scholarly journals Immobilization of Hazardous Wastes on One-Part Blast Furnace Slag-Based Geopolymers

2021 ◽  
Vol 13 (23) ◽  
pp. 13455
Author(s):  
Daniela Carolina Paz-Gómez ◽  
Inês Silveirinha Vilarinho ◽  
Silvia M. Pérez-Moreno ◽  
João Carvalheiras ◽  
José Luis Guerrero ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace Slag ◽  
Wastewater Sludge ◽  
Industrial Wastes ◽  
Hazardous Wastes ◽  
Leaching Tests ◽  
Construction Sector ◽  
High Carbon ◽  
Hardened State ◽  
Furnace Slag

The immobilization of hazardous wastes in ordinary Portland cement (OPC)-based materials has been widely studied and implemented. OPC-based materials have a high carbon footprint associated with their production and geopolymer materials are a sustainable and eco-friendly alternative. Therefore, this work aimed to immobilize two hazardous industrial wastes: copper wastewater sludge and phosphogypsum in one-part geopolymer materials. For that purpose, the precursor was partially substituted by these wastes (5, 10 and 20 wt.%) in the formulations. The geopolymer fresh and hardened state properties were evaluated, and the immobilisation of pollutants was determined through leaching tests. In phosphogypsum pastes (PG5, PG10 and PG20) it was observed that the compressive strength decreased with the increase in its amount, varying between 67 MPa and 19 MPa. In copper sludge pastes, the compressive strength of the specimens (CWS5 and CWS10) reached ~50 MPa. The mortars, MPG10 and MCWSs10, had compressive strengths of 13 MPa and 21 MPa, respectively. Leaching tests showed that pastes and mortars immobilise the hazardous species of the wastes, except for As from copper sludge, whose the best result was found in the compact paste (CWSs10) that leached 2 mg/kg of As. Results suggest that optimized compositions are suitable for the construction sector.

Assessment on Physical Properties and Environmental Load Emission of Concrete Using Early Strength Activator Blast Furnace Slag

2014 ◽  
Vol 905 ◽  
pp. 388-391
Author(s):  
Taeh Young Kim ◽  
Sung Ho Tae ◽  
Jin Hyoung Kim ◽  
Keun Hyeok Yang
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Physical Property ◽  
Wastewater Sludge ◽  
Industrial Wastes ◽  
Strength Development ◽  
Environmental Load ◽  
Alternative Material ◽  
Compressive Strength Development ◽  
Furnace Slag

In relation to global warming, there is a need for development of alternative material to reduce cement use by concrete. Accordingly in this study, A-BFS (Activator Blast Furnace Slag) mixed with an activator composed of industrial wastes such as wastewater sludge and sewage sludge was developed. Physical property for compressive strength development was tested on concrete mixed with the developed A-BFS. In addition, environmental load (CO2) emission and reduction performance were analyzed on concrete mixed with A-BFS.

The Influence of the Properties of the Material Used for Obtaining Geopolymers on Their Structure and Compressive Strength

2017 ◽  
Vol 68 (6) ◽  
pp. 1182-1187
Author(s):  
Ilenuta Severin ◽  
Maria Vlad
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Wheat Straw ◽  
Red Mud ◽  
Blast Furnace Slag ◽  
Complex Structure ◽  
Point Of View ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag ◽  
Straw Ash

This article presents the influence of the properties of the materials in the geopolymeric mixture, ground granulated blast furnace slag (GGBFS) + wheat straw ash (WSA) + uncalcined red mud (RMu), and ground granulated blast furnace slag + wheat straw ash + calcined red mud (RMc), over the microstructure and mechanical properties of the synthesised geopolymers. The activation solutions used were a NaOH solution with 8M concentration, and a solution realised from 50%wt NaOH and 50%wt Na2SiO3. The samples were analysed: from the microstructural point of view through SEM microscopy; the chemical composition was determined through EDX analysis; and the compressive strength tests was done for samples tested at 7 and 28 days, respectively. The SEM micrographies of the geopolymers have highlighted a complex structure and an variable compressive strength. Compressive strength varied from 24 MPa in the case of the same recipe obtained from 70% of GGBFS + 25% WSA +5% RMu, alkaline activated with NaOH 8M (7 days testing) to 85 MPa in the case of the recipe but replacing RMu with RMc with calcined red mud, alkaline activated with the 50%wt NaOH and 50%wt Na2SiO3 solution (28 days testing). This variation in the sense of the rise in compressive strength can be attributed to the difference in reactivity of the materials used in the recipes, the curing period, the geopolymers structure, and the presence of a lower or higher rate of pores, as well as the alkalinity and the nature of the activation solutions used.

scholarly journals Waste-Based One-Part Alkali Activated Materials

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2911
Author(s):  
Margarida Gonçalves ◽  
Inês Silveirinha Vilarinho ◽  
Marinélia Capela ◽  
Ana Caetano ◽  
Rui Miguel Novais ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Microstructural Analysis ◽  
Construction Materials ◽  
Sodium Metasilicate ◽  
High Compressive Strength ◽  
Hardened State ◽  
First Time ◽  
Furnace Slag ◽  
Alkali Activated

Ordinary Portland Cement is the most widely used binder in the construction sector; however, a very high carbon footprint is associated with its production process. Consequently, more sustainable alternative construction materials are being investigated, namely, one-part alkali activated materials (AAMs). In this work, waste-based one-part AAMs binders were developed using only a blast furnace slag, as the solid precursor, and sodium metasilicate, as the solid activator. For the first time, mortars in which the commercial sand was replaced by two exhausted sands from biomass boilers (CA and CT) were developed. Firstly, the characterization of the slag and sands (aggregates) was performed. After, the AAMs fresh and hardened state properties were evaluated, being the characterization complemented by FTIR and microstructural analysis. The binder and the mortars prepared with commercial sand presented high compressive strength values after 28 days of curing-56 MPa and 79 MPa, respectively. The mortars developed with exhausted sands exhibit outstanding compressive strength values, 86 and 70 MPa for CT and CA, respectively, and the other material’s properties were not affected. Consequently, this work proved that high compressive strength waste-based one-part AAMs mortars can be produced and that it is feasible to use another waste as aggregate in the mortar’s formulations: the exhausted sands from biomass boilers.

Optimization of Concrete Porous Mix Using Slag as Substitute Material for Cement and Aggregates

2017 ◽  
Vol 865 ◽  
pp. 282-288 ◽  
Author(s):  
Jul Endawati ◽  
Rochaeti ◽  
R. Utami
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Silica Fume ◽  
Blast Furnace Slag ◽  
Environmental Effect ◽  
Substitution Effect ◽  
Main Concern ◽  
Binder Material ◽  
Furnace Slag

In recent years, sustainability and environmental effect of concrete became the main concern. Substituting cement with the other cementitious material without decreasing mechanical properties of a mixture could save energy, reduce greenhouse effect due to mining, calcination and limestone refining. Therefore, some industrial by-products such as fly ash, silica fume, and Ground Iron Blast Furnace Slag (GIBFS) would be used in this study to substitute cement and aggregate. This substitution would be applied on the porous concrete mixture to minimize the environmental effect. Slag performance will be optimized by trying out variations of fly ash, silica fume, and slag as cement substitution material in mortar mixture. The result is narrowed into two types of substitution. First, reviewed from the fly ash substitution effect on binder material, highest compressive strength 16.2 MPa was obtained from mixture composition 6% fly ash, 3% silica fume and 17% grinding granular blast-furnace slag. Second, reviewed from slag types as cement substitution and silica fume substitution, highest compressive strength 15.2 MPa was obtained from mortar specimens with air-cooled blast furnace slag. It composed with binder material 56% Portland composite cement, 15% fly ash, 3% silica fume and 26% air-cooled blast furnace slag. Considering the cement substitution, the latter mixture was chosen.

Modeling of Alteration Behavior on Blended Cementitious Materials

2011 ◽  
Author(s):  
Hitoshi Owada ◽  
Tomoko Ishii ◽  
Mayumi Takazawa ◽  
Hiroyasu Kato ◽  
Hiroyuki Sakamoto ◽  
...  
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Chemical Composition ◽  
Mineral Composition ◽  
Blast Furnace Slag ◽  
Fine Powder ◽  
Cementitious Materials ◽  
Leaching Tests ◽  
Measured Concentration ◽  
Furnace Slag

A “realistic alteration model” is needed for various cementitious materials. Hypothetical settings of mineral composition calculated based on the chemical composition of cement, such as Atkins’s model, have been used to estimate the alteration of cementitious material. However, model estimates for the concentration of certain elements such as Al and S in leachate have been different from experimental values. In a previous study, we created settings for a mineralogical alteration model by taking the initial chemical composition of cementitious materials from analysis results in experiments and applying their ratios to certain hydrated cement minerals, then added settings for secondary generated minerals in order to account for Ca leaching. This study of alteration estimates for ordinary portland cement (OPC) in groundwater showed that the change in Al and S concentrations in simulated leachate approached values for actual leachate[1]. In the present study, we develop an appropriate mineral alteration model for blended cementitious materials and conduct batch-type leaching experiments that use crushed samples of blast furnace slag cement (BFSC), silica cement (SC), and fly ash cement (FAC). The cement blends in these experiments used OPC blended with blast furnace slag of 70 wt.%, silica cement consisting of an amorphous silica fine powder of 20 wt.%, and fly ash of 30 wt.%. De-ionized water was used as the leaching solution. The solid-liquid ratios in the leaching tests were varied in order to simulate the alteration process of cement hydrates. The compositions of leachate and minerals obtained from leaching tests were compared with those obtained from models using hypothetical settings of mineral composition. We also consider an alteration model that corresponds to the diversity of these materials. As a result of applying the conventional OPC model to blended cementitious materials, the estimated Al concentration in the aqueous solution was significantly different from the measured concentration. We therefore propose an improved model that takes better account of Al behavior by using a more reliable initial mineral model for Al concentration in the solution.

scholarly journals Investigação da resistência à compressão e da resistividade elétrica de concretos com diferentes tipos de cimento

2014 ◽  
Vol 4 (2) ◽  
pp. 113-128 ◽  
Author(s):  
R. A. Medeiros-Junior ◽  
M. G. Lima ◽  
M. H. F. Medeiros ◽  
L. V. Real
Keyword(s):  
Compressive Strength ◽  
Electrical Resistivity ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Direct Influence ◽  
Absolute Value ◽  
Furnace Slag

RESUMONesse estudo foi possível observar a influência de quatro tipos de cimento brasileiros na resistência à compressão e na Resistividade Elétrica Superficial (RES) de amostras de concreto. Foram analisadas três relações água/cimento, o que resultou em doze distintas dosagens. Os resultados mostraram que os tipos de cimentos tem influência direta em ambos os ensaios. De maneira geral, quando comparado com uma série de referência, os cimentos com adição de escória de alto forno e pozolanas apresentaram redução na resistência à compressão do concreto, porém ganho na RES. O cimento com adição de pozolana é o que apresenta o maior ganho de resistência à compressão no tempo, embora tenha o menor valor absoluto. Os resultados também indicaram que a RES cresce com o tempo de ensaio e diminui com o aumento da relação a/c do concreto. Foi encontrada uma boa correlação entre os ensaios, com R² variando de 0,823 a 0,999.Palavras chaves: resistência à compressão; resistividade elétrica superficial; cimentos; escória de alto forno; pozolana.ABSTRACTThis work studied the influence of four Brazilian types of cement on the compressive strength and electrical resistivity in samples of concrete. Three water/binder ratios were analyzed, which led to the preparation of twelve different samples. The results show that the types of cement has a direct influence on both tests. In general, compared to a reference, the cements with additions of blast furnace slag and pozzolans reduced the strength, but increased the electrical resistivity. It was also observed that the cement with pozzolan showed the highest gain in strength with time, although it resulted in the lowest absolute value. The results also indicated that the electrical resistivity increases with time and decreases with higher water/binder ratios. A good correlation was found between the mentioned tests with R2 ranging from 0.823 to 0.999.Keywords: compressive strength; electrical resistivity; cements; blast fumace slag; pozzolan.

Strength Properties of Activated Hwangtoh Mortars

2010 ◽  
Vol 168-170 ◽  
pp. 709-715
Author(s):  
Dongsik Oh ◽  
Doheom Song ◽  
Seongseok Go
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Building Materials ◽  
Strength Properties ◽  
Mixing Conditions ◽  
Substitution Ratio ◽  
Pozzolanic Properties ◽  
The Relationship ◽  
Furnace Slag

Hwangtoh (loess) has pozzolanic properties that mean it can be used as a cement admixture when activated at high temperatures, and that it can be used in combination with building materials such as fly ash or blast furnace slag. This study aimed to analyze the relationship between the compressive strength and the brick bond strength of various mortars containing hwangtoh, and also to find the optimum mixing conditions for the use of hwangtoh. It was found that the mortars’ strength properties are significantly influenced by the water/cement ratio W/C and the activated hwangtoh substitution ratio. We recommend the following materials and mixing conditions: W/C 60%, a cement substitution ratio of activated hwangtoh of 20 ~ 25%, and the addition of 10% blast furnace slag to improve the compressive strength of such mortars.

scholarly journals Application areas of phosphogypsum in production of mineral binders and composites based on them: a review of research results

2018 ◽  
Vol 149 ◽  
pp. 01012 ◽  
Author(s):  
Leonid Dvorkin ◽  
Nataliya Lushnikova ◽  
Mohammed Sonebi
Keyword(s):  
Mechanical Properties ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Setting Time ◽  
Industrial Wastes ◽  
Cement Clinker ◽  
Complete Replacement ◽  
Slaked Lime ◽  
The Impact ◽  
Furnace Slag

The increase of the consumption of gypsum products in construction industry with a limited amount of natural gypsum deposits requires alternative sources of gypsum-containing raw materials. In some countries which have fertilizers industry plants, the problem can be solved using industrial wastes, e.g. phosphorgypsum – a byproduct of fertilizers’ production. Kept in dumps over decades, phosphorgypsum is subjected to the chemical changes due to washing out impurities with rain and other natural factors. However, there are observed deviations of harmful impurities in dumped PG depending on its age., Phosphorgypsum of any age requires chemical treatment to neutralize remains of phosphorus and sulfuric acids, fluorine compounds. According to our researches one of the most simple and effective method of neutralization the impurities is using lime-containing admixtures. The paper presents results of laboratory tests of phosphorgypsum as a component of clinker and non-clinker binders. There were investigated the impact of phosphorgypsum as admixture for clinker binders to substitute natural gypsum. Neutralized phosphorgypsum can be applied as mineralizing admixture in calcination of Portland cement clinker. Adding 2 to 2.5% of phosphorgypsum as setting time regulator resulted in a similar physical and mechanical properties compared to mix made with natural gypsum. Another important area of phosphorgypsum application is sulphate activatoion of low-clinker blast-furnace slag cement (clinker content is less than 19%). According to results, the incorporation of phosphorgypsum as sulphate activator in cement has the better effect as natural gypsum. Other development has been carried out to modify the phosphorgypsum binder properties. Complex additive consisted of polycarboxylate-based superplasticizer and slaked lime permitted an increase mechanical properties of hardened phosphorgypsum binder due to significant a reduction of water consumption. Such modified binder can be used as partial or complete replacement of gypsum binder for filling cements and finishing plasters. It can substitute gypsum in non-clinker binders like supersulphated cements. There were also developed compositions of supersulphated cements based on low-alumina blast furnace slag and phosphorgypsum. Supersulphated cements were tested in normal-weight and light-weight concrete.

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