scholarly journals Origin of Lithium–Potassium-Rich Brines in the JianghanBasin, South China: Constraints by Water–Rock Reactions of Mesozoic–Cenozoic Igneous Rocks

Minerals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1330
Author(s):  
Chunlian Wang ◽  
Xiaocan Yu ◽  
Ruiqin Li ◽  
Lihong Liu ◽  
Kai Yan ◽  
...  
Keyword(s):  
Dissolution Rate ◽  
South China ◽  
Igneous Rocks ◽  
Distribution Area ◽  
Alkaline Solutions ◽  
Thermal Source ◽  
The Tibetan Plateau ◽  
Dissolution Rates ◽  
Weakly Alkaline ◽  
Increasing Temperature

A large number of lithium–potassium-rich brines have been found in Paleocene reservoirs in the Jianghan Basin, South China. First, the brines have exceptionally high lithium and potassium contents that are even higher than those in other closed basins on the Tibetan Plateau. Second, the enriched brines are widely distributed in the center of the basin. The Mesozoic and Cenozoic igneous rocks in the Jiangling depression are mainly basalt and granite, and their distribution area exceeds 50% of the basin. The large basalt body provided a thermal source for the water–rock reaction. The igneous rocks in the study area could have provided ore-forming elements, such as lithium and potassium, for the brine. A static immersion experiment at room temperature shows that fluids with certain salinities are more likely to activate K ions in basalt. However, weakly alkaline solutions more easily dissolve K. High-temperature water–rock experiments show that the dissolution rates of Ca, Mg, and Sr decrease with increasing temperature, while the dissolution rates of K and Li first increase and then decrease with increasing temperature. The dissolution of K and Li is easier when saline fluid reacts with volcanic rock. The dissolution rate of K is higher than that of Li in basalt, and the dissolution rate of Li is higher than that of K in granite. Compared with the results at normal temperatures, the ability of the fluid to leach elements at higher temperatures is significantly enhanced. Temperature is the main factor controlling the ability of fluid to leach elements. High-salinity fluid is the main carrier of ore-forming elements. According to the water–rock experiments, the mineral composition of the ancient brine in the Jiangling depression that formed during the Paleocene is consistent with that of the ore-rich brine found today, but different by a few orders of magnitude, indicating that the formation of lithium–potassium-rich brines requires a long time. The water–rock reaction is one of the important processes of brine formation, and surface evaporation and concentration are the main mechanisms of brine mineralization.

The reductive dissolution of synthetic goethite and hematite in dithionite

Clay Minerals ◽  
1987 ◽  
Vol 22 (3) ◽  
pp. 329-337 ◽  
Author(s):  
J. Torrent ◽  
U. Schwertmann ◽  
V. Barron
Keyword(s):  
Specific Surface ◽  
Dissolution Rate ◽  
Surface Area ◽  
Reductive Dissolution ◽  
Natural Environments ◽  
Dissolution Rates ◽  
Aluminium Substitution ◽  
Initial Dissolution Rate

AbstractThe reductive dissolution by Na-dithionite of 28 synthetic goethites and 26 hematites having widely different crystal morphologies, specific surfaces and aluminium substitution levels has been investigated. For both minerals the initial dissolution rate per unit of surface area decreased with aluminium substitution. At similar aluminium substitution and specific surface, goethites and hematites showed similar dissolution rates. These results suggest that preferential, reductive dissolution of hematite in some natural environments, such as soils or sediments, might be due to the generally lower aluminium substitution of this mineral compared to goethite.

scholarly journals Burial and Exhumation History of the Lujing Uranium Ore Field, Zhuguangshan Complex, South China: Evidence from Low-Temperature Thermochronology

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 116
Author(s):  
Yue Sun ◽  
Barry P. Kohn ◽  
Samuel C. Boone ◽  
Dongsheng Wang ◽  
Kaixing Wang
Keyword(s):  
Early Cretaceous ◽  
Late Cretaceous ◽  
South China ◽  
Thermal History ◽  
Fission Track ◽  
Thermal Evolution ◽  
Negative Relationship ◽  
The Tibetan Plateau ◽  
Uranium Ore ◽  
Production Area

The Zhuguangshan complex hosts the main uranium production area in South China. We report (U-Th)/He and fission track thermochronological data from Triassic–Jurassic mineralized and non-mineralized granites and overlying Cambrian and Cretaceous sandstone units from the Lujing uranium ore field (LUOF) to constrain the upper crustal tectono-thermal evolution of the central Zhuguangshan complex. Two Cambrian sandstones yield reproducible zircon (U-Th)/He (ZHe) ages of 133–106 Ma and low effective uranium (eU) content (270–776 ppm). One Upper Cretaceous sandstone and seven Mesozoic granites are characterized by significant variability in ZHe ages (154–83 Ma and 167–36 Ma, respectively), which show a negative relationship with eU content (244–1098 ppm and 402–4615 ppm), suggesting that the observed age dispersion can be attributed to the effect of radiation damage accumulation on 4He diffusion. Correspondence between ZHe ages from sandstones and granites indicates that surrounding sedimentary rocks and igneous intrusions supplied sediment to the Cretaceous–Paleogene Fengzhou Basin lying adjacent to the LUOF. The concordance of apatite fission track (AFT) central ages (61–54 Ma) and unimodal distributions of confined track lengths of five samples from different rock units suggest that both sandstone and granite samples experienced a similar cooling history throughout the entire apatite partial annealing zone (~110–60 °C). Apatite (U-Th-Sm)/He (AHe) ages from six non-mineralized samples range from 67 to 19 Ma, with no apparent correlation to eU content (2–78 ppm). Thermal history modeling of data suggests that the LUOF experienced relatively rapid Early Cretaceous cooling. In most samples, this was followed by the latest Early Cretaceous–Late Cretaceous reheating and subsequent latest Late Cretaceous–Recent cooling to surface temperatures. This history is considered as a response to the transmission of far-field stresses, involving alternating periods of regional compression and extension, related to paleo-Pacific plate subduction and subsequent rollback followed by Late Paleogene–Recent India–Asia collision and associated uplift and eastward extrusion of the Tibetan Plateau. Thermal history models are consistent with the Fengzhou Basin having been significantly more extensive in the Late Cretaceous–Early Paleogene, covering much of the LUOF. Uranium ore bodies which may have formed prior to the Late Cretaceous may have been eroded by as much as ~1.2 to 4.8 km during the latest Late Cretaceous–Recent denudation.

scholarly journals Characteristics of Deep Convective Systems and Initiation during Warm Seasons over China and Its Vicinity

2021 ◽  
Vol 13 (21) ◽  
pp. 4289
Author(s):  
Yang Li ◽  
Yubao Liu ◽  
Yun Chen ◽  
Baojun Chen ◽  
Xin Zhang ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
South China ◽  
Warm Season ◽  
Statistical Characteristics ◽  
The Tibetan Plateau ◽  
Spatiotemporal Resolution ◽  
Convective Systems ◽  
Seasonal And Diurnal Variations ◽  
Deep Convective Systems ◽  
Guizhou Plateau

The spatiotemporal statistical characteristics of warm-season deep convective systems, particularly deep convective systems initiation (DCSI), over China and its vicinity are investigated using Himawari-8 geostationary satellite measurements collected during April-September from 2016 to 2020. Based on a satellite brightness temperature multiple-threshold convection identification and tracking method, a total of 47593 deep convective systems with lifetimes of at least 3 h were identified in the region. There are three outstanding local maxima in the region, located in the southwestern, central and eastern Tibetan Plateau and Yunnan-Guizhou Plateau, followed by a region of high convective activities in South China. Most convective systems are developed over the Tibetan Plateau, predominantly eastward-moving, while those developed in Yunnan-Guizhou Plateau and South China mostly move westward and southwestward. The DSCI occurrences become extremely active after the onset of the summer monsoon and tend to reach a maximum in July and August, with a diurnal peak at 11–13 LST in response to the enhanced solar heating and monsoon flows. Several DCSI hotspots are identified in the regions of inland mountains, tropical islands and coastal mountains during daytime, but in basins, plains and coastal areas during nighttime. DCSI over land and oceans exhibits significantly different sub-seasonal and diurnal variations. Oceanic DCSI has an ambiguous diurnal variation, although its sub-seasonal variation is similar to that over land. It is demonstrated that the high spatiotemporal resolution satellite dataset provides rich information for understanding the convective systems over China and vicinity, particularly the complex terrain and oceans where radar observations are sparse or none, which will help to improve the convective systems and initiation nowcasting.

Neoproterozoic Amdo and Jiayuqiao microblocks in the Tibetan Plateau: Implications for Rodinia reconstruction

2020 ◽  
Author(s):  
Yiming Liu ◽  
Yuhua Wang ◽  
Sanzhong Li ◽  
M. Santosh ◽  
Runhua Guo ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
South China ◽  
Tectonic Setting ◽  
Parental Magma ◽  
Tibet Plateau ◽  
Geochemical Data ◽  
The Tibetan Plateau ◽  
South China Craton ◽  
Neoproterozoic Magmatism ◽  
T Values

The Tibetan Plateau is composed of several microblocks, the tectonic affinity and paleogeographic correlations of which remain enigmatic. We investigated the Amdo and Jiayuqiao microblocks in central Tibet Plateau with a view to understand their tectonic setting and paleogeographic position within the Neoproterozoic supercontinent Rodinia. We present zircon U-Pb and Lu-Hf isotope, and whole-rock geochemical data on Neoproterozoic granitic gneisses from these microblocks. Zircon grains from the Jiayuqiao granitic gneiss yielded an age of 857 ± 9 Ma with variable εHf(t) values (−8.9 to 4.0). The Amdo granitic gneisses yielded ages of 893 ± 5 Ma, 807 ± 5 Ma, and 767 ± 11 Ma, with εHf(t) values in the range of −4.9 to 3.5. Geochemically, the granitoids belong to high-K calc-alkaline series, with the protolith derived from partial melting of ancient crustal components. The ascending parental magma of the Amdo granitoids experienced significant mantle contamination as compared to the less contaminated magmas that generated the Jiayuqiao intrusions. In contrast to the Lhasa, Himalaya, South China, and Tarim blocks, we suggest that the Amdo and Jiayuqiao microblocks probably formed a unified block during the Neoproterozoic and were located adjacent to the southwestern part of South China craton. The Neoproterozoic magmatism was probably associated with the subduction of the peripheral ocean under the South China craton and the delamination of lithospheric mantle beneath the Jiangnan orogen.

scholarly journals The Role of Functional Excipients in Solid Oral Dosage Forms to Overcome Poor Drug Dissolution and Bioavailability

Pharmaceutics ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 393 ◽  
Author(s):  
Jannes van der Merwe ◽  
Jan Steenekamp ◽  
Dewald Steyn ◽  
Josias Hamman
Keyword(s):  
Dissolution Rate ◽  
Solid Dispersions ◽  
Aqueous Solubility ◽  
Dosage Forms ◽  
Oral Dosage ◽  
Drug Dissolution ◽  
Specific Reference ◽  
Dissolution Rates ◽  
Bioavailability Enhancement ◽  
Poor Solubility

Many active pharmaceutical ingredients (APIs) exhibit poor solubility and low dissolution rates in aqueous environments such as the luminal fluids of the gastrointestinal tract. The oral bioavailability of these compounds is usually very low as a result of their poor solubility properties. In order to improve the bioavailability of these poorly soluble drugs, formulation strategies have been applied as a means to improve their aqueous solubility and dissolution rates. With respect to formulation approaches, excipients can be incorporated in the formulation to assist in the dissolution process of the drug, or specialized dosage forms can be formulated that improve dissolution rate through various mechanisms. This paper provides an overview of selected excipients (e.g., alkalinizing agents, surfactants and sugars) that can be used in formulations to increase the dissolution rate as well as specialized dosage forms such as self-emulsifying delivery systems and formulation techniques such as inclusion complexes and solid dispersions. These formulation approaches are discussed with available examples with specific reference to positive outcomes in terms of drug solubility and bioavailability enhancement.

The Influence of Mechanical and Thermal Forcing by the Tibetan Plateau on Asian Climate

2007 ◽  
Vol 8 (4) ◽  
pp. 770-789 ◽  
Author(s):  
Guoxiong Wu ◽  
Yimin Liu ◽  
Qiong Zhang ◽  
Anmin Duan ◽  
Tongmei Wang ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
East Asia ◽  
South China ◽  
Local Heating ◽  
Lower Troposphere ◽  
Early Spring ◽  
The Tibetan Plateau ◽  
Continental Scale ◽  
The North ◽  
Meridional Winds

Abstract This paper attempts to provide some new understanding of the mechanical as well as thermal effects of the Tibetan Plateau (TP) on the circulation and climate in Asia through diagnosis and numerical experiments. The air column over the TP descends in winter and ascends in summer and regulates the surface Asian monsoon flow. Sensible heating on the sloping lateral surfaces appears from the authors’ experiments to be the major driving source. The retarding and deflecting effects of the TP in winter generate an asymmetric dipole zonal-deviation circulation, with a large anticyclone gyre to the north and a cyclonic gyre to the south. Such a dipole deviation circulation enhances the cold outbreaks from the north over East Asia, results in a dry climate in south Asia and a moist climate over the Indochina peninsula and south China, and forms the persistent rainfall in early spring (PRES) in south China. In summer the TP heating generates a cyclonic spiral zonal-deviation circulation in the lower troposphere, which converges toward and rises over the TP. It is shown that because the TP is located east of the Eurasian continent, in summertime the meridional winds and vertical motions forced by the Eurasian continental-scale heating and the TP local heating are in phase over the eastern and central parts of the continent. The monsoon in East Asia and the dry climate in middle Asia are therefore intensified.

Chlorite crystallinity as an indicator of metamorphic grade of low-temperature meta-igneous rocks: a case study from the Bükk Mountains, Northeast Hungary

Clay Minerals ◽  
1997 ◽  
Vol 32 (2) ◽  
pp. 205-222 ◽  
Author(s):  
P. Árkai ◽  
D. Sadek Ghabrial
Keyword(s):  
Low Temperature ◽  
Electron Microprobe ◽  
Metamorphic Grade ◽  
Igneous Rocks ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Facies Classification ◽  
Increasing Temperature ◽  
Relative Differences

AbstractX-ray diffraction chlorite crystallinity (ChC) indices and major element chemical compositions of chlorites and bulk rocks were determined and correlated in meta-igneous rocks from different Mesozoic formations in various tectonic units of the Bükk Mountains, NE Hungary. The rocks, of basic to acidic compositions, range from ocean-floor metamorphic prehnite-pumpellyite facies (diagenetic zone) through regional metamorphic prehnite-pumpellyite facies (anchizone) up to the regional metamorphic pumpellyite-actinolite and greenschist facies (epizone). As in the case of meta-sedimentary rocks, chlorite crystallinity can be applied as an empirical, complementary petrogenetic tool to determine relative differences in grades of low-temperature meta-igneous rocks. Electron microprobe and XRD data show that ChC is controlled mainly by the decreasing amounts of contaminants (mixed-layered components or discrete, intergrown phases of mostly smectitic composition) in chlorite with advancing metamorphic grade, up to the epizone. The apparent increase in calculated Aliv content of chlorite with increasing temperature is related to the decrease of these contaminants, as stated earlier by Jiang et al. (1994). On the basis of the significant correlations found between ChC and temperatures, derived by the chlorite-Aliv geothermometer of Cathelineau (1988), both methods may be used for estimating the approximate temperatures of metamorphism, in spite of the contrasting interpretation of chemical data from chlorites obtained by electron microprobe analyses. After determining the effects of changing bulk chemistry on chlorite composition and ChC, the chlorite crystallinity method may complement the correlation of the illite crystallinity-based zonal classification of meta-sediments and the mineral facies classification of meta-igneous rocks.

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