scholarly journals Resource-saving Technology for Disposal of Phenol-containing Industrial Wastewater Decontamination

Author(s):  

We have developed a resource-saving, low-waste technology for the disposal of highly toxic phenol-containing wastewater that enables to utilize phenol and formaldehyde as an organic binder. The technology involves the use of technogenic raw materials («overresin» water from the production of phenol-formaldehyde resins, soft wood waste, waste from the production and processing of laminated plastics) and processes of regeneration, recovery and conversion of phenol. The optimal technological parameters of phenol sorption on wood sorbent and secondary poly/condensation were experimentally established. This in turn provides a high degree of neutralization and extraction of resin-forming components from wastewater and subsequent production wood-polymer thermoplastic structural composite and sodium phenolate on their basis.

Author(s):  
O. Yu. Kichigina

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.


2021 ◽  
Vol 13 (2) ◽  
pp. 224-237
Author(s):  
Valentin CHANTURIA ◽  
◽  
Irina SHADRUNOVA ◽  
Olga GORLOVA ◽  
◽  
...  

Innovative processes of deep and complex processing of technogenic raw materials in the context of sustainable development of the mining industry and the economic challenges facing the mining industry should ensure the transition to a circular economy and the maximum use of natural resources. The article reflects the priority scientific and technological research on the involvement of technogenic mineral resources in efficient processing. Presented, developed at ICEMR RAS, including jointly with universities, research and production organizations and enterprises, modern innovative processes of deep and environmentally friendly processing of refractory mineral raw materials of complex material composition (tailings of enrichment of non-ferrous and noble metal ores, poor off-balance ores, slags ferrous and nonferrous metallurgy, sludge of metallurgical production) and hydro-mineral technogenic resources (acidic mineralized bottom-dump waters of mining enterprises of the copper-zinc complex of the Urals, saponite-containing circulating waters of diamond processing factories). Among other things, new directions in the field of selective disintegration of finely dispersed mineral raw materials based on energy effects and deep processing of slags are outlined; increasing the selectivity of enrichment processes; combined processing of technogenic raw materials; resource-saving processing of technogenic and hydro-mineral resources, obtaining secondary products from processing waste. It is shown that in the face of new economic challenges, Russia has sufficient scientific and technological potential in the field of deep and environmentally safe processing of technogenic raw materials in the form of developed and, to varying degrees, tested innovative resource-saving technologies that correspond to the world level, and in a number of technologies are superior to it.


2018 ◽  
Vol 4 ◽  
pp. 42-49
Author(s):  
Alexandra Niemirich ◽  
Oksana Vasheka ◽  
Oksana Petrusha ◽  
Nikolay Pogozhikh

One of the resource-saving methods of drying, from the point of view of preserving food and biological value, providing the appropriate recovery properties of dried food products (DFP) and energy intensity of the process, is drying with mixed heat supply (MHS drying). The scientific concept of work on the formation of a universal and DFP stable functional and technological potential is formulated, which is the basis for modeling and designing the formulation composition and technology of food products by groups and types with its use or interchangeability. As the subject of research for the formation of quality indicators of cereals, white cabbage is selected, as it is a typical vegetable for Ukraine and accordingly has a high degree of assimilation of natural micronutrients in the human body. Structural studies have shown the predominantly crystalline structure of polysaccharides, that is, less than their transformation under conditions of MHS drying, as compared with convective conditions. The effect of MHS drying on the formation of DFP quality indicators is determined by the method of recording IR spectra with Fourier transform. For studies of the violation of total internal reflection, it has been established that the process of DFP reduction leads to an increase in the availability of organic substances in the solvent, which will facilitate the extraction of extractives in the recovery of raw materials. It is established by the number of aroma, the more aromatic-forming substances are contained in the MHS drying samples irrespective of the process temperature, less in the dried samples of the convective method. This is due to the reduction of thermal and thermal effects during MHS drying, which slows down chemical transformations and removes aromatic substances. It is proved by the tensometric method, with the convective method due to shrinkage during dehydration, the changes during sorption and desorption are insignificant. When MHS drying, such changes are expressed: during the sorption of vapors, DFP is well restored, the capillaries swell, so the differential distribution function of the pores expands, the average radius of the capillaries increases 4 ... 6 times. The research results make it possible to form the functional and technological parameters of cabbage powder, to simulate the formulation of new food products with this ingredient and to optimize the production technology.


2018 ◽  
Vol 284 ◽  
pp. 1058-1062 ◽  
Author(s):  
Margarita A. Goncharova ◽  
R.A. Gorin ◽  
O.V. Karaseva

The results of the formation of curing systems based on finely dispersed converter slags are given, the structural and technological parameters influencing their quality are shown and analyzed. Special attention is paid to the development of optimum binding compositions based on such curing systems with an account of technogenic raw materials applied. The experimental results enable one to recommend it for modification of concrete and concrete mixtures in the production of both construction and repair work at the facilities of industrial enterprises, residential buildings, houses, boiler house foundations, etc.


2021 ◽  
Vol 4 (1) ◽  
pp. 131-137
Author(s):  
D. P. Kindzera ◽  
◽  
V. M. Atamaniuk ◽  
Z. Ya. Gnativ ◽  
I. M. Mitin ◽  
...  

In Ukraine, along with the growing demand for tonnage production of light fillers, the need for raw materials is growing, considering that most of the range of light fillers is made from natural raw materials. Thus, a promising direction of utilization of TPP slags and coal concentrate obtained by enrichment of primary coal sludge is there involvement to the production process after preliminary drying. Drying of the thermal power plant slag and the coal concentrate, which are hydraulic mixtures, by the filtration method will reduce energy consumption due to the displacement and removal of significant amount of moisture by the moving thermal agent due to the pressure drop. The results of studies of the thermal agent velocity effect on the drying process duration of TPP slag and coal concentrate, as well as the obtained values of heat transfer coefficients at different velocities of the thermal agent for TPP slag α = 40 ÷ 112 and coal concentrate α = 92,5 ÷ 294 will allow to calculate energy consumption and scientifically substantiate the optimal technological parameters for intensification of the drying process of the charge components for porous fillers production.


2019 ◽  
Vol 974 ◽  
pp. 379-385
Author(s):  
Alexander E. Fomin ◽  
Ruslan V. Lesovik ◽  
E.S. Glagolev ◽  
Sergey V. Biryukov

The paper investigates the surface wet magnetic separation (WMS) technogenic raw materials concentration tailings particles properties. The mechanical activation effect nature on the binder structural and phase characteristics is revealed. High pozzolan activity of WMC tails, which consists in genetic and morphological features of the surface of poly-mineral structures has been established. During mechanical activation of lime together with WMS tailings, an increase in the number of neoplasms occurs in the amorphous phase form with a low degree of polymerization, which is confirmed by the acid-soluble SiO2presence, as well as by X-ray phase analysis. The work results indicate a WMC waste particles surface high energy potential for its use in building materials for autoclaved hardening. This study will contribute to the energy and resource-saving technologies development, the solution of environmental problems in order to create a comfortable environment for life and work.


Author(s):  
I.O. Mikulionok

Advantages of use of a wood filler as a component of thermoplastic composite materials (TpCM) with use of a polymeric matrix are considered. The analysis of design of an area of preparation of wood and polymeric composition melt is made. Rational options of design of process of extrusion preparation and formation of TpCM are defined, their advantages and disadvantages are shown. The description of the industrial line for production of wood and polymeric sheets is provided. Recommendations about use of extrusive installations for processing TpCM are made (use of extrusion lines on the basis of a single-screw extruder, and for receiving production with increased requirements to quality – cascade schemes with a twin-screw extruder is preferable). Pictures of finished goods, and also rheological characteristics of wood and polymeric composition melt depending on structure and temperature are given. It is also shown that rheological characteristics of the filled TpCM with use of secondary polymeric raw materials can significantly differ from the corresponding characteristics of primary polymers. Bibl. 28, Fig. 2.


Author(s):  
А. С. Успанова ◽  
З. Х. Исмаилова ◽  
В. Х. Хадисов ◽  
М. Р. Хаджиев

Вопросы ресурсосбережения являются приоритетными в промышленности строительных материалов и изделий, все большее распространение получает применение техногенного сырья в строительных композитах. Это диктуется необходимостью утилизации техногенных отходов, повышением экономической эффективности производств и вопросами защиты окружающей среды. Особый интерес в проектировании составов строительных растворов представляет применение местных некондиционных песков, техногенных песков из отсевов бетонного лома и кирпичного лома. Данная статья посвящена исследованию зернового состава отсевов дробления бетонного лома и кирпичного боя, возможности создания рецептур строительных растворов на мелких песках с их использованием. Для большинства регионов нехватка крупнозернистых песков является особо актуальной, так как без их наличия производство бетонов и растворов высокого качества проблематично. Одним из способов решения данного вопроса является применение отсевов и мелких фракций дробления вторичного сырья, пригодного для использования в качестве заполнителя по химико-минералогическому и гранулометрическому составу. В результате рециклинга вторичного сырья образующие мелкие фракции отсевов представляют большой интерес для применения в качестве крупнозернистых песков или обогащающего материала для мелких песков с низким модулем крупности. Resource-saving issues are a priority in the building materials and products industry; the use of technogenic raw materials in building composites is becoming more widespread. This is dictated by the need to utilize industrial wastes, increase the economic efficiency of production and protect the environment. Of particular interest in the design of mortar compositions is the use of local substandard sand, industrial sand from screenings of concrete scrap and brick scrap. This article is devoted to the study of the grain composition of screenings for crushing concrete scrap and brick fighting, the possibility of creating mortar formulations on fine sand with their use. For most regions, the shortage of coarse-grained sand is especially urgent, since without their presence the production of concrete and high-quality mortars is problematic. One of the ways to solve this issue is the use of screenings and small fractions of crushing secondary raw materials suitable for use as a filler in chemical-mineralogical and particle size distribution. As a result of recycling of secondary raw materials, the fine screening fractions are of great interest for use as coarse-grained sands or an enrichment material for fine sands with a low modulus of fineness.


Author(s):  
A. S. Gaishun ◽  
E. S. Gaishun ◽  
E. V. Kovaleristova ◽  
K. S. Yavruyan

Objectives. The paper discusses the feasibility of using the technogenic raw materials of the coal series in the production of highly efficient wall ceramics. The interest in the man-made raw materials of the coal series (sludge, screenings and cake) as the raw materials used in the manufacture of ceramic products has now greatly increased. The reason for this was the reduction of the base of high-quality clay raw materials, the appreciation of its use in the production of wall ceramics, a large amount of accumulated reserves of various rocks of coal-based man-made raw materials.Method. The research used the following composition of the raw mix: 70% of technogenic raw materials of the coal series (screenings) and 30% of the clay raw materials. The determination of the physicomechanical properties of the samples was carried out according to GOST 530-2012. Coal dumps are fine- grained products, the solid part of which contains a significant amount of coal.Result. The technological parameters of obtaining wall ceramic products based on coal slimes are determined. Studied the main physico-technical characteristics of the materials obtained. Phase transformations occurring during the burning and patterns of the formation of the structure of the shard were studied. The feasibility of the production of highly efficient ceramic products with low thermal conductivity and density based on technogenic raw materials of the coal series using the technology of compression molding is shown.Conclusion. The results of theoretical studies are confirmed by practical data, which consist in the fact that in raw mixtures containing technogenic raw materials of coal series, a sharp increase in strength, taking into account the complete burning of carbon, occurs at temperatures of 1000-1060 ° C. The changes introduced during the production of products using this method will help achieve a significant energy saving of gas and optimization of the firing mode.


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