scholarly journals Contribution of the Paragenetic Sequence of Clay Minerals to Re-Examination of the Alteration Zoning in the Krafla Geothermal System

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 935
Author(s):  
David Escobedo ◽  
Patricia Patrier ◽  
Daniel Beaufort ◽  
Benoit Gibert ◽  
Léa Levy ◽  
...  

This paper revisits the clay mineralogy of the “smectite” alteration zone in the Krafla geo-thermal field via the study of an exploratory well in which temperatures range from 40 °C to 215 °C. The clay alteration consists of several mineral assemblages superimposed in time and space, resulting from different stages of water-rock interaction. Trioctahedral clay minerals (chlorite, corrensite and smectite) are observed throughout the studied section. These minerals can form in nearly closed systems as replacements of groundmass minerals/glass after interactions with resident and nearly stagnant fluids not far from chemical equilibrium (neutral to basic pH conditions) or from direct precipitation from geothermal fluids. They are locally superimposed by Al clay phases (smectite, illite/smectite and kaolinite), which result from intense leaching of the host rocks due to their interaction with low pH fluids under strong W/R ratios. The absence of mineralogical zoning is explained by the fact that hydrothermal alteration is strongly dependent on very recent hydrodynamics. The current fluid circulation generates trioctahedral clays at depth that cannot be distinguished from pervasive earlier alteration. The only easily detectable signature of current activity and the most relevant signature for geothermal exploration is the presence of Al dioctahedral phases since it indicates leaching and intense hydrothermal activity.

2021 ◽  
Author(s):  
Martina Zucchi

<div> <p><span>Extensional tectonics and related magmatism affecting continental crust can favour the development of geothermal systems. Granitoids intruded in the upper crust represent the main expression of magmatism; they are strictly controlled by brittle structures during their emplacement and exhumation. The cooling of the magmatic bodies produce a thermal perturbation in the hosting rocks resulting in thermo-metamorphic aureoles of several meter thick, usually characterised by valuable ore deposits. After the emplacement and during the cooling stage such granitoids can promote the geothermal fluids circulation mainly through the fault zones. In case of favourable geological and structural conditions, geothermal fluids can be stored in geological traps (reservoirs), generally represented by rock volumes with sufficient permeability for storing a significant amount of fluid. Traps are confined, at the top, by rocks characterised by low, or very low permeability, referred to as the cap rocks of a geothermal system. Several studies are addressed to the study of fluid migration through the permeable rock volumes, whereas few papers are dealing with fluid flow and fluid-rock interaction within the cap rocks. </span></p> </div><div> <p><span>In this presentation, an example of fault-controlled geothermal fluid within low permeability rocks is presented. The study area is located in the south-eastern side of Elba Island (Tuscan Archipelago, Italy), where a succession made up of shale, marl and limestone (Argille a Palombini Fm, early Cretaceous) was affected by contact metamorphism related to the Porto Azzurro monzogranite, which produced different mineral assemblages, depending on the involved lithotypes. These metamorphic rocks were dissected by high-angle normal faults that channelled superhot geothermal fluids. Fluid inclusions analyses on hydrothermal quartz and calcite suggest that at least three paleo-geothermal fluids permeated through the fault zones, at a maximum P of about 0.8 kbar. The results reveal how brittle deformation induces fluid flow in rocks characterised by very low permeability and allow the characterisation of the paleo-geothermal fluids in terms of salinity and P-T trapping conditions. </span></p> </div>


Minerals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 919
Author(s):  
Paolo Fulignati

The study of active and fossil hydrothermal systems shows clay minerals to be a fundamental tool for the identification and characterization of hydrothermal alteration facies. The occurrence and composition of hydrothermal alteration facies could provide useful information on the physicochemical conditions of the hydrothermal activity affecting a rock volume. In particular, clay minerals (i.e., smectite group, chlorite, illite, kaoline group, pyrophyllite, biotite) are pivotal for extrapolating important parameters that strongly affect the development of water/rock interaction processes such as the temperature and pH of the hydrothermal environment. This work aims to give a general reference scheme concerning the occurrence of clay minerals in hydrothermal alteration paragenesis, their significance, and the information that can be deduced by their presence and chemical composition, with some examples from active and fossil hydrothermal systems around the world. The main mineralogical geothermometers based on chlorite and illite composition are presented, together with the use of hydrogen and oxygen isotope investigation of clay minerals in hydrothermal systems. These techniques provide a useful tool for the reconstruction of the origin and evolution of fluids involved in hydrothermal alteration. Finally, a list of oxygen and hydrogen fractionation factor equations between the main clay minerals and water is also provided.


1962 ◽  
Vol 42 (2) ◽  
pp. 296-301 ◽  
Author(s):  
J. S. Clark ◽  
J. E. Brydon ◽  
H. J. Hortie

X-ray diffraction analysis was used to identify the clay minerals present in fourteen subsoil samples that were selected to represent some more important clay-bearing deposits in British Columbia. The clay mineralogy of the subsoils varied considerably but montmorillonitic clay minerals tended to predominate in the water-laid deposits of the south and illite in the soil parent materials of the Interior Plains region of the northeastern part of the Province.


Geosciences ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 8
Author(s):  
Mei Zhang ◽  
Hongfeng Lu ◽  
Qing Chen ◽  
Gayan Bandara ◽  
Hui Zhang ◽  
...  

In the northern South China Sea, pockmarks are widely distributed on the seabed offshore on the southwestern Xisha Uplift. The mineralogy and geochemistry of the clay minerals and surface sediments from the pockmark field were identified using X-ray diffraction (XRD) analysis and X-ray fluorescence (XRF) analysis to trace the provenance, weathering, and sediment transportation system in the area. The clay minerals are primarily comprised of illite, smectite, kaolinite, and chlorite, showing a distribution of average weight percentages of 35%, 35%, 18%, and 13%, respectively. Based on the surrounding fluvial drainage basins and various transport mechanisms (current or monsoon), illite and chlorite primarily originate from rivers in Taiwan and the Mekong and Red Rivers. Kaolinite primarily originates from the Pearl River, and smectite derived from the Luzon arc system is primarily transported by surface currents with significant influence from the Kuroshio intrusion.


2018 ◽  
Vol 31 ◽  
pp. 02003 ◽  
Author(s):  
Yunus Daud ◽  
Syamsu Rosid ◽  
Fikri Fahmi ◽  
Faris Maulana Yunus ◽  
Reza Muflihendri

Ijen geothermal area is high-temperature geothermal system located in Bondowoso regency, East Java. It is categorized as caldera-hosted geothermal system which is covered by quaternary andesitic volcanic rocks with steep topography at the surrounding. Several surface thermal manifestations are found, such as altered rocks near Mt. Kukusan and a group of Blawan hotsprings in the northern part of the caldera. Geomagnetic survey was conducted at 72 stations which is distributed inside the caldera to delineate the existence of hydrothermal activity. Magnetic anomaly was obtained by reducing total magnetic measured on the field by IGRF and diurnal variation. Reduction to pole (RTP) method was applied with geomagnetic inclination of about -32°. In general, the result shows that high magnetic anomaly is distributed at the boundary of study area, while low magnetic anomaly is observed in the centre. The low anomaly indicates demagnetized rock that probably caused by hydrothermal activity. It has a good correlation with surface alteration observed close to Mt. Kukusan as well as high temperature reservoir drilled in the centre of caldera. Accordingly, the low magnetic anomaly also presents the possibility of geothermal reservoir in Ijen geothermal area.


2004 ◽  
Vol 5 (1) ◽  
pp. 43
Author(s):  
K.G. PEHLIVANOGLOU ◽  
G. TRONTSIOS ◽  
A. TSIRAMBIDES

The Thermaikos Gulf constitutes the NW part of the North Aegean Sea and is limited eastward from the Chalkidiki Peninsula and westward from the Pieria Prefecture. Its plateau covers an area of 3,500 km2. The mechanisms responsible for the grain size distribution into the Gulf, the clay mineralogy and the chemistry of some bottom sediments from the outer Thermaikos Gulf, are examined. Source mixing during transportation, flocculation, differential settling processes and organic matter appear to be the main mechanisms for the distribution of clay minerals in shallow waters. All grain size fractions studied present a wide range of values confirming the extreme variations of the discharged load and the variability in marine processes. Plagioclases predominate over K-feldspars, while quartz is the most abundant mineral present. In addition, micas, chlorites, amphiboles and pyroxenes exist as primary and/or accessory minerals in all samples. Among clay minerals, illite predominates over smectite and smectite over chlorite (+ kaolinite). The ordered interstratified phase of I/S, with 30-35% S layers, is present in the 2-0.25µm fraction. The randomly interstratified phase of I/S, with 50% S layers, is present in the <0.25& micro; m fraction. On average the clay mineral content of the studied samples is: 48% I, 23% S, 17% Ch (+K) and 12% others for the 2-0.25µm fraction and 50% I, 30% S and 20% Ch (+K) for the <0.25 µm fraction. All these minerals are the weathering products of the rocks from the drainage basins of the rivers flowing into the Gulf, as well as of the Neogene and Quaternary unconsolidated sediments of the surrounding coasts. The terrigenous input, the water mass circulation and, to a lesser extent, the quality of the discharged material and the differential settling of grains, control the grain size distribution within the outer Thermaikos Gulf. The chemical composition of the analysed samples is generally in agreement with their mineral composition and signifies their terrigenous origin presenting discretely clastic character.


1993 ◽  
Vol 35 (4) ◽  
pp. 287-305 ◽  
Author(s):  
Koichi KITAOKA ◽  
Yuki YUSA ◽  
Kokichi KAMIYAMA ◽  
Shinji OHSAWA ◽  
Michael K. STEWART ◽  
...  

Clay Minerals ◽  
2006 ◽  
Vol 41 (4) ◽  
pp. 863-877 ◽  
Author(s):  
S. Guggenheim ◽  
J. M. Adams ◽  
D. C. Bain ◽  
F. Bergaya ◽  
M. F. Brigatti ◽  
...  

Brindley et al. (1951) reported the earliest efforts to obtain international collaboration on nomenclature and classification of clay minerals, initiated at the International Soil Congress in Amsterdam in 1950. Since then, national clay groups were formed, and they proposed various changes in nomenclature at group meetings of the International Clay Conferences. Most of the national clay groups have representation on the Nomenclature Committee of the Association Internationale pour l'Etude des Argiles (AIPEA, International Association for the Study of Clays), which was established in 1966. The precursor committee to the AIPEA Nomenclature Committee was the Nomenclature Subcommittee of the Comité International pour l'Etude des Argiles (OPEA, International Committee for the Study of Clays).


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