents for aged samples. Thermal analysis revealed that the melting point of the PE100-PE100 sample is obviously larger than the one for the PE80-PE80 joint, for the PE80 chains deteriorate the crystallization of PE100. Further, the PE80-PE80 sample showed the lowest lamellar thickness and crystalline molecular weight among the studied joints. The aging process was found to increase lamellar thickness and molecular weight, though in the PE100-PE100 sample such quantities very limitedly increased. The yield stress of aged joints was higher than that for just-prepared samples, while an inverse trend was seen for strain at break. From a practical viewpoint, the PE100-PE100 welds offer better properties.

Mechanical and Morphological Properties of Sisal/Glass Fiber-Polypropylene Composites

2008 ◽  
Vol 47-50 ◽  
pp. 486-489 ◽  
Author(s):  
Kasama Jarukumjorn ◽  
Nitinat Suppakarn ◽  
Jongrak Kluengsamrong
Keyword(s):  
Mechanical Properties ◽  
Glass Fiber ◽  
Natural Fiber ◽  
Hybrid Composites ◽  
Weight Ratio ◽  
Morphological Properties ◽  
Fiber Reinforced ◽  
Polypropylene Composites ◽  
Specific Strength ◽  
Fiber Reinforced Polymer Composites

Natural fiber reinforced polymer composites became more attractive due to their light weight, high specific strength, biodegradability. However, some limitations e.g. low modulus, poor moisture resistance were reported. The mechanical properties of natural fiber reinforced composites can be improved by hybridization with synthetic fibers such as glass fiber. In this research, mechanical properties of short sisal-PP composites and short sisal/glass fiber hybrid composites were studied. Polypropylene grafted with maleic anhydride (PP-g-MA) was used as a compatibilizer to enhance the compatibility between the fibers and polypropylene. Effect of weight ratio of sisal and glass fiber at 30 % by weight on the mechanical properties of the composites was investigated. Morphology of fracture surface of each composite was also observed.

scholarly journals Effect of Diatomaceous Biosilica and Talc on the Properties of Dielectric Elastomer Based Composites

Energies ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5828
Author(s):  
Ewa Olewnik-Kruszkowska ◽  
Weronika Brzozowska ◽  
Arkadiusz Adamczyk ◽  
Magdalena Gierszewska ◽  
Izabela Wojtczak ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dielectric Constant ◽  
Dielectric Properties ◽  
Environmentally Friendly ◽  
Polymeric Materials ◽  
Dielectric Elastomer ◽  
Thermal And Mechanical Properties ◽  
Valuable Source ◽  
Natural Fillers

Currently, scientists are still looking for new polymeric materials characterized by improved mechanical, thermal as well as dielectric properties. Moreover, it should be stressed that new composites should be environmentally friendly. For this reason, the aim of this work is to establish the influence of natural fillers in the form of diatomaceous biosilica (B) and talc (T) on the properties of dielectric elastomer (DE)-based composites. The dielectric elastomer-based materials have been tested taking into account their morphology, thermal and mechanical properties. Moreover, the dielectric constant of the obtained materials was evaluated. Obtained results revealed that the presence of both diatomaceous biosilica and talc significantly increases dielectric properties while having no significant effect on the mechanical properties of the obtained composites. It should be stressed that the performed analyses constitute a valuable source of knowledge on the effective modification of the thermal and dielectric properties of newly obtained materials.

scholarly journals Morpho-Structural, Thermal and Mechanical Properties of PLA/PHB/Cellulose Biodegradable Nanocomposites Obtained by Compression Molding, Extrusion, and 3D Printing

Nanomaterials ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 51 ◽  
Author(s):  
Adriana Nicoleta Frone ◽  
Dan Batalu ◽  
Ioana Chiulan ◽  
Madalina Oprea ◽  
Augusta Raluca Gabor ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Interfacial Adhesion ◽  
Compression Molding ◽  
Processing Technique ◽  
Single Step ◽  
Thermal And Mechanical Properties ◽  
Reactive Blending ◽  
Scanning Calorimetry ◽  
The Impact

Biodegradable blends and nanocomposites were produced from polylactic acid (PLA), poly(3-hydroxybutyrate) (PHB) and cellulose nanocrystals (NC) by a single step reactive blending process using dicumyl peroxide (DCP) as a cross-linking agent. With the aim of gaining more insight into the impact of processing methods upon the morphological, thermal and mechanical properties of these nanocomposites, three different processing techniques were employed: compression molding, extrusion, and 3D printing. The addition of DCP improved interfacial adhesion and the dispersion of NC in nanocomposites as observed by scanning electron microscopy and atomic force microscopy. The carbonyl index calculated from Fourier transform infrared spectroscopy showed increased crystallinity after DCP addition in PLA/PHB and PLA/PHB/NC, also confirmed by differential scanning calorimetry analyses. NC and DCP showed nucleating activity and favored the crystallization of PLA, increasing its crystallinity from 16% in PLA/PHB to 38% in DCP crosslinked blend and to 43% in crosslinked PLA/PHB/NC nanocomposite. The addition of DCP also influenced the melting-recrystallization processes due to the generation of lower molecular weight products with increased mobility. The thermo-mechanical characterization of uncross-linked and cross-linked PLA/PHB blends and nanocomposites showed the influence of the processing technique. Higher storage modulus values were obtained for filaments obtained by extrusion and 3D printed meshes compared to compression molded films. Similarly, the thermogravimetric analysis showed an increase of the onset degradation temperature, even with more than 10 °C for PLA/PHB blends and nanocomposites after extrusion and 3D-printing, compared with compression molding. This study shows that PLA/PHB products with enhanced interfacial adhesion, improved thermal stability, and mechanical properties can be obtained by the right choice of the processing method and conditions using NC and DCP for balancing the properties.

Thermal and Mechanical Properties of Cyclized Polybutadiene Dielectrics

1986 ◽  
Vol 76 ◽  
Author(s):  
C. W. Wilkins ◽  
H. E. Bair ◽  
M. G. Chan ◽  
R. S. Hutton
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Physical And Mechanical Properties ◽  
Mechanical Analysis ◽  
Infrared Analysis ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
The Difference ◽  
Thermal Mechanical Analysis ◽  
Lower Glass Transition Temperature

ABSTRACTWe have studied some of the physical and mechanical properties of cyclized polybutadiene (CBR) dielectrics by dynamic mechanical analysis, thermal mechanical analysis, thermogravimetry, infrared analysis, and differential scanning calorimetry. Of interest is the difference in properties between thin (<30 μm) films which have been cured under vacuum and those which have been cured in air. Our results indicate that curing under vacuum prevents oxidation and reduces crosslinking. Vacuum cured films have 20% smaller moduli and 200 lower glass transition temperature than do films produced in air.

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