scholarly journals Atmospheric Soda Pulping of Banana Stem

2019 ◽  
Vol 9 (1) ◽  
pp. 5808-5812
Keyword(s):  
Lignin Content ◽  
Cellulose Degradation ◽  
Infrared Spectrometry ◽  
Cellulose Content ◽  
Sem Images ◽  
Solid Ratio ◽  
Alkaline Pulping ◽  
Cellulose Fibrils ◽  
Soda Pulping ◽  
Banana Stem

Banana stem is one of the most explored non-wood lignocellulose due to its high cellulose content with small amount of lignin. The conventional pulping processes efficiently remove the lignin, but there is potential to reduce the energy and chemical consumptions due to the low lignin content of banana stem. In this work, soda pulping was carried out for 60-120 minutes using 16-20% w/v alkali charge at boiling temperature of 105°C. The efficiency of lignin removal at low temperature was evaluated using kappa number analysis. The effects of pulping time and alkali charge on pulp properties were investigated using fourier transform infrared spectrometry (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Soda pulping using 18% w/v alkali charge at 10 liquid-to-solid ratio for 90 minutes under atmospheric pressure efficiently removed lignin with minimal cellulose degradation. Extended pulping time and concentrated alkali charge would induce cellulose degradation. FTIR analysis verified that alkaline pulping caused depolymerization on both lignin and cellulose. SEM images of banana stem showed ordered structure cellulose fibrils arrangement. Removal of lignin and hemicellulose was observed through smoother surface of the banana pulp. However, TGA analysis suggested that a better thermal stability could be achieved through pulping using 16% w/v alkali charge.

scholarly journals Comparative study of the reaction kinetics of three residual biomasses

BioResources ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. 2891-2905
Author(s):  
Arnaldo Martinez ◽  
Lourdes Meriño ◽  
Alberto Albis ◽  
Jorge Ortega
Keyword(s):  
Activation Energy ◽  
Heating Rate ◽  
Lignin Content ◽  
Cellulose Degradation ◽  
Calorific Value ◽  
Degradation Process ◽  
Proximate Analysis ◽  
Cellulose Content ◽  
Heating Rates ◽  
Biomass Residues

Kinetic analysis for the combustion of three agro-industrial biomass residues (coconut husk, corn husk, and rice husk) was carried out in order to provide information for the generation of energy from them. The analysis was performed using the results of the data obtained by thermogravimetric analysis (TGA) at three heating rates (10, 20, and 30 K/min). The biomass residues were characterized in terms of proximate analysis, elemental analysis, calorific value, lignin content, α-cellulose content, hemicellulose content, and holocellulose content. The biomass fuels were thermally degraded in an oxidative atmosphere. The results showed that the biomass thermal degradation process is comprised of the combustion of hemicellulose, cellulose, and lignin. The kinetic parameters of the distributed activation energy model indicated that the activation energy distribution for the pseudocomponents follows lignin, cellulose, and hemicellulose in descending order. The activation energy values for each set of reactions are similar between the heating rates, which suggests that it is independent of the heating rate between 10 K/min and 30 K/min. For all the biomass samples, the increased heating rate resulted in the overlap of the hemicellulose and cellulose degradation events.

scholarly journals The effect of chip size and alkaline pre-hydrolysis conditions on following soda pulping of hornbeam wood

2019 ◽  
Vol 70 (4) ◽  
pp. 329-336
Author(s):  
Ahmad Jahan Latibari ◽  
Abdulrahim Mohebalian ◽  
Ajang Tajdini ◽  
Shadman Pourmosua
Keyword(s):  
Lignin Content ◽  
Total Yield ◽  
Strength Properties ◽  
Test Methods ◽  
Standard Test ◽  
Cellulose Content ◽  
Hemicellulose Removal ◽  
Soda Pulping ◽  
Chip Size ◽  
The Impact

The impact of chip size and hydrolysis temperature on changing chemical composition of hornbeam wood and following soda pulping is investigated. Three chip sizes, two temperatures (60 and 90 °C) and 120 minutes retention time in pre-hydrolysis step were selected. After pre-hydrolysis treatment, the sample was divided into two portions; one third was used for chemical analysis and the other two thirds for soda pulping. The reference soda pulping conditions were used on either treated or untreated chips. The influence of pre-hydrolysis was determined measuring cellulose and lignin content, residual alkali and the hemicelluloses removal. The lignin and cellulose content were marginally increased and the hemicellulose removal was higher at larger chip size. Total yield and rejects, kappa number and strength properties of the unbleached pulp were measured using corresponding Tappi standard test methods. The pulping total yield and rejects of the treated chips varied between 30.31 % and 48.14 % and 0.83 % to 7.31 %, respectively. The reject from soda pulping of untreated chips was 24.16. Prehydrolysis treatment reduced the tensile index, but the tear index was only marginally improved.

Potentiality of Banana (Musa) Stem as Raw Material in Chemical Nonwood Pulping

2007 ◽  
Vol 4 (2) ◽  
pp. 55
Author(s):  
Soo Kwan Leong ◽  
Rakmi Abd Rahman
Keyword(s):  
Batch Reactor ◽  
Agricultural Waste ◽  
Chemical Substance ◽  
Raw Material ◽  
Rice Hull ◽  
Cellulose Content ◽  
Agriculture Industry ◽  
Chemical Pulping ◽  
Soda Pulping ◽  
Banana Stem

Wood is not sufficient in many countries to meet the rise demand for paper and pulp. In recent years, a lot of researches have been done to find a new, non-wood raw material for paper production especially using agricultural waste. Agriculture industry is one of the main industries in Malaysia which has generated a large amount of waste every year such as banana stem, rice hull, sugarcane bagasse and wheat straw. These are regarded as abundant, inexpensive and readily available natural resources for pulping industry. The purpose of this paper is to study of the pulping potentialities of banana stems which are growing in Malaysia. In this research the banana stem is used as raw material in the pulping process for the purpose of producing cellulose as pulp. The chemical pulping method which is used in the study is soda pulping, where NaOH is the main chemical substance used in cooking and with anthroquinone as the additive. Temperature, residence time and dosage of chemical were the parameters to be manipulated in this non-wood chemical pulping process to get an optimum condition for pulping. A 3 litre batch reactor was used in this non-wood chemical pulping process. The concentration of NaOH used was varied from 10 – 45 % and cooking temperature was varied from 100 – 200 °C. The ratio of solid to liquid is set at 1:8 and also the cooking period was varied from 30 – 210 minutes. The result shows that the optimum yield of pulp from this study is at 20 % w/w NaOH, cooking at 160 °C with 120 minutes. The yield of pulp is around 30 %. The cellulose content in the pulp produced is as high as 90 %.

scholarly journals Potentiality of Banana (Musa) Stem as Raw Material in Chemical Nonwood Pulping

2007 ◽  
Vol 4 (2) ◽  
pp. 55
Author(s):  
Leong Soo Kwan ◽  
Rakmi Abd Rahman
Keyword(s):  
Batch Reactor ◽  
Agricultural Waste ◽  
Chemical Substance ◽  
Raw Material ◽  
Rice Hull ◽  
Cellulose Content ◽  
Agriculture Industry ◽  
Chemical Pulping ◽  
Soda Pulping ◽  
Banana Stem

Wood is not sufficient in many countries to meet the rise demand for paper and pulp. In recent years, a lot of researches have been done to find a new, non-wood raw material for paper production especially using agricultural waste. Agriculture industry is one of the main industries in Malaysia which has generated a large amount of waste every year such as banana stem, rice hull, sugarcane bagasse and wheat straw. These are regarded as abundant, inexpensive and readily available natural resources for pulping industry. The purpose of this paper is to study of the pulping potentialities of banana stems which are growing in Malaysia. In this research the banana stem is used as raw material in the pulping process for the purpose of producing cellulose as pulp. The chemical pulping method which is used in the study is soda pulping, where NaOH is the main chemical substance used in cooking and with anthroquinone as the additive. Temperature, residence time and dosage of chemical were the parameters to be manipulated in this non-wood chemical pulping process to get an optimum condition for pulping. A 3 litre batch reactor was used in this non-wood chemical pulping process. The concentration of NaOH used was varied from 10 – 45 % and cooking temperature was varied from 100 – 200 °C. The ratio of solid to liquid is set at 1:8 and also the cooking period was varied from 30 – 210 minutes. The result shows that the optimum yield of pulp from this study is at 20 % w/w NaOH, cooking at 160 °C with 120 minutes. The yield of pulp is around 30 %. The cellulose content in the pulp produced is as high as 90 %.

Characterisation of compound middle lamella isolated by a combination of wet-beating, sedimentation, and methanol dialysis

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Yasuyuki Matsushita ◽  
Taichi Fukumura ◽  
Dan Aoki ◽  
Kazuhiko Fukushima
Keyword(s):  
Secondary Wall ◽  
Lignin Content ◽  
Middle Lamella ◽  
Natural State ◽  
Cellulose Content ◽  
Nmr Analysis ◽  
Sem Images ◽  
Simple Method ◽  
Compound Middle Lamella ◽  
C Nmr

Abstract A simple method was developed to isolate the compound middle lamella (CML) in its natural state using wet-beating, sedimentation, and methanol dialysis. The isolated CML fraction was characterised. The CML was isolated in 2.0% yield from the mature wood of Ginkgo biloba. Scanning electron microscopy (SEM) images of the isolated CML fraction showed the presence of flake-like structures. However, some small amounts of secondary wall substance was observed. The lignin content of the CML fraction was approximately 45%. Thioacidolysis reactions with the isolated CML fraction revealed that the lignin β-O-4 structure was scarce in the isolated fraction and that numerous structures with two or more consecutive condensed-type bonds were present. Results from the solid-state carbon-13 nuclear magnetic resonance (13C NMR) experiments indicated that the CML fraction had low crystallinity, indicating low cellulose content. Liquid-state NMR analysis of the lignin from the CML fraction revealed the absence of p-hydroxyphenyl (H) units.

scholarly journals Analysis by Pineapple Leaf in Chemical Pulping Process

2015 ◽  
Vol 773-774 ◽  
pp. 1215-1219
Author(s):  
Zawawi Daud ◽  
Mohd Zainuri Mohd Hatta ◽  
Angzzas Sari Mohd Kassim ◽  
Ashuvila Mohd Kassim ◽  
Halizah Awang
Keyword(s):  
Chemical Composition ◽  
Oil Palm ◽  
Lignin Content ◽  
Wood Fiber ◽  
Health Benefit ◽  
Ananas Comosus ◽  
Cellulose Content ◽  
Pineapple Leaf Fiber ◽  
Banana Stem ◽  
Leaf Fiber

Malaysia has an abundance of agro waste material that have not been fully utilized to a maximum production. Thus, the finding of a new alternative fiber in non wood material will be favorable in paper production. Pineapple (Ananas Comosus) is the common tropical plant, which consists of coalesced berries. This pineapple is leading member of the family of Bromeliaceae and it came from genus Ananas. Fiber bundle from pineapple leaf can be separated from the cortex where it reveals the pineapple leaf fiber in multi-cellular and lignocelluloses pattern. This leaf has a ribbon-like structure and cemented together by lignin, pentosan-like materials, where it contributes to the strength of fiber [7]. All parts in pineapple from fruits to leaves could be consumed to give a health benefit for human life. Pineapple had been used as textile fiber, anti-inflammatory and also anti-helminthic agent. According to the FAO online database, the Malaysian country had consumed 255,000 tones per year and in third position in the world of consuming pineapple production. Pineapple is mainly produced as canned fruits and also coarse textiles in some Southeast Asian countries. Leaves of pineapple had been used as coarse textiles because of the fiber composition and structure inside the leaves [3]. All fibrous in non wood materials especially pineapple leaf consists of cellulose, holocellulose, hemicelluloses and lignin along with some extraneous material called extractives such as gum and resin. Previous research indicates pineapple leaf fiber contained higher cellulose content than wood fiber. Pineapple leaf fibers also consist of lignin [23], an adhesive component that binds the cellulose and hemicellulose. Pineapple leaf fiber had the lowest lignin content than other alternative fiber, which is favorable during chemical processing [12]. The chemical composition aspects have been considered in the previous literature, such as banana stem, coconut and oil palm and had been reported extensively. Pineapple leaf reported has a lowest lignin (10.5%) rather than banana stem (18.6%), oil palm (20.5%) and coconut (32.8%) that suggest can undergo bleaching more easily and have high fiber strength [12]. Besides that, pineapple leaf contains high holocelulose content (87.6%) than banana stem (65.2%), oil palm (83.5%) and coconut (56.3%) [11]. Those properties depend on the content of chemical composition in the pineapple leaf fiber, which is cellulose, hemicelluloses and lignin content [15].

Effect of Biogas Production Characteristics of Dry Anaerobic Fermentation of Wheat Straw Pretreated by a Microbial Community with High Cellulose-Degradation Ability

2011 ◽  
Vol 347-353 ◽  
pp. 2996-3000 ◽  
Author(s):  
Jun Ling Niu ◽  
Lei Liu ◽  
Quan Guo Zhang
Keyword(s):  
Wheat Straw ◽  
Anaerobic Fermentation ◽  
Biogas Production ◽  
Lignin Content ◽  
Cellulose Degradation ◽  
Gas Production ◽  
Reducing Sugar ◽  
Cellulose Content ◽  
Microbial System ◽  
Pretreated Wheat Straw

The study on the changes of composition and content reducing sugar of wheat straw after pretreated with composite microbial system for degrading cellulose was carried out, and the experimental study on the dry anaerobic fermentation of the pretreated wheat straw was followed. The results showed for pretreated wheat straw there is a significant increase for the amount of reducing sugar, the hemicellulose content decreased 49.43%, the cellulose content also decreased a little, but the lignin content had little change. For the dry anaerobic fermentation process, the reaction is started fast, the pH values declined faster in the prophase for the pretreated straw, the mixed biogas production and the methane content have been increased over that of non-pretreated wheat straw, and the gas was produced more steadily. The accumulated gas production had been to 4810mL, which was more than the non pretreated straw, before the maximum gas production was appeared.

Analysis of Sound Reduction and Strong Drag Composite Concrete Fibers Gedebok Banana Results Delignification with Sodium Hydroxide Solvent (Naoh)

2018 ◽  
Vol 6 (02) ◽  
pp. 105-120
Author(s):  
Muhammad Rouf Suprayogi ◽  
Annisa Mufida ◽  
Edwin Azwar
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Lignin Content ◽  
Sound Intensity ◽  
Cellulose Fiber ◽  
Cellulose Content ◽  
Cellulose Powder ◽  
Drying Method ◽  
Normal Concrete ◽  
Sound Reduction

In composite science, desirable materials that are lighter but have the power and quality that can match or even exceed the material that has been there before. The purpose of this study was to investigate the effect of cellulose fiber addition from banana gedebok to tensile strength, compressive strength and damping of concrete composite sound. To achieve this objective, mixing of cellulose fibers with K-275 quality concrete mix with variation of 0% and 5% substitution in which the cellulose is varied in powder and wicker form. Delignification of lignin content from banana gedebok was done by soaking and drying method without any variation and yielding powder having cellulose content of 13,0388%, hemicellulose 18,2796% and lignin 0,6684%. This study produces concrete composites that have a tensile strength and a compressive strength lower than that of normal concrete. Normally reinforced concrete tensile strength value 94.5 kg / cm2, 71.4 kg / cm2 cellulose powder concrete and 90.3 kg / cm2 cellulose woven concrete. Normal concrete compressive strength value 334,22 kg / cm2, cellulose powder concrete 215,7 kg / cm2, and cellulose webbing concrete 157,98 kg / cm2. As for the power damping sound of cellulose webbing concrete has the highest damping power compared to other concrete with the absorbed sound intensity that is 52-68 dB

scholarly journals Recycling Waste Cotton Cloths for the Isolation of Cellulose Nanocrystals: A Sustainable Approach

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 626
Author(s):  
Siti Hajar Mohamed ◽  
Md. Sohrab Hossain ◽  
Mohamad Haafiz Mohamad Kassim ◽  
Mardiana Idayu Ahmad ◽  
Fatehah Mohd Omar ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Cellulose Nanocrystals ◽  
Value Added ◽  
Crystallinity Index ◽  
Attenuated Total Reflection ◽  
Cellulose Content ◽  
Scanning Calorimetry ◽  
Good Thermal Stability ◽  
Alkaline Pulping ◽  
Hydrolysis Of Cellulose

There is an interest in the sustainable utilization of waste cotton cloths because of their enormous volume of generation and high cellulose content. Waste cotton cloths generated are disposed of in a landfill, which causes environmental pollution and leads to the waste of useful resources. In the present study, cellulose nanocrystals (CNCs) were isolated from waste cotton cloths collected from a landfill. The waste cotton cloths collected from the landfill were sterilized and cleaned using supercritical CO2 (scCO2) technology. The cellulose was extracted from scCO2-treated waste cotton cloths using alkaline pulping and bleaching processes. Subsequently, the CNCs were isolated using the H2SO4 hydrolysis of cellulose. The isolated CNCs were analyzed to determine the morphological, chemical, thermal, and physical properties with various analytical methods, including attenuated total reflection-Fourier transform-infrared spectroscopy (ATR-FTIR), field-emission scanning electron microscopy (FE-SEM), energy-filtered transmission electron microscopy (EF-TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed that the isolated CNCs had a needle-like structure with a length and diameter of 10–30 and 2–6 nm, respectively, and an aspect ratio of 5–15, respectively. Additionally, the isolated CNCs had a high crystallinity index with a good thermal stability. The findings of the present study revealed the potential of recycling waste cotton cloths to produce a value-added product.

scholarly journals Synthesis of lactic acid from sugar palm trunk waste (Arenga pinnata): Preliminary hydrolysis and fermentation studies

2020 ◽  
Vol 21 (5) ◽  
Author(s):  
WHINY HARDIYATI ERLIANA ◽  
Tri Widjaja ◽  
ALI ALTWAY ◽  
LILY PUDJIASTUTI
Keyword(s):  
Lactic Acid ◽  
Lignin Content ◽  
Agricultural Waste ◽  
Lactic Acid Production ◽  
Lactobacillus Rhamnosus ◽  
Lactobacillus Brevis ◽  
Reducing Sugar ◽  
Cellulose Content ◽  
Acid Pretreatment ◽  
Acid Fermentation

Abstract. Erliana WH, Widjaja T, Altway A, Pudjiastuti L. 2020. Synthesis of lactic acid from sugar palm trunk waste (Arenga pinnata): Hydrolysis and fermentation studies. Biodiversitas 21: 2281-2288. The increasing problems of global energy and the environment are the main reasons for developing products with new techniques through green methods. Sugar palm trunk waste (SPTW) has potential as agricultural waste because of its abundant availability, but it is not used optimally. This study was aimed to determine the effect of various microorganisms on increasing lactic acid production by controlling pH and temperature conditions in the fermentation process. SPTW contains 43.88% cellulose, 7.24% hemicellulose, and 33.24% lignin. The lignin content in SPTW can inhibit reducing sugar formation; the pretreatment process should remove this content. In the study, the pretreatment process was conducted using acid-organosolv. In the acid pretreatment, 0.2 M H2SO4 was added at 120oC for 40 minutes; organosolv pretreatment using 30% ethanol (v/v) at 107oC for 33 minutes was able to increase cellulose content by 56.33% and decrease lignin content by 27.09%. The pretreatment was followed by an enzymatic hydrolysis process with a combination of commercial cellulase enzymes from Aspergillus niger (AN) and Trichoderma reesei (TR), with variations of 0:1, 1:0, 1:1, 1:2 and 2:1. The best reducing sugar concentration was obtained with an AN: TR ratio of 1:2 to form reducing sugar from cellulose. Subsequently, lactic acid fermentation was carried out using lactic acid bacteria at 37oC and pH 6 incubated for 48 hours. The highest lactic acid concentration (33.292 g/L) was obtained using a mixed culture of Lactobacillus rhamnosus and Lactobacillus brevis to convert reducing sugar become lactic acid.

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