scholarly journals RECENT APPLICATIONS AND INNOVATIONS OF CELLULOSE BASED MATERIALS: A CRITICAL REVIEW

2021 ◽  
Vol 55 (1-2) ◽  
pp. 1-12
Author(s):  
TSHWAFO ELIAS MOTAUNG

"This review presents recent research on cellulosic materials and its latest uses, as well as scientific possibilities for more applications. Cellulose continues to display its advantages over synthetic fibers and its potential to replace fossilbased materials, which are known to harm ecosystems. Common attractive applications of cellulose include packaging, healthcare materials, electronics and printing. Most applications seem to rotate around the equilibrium of hydrophilicity, its mechanical properties and optical properties. Details on industrial applications, knowledge gaps and green innovations in cellulose conductivity, as well as limitations of its thermal degradation, are thoroughly covered. Most innovations are motivated by industrial needs, because renewability and inexpensiveness are the latest additional values to most industries. All common and innovative pretreatments are well summarized in this review. Furthermore, the paper provides interesting details on cellulose polymer composites, their applications and some recommendations for further research."

2019 ◽  
Vol 23 ◽  
pp. 57-63 ◽  
Author(s):  
Chin Wei Lai

This chapter reviews recent development of graphene-based polymer composites. The formation of graphene oxide and graphene are a vital two dimensional (2D) material has received a lot of research interest in commercialization aspect due to its excellent electrical, thermal as well as mechanical properties at very low filler content. In this manner, utilization of graphene-based polymer composites with different polymer matrixes have been attracted increasing attention in recent years for both fundamental studies and applied research into industrial applications in many fields. Herein, novel properties of polymer (epoxy, polystyrene, and PANI) / graphene composites will be reviewed along with detailed examples drawn from the scientific literature. Keywords: Graphene-based polymer composites, thermo-mechanical properties, two dimensional (2D) materials


2016 ◽  
Vol 369 ◽  
pp. 17-23 ◽  
Author(s):  
L.H. de Carvalho ◽  
A.G. Barbosa de Lima ◽  
E.L. Canedo ◽  
A.F.C. Bezerra ◽  
W.S. Cavalcanti ◽  
...  

Despite the ever-growing worldwide interest in the use of lignocellulosic fibers as reinforcement in either thermoset or thermoplastic matrices, the use of these fibers to replace synthetic ones, is limited. The reasons for these limitations are associated with the vegetable fiber’s heterogeneity, lower compatibility to most polymers, inferior durability, flammability, poorer mechanical properties and higher moisture absorption when compared with synthetic fibers. Nevertheless, despite these drawbacks, vegetable fiber reinforced polymer composites are lighter in weight, more sustainable and can be used for non-structural products. Strategies to minimize these drawbacks include fiber and or matrix modification, the use of compatibilizers, fiber drying and the concomitant use of vegetable and synthetic fibers, for the production of hybrid composites, the latter being an unquestionable way to increment overall mechanical and thermal properties of these hybrid systems. Here we present data on the water sorption of polymer composites having thermoset and thermoplastic matrices as a function of vegetable fiber identity, content and hybridization with glass fibers. Our data indicates that, regardless if the matrix is a thermoset of a thermoplastic, water absorption tends to be relatively independent of vegetable fiber identity and to be significantly dependent of its content. Fiber drying prior to composite manufacturing and hybridization with glass fibers leads to lower overall water absorption and higher mechanical properties.


Author(s):  
Piyush P. Gohil ◽  
Kundan Patel ◽  
Vijaykumar Chaudhary ◽  
Ronak Ramjiyani

The advancement of polymer composites containing natural fibers as a manageable option material for certain designing applications, especially aviation and car applications, is a well-known area of investigation. Nevertheless, the high mechanical properties connected with synthetic fibers they are awesome and lavish contrasted with natural fibers. The utilization of natural plant fibers and mixes of natural and synthetic fibers for making ease building materials has produced much interest recently. In the present work, bamboo–glass hybrid polyester composites were produced and their mechanical properties like elasticity and flexural quality were assessed for different weight fraction and distinctive stacking sequence. The outcomes observed that bamboo–glass mixture composites offered the benefits of both natural and synthetic fibers. It is also observed that hybridization started a material with general intermediate properties between pure glass and pure bamboo. However, the significance of controlling the stacking grouping to upgrade properties was evident.


Author(s):  
K Palani Kumar ◽  
D Keshavan ◽  
Elango Natarajan ◽  
Arvind Narayan ◽  
K Ashok Kumar ◽  
...  

In recent times, polymer composites have played an epochal role in transforming material science. Some of their properties such as toughness, strength, flexibility and rigidity have helped them supplant conventional materials such as iron, steel, and aluminium on several occasions. Apart from this, they are light in weight and more cost-efficient, which make them a viable alternative. They have found their application in several fields such as automobile industry, aerospace industry, construction and pipeline industry. Owing to its excellent impact strength, tensile and hardness, natural fibres serve as an excellent replacement. Natural fibres are an environmental friendly, biodegradable and are readily available. The present investigation uses a new fibre for manufacturing the eco-friendly composite material. Mechanical properties such as tensile strength, shear stress, flexural rigidity, impact strength and hardness of a coconut fibre-reinforced polymer composite material are evaluated as per respective ASTM standards. A surface analysis of the material using a scanning electron microscope is also performed. The results are categorized and tabulated accordingly. The values obtained appear to fall in line with the experimental data and hence can be espoused as an alternative material especially in the automotive sector.


Soft Matter ◽  
2021 ◽  
Author(s):  
Bavand Keshavarz ◽  
Brady Zarket ◽  
Samiul Amin ◽  
Ronak Rughani ◽  
Sivaramakrishnan Muthukrishnan ◽  
...  

Characterizing and understanding the viscoelastic mechanical properties of natural and synthetic fibers is of great importance in many biological and industrial applications. Microscopic techniques such as micro/nano indentation have been...


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1648
Author(s):  
Muaffaq M. Nofal ◽  
Shujahadeen B. Aziz ◽  
Jihad M. Hadi ◽  
Wrya O. Karim ◽  
Elham M. A. Dannoun ◽  
...  

In this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co2+ ions. A range of techniques was used to characterize the Co2+ complex and polymer composite, such as Ultraviolet–visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (n), dielectric properties including real and imaginary parts (εr, and εi) were also investigated. The FRIR and XRD spectra were used to examine the compatibility between the PVA polymer and Co2+-polyphenol complex. The extent of interaction was evidenced from the shifts and change in the intensity of the peaks. The relatively wide amorphous phase in PVA polymer increased upon insertion of the Co2+-polyphenol complex. The amorphous character of the Co2+ complex was emphasized with the appearance of a hump in the XRD pattern. From UV-Visible spectroscopy, the optical properties, such as absorption edge, refractive index (n), (εr), (εi), and bandgap energy (Eg) of parent PVA and composite films were specified. The Eg of PVA was lowered from 5.8 to 1.82 eV upon addition of 45 mL of Co2+-polyphenol complex. The N/m* was calculated from the optical dielectric function. Ultimately, various types of electronic transitions within the polymer composites were specified using Tauc’s method. The direct bandgap (DBG) treatment of polymer composites with a developed amorphous phase is fundamental for commercialization in optoelectronic devices.


Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 618
Author(s):  
Layla Shafei ◽  
Puja Adhikari ◽  
Wai-Yim Ching

Clay mineral materials have attracted attention due to their many properties and applications. The applications of clay minerals are closely linked to their structure and composition. In this paper, we studied the electronic structure properties of kaolinite, muscovite, and montmorillonite crystals, which are classified as clay minerals, by using DFT-based ab initio packages VASP and the OLCAO. The aim of this work is to have a deep understanding of clay mineral materials, including electronic structure, bond strength, mechanical properties, and optical properties. It is worth mentioning that understanding these properties may help continually result in new and innovative clay products in several applications, such as in pharmaceutical applications using kaolinite for their potential in cancer treatment, muscovite used as insulators in electrical appliances, and engineering applications that use montmorillonite as a sealant. In addition, our results show that the role played by hydrogen bonds in O-H bonds has an impact on the hydration in these crystals. Based on calculated total bond order density, it is concluded that kaolinite is slightly more cohesive than montmorillonite, which is consistent with the calculated mechanical properties.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1058
Author(s):  
Hikaru Okubo ◽  
Haruka Kaneyasu ◽  
Tetsuya Kimura ◽  
Patchiya Phanthong ◽  
Shigeru Yao

Each year, increasing amounts of plastic waste are generated, causing environmental pollution and resource loss. Recycling is a solution, but recycled plastics often have inferior mechanical properties to virgin plastics. However, studies have shown that holding polymers in the melt state before extrusion can restore the mechanical properties; thus, we propose a twin-screw extruder with a molten resin reservoir (MSR), a cavity between the screw zone and twin-screw extruder discharge, which retains molten polymer after mixing in the twin-screw zone, thus influencing the polymer properties. Re-extruded recycled polyethylene (RPE) pellets were produced, and the tensile properties and microstructure of virgin polyethylene (PE), unextruded RPE, and re-extruded RPE moldings prepared with and without the MSR were evaluated. Crucially, the elongation at break of the MSR-extruded RPE molding was seven times higher than that of the original RPE molding, and the Young’s modulus of the MSR-extruded RPE molding was comparable to that of the virgin PE molding. Both the MSR-extruded RPE and virgin PE moldings contained similar striped lamellae. Thus, MSR re-extrusion improved the mechanical performance of recycled polymers by optimizing the microstructure. The use of MSRs will facilitate the reuse of waste plastics as value-added materials having a wide range of industrial applications.


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