scholarly journals Fabrication of Environmental-Friendly Magnetite Nanoparticle Surface Coatings for the Efficient Collection of Oil Spill

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3081
Author(s):  
Mahmood M. S. Abdullah ◽  
Hamad A. Al-Lohedan

Over the past few decades, there has been an increased trend for the use of natural compounds and their derivatives as alternatives to traditional chemicals and is due to their renewability, green character, and wide availability. This work aims to convert sodium alginate (S.ALG), a natural polysaccharide, into amides through its conversion to alginic acid (H.ALG). The formed H.ALG was esterified using methanol, followed by a reaction with octadecylamine (OA) and dodecylamine (DA) to produce corresponding amides, OA-ALG, and DA-ALG, respectively. The synthesized OA-ALG and DA-ALG were used as capping agents to further form hydrophobic magnetite nanoparticles (MNPs), OA-MNPs and DA-MNPs, respectively. The chemical structures, morphology, hydrophobicity, and magnetic properties of OA-MNPs and DA-MNPs were investigated using different instrumental techniques. Furthermore, the efficacy of as-synthesized MNPs as oil spill collectors were also evaluated using different ratios of MNPs:crude oil. From the analysis of results, the OA-MNPs and DA-MNPs exhibited high efficiency in the collection of oil spill even at low ratios of MNPs:crude oil.

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1841
Author(s):  
Kang Li ◽  
Xuejie Zhang ◽  
Yan Qin ◽  
Ying Li

Aerogels have been widely used in the adsorption of pollutants because of their large specific surface area. As an environmentally friendly natural polysaccharide, cellulose is a good candidate for the preparation of aerogels due to its wide sources and abundant polar groups. In this paper, an approach to construct cellulose nanofibers aerogels with both the good mechanical property and the high pollutants adsorption capability through chemical crosslinking was explored. On this basis, TiO2 nanoparticles were loaded on the aerogel through the sol-gel method followed by the hydrothermal method, thereby the enriched pollutants in the aerogel could be degraded synchronously. The chemical cross-linker not only helps build the three-dimensional network structure of aerogels, but also provides loading sites for TiO2. The degradation efficiency of pollutants by the TiO2@CNF Aerogel can reach more than 90% after 4 h, and the efficiency is still more than 70% after five cycles. The prepared TiO2@CNF Aerogels have high potential in the field of environmental management, because of the high efficiency of treating organic pollutes and the sustainability of the materials. The work also provides a choice for the functional utilization of cellulose, offering a valuable method to utilize the large amount of cellulose in nature.


Marine Drugs ◽  
2021 ◽  
Vol 19 (6) ◽  
pp. 330
Author(s):  
Timofey V. Malyarenko ◽  
Alla A. Kicha ◽  
Valentin A. Stonik ◽  
Natalia V. Ivanchina

Sphingolipids are complex lipids widespread in nature as structural components of biomembranes. Commonly, the sphingolipids of marine organisms differ from those of terrestrial animals and plants. The gangliosides are the most complex sphingolipids characteristic of vertebrates that have been found in only the Echinodermata (echinoderms) phylum of invertebrates. Sphingolipids of the representatives of the Asteroidea and Holothuroidea classes are the most studied among all echinoderms. In this review, we have summarized the data on sphingolipids of these two classes of marine invertebrates over the past two decades. Recently established structures, properties, and peculiarities of biogenesis of ceramides, cerebrosides, and gangliosides from starfishes and holothurians are discussed. The purpose of this review is to provide the most complete information on the chemical structures, structural features, and biological activities of sphingolipids of the Asteroidea and Holothuroidea classes.


1977 ◽  
Vol 1977 (1) ◽  
pp. 15-18 ◽  
Author(s):  
James J. Reynolds

ABSTRACT The subjects under consideration are the liability imposed upon shippers, producers, refiners, and other handlers of oil, and the compensation monies available to persons damaged from oil spills. The liability and compensation system in existence today is one that provides little or no coverage in some instances, adequate coverage in some instances, and double coverage in still other instances. It has been correctly described as a “patchwork.” In the past three years, concerted efforts have been made by industry, government, and environmentalists to legislate improvements to the system. An attempt to enact a comprehensive oil spill liability and compensation law made substantial progress in the last Congress. This paper reviews the system as it now exists, the problems caused by the existing system, the proposed legislative changes, and the status of the legislation today.


2011 ◽  
Vol 2 (1) ◽  
pp. 31-34
Author(s):  
V A Perepechai ◽  
A V Zozulya ◽  
I I Skorikov ◽  
S N Dimitriadi ◽  
V N Gornostaev

A retrospective analysis of results of percutaneous nephrolithotripsy (PNLT) for corallike nephrolithiasis in lithotripter "Swiss LithoClast ® Master" and transurethral nephrolithotripsy (TUNLT). In the period 20072010 167 PNLT and 11 TUNLT were performed. Complete elimination at PNLL was achieved in 83.2% of patients, residual concretions – in 16,8% of cases, with complete elimination TUNLT – 36,4%, residual concretions – 63,6%. In 3% of patients needed for the complete elimination of the implementation of additional percutaneous accesses, while 12.6% of the patients was necessary to repeat PNLT. Complications from PNLT + DLT developed in 30,2% of cases, and when the TUNLT + DLT – in 18,2%. Percutaneous technology in comparison to open surgery with corallike nephrolithiasis can significantly shorten the postoperative rehabilitation period and be choice method of the treatment due to its high efficiency and less traumatic.


Marine Drugs ◽  
2021 ◽  
Vol 19 (11) ◽  
pp. 610
Author(s):  
Junjie Yan ◽  
Weiwei Liu ◽  
Jiatong Cai ◽  
Yiming Wang ◽  
Dahong Li ◽  
...  

Phenazines are a large group of nitrogen-containing heterocycles, providing diverse chemical structures and various biological activities. Natural phenazines are mainly isolated from marine and terrestrial microorganisms. So far, more than 100 different natural compounds and over 6000 synthetic derivatives have been found and investigated. Many phenazines show great pharmacological activity in various fields, such as antimicrobial, antiparasitic, neuroprotective, insecticidal, anti-inflammatory and anticancer activity. Researchers continued to investigate these compounds and hope to develop them as medicines. Cimmino et al. published a significant review about anticancer activity of phenazines, containing articles from 2000 to 2011. Here, we mainly summarize articles from 2012 to 2021. According to sources of compounds, phenazines were categorized into natural phenazines and synthetic phenazine derivatives in this review. Their pharmacological activities, mechanisms of action, biosynthetic pathways and synthetic strategies were summarized. These may provide guidance for the investigation on phenazines in the future.


Author(s):  
Gunnar Völkel ◽  
Simon Laban ◽  
Axel Fürstberger ◽  
Silke D Kühlwein ◽  
Nensi Ikonomi ◽  
...  

Abstract Motivation Cancer is a complex and heterogeneous disease involving multiple somatic mutations that accumulate during its progression. In the past years, the wide availability of genomic data from patients’ samples opened new perspectives in the analysis of gene mutations and alterations. Hence, visualizing and further identifying genes mutated in massive sets of patients are nowadays a critical task that sheds light on more personalized intervention approaches. Results Here, we extensively review existing tools for visualization and analysis of alteration data. We compare different approaches to study mutual exclusivity and sample coverage in large-scale omics data. We complement our review with the standalone software AVAtar (‘analysis and visualization of alteration data’) that integrates diverse aspects known from different tools into a comprehensive platform. AVAtar supplements customizable alteration plots by a multi-objective evolutionary algorithm for subset identification and provides an innovative and user-friendly interface for the evaluation of concurrent solutions. A use case from personalized medicine demonstrates its unique features showing an application on vaccination target selection. Availability AVAtar is available at: https://github.com/sysbio-bioinf/avatar Contact [email protected], phone: +49 (0) 731 500 24 500, fax: +49 (0) 731 500 24 502


2016 ◽  
Vol 3 (4) ◽  
pp. 46-67 ◽  
Author(s):  
Rhythm Walia ◽  
M.P.S. Bhatia

With the advent of web 2.0 and anonymous free Internet services available to almost everyone, social media has gained immense popularity in disseminating information. It has become an effective channel for advertising and viral marketing. People rely on social networks for news, communication and it has become an integral part of our daily lives. But due to the limited accountability of users, it is often misused for the spread of rumors. Such rumor diffusion hampers the credibility of social media and may spread social panic. Analyzing rumors in social media has gained immense attention from the researchers in the past decade. In this paper the authors provide a survey of work in rumor analysis, which will serve as a stepping-stone for new researchers. They organized the study of rumors into four categories and discussed state of the art papers in each with an in-depth analysis of results of different models used and a comparative analysis between approaches used by different authors.


Sensors ◽  
2019 ◽  
Vol 19 (11) ◽  
pp. 2488 ◽  
Author(s):  
Jessanne Y. Lichtenberg ◽  
Yue Ling ◽  
Seunghyun Kim

Non-specific adsorption (NSA) is a persistent problem that negatively affects biosensors, decreasing sensitivity, specificity, and reproducibility. Passive and active removal methods exist to remedy this issue, by coating the surface or generating surface forces to shear away weakly adhered biomolecules, respectively. However, many surface coatings are not compatible or effective for sensing, and thus active removal methods have been developed to combat this phenomenon. This review aims to provide an overview of methods of NSA reduction in biosensing, focusing on the shift from passive methods to active methods in the past decade. Attention is focused on protein NSA, due to their common use in biosensing for biomarker diagnostics. To our knowledge, this is the first review to comprehensively discuss active NSA removal methods. Lastly, the challenges and future perspectives of NSA reduction in biosensing are discussed.


2014 ◽  
Vol 14 (2) ◽  
pp. 305-312 ◽  
Author(s):  
Michael Endl ◽  
Christoph Bergmann ◽  
John Hearnshaw ◽  
Stuart I. Barnes ◽  
Robert A. Wittenmyer ◽  
...  

AbstractThe ‘holy grail’ in planet hunting is the detection of an Earth-analogue: a planet with similar mass as the Earth and an orbit inside the habitable zone. If we can find such an Earth-analogue around one of the stars in the immediate solar neighbourhood, we could potentially even study it in such great detail to address the question of its potential habitability. Several groups have focused their planet detection efforts on the nearest stars. Our team is currently performing an intensive observing campaign on the α Centauri system using the High Efficiency and Resolution Canterbury University Large Échelle Spectrograph (Hercules) at the 1 m McLellan telescope at Mt John University Observatory in New Zealand. The goal of our project is to obtain such a large number of radial velocity (RV) measurements with sufficiently high temporal sampling to become sensitive to signals of Earth-mass planets in the habitable zones of the two stars in this binary system. Over the past few years, we have collected more than 45 000 spectra for both stars combined. These data are currently processed by an advanced version of our RV reduction pipeline, which eliminates the effect of spectral cross-contamination. Here we present simulations of the expected detection sensitivity to low-mass planets in the habitable zone by the Hercules programme for various noise levels. We also discuss our expected sensitivity to the purported Earth-mass planet in a 3.24-day orbit announced by Dumusque et al. (2012).


Marine Drugs ◽  
2020 ◽  
Vol 18 (6) ◽  
pp. 321 ◽  
Author(s):  
Minghua Jiang ◽  
Zhenger Wu ◽  
Heng Guo ◽  
Lan Liu ◽  
Senhua Chen

Marine-derived fungi are a significant source of pharmacologically active metabolites with interesting structural properties, especially terpenoids with biological and chemical diversity. In the past five years, there has been a tremendous increase in the rate of new terpenoids from marine-derived fungi being discovered. In this updated review, we examine the chemical structures and bioactive properties of new terpenes from marine-derived fungi, and the biodiversity of these fungi from 2015 to 2019. A total of 140 research papers describing 471 new terpenoids of six groups (monoterpenes, sesquiterpenes, diterpenes, sesterterpenes, triterpenes, and meroterpenes) from 133 marine fungal strains belonging to 34 genera were included. Among them, sesquiterpenes, meroterpenes, and diterpenes comprise the largest proportions of terpenes, and the fungi genera of Penicillium, Aspergillus, and Trichoderma are the dominant producers of terpenoids. The majority of the marine-derived fungi are isolated from live marine matter: marine animals and aquatic plants (including mangrove plants and algae). Moreover, many terpenoids display various bioactivities, including cytotoxicity, antibacterial activity, lethal toxicity, anti-inflammatory activity, enzyme inhibitor activity, etc. In our opinion, the chemical diversity and biological activities of these novel terpenoids will provide medical and chemical researchers with a plenty variety of promising lead compounds for the development of marine drugs.


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