scholarly journals Degradation of Diclofenac in Urine by Electro-Permanganate Process Driven by Microbial Fuel Cells

Water ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2047
Author(s):  
Xuxu Wang ◽  
Ying Wang ◽  
Jian Zhang ◽  
Pengbo Duanmu ◽  
Liushi Zheng ◽  
...  
Keyword(s):  
Microbial Fuel Cells ◽  
Density Functional ◽  
Maximum Output Power ◽  
Primary Electron ◽  
Maximum Output ◽  
Anode Chamber ◽  
Permanganate Oxidation ◽  
Oxidation Technology ◽  
Cathodic Chamber ◽  
Manganese Species

A novel microbial fuel cell-assisted electro-permanganate process (MFC-PM) was proposed for enhanced diclofenac degradation compared to that of the permanganate oxidation process. By utilizing eco-friendly bio-electricity in situ, the MFC-PM process could activate the simultaneous anodic biological metabolism of urea and the cathodic electro-permanganate process. Density functional analysis and experimental evidence revealed the reactive manganese species (Mn(VII)aq, Mn(VI)aq, Mn(V)aq, and Mn(III)aq), generated via single electron transfer, contributed to diclofenac degradation in the cathodic chamber. The sites of diclofenac with a high Fukui index were preferable to be attacked by reactive manganese species, and diclofenac degradation was mainly accomplished through the ring hydroxylation, ring opening, and decarboxylation processes. Biological detection revealed clostridia were the primary electron donor in the anode chamber in an anaerobic environment. Furthermore, maximum output power density of 1.49 W m−3 and the optimal removal of 94.75% diclofenac were obtained within 20 min under the conditions of pH = 3.0, [DCF]0 = 60 µM, and [PM]0 = 30 µM. Diclofenac removal efficiency increased with external resistance, higher PM dosage, and lower catholyte pH. In addition, the MFC-PM process displayed excellent applicability in urine and other background substances. The MFC-PM process provided an efficient and energy-free bio-electricity catalytic permanganate oxidation technology for enhancing diclofenac degradation.

Continuous Flow Microbial Fuel Cell for Organic Wastewater Treatment

2013 ◽  
Vol 777 ◽  
pp. 92-95
Author(s):  
Wei Ping Liu ◽  
Xia Fei Yin
Keyword(s):  
Wastewater Treatment ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Continuous Flow ◽  
Removal Rate ◽  
Maximum Output Power ◽  
Maximum Output ◽  
Anode Chamber ◽  
Cathode Chamber ◽  
Organic Wastewater

A continuous flow double chamber microbial fuel cell (MFC) for wastewater treatment was constructed. Anaerobic activated sludge was used as bacterial source and simulated organic wastewater was used as substrate. Effluent of anode chamber was used directly as influent of the cathode chamber. The aerobic microorganisms could degrade organic matters further. The electricity production and organic wastewater treatment of the MFC were studied. The results show that the wastewater chemical oxygen demand (COD) of the total removal rate was 74.1%~77.45%, the anode chamber in which the removal rate of COD is 32.2%~35.3%, and COD removal efficiency of aerobic biological treatment in the cathode chamber was 60.2%~66.7%. The continuous flow system could improve the removal rate further. The maximum current density of MFC was 1.56 mAm-2, the maximum output power was 24.336 mWm-2.

scholarly journals Rainwater-driven microbial fuel cells for power generation in remote areas

2021 ◽  
Vol 8 (11) ◽  
Author(s):  
Mohamed Taha Amen ◽  
Ahmed S. Yasin ◽  
Mohamed I. Hegazy ◽  
Mohammad Abu Hena Mostafa Jamal ◽  
Seong-Tshool Hong ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Microbial Fuel Cells ◽  
Maximum Output Power ◽  
Cell Voltage ◽  
Open Circuit ◽  
Bacterial Biofilm ◽  
Anode Surface ◽  
Maximum Output ◽  
Anaerobic Conditions ◽  
Cyclic Voltammetry Analysis

The possibility of using rainwater as a sustainable anolyte in an air-cathode microbial fuel cell (MFC) is investigated in this study. The results indicate that the proposed MFC can work within a wide temperature range (from 0 to 30°C) and under aerobic or anaerobic conditions. However, the rainwater season has a distinct impact. Under anaerobic conditions, the summer rainwater achieves a promised open circuit potential (OCP) of 553 ± 2 mV without addition of nutrients at the ambient temperature, while addition of nutrients leads to an increase in the cell voltage to 763 ± 3 and 588 ± 2 mV at 30°C and ambient temperature, respectively. The maximum OCP for the winter rainwater (492 ± 1.5 mV) is obtained when the reactor is exposed to the air (aerobic conditions) at ambient temperature. Furthermore, the winter rainwater MFC generates a maximum power output of 7 ± 0.1 mWm −2 at a corresponding current density value of 44 ± 0.7 mAm −2 at 30°C. While, at the ambient temperature, the maximum output power is obtained with the summer rainwater (7.2 ± 0.1 mWm −2 at 26 ± 0.5 mAm −2 ). Moreover, investigation of the bacterial diversity indicates that Lactobacillus spp. is the dominant electroactive genus in the summer rainwater, while in the winter rainwater, Staphylococcus spp. is the main electroactive bacteria. The cyclic voltammetry analysis confirms that the electrons are delivered directly from the bacterial biofilm to the anode surface and without mediators. Overall, this study opens a new avenue for using a novel sustainable type of MFC derived from rainwater.

scholarly journals Simultaneous Removal of Trivalent Arsenic and Nitrate Using Microbial Fuel Cells

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 673
Author(s):  
Jing Guo ◽  
Jianping Cheng ◽  
Jiaquan Wang ◽  
Shuheng Hu
Keyword(s):  
Fuel Cells ◽  
Microbial Fuel Cells ◽  
Removal Rate ◽  
Electric Energy ◽  
Bacterial Biomass ◽  
Reference Value ◽  
Stable Operation ◽  
Maximum Output ◽  
Anode Chamber ◽  
Trivalent Arsenic

A rectangular double chamber with trivalent arsenic as the electron donor of the biological anode was constructed by microbial fuel cells (MFC), and the feasibility of the MFC simultaneous degradation of trivalent arsenic and nitrate was studied. Experimental results show that the co-matrix-coupled MFC reactor oxidizes trivalent arsenic in an anode chamber and degrades nitrate in the cathode chamber. The removal rate of trivalent arsenic is about 63.35%, and the degradation rate of nitrate is about 55.95% during the complete and stable operation period. MFC can continuously output electric energy, and the maximum output voltage is 388 mV. We compared and analyzed the main functional microflora of biofilm microorganisms in an anode chamber. In the long-term arsenic-polluted environment, the activity of Acinetobacter, Pseudomonas bacteria with arsenic resistance, was improved. It is inferred that a fraction of trivalent arsenic was oxidized to pentavalent arsenic by electrode-attached microorganisms. While remaining trivalent, arsenic was taken up by the suspended bacterial biomass and converted into stable arsenide. The results of this study have theoretical reference value for the expansion of the MFC application scope.

Characterization of microwave-sintered ceramic composites

1993 ◽  
Vol 51 ◽  
pp. 1136-1137
Author(s):  
X. Zhang ◽  
Y. Pan ◽  
T.T. Meek
Keyword(s):  
Matrix Material ◽  
Maximum Output Power ◽  
Ceramic Matrix Composite ◽  
Ceramic Composites ◽  
Processing Technique ◽  
Structure Characterization ◽  
Alumina Powder ◽  
Maximum Output ◽  
Sintered Ceramic

Industrial microwave heating technology has emerged as a new ceramic processing technique. The unique advantages of fast sintering, high density, and improved materials properties makes it superior in certain respects to other processing methods. This work presents the structure characterization of a microwave sintered ceramic matrix composite.Commercial α-alumina powder A-16 (Alcoa) is chosen as the matrix material, β-silicon carbide whiskers (Third Millennium Technologies, Inc.) are used as the reinforcing element. The green samples consisted of 90 vol% Al2O3 powder and 10 vol% ultrasonically-dispersed SiC whiskers. The powder mixture is blended together, and then uniaxially pressed into a cylindrical pellet under a pressure of 230 MPa, which yields a 52% green density. The sintering experiments are carried out using an industry microwave system (Gober, Model S6F) which generates microwave radiation at 2.45 GHz with a maximum output power of 6 kW. The composites are sintered at two different temperatures (1550°C and 1650°C) with various isothermal processing time intervals ranging from 10 to 20 min.

scholarly journals One-Step Preparation of Biochar Electrodes and Their Applications in Sediment Microbial Electrochemical Systems

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 508
Author(s):  
Kui You ◽  
Zihan Zhou ◽  
Chao Gao ◽  
Qiao Yang
Keyword(s):  
Output Power ◽  
Electrode Materials ◽  
Maximum Output Power ◽  
Composite Cathode ◽  
Maximum Output ◽  
Electrochemical Systems ◽  
Composite Cathodes ◽  
One Step ◽  
Microbial Electrochemical Systems ◽  
Hot Melt

Biochar is a kind of carbon-rich material formed by pyrolysis of biomass at high temperature in the absence or limitation of oxygen. It has abundant pore structure and a large surface area, which could be considered the beneficial characteristics for electrodes of microbial electrochemical systems. In this study, reed was used as the raw material of biochar and six biochar-based electrode materials were obtained by three methods, including one-step biochar cathodes (BC 800 and BC 700), biochar/polyethylene composite cathodes (BP 5:5 and BP 6:4), and biochar/polyaniline/hot-melt adhesive composite cathode (BPP 5:1:4 and BPP 4:1:5). The basic physical properties and electrochemical properties of the self-made biochar electrode materials were characterized. Selected biochar-based electrode materials were used as the cathode of sediment microbial electrochemical reactors. The reactor with pure biochar electrode (BC 800) achieves a maximum output power density of 9.15 ± 0.02 mW/m2, which increases the output power by nearly 80% compared with carbon felt. When using a biochar/polyaniline/hot-melt adhesive (BPP 5:1:4) composite cathode, the output power was increased by 2.33 times. Under the premise of ensuring the molding of the material, the higher the content of biochar, the better the electrochemical performance of the electrodes. The treatment of reed powder before pyrolysis is an important factor for the molding of biochar. The one-step molding biochar cathode had satisfactory performance in sediment microbial electrochemical systems. By exploring the biochar-based electrode, waste biomass could be reused, which is beneficial for the environment.

scholarly journals Novel Heat-Mitigating Chip-on-Probe for Brain Stimulation Behavior Experiments

Sensors ◽  
2020 ◽  
Vol 20 (24) ◽  
pp. 7334
Author(s):  
Seongwoog Oh ◽  
Jungsuek Oh
Keyword(s):  
Brain Stimulation ◽  
Heat Sink ◽  
Transmission Loss ◽  
Maximum Output Power ◽  
Circuit Board ◽  
Oxide Semiconductor ◽  
Normal Operation ◽  
Cmos Process ◽  
Maximum Output ◽  
The Brain

This paper proposes a novel design for a chip-on-probe with the aim of overcoming the heat dissipation effect during brain stimulations using modulated microwave signals. The temperature of the stimulus chip during normal operation is generally 40 °C–60 °C, which is sufficient to cause unintended temperature effects during stimulation. This effect is particularly fatal in brain stimulation applications that require repeated stimulation. This paper proposes, for the first time, a topology that vertically separates the stimulus chip generating the stimulus signal and the probe delivering the signal into the brain to suppress the heat transfer while simultaneously minimizing the radio frequency (RF) transmission loss. As the proposed chip-on-probe should be attached to the head of a small animal, an auxiliary board with a heat sink was carefully designed considering the weight that does not affect the behavior experiment. When the transition structures are properly designed, a heat sink can be mounted to maximize the cooling effect, reducing the temperature by more than 13 °C in a simulation when the heat generated by the chip is transferred to the brain, while the transition from the chip to the probe experiences a loss of 1.2 dB. Finally, the effectiveness of the proposed design is demonstrated by fabricating a chip with the 0.28 μm silicon-on-insulator (SOI) complementary metal–oxide–semiconductor (CMOS) process and a probe with a RT6010 printed-circuit board (PCB), showing a temperature reduction of 49.8 °C with a maximum output power of 11 dBm. In the proposed chip-on-probe device, the temperature formed in the area in contact with the brain is measured at 31.1 °C.

scholarly journals Study of the Properties of a Hybrid Piezoelectric and Electromagnetic Energy Harvester for a Civil Engineering Low-Frequency Sloshing Environment

Energies ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 391
Author(s):  
Nan Wu ◽  
Yuncheng He ◽  
Jiyang Fu ◽  
Peng Liao
Keyword(s):  
Output Power ◽  
Energy Harvester ◽  
Civil Engineering ◽  
Maximum Output Power ◽  
Low Frequency ◽  
Electromagnetic Energy ◽  
Maximum Output ◽  
Piezoelectric Film ◽  
Hybrid Energy ◽  
Level Height

In this paper a novel hybrid piezoelectric and electromagnetic energy harvester for civil engineering low-frequency sloshing environment is reported. The architecture, fabrication and characterization of the harvester are discussed. The hybrid energy harvester is composed of a permanent magnet, copper coil, and PVDF(polyvinylidene difluoride) piezoelectric film, and the upper U-tube device containing a cylindrical fluid barrier is connected to the foundation support plate by a hinge and spring. The two primary means of energy collection were through the vortex street, which alternately impacted the PVDF piezoelectric film through fluid shedding, and the electromotive force (EMF) induced by changes in the magnetic field position in the conducting coil. Experimentally, the maximum output power of the piezoelectric transformer of the hybrid energy harvester was 2.47 μW (circuit load 270 kΩ; liquid level height 80 mm); and the maximum output power of the electromagnetic generator was 2.72 μW (circuit load 470 kΩ; liquid level height 60 mm). The low-frequency sloshing energy collected by this energy harvester can drive microsensors for civil engineering monitoring.

scholarly journals The Investigation on Ultrafast Pulse Formation in a Tm–Ho-Codoped Mode-Locking Fiber Oscillator

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3460
Author(s):  
Jingcheng Shang ◽  
Yizhou Liu ◽  
Shengzhi Zhao ◽  
Yuefeng Zhao ◽  
Yuzhi Song ◽  
...  
Keyword(s):  
Maximum Output Power ◽  
Single Pulse ◽  
Mode Locking ◽  
Maximum Output ◽  
Polarization Rotation ◽  
Nonlinear Polarization ◽  
Soliton Pulse ◽  
Proper Design ◽  
Nonlinear Polarization Rotation ◽  
Pulse Formation

We experimentally investigate the formation of various pulses from a thulium–holmium (Tm–Ho)-codoped nonlinear polarization rotation (NPR) mode-locking fiber oscillator. The ultrafast fiber oscillator can simultaneously operate in the noise-like and soliton mode-locking regimes with two different emission wavelengths located around 1947 and 2010 nm, which are believed to be induced from the laser transition of Tm3+ and Ho3+ ions respectively. When the noise-like pulse (NLP) and soliton pulse (SP) co-exist inside the laser oscillator, a maximum output power of 295 mW is achieved with a pulse repetition rate of 19.85-MHz, corresponding to a total single pulse energy of 14.86 nJ. By adjusting the wave plates, the fiber oscillator could also deliver the dual-NLPs or dual-SPs at dual wavelengths, or single NLP and single SP at one wavelength. The highest 61-order harmonic soliton pulse and 33.4-nJ-NLP are also realized respectively with proper design of the fiber cavity.

LD-pumped high-power continuous-wave Pr3+:YLF deep red lasers at 718.5 and 720.8 nm

Laser Physics ◽  
2021 ◽  
Vol 32 (2) ◽  
pp. 025801
Author(s):  
Xiangrui Liu ◽  
Zhuang Li ◽  
Chengkun Shi ◽  
Bo Xiao ◽  
Run Fang ◽  
...  
Keyword(s):  
Output Power ◽  
High Power ◽  
Slope Efficiency ◽  
Laser Emission ◽  
Continuous Wave ◽  
Optical Glass ◽  
Maximum Output Power ◽  
Glass Plate ◽  
Maximum Output ◽  
First Time

Abstract We demonstrated 22 W LD-pumped high-power continuous-wave (CW) deep red laser operations at 718.5 and 720.8 nm based on an a-cut Pr3+:YLF crystal. The output power of both polarized directions reached the watt-level without output power saturation. A single wavelength laser operated at 720.8 nm in the π-polarized direction was achieved, with a high output power of 4.5 W and high slope efficiency of approximately 41.5%. To the best of our knowledge, under LD-pumped conditions, the laser output power and slope efficiency are the highest at 721 nm. By using a compact optical glass plate as an intracavity etalon, we suppressed the π-polarized 720.8 nm laser emission. And σ-polarized single-wavelength laser emission at 718.5 nm was achieved, with a maximum output power of 1.45 W and a slope efficiency of approximately 17.8%. This is the first time that we have achieved the σ-polarized laser emission at 718.5 nm generated by Pr3+:YLF lasers.

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