CHEMICAL CORROSION PROCESSES OCCURRING IN THE MATERIAL OF LARGE-BLOCK POROUS CERAMICS

2021 ◽  
Vol 97 (5) ◽  
pp. 93-105
Author(s):  
D.Y. ZHELDAKOV ◽  
◽  
S.A. TURSUKOV ◽  
I.R. KHUSAINOV ◽  
◽  
...  

Large-block porous ceramics, which enter the market of building materials, have a number of undeniable qualities: low thermal conductivity, low density, high aesthetic qualities. According to its design features, this material is a modern prototype of hollow bricks used in construction since the nineteenth century. Field studies of the work of enclosing structures using hollow bricks have shown that in many cases, the bricks laid in the enclosing structures of buildings 60-80 years ago were significantly destroyed. In this case, the destruction mechanism does not depend on the polythermal load on the material. The hypothesis that the destruction is associated with the chemical destruction of the material was investigated using the developed method for determining the chemical resistance of the material of wall ceramics. The conducted studies confirmed the hypothesis. Studies of the chemical resistance of the material of large-block porous ceramics should be taken into account in the production technology of ceramics.

2021 ◽  
Vol 02 ◽  
Author(s):  
Pernille D. Pedersen ◽  
Nina Lock ◽  
Henrik Jensen

: The NOx gasses (NO and NO2) are among the most important air pollutants, due to the toxicity of NO2, as well as the role of NOx in the tropospheric oxidation of Volatile Organic Carbons (VOCs), contributing to the formation of other hazardous air pollutants. Air pollution is one of the biggest health threats world-wide, hence reducing NOx levels is an important objective of the UN sustainable development goals, e.g. #3, “Good health and well-being” and #11 “Sustainable cities and communities”. Photocatalysis using TiO2 and light is a promising technique for removing NOx along with other pollutants, as demonstrated on laboratory scale. Furthermore, a long range of real-life test studies of varying scales have been conducted during the past two decades. The results of these studies have been conflicting, with some studies reporting no effect on the ambient air quality and others reporting significant reductions of NOx level. However, the studies are very difficult to compare and assess due to the very different approaches used, which consequently vary in quality. In this review, we aim to develop a set of objective evaluation criteria to assess the quality of the individual studies in order to simplify the interpretation and comparison of the existing studies. Moreover, we propose some guidelines for future test-studies. Furthermore, the approaches and main conclusions from 23 studies are independently assessed and discussed herein.


2010 ◽  
Vol 63 ◽  
pp. 147-151 ◽  
Author(s):  
David A. Schiraldi ◽  
Matthew D. Gawryla ◽  
Saeed Alhassan

A simple, inexpensive, and environmentally-friendly process for converting mixtures of clays and polymers has been developed. Polymer and clay are combined in water, and the mixtures are freeze dried to produce materials which have bulk densities typically in the range of 0.03 – 0.15 g/cm3. These low density polymer/clay aerogel materials possess good mechanical properties similar to those of traditional polymer foams, can be reinforced with fibers, modified with nanoparticles, biomineralized, or converted into porous ceramics.


2020 ◽  
Vol 185 ◽  
pp. 04042
Author(s):  
Tao Tian ◽  
Shanyu Liu ◽  
Rong Wang ◽  
Ying Lei ◽  
Changlin Zheng

Chemical resistance is one of the important evaluation factors of ceramic tiles. This article describes the method for determining the chemical resistance of ceramic tiles, and discusses the influence of acid-base solution concentration on the test results during the experiment, and proposes corresponding improvement measures.


2016 ◽  
Vol 852 ◽  
pp. 1482-1487
Author(s):  
Fan Cheng ◽  
Yu Hao Jiang ◽  
Jin Bo Chen ◽  
Peng Bo Lu ◽  
Ling Feng Su ◽  
...  

Eco-friendly building materials with perfect thermal insulation & sound absorption property have become intriguing and eye-catching in recent years. In this work, the ultra low-density binderless sandwiching materials were firstly fabricated with ultra low-density of 60-80 kg/m3 by self-designed rapid steam injection technology. The main experimental factor of density, holding time, transmission time, steam injection pressure and fiber’s dimension was respectively investigated to their effects on formation of the new building materials. IR, Py GC-MS and AFM analysis were performed to study the mechanism of binderless sandwiching materials under steam injection process. The bending strength, thermal insulation & sound absorption property of the new materials were also studied. This new building material with no resin use and no formaldehyde release is expected to be reserved as the sandwich for designing thermal insulation & noise reduction building materials.


2016 ◽  
Vol 690 ◽  
pp. 150-155 ◽  
Author(s):  
Toyohiko Sugiyama ◽  
Keiji Kusumoto ◽  
Masayoshi Ohashi ◽  
Akinori Kamiya

The global warming is one of the most serious problems. The decrease of CO2 emissions in our daily life is an important subject today. Recently, an application of water retentive materials as a paving material has attracted a great deal of attention in Japan. This material is effective for reducing heat island phenomenon, which is also a recent problem in many cities in Japan. Water retained in the material during rainfall evaporates when heated by sunshine. The latent heat absorbed by evaporating water works to cool the surroundings. The water retentive ceramic products are expected to be useful for building materials as well as pavements. Several performances are required on the water retentive ceramics when it is used as building materials. Its cost and quality are the important factors. Porous ceramic materials formed by pressing without firing is one of ideal low cost and eco-friendly candidates. The porous ceramics is also expected to be produced from recycled ceramic materials. By optimizing its composition and forming method, a water retentive material with high performance was developed. The trial product had the properties as follows; fracture toughness: 1300N, bending strength: 175N/cm, water absorption: larger than 30%, and precision in size (length): +-0.5mm for 150mm. The product showed also enough frost resistance. In this paper, the fundamental properties of the porous ceramics prepared without firing are discussed with referring to the results of the field experiments.Another subject recently studied by several tile manufactures in Japan is the glazed tile with high solar reflectance. The exterior walls covered with such a high solar reflectance tile keeps the surface temperature of the wall lower under the strong sunshine of summer. It is effective against heat-island phenomenon. In this paper, the outline of the research results on visible and infrared reflectance of many kinds of glazes is also discussed.


2018 ◽  
Vol 195 ◽  
pp. 01022 ◽  
Author(s):  
Muh. Yamin ◽  
Rudito ◽  
Andi Lisnawati ◽  
Mohammad Lutfi

The accumulation of rice husks (RH), oil palm empty fruit bunch (OPEFB), and plastic waste (PW) can reduce the fertility of the soil. The objective of this study was to compare the quality of the low density particle boards using that waste. Experimental design was used by testing the quality of particle boards with a substitution of 50 % by weight of the total mixes for each waste (RH and OPEFB) and 50% of PW with 3 replications. The results revealed that the quality of the low density particle boards based on water content, density, and modulus of rupture (MOR) tests meet the requirements of SNI 03-2105-2006, whereas the modulus of elasticity (MOE), thickness swelling, water absorption, and the tension perpendicular to surface tests do not comply to the requirements. This preliminary study revealed that the quality of particle boards using OPEFB was better than the particle boards using RH for building materials such as ceilings.


2017 ◽  
Vol 18 (1) ◽  
pp. 203-213 ◽  
Author(s):  
Chengchao Guo ◽  
Xuanxuan Chu ◽  
Fuming Wang

Abstract Tailings reservoirs generally consist of a tailings dam, a tailings conveying system and a drainage system, which are indispensable facilities and provide security and environmental protection for storing tailings and clarifying water in some industries (e.g., metallurgy, non-ferrous building materials, nuclear and chemical industries). Consequently, consolidating seepage prevention and treatment is important. When applied to seepage prevention works for tailings reservoirs, current seepage prevention technologies can cause destruction of the dam and require further construction sites. It is therefore essential to adopt new types of advanced and practical technologies. Aimed at studying the feasibility of the application of non-water reaction polymer grouting technology in seepage prevention of tailings reservoirs and acquiring the properties for practical engineering, an analysis of the environmental impact, chemical resistance and permeability of the polymer material, and the main technical characteristics of the polymer cutoff wall was conducted. The test results showed that the polymer grouting technology applied to seepage prevention works of a tailings reservoir caused little disturbance to the dam, possessed good anti-seepage performance and perfect durability. This study may provide a reference for the seepage control of tailings reservoirs.


2021 ◽  
Vol 2 (2) ◽  
pp. 1-8
Author(s):  
Arslanov Islom Kimsanovich

This scientific article provides physicochemical studies where the addition of a gel polymer has a positive effect on the process of structure formation. The presence of chemical bonds between the components, a change in the morphology of the structure, a decrease in microporosity, an increase in the density and thermal stability of the urea composition are shown. Polymer composite materials are used as chemically resistant coatings, polymer mortars and polymer concretes. Along with such valuable properties as incombustibility, colorlessness, good miscibility with water, etc., urea resins and compositions based on them have a number of disadvantages. The object of the study is a carbamide composition with a quartz filler and an addition of a gel polymer, its structure formation and chemical resistance. The methodological basis of the study is the polystructural theory of composite building materials (CBM) and the modeling of the study of the chemical resistance of the urea composition in aggressive conditions. The issues of finding effective water-binding additives and studying their effect on structure formation, properties and technology of urea compositions remain relevant and require additional research. It is shown that with the optimal content of the gel-polymer additive in the composition of 0.13% of the filler weight, the compressive strength and specific impact strength increase by 17; 13% and shrinkage is reduced by 7%. It was found that due to the enhancement of the adhesive bond between the components and the improvement of the pore structure under the action of the gel-polymer additive, the chemical resistance of the urea composition with quartz filler increases. So, water, acid and alkali resistance are 0.75; 0.80 and 0.85 and which, respectively, are 6, 7 and 7 points higher than the reference composition.


2021 ◽  
Author(s):  
Abdelrhman Muhamed Fahmy Sayed Ahmed ◽  
Fatma Muhamed Helmy

Abstract Abusir is the name of an elaborate burial area, dotted with 19 pyramids other temples, stretching on the western side of the Nile from the south of the Giza Plateau to the northern rim of Saqqara. It seems to have been created as the resting site for the Pharaos dated from 2494 to 2345 BC. The name Abusir, originally spoken as Busiri, means” temple of Osiris”. Over time, the name has become so popular, that more than 60 villages now carry this name. But only one is the archaeological site. This paper does not refer to all of the Abusir archaeological area, but focuses one of its most important sites: Sahure pyramid, one of Egypt’s little known, but heavily damaged treasure. One of the highlights of the relevant research is the discovery of a piece of cement (Basaltic mortar/concrete), which consists of several materials and which is harder than any cement produced today and detection of a clear and significant Anorthite mineral (Plagioclase) in the mortar sample which had been proven by XRD, XRF (analysis) and Polarized light microscope (investigation). The main objectives of this paper are 1) to reveal and identify the construction materials of the pyramid and the construction of the pyramid,2) to evaluate the durability and vulnerability of the Ancient construction materials of Sahure pyramid,3) to compare the decayed patterns of the different construction materials, 4) to study the pyramid building materials from geological, meteorological, geochemical, petrological and petrophysical point of view, and 5) to present a proposal for scientific conservation and protection of the pyramid. Laboratories and field studies have been carried out by researchers from various countries to investigate and understand the problems of the pyramid leading to the final results which confirmed the impact of the geo environment conditions on the structural and engineering stability of the pyramid.


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