scholarly journals The Corrosion Resistance and Mechanism of AT13/Fe-Based Amorphous Composite Coatings

Micromachines ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 56
Author(s):  
Zhenhua Chu ◽  
Shikun Teng ◽  
Yuyun Zhou ◽  
Xingwei Zheng ◽  
Jingxiang Xu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Composite Coatings ◽  
High Strength ◽  
Corrosion Current ◽  
High Wear Resistance ◽  
Corrosion Mechanism ◽  
Amorphous Coating ◽  
Immersion Corrosion ◽  
Long Time ◽  
Glassy Coating

Due to high strength, high wear resistance and high corrosion resistance, the amorphous metallic glasses were investigated widely. In the present study, the corrosion resistance of amorphous coating and composite coatings with various proportions of AT13 (Al2O3–13 wt.% TiO2) ceramic as additions in 3.5 wt.% NaCl solution were studied. The corrosion resistance was improved obviously as the addition of AT13, and when the content of AT13 was 15 wt.%, the composite coating had the lowest corrosion current density (1.75 × 10−6 A cm−2) and the highest corrosion potential (−411 mV), which was 5.14 × 10−5 A cm−2 and −580 mV for Fe-based metallic glassy coating, respectively. The corrosion mechanism was proposed according to the long-time immersion corrosion test.

scholarly journals The Corrosion Resistance and Mechanism of AT13/Fe-based Amorphous Composite Coatings

2021 ◽  
Author(s):  
Zhenhua Chu ◽  
Shikun Teng ◽  
Yuyun Zhou ◽  
Xingwei Zheng ◽  
Jingxiang Xu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Composite Coatings ◽  
Corrosion Current ◽  
Amorphous Coating ◽  
Passivation Film ◽  
Immersion Corrosion ◽  
Long Time ◽  
Naoh Solution ◽  
Superior Corrosion Resistance ◽  
Glassy Coating

In the present study, the corrosion resistance of amorphous coating and composite coatings in 3.5 wt.% NaCl, 0.5 M H2SO4 and 10 wt.% NaOH solution were studied. The composite coatings exhibit superior corrosion resistance. When the content of AT13 （Al2O3–13 wt.% TiO2）was 15 wt.%, the composite coating has the lowest corrosion current density (1.75×10-6 A cm-2), which is 5.14×10-5 A cm-2 for Fe-based metallic glassy coating, and the highest corrosion potential (-411 mV), which is -580 mV for Fe-based metallic glassy coating. The breakdown potential of the passivation film in 3.5 wt.% NaCl solution was much higher than that of 316L.The long-time immersion corrosion tests carried out on different coatings showed that the corrosion protection effect of coating was enhanced with the increase of the amount of AT13 added.

The Roles of Ti Particles in Improving the Corrosion Resistance of Electrochemically Assembled Ni-Ti Composite Coatings

CORROSION ◽  
10.5006/2408 ◽  
2017 ◽  
Vol 73 (9) ◽  
pp. 1107-1118 ◽  
Author(s):  
Yuantao Zhao ◽  
Lianbo Wang ◽  
Zhenbo Qin ◽  
Chengxi Wang ◽  
Zhou Xu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Composite Coatings ◽  
Corrosion Current ◽  
Localized Corrosion ◽  
Corrosion Mechanism ◽  
Nacl Solution ◽  
Oriented Texture ◽  
Naoh Solution ◽  
Order Of Magnitude ◽  
Ti Particles

The influences of co-deposited Ti particles on corrosion behavior of electrodeposited Ni-Ti coatings were investigated. The co-deposited Ti particles caused the refined crystallite size and random-oriented texture of Ni-Ti coating. In 3.5 wt% sodium chloride (NaCl) solution, the buried Ti particles in Ni matrix blocked the corrosion path and rapid intercrystalline corrosion. The inert TiO2 could form on the exposed Ti particles and hinder localized corrosion. In 10 wt% sodium hydroxide (NaOH) solution, Ni matrix crystallites, refined by co-deposited Ti particles, contributed to formation of the passive Ni(OH)2 film. The corrosion current of Ni-Ti coating decreased by about one order of magnitude in both solutions with respect to pure Ni coating, demonstrating the co-deposited Ti particles greatly improved the corrosion resistance of Ni-Ti composite coatings. Finally, a corrosion mechanism was built to explain the co-deposited Ti particles improved corrosion resistance of the Ni-Ti composite coatings.

scholarly journals An Overview on the Tribological Performance of Titanium Alloys with Surface Modifications for Biomedical Applications

Lubricants ◽  
2019 ◽  
Vol 7 (8) ◽  
pp. 65 ◽  
Author(s):  
Kaur ◽  
Ghadirinejad ◽  
Oskouei
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Titanium Alloys ◽  
Weight Ratio ◽  
High Strength ◽  
Surface Modifications ◽  
Tribological Performance ◽  
The Body ◽  
High Wear Resistance ◽  
Medical Implants

The need for metallic biomaterials will always remain high with their growing demand in joint replacement in the aging population. This creates need for the market and researchers to focus on the development and advancement of the biometals. Desirable characteristics such as excellent biocompatibility, high strength, comparable elastic modulus with bones, good corrosion resistance, and high wear resistance are the significant issues to address for medical implants, particularly load-bearing orthopedic implants. The widespread use of titanium alloys in biomedical implants create a big demand to identify and assess the behavior and performance of these alloys when used in the human body. Being the most commonly used metal alloy in the fabrication of medical implants, mainly because of its good biocompatibility and corrosion resistance together with its high strength to weight ratio, the tribological behavior of these alloys have always been an important subject for study. Titanium alloys with improved wear resistance will of course enhance the longevity of implants in the body. In this paper, tribological performance of titanium alloys (medical grades) is reviewed. Various methods of surface modifications employed for titanium alloys are also discussed in the context of wear behavior.

EFFECT OF TiO2 PARTICLES ON MICRO-HARDNESS, CORROSION, WEAR AND FRICTION OF Ni–P–TiO2 COMPOSITE COATINGS AT DIFFERENT ANNEALING TEMPERATURES

2016 ◽  
Vol 23 (01) ◽  
pp. 1550082 ◽  
Author(s):  
PRASANNA GADHARI ◽  
PRASANTA SAHOO
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Composite Coatings ◽  
Corrosion Current ◽  
Xrd Analysis ◽  
Charge Transfer Resistance ◽  
Micro Hardness ◽  
Transfer Resistance ◽  
X Ray ◽  
Annealing Temperatures

The present study investigates the effect of titania particles on the micro-hardness, wear resistance, corrosion resistance and friction of electroless Ni–P–TiO2 composite coatings deposited on mild steel substrates at different annealing temperatures. The experimental results confirmed that the amount of TiO2 particles incorporated in the coatings increases with increase in the concentration of particles in the electroless bath. In presence of TiO2 particles, hardness, wear resistance and corrosion resistance of the coating improve significantly. At higher annealing temperature, wear resistance increases due to formation of hard Ni3P phase and incorporation of titania particles in the coated layer. Charge transfer resistance and corrosion current density of the coatings reduce with an increase in TiO2 particles, whereas corrosion potential increases. Microstructure changes and composition of the composite coating due to heat treatment are studied with the help of scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA) and X-ray diffraction (XRD) analysis.

Research on the Corrosion Resistance of Ni-ZrO2 Nanocomposite Coatings

2014 ◽  
Vol 633-634 ◽  
pp. 787-790
Author(s):  
Lin Wang ◽  
Jin Lin Lu ◽  
Cheng Wei Li ◽  
Shu Mei Kang
Keyword(s):  
Corrosion Resistance ◽  
Current Density ◽  
Composite Coatings ◽  
Process Condition ◽  
Corrosion Current ◽  
Bath Temperature ◽  
Nanocomposite Coating ◽  
Test Method ◽  
Optimum Process ◽  
Orthogonal Test Method

In order to improve the corrosion resistance of Ni-nanoZrO2 composite coatings. By orthogonal test method,the process for composite electroplating of Ni-ZrO2 was optimized involved current density、bath temperature、the ZrO2 particle concentration. Corrosion resistance and the hardness were tested, microstructure was observed with a scanning electron microscope. The optimized technological conditions are:current density i4A/dm2,bath temperature 45°C, nanoZrO2 addition 7g/L. In this optimum process condition, corrosion current density is 6.186×10-6 A/cm2, corrosion resistance is good, and its hardness is much better than pure nickel plating, also a flat morphology and compact microstructure Ni-ZrO2 nanocomposite coating is get.

Corrosion Resistance of Rare Earth Modified Chromizing Coating on P110 Oil Casing Tube Steel by Pack Cementation

2009 ◽  
Vol 79-82 ◽  
pp. 1075-1078
Author(s):  
Nai Ming Lin ◽  
Fa Qin Xie ◽  
Tao Zhong ◽  
Xiang Qing Wu ◽  
Wei Tian
Keyword(s):  
Corrosion Resistance ◽  
Rare Earth ◽  
Steel Substrate ◽  
Electrochemical Corrosion ◽  
Corrosion Current ◽  
Pack Cementation ◽  
Tube Steel ◽  
X Ray ◽  
Immersion Corrosion ◽  
P110 Steel

The rare earth (RE) modified chromizing coating was obtained on P110 oil casing tube steel (P110 steel) substrate by means of pack cementation technique to enhance the resistance against corrosion of P110 steel. Scanning Electron Microscopy (SEM), Energy Dispersive X-ray analysis (EDX) and X-ray diffraction (XRD) were employed to research microstructure, composition distribution and phase constitution of the chromizing coating. The effect of minor addition of RE on the microstructure of chromizing was discussed. Corrosion resistance of chromizing coating was investigated and compared with that of bare P110 steel via electrochemical corrosion and immersion corrosion in simulated oilfield brine solution, respectively. The results showed that a uniform, continuous and compact coating was formed on P110 steel. The coating with RE addition was more compact than that of the coating added no RE, and a small amount of RE addition could promote the chromizing procedure notably. From SEM and EDX investigation, it had been confirmed that the coating was composed of two different layers, an out layer and an inner layer; the coating mainly contains Fe and Cr; the concentration of Cr decreased as the distance from the surface increased, yet Fe presented the inverse trend. XRD analysis indicated the coating was built up by (Cr, Fe)23C6 referring to the out layer, (Cr, Fe)7C3, Cr7C3 and α-(Cr, Fe) corresponding to the inner layer. Electrochemical corrosion consequence was obtained as follows: the self-corroding electric potential of chromizing coating was higher, and the corrosion current density was lower than that of bare P110 steel, which revealed that chromizing coating had better anti-corrosion performance; immersion corrosion results demonstrated the mass loss of chromized P110 steel was lower, and this meant that chromizing coating had a better corrosion resistance than that of bare P110 steel on the experimental condition. A compact (Cr, Fe)xCy coating can be fabricated by pack cementation technique. As a result of minor RE addition, microstructure and corrosion resistance of the chromizing coating are improved obviously.

Investigation on corrosion performance of multilayer Ni-P/TiO2 composite coating on steel

2016 ◽  
Vol 23 (3) ◽  
pp. 309-314
Author(s):  
M. Edwin Sahayaraj ◽  
J.T. Winowlin Jappes ◽  
I. Siva ◽  
N. Rajini
Keyword(s):  
Corrosion Resistance ◽  
Mild Steel ◽  
Corrosion Behavior ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Multilayer Coating ◽  
Electroless Nickel ◽  
Corrosion Mechanism ◽  
Corrosion Performance ◽  
Electroless Ni

AbstractElectroless nickel coating treatment improves the corrosion resistance of mild steel. This work aims at studying the corrosion behavior of electroless Ni-P/TiO2 composite and multilayer coatings applied to the mild steel substrate as their as-plated state and furnace annealed at various temperatures and compared both the coatings’ corrosion performance. The corrosion behavior of the deposits was evaluated by potentiodynamic polarization studies in 3.5 wt% sodium chloride solution. The results showed that the corrosion resistance of the multilayer coating was two times higher compared to the composite coatings. Further, the corrosion mechanism was discussed in terms of microstructure, phase transformation, grain size, and microstrain.

scholarly journals Study on microstructure and mechanical properties of Fe-based amorphous particle-reinforced Al-based matrix composites

2020 ◽  
Vol 29 ◽  
pp. 2633366X2092140 ◽  
Author(s):  
Xiang Zhou ◽  
Wei Long ◽  
Xiaoping Zhou
Keyword(s):  
Tensile Strength ◽  
Corrosion Resistance ◽  
Pure Aluminum ◽  
High Strength ◽  
Corrosion Current ◽  
Amorphous Structure ◽  
Matrix Composites ◽  
Remarkable Effect ◽  
Amorphous Particle ◽  
Al Matrix

Fe52Cr15Mo26C3B1Y3 amorphous particle-reinforced pure aluminum (Al) matrix composite was prepared by powder metallurgy. The ferrum (Fe)-based amorphous particles prepared by atomization method have good amorphous structure, and the circular reinforcement particles are evenly distributed in the Al matrix. The composite has high strength, hardness, and excellent corrosion resistance. The hardness of the composite increases gradually with the increase in the content of the reinforcement, from 46 Vickers hardness (HV) of pure Al to 220.5 HV, with remarkable effect. The tensile strength of the composite increases first and then decreases with the increase in the content of the reinforcement. When the content of reinforcement is 15%, the maximum tensile strength is 234 MPa, which is 154% higher than that of pure Al. The fracture mode of the composite is the mixture of plastic fracture and brittle fracture. The corrosion resistance of pure Al is significantly improved by the addition of reinforcements, which shows that the composite has a smaller corrosion current density and a more positive corrosion potential than that of pure Al.

scholarly journals In Situ Formation of Ti47Cu38Zr7.5Fe2.5Sn2Si1Nb2 Amorphous Coating by Laser Surface Remelting

Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3660 ◽  
Author(s):  
Peizhen Li ◽  
Lingtao Meng ◽  
Shenghai Wang ◽  
Kunlun Wang ◽  
Qingxuan Sui ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Elastic Modulus ◽  
Laser Surface ◽  
Corrosion Mechanism ◽  
Amorphous Coating ◽  
Laser Surface Remelting ◽  
The Matrix ◽  
In Situ Formation ◽  
Amorphous Coatings

In previous studies, Ti-based bulk metallic glasses (BMGs) free from Ni and Be were developed as promising biomaterials. Corresponding amorphous coatings might have low elastic modulus, remarkable wear resistance, good corrosion resistance, and biocompatibility. However, the amorphous coatings obtained by the common methods (high velocity oxygen fuel, laser cladding, etc.) have cracks, micro-pores, and unfused particles. In this work, a Ti-based Ti47Cu38Zr7.5Fe2.5Sn2Si1Nb2 amorphous coating with a maximum thickness of about 100 μm was obtained by laser surface remelting (LSR). The in-situ formation makes the coating dense and strongly bonded. It exhibited better corrosion resistance than the matrix and its corrosion mechanism was discussed. The effects of LSR on the microstructural evolution of Ti-based prefabricated alloy sheets were investigated. The nano-hardness in the heat affected zone (HAZ) was markedly increased by 51%, meanwhile the elastic modulus of the amorphous coating was decreased by 18%. This demonstrated that LSR could be an effective method to manufacture the high-quality amorphous coating. The in-situ amorphous coating free from Ni and Be had a low modulus, which might be a potential corrosion-resistant biomaterial.

LANGALLOY 400

Alloy Digest ◽  
2007 ◽  
Vol 56 (6) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Curie Temperature ◽  
Physical Properties ◽  
Tensile Properties ◽  
Copper Alloy ◽  
Room Temperature ◽  
High Strength ◽  
Nickel Copper ◽  
Long Time ◽  
Compositional Changes

Abstract Langalloy 400 is a nickel-copper alloy for general use. It has an excellent combination of high strength, ductility, and corrosion resistance. The Curie temperature of the alloy is close to room temperature and varies with slight compositional changes. Langalloy 400 has been used as marine fasteners for a long time. This datasheet provides information on physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming and machining. Filing Code: Ni-651. Producer or source: Langley Alloys.

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