scholarly journals Ta/Ti/Ni/Ceramic Multilayered Composites by Combustion Synthesis: Microstructure and Mechanical Properties

Metals ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 38
Author(s):  
Olga Kamynina ◽  
Sergey Vadchenko ◽  
Natalia Shkodich ◽  
Ivan Kovalev
Keyword(s):  
Crystal Structure ◽  
Mechanical Properties ◽  
High Temperature ◽  
Chemical Composition ◽  
Liquid Phase ◽  
Flexural Strength ◽  
Combustion Synthesis ◽  
Interfacial Layers ◽  
Multilayered Composites ◽  
Metallic Foils

Ta/Ti/Ni/ceramic multilayered composites were successfully prepared by combustion synthesis. Laminated composites Ti–Ta–(Ti + 0.65C)–Ni–(Ti + 1.7B)–(Ti + 1.7B)–Ta–Ni-Ti and 3(Ti + 1.7B)–Ta–(5Ti + 3Si)–Ta–(Ti + 1.7B)–Ta–(5Ti + 3Si)–Ta–3(Ti + 1.7B) were combustion synthesized in an Ar atmosphere using (1) metallic foils (Ti, Ta, Ni) and (2) reactive tapes (Ti + 0.65C), (Ti + 1.7B), and (5Ti + 3Si), which, upon combustion, yielded ceramic layers as starting materials. The microstructure, crystal structure, and chemical composition of multilayered composites were characterized by SEM, EDX, and XRD. Their flexural strength was measured at 1100 °C. Upon combustion, Ta foils turned strongly joined with Ti ones due to the development of high temperature in the reactive layers yielding TiCx and TiBy. The formation of a liquid phase between metallic foils and reactive tapes and mutual interdiffusion between melted components during combustion favored strong joining between refractory metallic foils. Good joining between metals and ceramics is reached due to the formation of thin interfacial layers in the form of cermets and eutectic solutions.

Intermetallics of Aluminum

2019 ◽  
Author(s):  
Georg Frommeyer ◽  
Sven Knippscheer
Keyword(s):  
Crystal Structure ◽  
Mechanical Properties ◽  
Plastic Deformation ◽  
High Temperature ◽  
Physical Properties ◽  
Intermetallic Compounds ◽  
Oxidation Behavior ◽  
Physical And Mechanical Properties ◽  
Structural Materials

Aluminum-rich intermetallic compounds of the Al3X-type with transmission metals (X = Ti. Zr, Nb, V) of Groups IVb and Vb are of interest in the development of novel high-temperature and lightweight structural materials. This article describes the important physical and mechanical properties of trialuminides with DO22 structure and their L12 variations. Topical coverage includes: crystal structure and selected physical properties, plastic deformation, oxidation behavior, and applications.

scholarly journals Experimental study on high temperature mechanical properties of aluminate cement mortar mixed with fiber

2021 ◽  
Vol 25 (6 Part B) ◽  
pp. 4441-4448
Author(s):  
Ping Xu ◽  
Dong Han ◽  
Jian-Xin Yu ◽  
Yu-Hao Cui ◽  
Min-Xia Zhang
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Flexural Strength ◽  
Volume Fraction ◽  
Cement Mortar ◽  
Steel Fibers ◽  
Basalt Fibers ◽  
High Temperature Mechanical Properties ◽  
Micro Structures ◽  
Aluminate Cement

The aim of the present paper is to study the mechanical properties of aluminate cement mortar mixed with different chopped fibers under high temperature. The specimens with a size of 40 mm ? 40 mm ? 160 mm is treated at various tempera?tures of 25?C, 200?C, 400?C, 600?C, and 800?C. The compressive and flexural strength of the aluminate cement mortar and its micro-structures are tested. The results show that the chopped steel fibers and basalt fibers are effective in improv?ing the high temperature mechanical properties of aluminate cement mortar. When the volume fraction of chopped steel fibers is 2%, the compressive strength and flexural strength of the test block treated at the temperature of 800?C increase by 18.3% and 128.6%, respectively.

Microstructure and Mechanical Properties of SiC Whisker-Reinforced ZrB2 Ultra-High Temperature Ceramic

2008 ◽  
Vol 368-372 ◽  
pp. 1730-1732 ◽  
Author(s):  
Ping Hu ◽  
Xing Hong Zhang ◽  
Jie Cai Han ◽  
Song He Meng ◽  
Bao Lin Wang
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
High Temperature ◽  
Flexural Strength ◽  
Hot Pressing ◽  
Room Temperature ◽  
Pressing Temperature ◽  
Sintering Time ◽  
Microstructure And Mechanical Properties ◽  
Ultra High Temperature

SiC whisker-reinforced ZrB2 matrix ultra-high temperature ceramic were prepared at 2000°C for 1 h under 30MPa by hot pressing and the effects of whisker on flexural strength and fracture toughness of the composites was examined. The flexural strength and fracture toughness are 510±25MPa and 4.05±0.20MPa⋅m1/2 at room temperature, respectively. Comparing with the SiC particles-reinforced ZrB2 ceramic, no significant increase in both strength and toughness was observed. The microstructure of the composite showed that the SiC whisker was destroyed because the SiC whisker degraded due to rapid atom diffusivity at high temperature. The results suggested that some related parameters such as the lower hot-pressing temperature, a short sintering time should be controlled in order to obtain SiC whiskerreinforced ZrB2 composite with high properties.

Effect of Y2O3 on the Sintering, Mechanical and Dielectric Properties of Mullite/h-BN Composites

2016 ◽  
Vol 848 ◽  
pp. 28-31
Author(s):  
Han Jin ◽  
Yong Feng Li ◽  
Zhong Qi Shi ◽  
Hong Yan Xia ◽  
Guan Jun Qiao
Keyword(s):  
Fracture Toughness ◽  
Dielectric Constant ◽  
Phase Composition ◽  
High Temperature ◽  
Dielectric Properties ◽  
Liquid Phase ◽  
Flexural Strength ◽  
Sintering Temperature ◽  
Pressureless Sintering ◽  
Different Temperatures

Mullite/10 wt. %h-BN composites with 5 wt. % Y2O3 additive were fabricated by pressureless sintering at different temperatures. The densification, phase composition, microstructure, mechanical and dielectric properties of the mullite/h-BN composites were investigated. With the addition of Y2O3, the sintering temperature of the mullite/h-BN composites declined, while the density, mechanical and dielectric properties all increased. The addition of Y2O3 promoted the formation of liquid phase at high temperature, which accelerated the densification. Besides, Y2O3 particles which were located at the grain boundaries inhibited the grain growth of mullite matrix. For the mullite/h-BN composites with Y2O3 additive, the appropriate sintering temperature was about 1600°C. The relative density, flexural strength, fracture toughness and dielectric constant of the Y2O3 doped mullite/h-BN composite sintered at 1600 °C reached 82%, 135 MPa, 2.3 MPa·m1/2 and 4.9, respectively.

Effect of MgF2 Additive on the Mechanical Properties in Hydroxyapatite / Zirconia Composites

2006 ◽  
Vol 510-511 ◽  
pp. 478-481 ◽  
Author(s):  
Sung Hwan Kim ◽  
Hyun Chan Lee ◽  
Hee Gon Bang ◽  
Sang Yeup Park
Keyword(s):  
Crystal Structure ◽  
Mechanical Properties ◽  
Flexural Strength ◽  
Vickers Hardness ◽  
Tricalcium Phosphate ◽  
Decomposition Temperature ◽  
Phase Decomposition ◽  
Zirconia Composites ◽  
Ion Substitution

In this study, the effect of MgF2 additive on the mechanical properties of hydroxyapatite (HAp)/zirconia composites was investigated. As a fluoride additive, MgF2 was added to HAp/zirconia composites for the suppression of phase decomposition from HAp to tricalcium phosphate (TCP). Due to the dissolution of MgF2 at the phase decomposition temperature of HAp, the phase decomposition of non-stoichiometric HAp was suppressed. When MgF2 (5, 10 vol%) was added to HAp/zirconia composites, the decomposition of HAp was completely suppressed below 1400oC due to the ion substitution F- of for OH- in the HAp crystal structure. The flexural strength and Vickers hardness of composites was revealed more higher values compared with the MgF2-free composites.

High Temperature Mechanical Properties of Ni-YSZ Cermets for SOFC Anode

2010 ◽  
Author(s):  
Fumitada Iguchi ◽  
Hiromichi Kitahara ◽  
Hiroo Yugami
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Flexural Strength ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Strain Diagram ◽  
Thermal Cycles ◽  
High Temperature Mechanical Properties ◽  
Sofc Anode ◽  
The Difference

The mechanical properties of Ni-YSZ cermets at high temperature in reduction atmosphere were evaluated by the four points bending method. We studied the influences of reduction and thermal cycles, i.e. a cycle from R.T. to 800°C, to flexural strength and Young’s modulus. The flexural strength of Ni-YSZ at room temperature was lower than that of NiO-YSZ by about 10 to 20% mainly caused by the increment of porosity. But, the flexural strength of Ni-YSZ at 800°C was drastically decreased by an half of that at R.T. In addition, the stress–strain diagram of Ni-YSZ at 800°C indicated that it showed weak ductility. The maximum observed strain was over 0.5% at 30MPa. On the contrary, NiO-YSZ showed only brittlely at 800°C. The difference was caused by Ni metal in the Ni-YSZ cermets. Therefore, it was expected that Ni-YSZ is easily deformed in operation, though residual stress between an anode and an electrolyte was low. The influence of thermal cycles to flexural strength and Young’s modulus was not observed clearly. At the same time, the differences of microstructure were not observed. Therefore, it was concluded that the cycle does not change mechanical properties significantly.

Effect of the Sintering Additives on the Microstructure and the Properties of Textured Silicon Nitride

2005 ◽  
Vol 287 ◽  
pp. 242-246
Author(s):  
Dong Soo Park ◽  
Y.M. Kim ◽  
Byung Dong Hahn ◽  
Chan Park
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Silicon Nitride ◽  
Flexural Strength ◽  
Room Temperature ◽  
Sintering Additives ◽  
Significant Difference ◽  
Grain Width

Silicon nitride samples without and with 3 wt% of the aligned b-silicon nitride whisker seeds were prepared with 8.2 wt% Er2O3 and 1.9 wt% AlN. After sintering at 2148 K for 4h, the samples exhibited densities higher than 99.5% TD. The microstructures and properties of the samples were compared with those of the samples sintered with 4.8 wt% Y2O3 and 2.2 wt% Al2O3 at 2273 K for 4h. For samples without the whiskers, the sample with 4.8 wt% Y2O3 + 2.2 wt% Al2O3 had coarser microstructures than those with with 8.2 wt% Er2O3 + 1.9 wt% AlN. However, the samples with the whisker seeds, the former sample appeared to have only slightly larger grains than the latter sample in spite of the significant difference in the sintering temperatures. For the samples without the whisker seeds, the room temperature flexural strength was higher for the sample with Er2O3 + AlN. However, for the samples with the aligned whisker seeds, the sample with Y2O3 + Al2O3 exhibited higher room temperature flexural strength than that with Er2O3 + AlN although the average grain width of the former sample was larger than that of the latter sample. In case of the high temperature flexural strength at 1673 K, the flexural strengths of the samples with the whisker seeds were higher than double the strengths of the samples without the whisker seeds. For samples without the whisker seeds, the sample with Er2O3 + AlN exhibited better mechanical properties than that with Y2O3 + Al2O3. However, for the samples with the aligned whisker seeds, the sample with Y2O3 + Al2O3 exhibited better mechanical properties than those with Er2O3 + AlN. The results were explained in terms of the microstructures of the samples.

Performance of ilmenite concrete at sustained elevated temperatures

1988 ◽  
Vol 15 (5) ◽  
pp. 776-783
Author(s):  
H. S. Wilson
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
High Temperature ◽  
Flexural Strength ◽  
Key Words ◽  
Elevated Temperatures ◽  
Cement Ratio ◽  
Nondestructive Tests ◽  
High Temperature Mechanical Properties ◽  
Curing Period

Two similar mixes were made with cement contents of about 350 kg/m3 and a water–cement ratio of 0.50. The concrete specimens, moist cured for 7 days, were cured in air for 28 and 120 days, respectively, prior to heating. The exposure temperatures were 75, 150, 300, and 450 °C. The periods of exposure at each temperature were 2, 30, and 120 days.The compressive strengths, before heating, of the specimens cured for 35 and 120 days were 41.0 and 46.2 MPa, respectively, and the flexural strengths were 4.9 and 5.8 MPa. Compared with those strengths, the strengths of the specimens heated for 30 days or more increased at 75 °C but decreased at higher temperatures. The losses increased with increase in temperature, reaching about 30% at 450 °C.The flexural strength of the concrete cured in air for 28 days was more adversely affected than was the compressive strength. The flexural and compressive strengths of the concrete cured in air for 120 days were affected to about the same degree. The longer curing period had little effect on the relative losses in compressive strength, but the longer curing period reduced the loss in flexural strength. In most applications, the loss in strength could be compensated by proportioning the mix to overdesign for strength. Key words: high-density concrete, ilmenite, aggregates, high temperature, mechanical properties, nondestructive tests.

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