scholarly journals A Rheological Model for Evaluating the Behavior of Shear Thickening of Highly Flowable Mortar

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1011
Author(s):  
Mengyuan Li ◽  
Jianguo Han ◽  
Yuqi Zhou ◽  
Peiyu Yan
Keyword(s):  
Fly Ash ◽  
Yield Stress ◽  
Silica Fume ◽  
Rheological Model ◽  
Shear Thickening ◽  
Rheological Parameters ◽  
Bingham Model ◽  
Consistency Coefficient ◽  
Lubrication Layer ◽  
Binder Ratio

Neither the modified Bingham model nor the Herschel–Bulkley model can be used to characterize and calculate the performance of shear thickening of highly flowable mortar because of their incalculability of the rheological parameters. A new exponential rheological model was established to solve the characterization and calculation of shear thickening of the lubrication layer (highly flowable mortar) during the pumping of concrete in this paper. This new exponential rheological model has three rheological parameters, namely, yield stress, consistency coefficient, and consistency exponent. They can quantitatively describe the yield stress, differential viscosity, and shear thickening degree of highly flowable mortar. The calculating results of the rheological parameters of the newly established model for the mortars with different compositions showed that the consistency exponent of mortar decreased with the increase of its sand-binder ratio or the dosage of fly ash in the binder. This indicates that the shear thickening degree of mortar decreases. The consistency exponent of mortar initially decreases and subsequently increases with the increase in silica fume content or the dosage of the superplasticizer. It illustrates that the degree of the shear thickening of mortar initially decreased and subsequently increased. These varying patterns were confirmed by the rheological experiment of mortars.

scholarly journals Evolution of flow properties, plastic viscosity, and yield stress of alkali-activated fly ash/slag pastes

2020 ◽  
Vol 5 ◽  
pp. 141-149
Author(s):  
Mohammed Fouad Alnahhal ◽  
Taehwan Kim ◽  
Ailar Hajimohammadi
Keyword(s):  
Fly Ash ◽  
Yield Stress ◽  
Plastic Viscosity ◽  
Rheological Parameters ◽  
Time Intervals ◽  
Increasing Trend ◽  
Binder Ratio ◽  
Drastic Effect ◽  
Effect On Yield ◽  
Alkali Activated

The development of cementless concrete is attracting increasing attention in practice and research to reduce both greenhouse gas emissions and energy consumption of concrete. Alkali-activated materials (AAMs) are one of the viable alternatives to replace Portland cement due to their lower CO2 emissions. This study investigated the evolution of rheological parameters of alkali-activated fly ash/slag pastes as a function of time. Flowability and rheological measurements were carried out to determine the fluidity, plastic viscosity, and yield stress at different time intervals. The effects of the slag content, the concentration of SiO2 in the activator, and the solution/binder ratio were considered. Based on the results, the yield stress and plastic viscosity followed an increasing trend over time coinciding with a reduction in the paste fluidity. The plastic viscosity of AAM pastes was in the range of 1.3–9.5 Pa.s and 2.6–28.9 Pa.s after 5 min and 45 min of mixing, respectively. Given the same alkali activator, the higher content of slag the paste had, the higher yield stress the paste showed. In addition, this paper confirmed that the SiO2/Na2O ratio in the activator had no significant effect on yield stress, but a drastic effect of this ratio was found on the plastic viscosity of the paste.

scholarly journals Effect of Silica Fume on the Rheological Properties of Cement Paste with Ultra-Low Water Binder Ratio

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 554
Author(s):  
Juan He ◽  
Congmi Cheng ◽  
Xiaofen Zhu ◽  
Xiaosen Li
Keyword(s):  
Hysteresis Loop ◽  
Rheological Properties ◽  
Yield Stress ◽  
Silica Fume ◽  
Plastic Viscosity ◽  
Rheological Parameters ◽  
Loop Area ◽  
Binder Ratio ◽  
Hysteresis Loop Area ◽  
Water Binder Ratio

The effect of silica fume on the rheological properties of a cement–silica fume–high range water reducer–water mixture with ultra-low water binder ratio (CSHWM) was studied. The results indicate that the W/B ratio and silica fume content have different effects on the rheological parameters, including the yield stress, plastic viscosity, and hysteresis loop area. The shear-thickening influence of CSHWM decreased with the increased silica fume content. When the silica fume content increased from 0% to 35%, the mixture with W/B ratio of 0.19 and 0.23 changed from a dilatant fluid to a Newtonian fluid, and then to a pseudoplastic fluid. When the silica fume content was less than 15%, the yield stress was close to 0. With the increase of silica fume content, the yield stress increased rapidly. The plastic viscosity and hysteresis loop area decreased slightly with the addition of a small amount of silica fume, but increased significantly with the continuous increase of silica fume. Compared with the Bingham and modified Bingham models, the Herschel–Buckley model is more applicable for this CSHWM.

Influence of Ground Slag on the Rheology of Mortar

2013 ◽  
Vol 438-439 ◽  
pp. 67-71
Author(s):  
Qian Qian Zhang ◽  
Jian Zhong Liu ◽  
Jia Ping Liu
Keyword(s):  
Film Thickness ◽  
Specific Surface ◽  
Yield Stress ◽  
Surface Area ◽  
Specific Surface Area ◽  
Water Film ◽  
Plastic Viscosity ◽  
Rheological Parameters ◽  
Water Film Thickness ◽  
Binder Ratio

The effects of ground slag with different specific surface area on the rheology of mortar at water-binder ratio of 0.25, 0.28 and 0.30 were investigated, and the combined effects of packing density and solid surface area on the rheology of mortar were evaluated in terms of the water film thickness. The results show that with the increasing of specific surface area of slag (220 m2/kg-784 m2/kg), plastic viscosity and yield stress decrease. The correlations of yield stress and plastic viscosity to the water film thickness are basically linear with high correlation R2 values. The action of the ground slag on the rheology of mortar can be characterized by water film thickness, and with the increasing of water film thickness the rheological parameters decrease.

Effect of Fly Ash and Nano-CaCO3 on the Viscosity of Cement Paste

2013 ◽  
Vol 357-360 ◽  
pp. 968-971 ◽  
Author(s):  
Ren Juan Sun ◽  
Zhi Qin Zhao ◽  
Da Wei Huang ◽  
Gong Feng Xin ◽  
Shan Shan Wei ◽  
...  
Keyword(s):  
Fly Ash ◽  
Cement Paste ◽  
Bingham Model ◽  
Reduced Viscosity ◽  
Binder Ratio ◽  
Water To Binder Ratio

The effect of fly ash and nanoCaCO3 on the viscosity of pastes was studied. The rheological value of cement paste was determined by the rotation rheometer NXS-11B. In the study, five different dosages (0%, 20%, 30%, 40%, and 50%) of fly ash and three levels of nanoCaCO3, 0.5%, 1%, and 2.5%, were considered. Viscosity of the pastes, made with fly ash and nanoCaCO3 at a constant water-to-binder ratio of 0.35, were measured and analyzed. The results indicate that the pastes with fly ash or/and nanoCaCO3 still fit the Bingham model. The addition of fly ash reduced viscosity, however, the addition of nanoCaCO3 increased viscosity. The effect of nanoCaCO3 is more significantly than fly ash on viscosity.

High Performance Concrete with Ternary Binders

2018 ◽  
Vol 761 ◽  
pp. 120-123 ◽  
Author(s):  
Vlastimil Bílek ◽  
David Pytlík ◽  
Marketa Bambuchova
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Silica Fume ◽  
High Performance ◽  
Ordinary Portland Cement ◽  
High Performance Concrete ◽  
Fresh Concrete ◽  
Binder Ratio ◽  
Water To Binder Ratio ◽  
Condensed Silica Fume

Use a ternary binder for production of a high performance concrete with a compressive strengths between 120 and 170 MPa is presented. The water to binder ratio of the concrete is 0.225 and the binder is composed of Ordinary Portland Cement (OPC), condensed silica fume (CSF), ground limestone (L), fly ash (FA) and metakaoline (MK). The dosage of (M + CSF) is kept at a constant level for a better workability of fresh concrete. Different workability, flexural and compressive strengths were obtained for concretes with a constant cement and a metakaoline dosage, and for a constant dosage (FA + L) but a different ratio FA / L. An optimum composition was found and concretes for other tests were designed using this composition.

Creep, shrinkage, frost, and sulphate resistance of high strength concrete

1995 ◽  
Vol 22 (3) ◽  
pp. 621-636 ◽  
Author(s):  
Sujit Ghosh ◽  
K. W. Nasser
Keyword(s):  
Fly Ash ◽  
Silica Fume ◽  
Frost Resistance ◽  
High Strength Concrete ◽  
High Strength ◽  
Air Entrainment ◽  
Strength Concrete ◽  
Binder Ratio ◽  
Matrix Morphology ◽  
Creep And Shrinkage

A comprehensive study was undertaken to determine the shrinkage, creep, and durability of high strength concrete (50–70 MPa) containing silica fume and lignite fly ash. The concrete mixtures contained normal CSA type 10 (ASTM type 1) portland cement, 10% condensed silica fume, and different amounts of fly ash that varied between 0 and 80% of the weight of binder in the mixture. The aggregates-to-binder ratio by weight was maintained at 5 and the weight of the superplasticizer was varied between 1.5% and 2.2% of the binder while the water-to-binder ratio was maintained at 0.27. The test program consisted of compressive strength tests at various ages on concrete cylinders; drying shrinkage tests at room temperature; creep tests of sealed and unsealed concrete at room temperature (21 °C (70°F)) and at high temperatures (up to 232 °C (450°F)) under three different stress regimes; frost resistance tests on concrete prisms up to 300 freezing and thawing cycles; and sulphate resistance tests on concrete prisms immersed in 5% Na2SO4 solution for up to 10 months. The results indicated that up to 60% fly ash replacement with 10% silica fume showed either superior or similar 28- and 56-day compressive strengths when compared with the 100% cement control mixture. Fly ash + silica fume concrete indicated lower shrinkage and long-term creep. Creep increased with increase in temperature due to physico-chemical processes, which were confirmed by microstructure analysis using the scanning electron microscope. The creep and shrinkage data of high fly ash + silica fume concrete fitted well to the current ACI creep and shrinkage model. Replacement of cement by up to 35% fly ash and 10% silica fume indicated enhanced frost resistance, without any air-entrainment. The addition of 8% air-entrainment to the 20% fly ash + 10% silica fume mixture increased the durability factor by about 10%. For the 50% fly ash + 10% silica fume mixture, the frost durability factor was found comparable to that of the 100% cement control mixture, and air entrainment did not improve its value appreciably. Sulphate resistance of concrete made with 100% CSA type 10 cement was found satisfactory; however, with increasing fly ash contents (up to 50%), the expansion due to sulphate action was suppressed. A study of matrix morphology and microstructure bonding, using the scanning electron microscope, helped to explain the observed results in a comprehensive manner. Key words: creep, shrinkage, compressive strength, frost resistance, durability factor, sulphate resistance, fly ash, silica fume, high-strength concrete, SEM micrograph, matrix morphology.

scholarly journals Geopolymer Mortar Incorporating High Calcium Fly Ash and Silica Fume

2019 ◽  
Vol 65 (1) ◽  
pp. 3-16 ◽  
Author(s):  
V.C. Prabha ◽  
V. Revathi
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Hydroxide ◽  
Silica Fume ◽  
Sodium Hydroxide Solution ◽  
Test Results ◽  
Dense Microstructure ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Binder Ratio

AbstractAn attempt was made in the present work to study the compressive strength and microstructure of geopolymer containing high calcium fly ash (HCFA) and silica fume. Concentration of sodium hydroxide solution 8M, 10M, 12M & 14M, liquid to binder ratio 0.5 and sodium hydroxide to sodium silicate ratio 2.5 were selected for the mixes. Geopolymer mortar test results indicated that the mix with 40% silica fume by the weight of HCFA yielded higher compressive strength under ambient curing. The XRD pattern typically shows the major portion of amorphous phase of geopolymer. The existence of C-A-S-H gel, N-A-S-H gel and hydroxysodalite gel products were observed through SEM which developed dense microstructure and thus enhanced strength of HCFA and silica fume geopolymer.

Modelling the Yield Stress of Fly-Ash Added Superplasticized Cement Paste at Different Temperatures Using Artificial Neural Network

2022 ◽  
Vol 1048 ◽  
pp. 366-375
Author(s):  
Pavan Chandrasekar ◽  
Anjala Nourin ◽  
Addepalli Sri Naga Bhushana Aravind Gupta ◽  
Bavineni Venkata Jyoshna ◽  
Dhanya Sathyan
Keyword(s):  
Neural Network ◽  
Artificial Neural Network ◽  
Fly Ash ◽  
Yield Stress ◽  
Cement Paste ◽  
Test Temperature ◽  
Fresh Concrete ◽  
Rheological Parameters ◽  
Different Temperatures ◽  
Artificial Neural

Abstract: Rheology is the science that concerns the flow of liquids, and the distortion of solids under an applied force. The study of the rheology of concrete determines the properties of fresh concrete. The rheological parameters are affected by temperature, stress conditions and several other factors. The main intention of this research is to model the rheological parameters of the fly ash incorporated cement with various types of superplasticizers exposed under different temperatures using an Artificial Neural Network. Test data were generated by performing rheological tests on cement paste at three distinct temperatures (15, 27, 35°C). Mixes were prepared using OPC, fly ash (15, 25, 35%) and superplasticizers of four different families. By conducting experiments, 252 data have been generated by modifying the combination of fly-ash, superplasticizer, and test temperature. Among the 252 data, 80% has been utilized for training and 20% is utilized for predicting the model’s accuracy. The input layer of the model consists of test temperature, the amount of fly ash replaced, cement and water content, and four different groups of superplasticizers. The cement paste’s yield stress was the output parameter of the model. The model generated data has been compared with the experimentally generated data to determine the accuracy of the model.Keywords: Rheology, Fly Ash, Superplasticizer, Temperature, ANN

Ultrasound In Situ Testing of early Hydration Process of Supplementary Cementitious Pastes

2011 ◽  
Vol 477 ◽  
pp. 132-135 ◽  
Author(s):  
Zhi Yong Liu ◽  
Yun Sheng Zhang ◽  
Guo Wen Sun ◽  
Qian Jiang ◽  
Wei Wei Zhu
Keyword(s):  
Fly Ash ◽  
Silica Fume ◽  
Hydration Process ◽  
Mineral Admixtures ◽  
Early Hydration ◽  
Water To Cement Ratio ◽  
Influence Of Water ◽  
Binder Ratio ◽  
Water To Binder Ratio

The early hydration process was investigated using ultrasonic monitoring apparatus for pastes made with various mineral admixtures: silica fume (4%, 13%), slag (10%, 30%, 50%, 70%), and fly ash (10%, 30%, 50%). The influence of water to binder ratio (0.23, 0.35 and 0.53) was also studied. The results show that the hydration rate of cementitious material is obviously accelerated with decreasing in water to cement ratio and Silica fume addition, while the reverse phenomenon is observed when fly ash and slag are incorporated.

Influence of Fly Ash and Silica Fume on Anti-Corrosion Characteristics of Mortar in Sulfuric Acid

2011 ◽  
Vol 261-263 ◽  
pp. 306-312
Author(s):  
Hong Guang Min ◽  
Zhi Gang Song ◽  
Yan Tao Li ◽  
Yi Jie Shen
Keyword(s):  
Sulfuric Acid ◽  
Fly Ash ◽  
Silica Fume ◽  
Partial Correlation ◽  
Ph Value ◽  
Immersion Test ◽  
Replacement Ratio ◽  
Acid Consumption ◽  
Binder Ratio

A long term immersion test of mortar in sulfuric acid is carried out to investigate the effects of fly ash (FA) and silica fume (SF) on anti-corrosion characteristics. The mortar specimens have water to binder ratios (W/B) ranging from 0.5 to 0.7 and are divided into two series. Series one uses admixture of FA with replacement ratio from 0~0.3 and series two uses admixture of SF with replacement ratio from 0~0.1. The specimens are soaked in sulfuric acid with a pH value of 3.50 for 150 days. The portable pH meter is used to monitor the pH changing of the soak solution. The titrating sulfuric acid with concentration of 0.125mol/l is added to maintain the original pH value of the solution and then sulfuric acid consumption of specimens is recorded. A partial correlation analysis of experiment results shows that the effects of FA and SF on mortar resistance to sulfuric acid would change with the water binder ratio.

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