scholarly journals Formation of Nanostructure during Replication of a Hierarchical Plant Surface

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2811
Author(s):  
Dora Kroisová ◽  
Štěpánka Dvořáčková ◽  
Petr Kůsa

Plant and animal surfaces have become a model for preparing special synthetic surfaces with low wettability, reflectivity, or antibacterial properties. Processes that lead to the creation of replicas of natural character use two-step imprinting methods. This article describes a technique of synthetic polymer surface preparation by the process of two-stage imprinting. The laboratory-prepared structure copies the original natural pattern at the micrometer and sub-micrometer levels, supplemented by a new substructure. The new substructure identified by the scanning electron microscope is created at the nanometer level during the technological process. The nanostructure is formed only under the conditions that a hierarchical structure forms the surface of the natural replicated pattern, the replication mold is from a soft elastomeric material, and the material for producing the synthetic surface is a polymer capable of crystallizing. A new nanometer substructure formation occurs when the polymer cools to standard laboratory temperature and atmospheric pressure.

Author(s):  
RB Tyata ◽  
DP Subedi ◽  
A Shrestha ◽  
D Baral

In this paper, an atmospheric pressure plasma jet (APPJ) in air that is expected to be useful for polymer surface modification has been reported. The plasma jet was produced by applying (10 - 30) kHz, (0 - 20) kV AC source. The electrical and optical measurements have also been reported. The use of solenoid as an external electrode has been found to be more effective in boosting the jet to a distance up to 30 mm even with a small flow rate of air. The characteristic of the proposed APPJ was investigated by measuring the effect of treatment on a PE film on the jet for different exposition time and distance from the nozzle. It has been confirmed that the jet can modify polymer film with a work distance of over 25mm. This plasma jet can be useful for the treatment and cleaning of objects having large structures and could be used in wider areas of application. DOI: http://dx.doi.org/10.3126/kuset.v8i1.6035 KUSET 2012; 8(1): 15-22


2020 ◽  
Vol 8 (2) ◽  
Author(s):  
Semih Akin ◽  
Ted Gabor ◽  
Seunghwan Jo ◽  
Hangeun Joe ◽  
Jung-Ting Tsai ◽  
...  

Abstract In recent years, the metallization of polymers has been intensely studied as it takes advantage of both plastics and metals. Laser direct writing (LDW) is one of the most widely used technologies to obtain metal patterns on polymer substrates. In LDW technology, different methods including injection-molding, drop-casting, dip coating, and spin coating are utilized for surface preparation of polymer materials prior to the laser activation process. In this study, an atomization based dual regime spray coating system is introduced as a novel method to prepare the surface of the materials for LDW of metal patterns. Copper micropatterns on the polymer surface were achieved with a minimum feature size of 30 μm, having a strong adhesion and excellent conductivity. The results show that the dual regime spray deposition system can be potentially used to obtain uniform thin film coating with relatively less material consumption on the substrates for surface preparation of laser direct metallization of polymers.


Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2711
Author(s):  
Dariusz Korzec ◽  
Thomas Andres ◽  
Eva Brandes ◽  
Stefan Nettesheim

The treatment of a polymer surface using an atmospheric pressure plasma jet (APPJ) causes a local increase of the surface free energy (SFE). The plasma-treated zone can be visualized with the use of a test ink and quantitatively evaluated. However, the inked area is shrinking with time. The shrinkage characteristics are collected using activation image recording (AIR). The recording is conducted by a digital camera. The physical mechanisms of activation area shrinkage are discussed. The error sources are analyzed and methods of error reduction are proposed. The standard deviation of the activation area is less than 3%. Three polymers, acrylonitrile butadiene styrene (ABS), high-density polyethylene (HDPE), and polyoxymethylene (POM), are examined as a test substrate material. Due to a wide variation range of SFE and a small hydrophobic recovery, HDPE is chosen. Since the chemical mixtures tend to temporal changes of the stoichiometry, the pure formamide test ink with 58 mN/m is selected. The method is tested for the characterization of five different types of discharge: (i) pulsed arc APPJ with the power of about 700 W; (ii) piezoelectric direct discharge APPJ; (iii) piezoelectric driven needle corona in ambient air; (iv) piezoelectric driven plasma needle in argon; and (v) piezoelectric driven dielectric barrier discharge (DBD). For piezoelectrically driven discharges, the power was either 4.5 W or 8 W. It is shown how the AIR method can be used to solve different engineering problems.


Soft Matter ◽  
2012 ◽  
Vol 8 (28) ◽  
pp. 7323-7347 ◽  
Author(s):  
Guillaume Delaittre ◽  
Alexandra M. Greiner ◽  
Thomas Pauloehrl ◽  
Martin Bastmeyer ◽  
Christopher Barner-Kowollik

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