scholarly journals Modification of Takari natural sand based silica with BSA (SiO2@BSA) for biogenic amines compound adsorbent

2021 ◽  
Vol 9 (1) ◽  
pp. 36-55
Author(s):  
Johnson N. Naat ◽  
◽  
Yantus A. B Neolaka ◽  
Yosep Lawa ◽  
Calvin L. Wolu ◽  
...  
Keyword(s):  
Bovine Serum Albumin ◽  
Biogenic Amines ◽  
Contact Time ◽  
Chemical Adsorption ◽  
Batch Method ◽  
Natural Sand ◽  
Thermodynamic Studies ◽  
Sem Image ◽  
Pseudo Second Order ◽  
Compound Adsorbent

<abstract> <p>The modification of Takari natural sand‑based silica with bovine serum albumin/BSA (SiO<sub>2</sub>@BSA) as an adsorbent for biogenic amines compounds has been successfully synthesized. The SiO<sub>2</sub>@BSA was synthesized by using the batch method, then was characterized by using FTIR and SEM. Here, A typical BSA group was identified with the new formed namely C–N and C–H, and N–H. The SEM image shows the surface morphology in granular, non‑uniform, rough, and agglomerated forms. Several parameters such as adsorbent dosages, pH, and contact time, shows this material was optimum for adsorption of BSA at pH 5 with adsorbent dosages is 0.1 g during 80 min of contact time. The mechanism adsorption of BSA in this material was found out by using six kinetics modeling, and thermodynamic studies. Here, the adsorption of BSA was fitted with pseudo‑second‑order kinetics. Furthermore, the thermodynamic studies show that adsorption of BSA is spontaneously and follows chemical adsorption.</p> </abstract>

scholarly journals The adsorption and Fenton behavior of iron rich Terra Rosa soil for removal of aqueous anthraquinone dye solutions: kinetic and thermodynamic studies

2017 ◽  
Vol 76 (11) ◽  
pp. 3114-3125 ◽  
Author(s):  
Doga Aktas ◽  
Nadir Dizge ◽  
H. Cengiz Yatmaz ◽  
Yasemin Caliskan ◽  
Yasin Ozay ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Contact Time ◽  
Oxidation Process ◽  
Second Order ◽  
Order Kinetic ◽  
Anthraquinone Dye ◽  
Thermodynamic Studies ◽  
Soil Loading ◽  
Pseudo Second Order ◽  
The Impact

Abstract Adsorption and advanced oxidation processes are being extensively used for treatment of wastewater containing dye chemicals. In this study, the adsorption and Fenton behavior of iron rich Terra Rosa soil was investigated for the treatment of aqueous anthraquinone dye (Reactive Blue 19 (RB19)) solutions. The impact of pH, initial dye concentration, soil loading rate, contact time and temperature was systematically investigated for adsorption process. A maximum removal efficiency of dye (86.6%) was obtained at pH 2, soil loading of 10 g/L, initial dye concentration of 25 mg/L, and contact time of 120 min. Pseudo-first-order, pseudo-second-order, Elovich, and Weber–Morris kinetic models were applied to describe the adsorption mechanism and sorption kinetic followed a pseudo-second-order kinetic model. Moreover, Langmuir, Freundlich and Temkin isotherm models were used to investigate the isothermal mechanism and equilibrium data were well represented by the Langmuir equation. The maximum adsorption capacity of soil was found as 4.11 mg/g using Langmuir adsorption isotherm. The effect of soil loading and hydrogen peroxide (H2O2) dosage was solely tested for Fenton oxidation process. The highest removal efficiency of dye (89.4%) was obtained at pH 2, H2O2 dosage of 10 mM, soil loading of 5 g/L, initial dye concentration of 50 mg/L, and contact time of 60 min. Thermodynamic studies showed that when the adsorption dosage of dye was 25 mg/L at 293–313 K, adsorption enthalpy (ΔH) and entropy (ΔS) were negative and adsorption free energy (ΔG) was positive. This result indicated that the adsorption was exothermic. Morphological characteristics of the soil were evaluated by X-ray fluorescence (XRF), scanning electron microscopy (SEM), and attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy before and after the adsorption and oxidation process.

scholarly journals Removal of Methylene Blue from Aqueous Solution Using Agricultural Residue Walnut Shell: Equilibrium, Kinetic, and Thermodynamic Studies

2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Ranxiao Tang ◽  
Chong Dai ◽  
Chao Li ◽  
Weihua Liu ◽  
Shutao Gao ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Particle Size ◽  
Contact Time ◽  
Walnut Shell ◽  
Chemical Adsorption ◽  
Solution Ph ◽  
Adsorption Mechanisms ◽  
Bet Method ◽  
Pseudo Second Order ◽  
Optimized Conditions

Walnut shell (WS), as an economic and environmental-friendly adsorbent, was utilized to remove methylene blue (MB) from aqueous solutions. The effects of WS particle size, solution pH, adsorbent dosage and contact time, and concentration of NaCl on MB removal were systematically investigated. Under the optimized conditions (i.e., contact time ~ 2 h, pH ~ 6, particle size ~ 80 mesh, dye concentration 20 mg/L, and 1.25 g/L adsorbent), the removal percentages can achieve ~97.1%, indicating WS was a promising absorbent to remove MB. Other supplementary experiments, such as Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), and Brunauer-Emmett-Teller (BET) method, were also employed to understand the adsorption mechanisms. FTIR confirmed that the successful adsorption of MB on WS particles was through functional groups of WS. Using DLS method, the interactions between WS particles and dyes under various pH were investigated, which can be ascribed to the electrostatic forces. Kinetic data can be well fitted by the pseudo-second-order model, indicating a chemical adsorption. The adsorption isotherms were well described by both Langmuir and Freundlich models. Dubinin-Radushkevich model also showed that the adsorption process was a chemical adsorption. Thermodynamic data indicated that the adsorption was spontaneous, exothermic, and favorable at room temperature.

scholarly journals Adsorptive Applications of Montmorillonite Clay for the Removal of Ag(I) and Cu(II) from Aqueous Medium

2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Naser M. Alandis ◽  
Waffa Mekhamer ◽  
Omar Aldayel ◽  
Jameel A. A. Hefne ◽  
Manawwer Alam
Keyword(s):  
Waste Water ◽  
Aqueous Solutions ◽  
Metal Concentration ◽  
Contact Time ◽  
Adsorption Process ◽  
Distribution Coefficients ◽  
Kinetic Characteristics ◽  
Batch Method ◽  
Equilibrium Studies ◽  
Pseudo Second Order

The present work aims to investigate the ability of Saudi clay containing montmorillonite to remove Ag(I) and Cu(II) ions from aqueous solutions for waste water purification. The effect of pH, adsorbent mass, metal concentration, and contact time on the removal process has been investigated. The batch method was applied, using solution metal concentrations ranging from 40 to 2000 mg/L. Adsorption percentage and distribution coefficients (Kd) were determined as a function of metal concentration. pH 6 was found to be optimal for the adsorption. Adsorption reached equilibrium in 5 min for both Ag(I) and Cu(II) ions. The study on adsorption’s kinetic characteristics showed the adsorption process of these metal ions was of pseudo-second-order. Furthermore, the adsorption rate of Ag(I) was higher than that of Cu(II), and their adsorption appeared to follow the Langmuir isotherm. From the equilibrium studies, it was observed that the selectivity of Ag(I) was higher than that of Cu(II). The results showed that Saudi clay has the potential to be a suitable adsorbent for Ag(I) and Cu(II) removal from aqueous solutions compared with other adsorbents.

Nano-ZrO2/TiO2 Impregnated Orange Wood Sawdust and Peach Stone Shell Adsorbents for Cr (VI) Removal

2020 ◽  
Vol 16 (7) ◽  
pp. 880-892
Author(s):  
Şerife Parlayıcı ◽  
Kübra Tuna Sezer ◽  
Erol Pehlivan
Keyword(s):  
Contact Time ◽  
Ph Value ◽  
Order Kinetic ◽  
Adsorption Parameters ◽  
Wood Sawdust ◽  
Adsorption Data ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Ft Ir ◽  
Equilibrium Status

Background: In this work, Cr (VI) adsorption on nano-ZrO2๏TiO2 impregnated orange wood sawdust (Zr๏Ti/OWS) and nano-ZrO2๏TiO2 impregnated peach stone shell (Zr๏Ti/PSS) was investigated by applying different adsorption parameters such as Cr (VI) concentrations, contact time, adsorbent dose, and pH for all adsorbents. Methods: The adsorbents were characterized by SEM and FT-IR. The equilibrium status was achieved after 120 min of contact time and optimum pH value around 2 were determined for Cr (VI) adsorption. Adsorption data in the equilibrium is well-assembled by the Langmuir model during the adsorption process. Results: Langmuir isotherm model showed a maximum adsorption value of OWS: 21.65 mg/g and Zr๏Ti/OWS: 27.25 mg/g. The same isotherm displayed a maximum adsorption value of PSS: 17.64 mg/g, and Zr๏Ti/PSS: 31.15 mg/g. Pseudo-second-order kinetic models (R2=0.99) were found to be the best models for describing the Cr (VI) adsorption reactions. Conclusıon: Thermodynamic parameters such as changes in ΔG°, ΔH°, and ΔS° have been estimated, and the process was found to be spontaneous.

Thermodynamic Studies of SN38 Hydrolysis in the Presence of Human and Bovine Serum Albumin

2011 ◽  
Vol 1 (2) ◽  
pp. 140-151 ◽  
Author(s):  
Balasubramanian Sivakumar ◽  
Rishi Thakur ◽  
Sasank Kunadharaju ◽  
Michalakis Savva
Keyword(s):  
Bovine Serum Albumin ◽  
Serum Albumin ◽  
Bovine Serum ◽  
Thermodynamic Studies

Removal of Methylene Blue and Orange-G from Waste Water Using Magnetic Biochar

2015 ◽  
Vol 14 (04) ◽  
pp. 1550009 ◽  
Author(s):  
N. M. Mubarak ◽  
Y. T. Fo ◽  
Hikmat Said Al-Salim ◽  
J. N. Sahu ◽  
E. C. Abdullah ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Contact Time ◽  
Agitation Speed ◽  
Adsorption Kinetic ◽  
Maximum Adsorption Capacity ◽  
Optimum Conditions ◽  
Magnetic Biochar ◽  
Design Expert ◽  
Orange G ◽  
Pseudo Second Order

The study on the removal of methylene blue (MB) and orange-G dyes using magnetic biochar derived from the empty fruit bunch (EFB) was carried out. Process parameters such as pH, adsorbent dosage, agitation speed and contact time were optimized using Design-Expert Software v.6.0.8. The statistical analysis reveals that the optimum conditions for the maximum adsorption of MB are at pH 2 and pH 10, dosage 1.0 g, and agitation speed and contact time of 125 rpm and 120 min respectively. While for orange-G, at pH 2, dosage 1.0 g, and agitation speed and contact time of 125 rpm and 120 min respectively. The maximum adsorption capacity of 31.25 mg/g and 32.36 mg/g for MB and orange-G respectively. The adsorption kinetic for both dyes obeyed pseudo-second order.

Kinetic Study of Methyl Orange Adsorption from Solution by IOCZ

2013 ◽  
Vol 684 ◽  
pp. 194-197
Author(s):  
Yi Ke Li ◽  
Bing Lu Zhao ◽  
Wei Xiao ◽  
Run Ping Han ◽  
Yan Qiang Li
Keyword(s):  
Methyl Orange ◽  
Contact Time ◽  
Adsorption Mechanism ◽  
Order Model ◽  
Initial Concentration ◽  
Pseudo Second Order ◽  
Adsorption From Solution ◽  
Adsorption Quantity ◽  
Regressive Analysis

The effect of contact time and the determination of the kinetic parameters of adsorption of methyl orange (MO) from aqueous solution onto Iron-Oxide-Coated-Zeolite (IOCZ) powder are important in understanding the adsorption mechanism. The effect of contact time on adsorption quantity was studied at different initial concentration and temperature, respectively. The pseudo-second-order model was adopted to fit the experimental data using non-linear regressive analysis and it was used to predict the adsorption behavior. The results showed that the process of adsorption MO was endothermic and chemisorption. The pore diffusion was not significant.

Biosorption of As(V) from aqueous solutions by living cells of Bacillus cereus

2012 ◽  
Vol 66 (8) ◽  
pp. 1699-1707 ◽  
Author(s):  
A. K. Giri ◽  
R. K. Patel ◽  
P. C. Mishra
Keyword(s):  
Aqueous Solutions ◽  
Bacillus Cereus ◽  
Contact Time ◽  
Living Cells ◽  
Optimum Conditions ◽  
Order Model ◽  
Initial Concentration ◽  
Pseudo Second Order ◽  
Biomass Dosage ◽  
Batch Biosorption

In this work, the biosorption of As(V) from aqueous solutions by living cells of Bacillus cereus has been reported. The batch biosorption experiments were conducted with respect to biosorbent dosage 0.5 to 15 g/L, pH 2 to 9, contact time 5 to 90 min, initial concentration 1 to 10 mg/L and temperature 10 to 40 °C. The maximum biosorption capacity of B. cereus for As(V) was found to be 30.04 at pH 7.0, at optimum conditions of contact time of 30 min, biomass dosage of 6 g/L, and temperature of 30 ± 2 °C. Biosorption data were fitted to linearly transformed Langmuir isotherms with R2 (correlation coefficient) &gt;0.99. Bacillus cereus cell surface was characterized using AFM and FTIR. The metal ions were desorbed from B. cereus using both 1 M HCl and 1 M HNO3. The pseudo-second-order model was successfully applied to predict the rate constant of biosorption.

scholarly journals Uptake of Zn, Pb, Cu and Fe Ions from Spent and Unspent Engine Oil Using Termite Soil

2017 ◽  
Vol 9 (3) ◽  
pp. 85
Author(s):  
Iwekumo Agbozu ◽  
Bassey Uwem ◽  
Boisa Ndokiari
Keyword(s):  
Contact Time ◽  
Diffusion Constant ◽  
Reaction Rates ◽  
Second Order ◽  
Engine Oil ◽  
Initial Reaction ◽  
Kinetics Equation ◽  
Spent Engine Oil ◽  
Pseudo Second Order ◽  
Fe Ions

Removal of Zn, Pb, Cu and Fe ions from unspent and spent engine oil was studied using Termite soil. Process parameters such as contact time and adsorbent dosage were varied. Values from contact time were used for predicting kinetics equation of their uptake. At optimum time of 40 minutes, percentage adsorption was of the order Fe>Zn>Cu>Pb for both spent and unspent engine oil. Kinetics equation such as Elovich, Intra-particle, Pseudo-first order and Pseudo-second order were tested. Results obtained shows that their sequestering pattern fit into the pseudo-second order kinetics. Initial reaction rates, h (mg/g.min) and α (mg. g-1min-1) for all metal ions obtained from Pseudo-second order and Elovich kinetic models followed the trends Zn>Fe>Cu>Pb and Zn>Fe>Pb>Cu respectively in spent engine oil while for unspent engine oil, the trend was Fe>Zn>Cu>Pb for h (mg/g.min) and Zn>Fe>Pb>Cu for α (mg. g-1min-1). Electrostatic attraction existing on the surface of the adsorbent assisted in the high initial reaction of Zn and Fe ions, implying good affinity of the ions for the adsorbent. Desorption constant ᵦ (g/mg) was of the trend Cu>Pb>Fe>Zn and Cu>Pb>Zn>Fe for spent and unspent engine oils respectively. Intra-particle diffusion constant kid (mgg-1min-1/2) followed a similar pattern, revealing strong binding between Zn and termite soil than any of the metal ion. This pilot research has been able to suggest a kinetic process for uptake of the studied ions from spent and unspent engine oil.

scholarly journals Biosorption of Congo Red and Methylene Blue by pretreated waste Streptomyces fradiae biomass - Equilibrium, kinetic and thermodynamic studies

2018 ◽  
Vol 83 (1) ◽  
pp. 107-120 ◽  
Author(s):  
Zdravka Velkova ◽  
Gergana Kirova ◽  
Margarita Stoytcheva ◽  
Velizar Gochev
Keyword(s):  
Methylene Blue ◽  
Congo Red ◽  
Contact Time ◽  
Order Kinetic ◽  
Batch Experiments ◽  
Streptomyces Fradiae ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Kinetic And Thermodynamic Studies ◽  
Pretreated Biomass

Pretreated waste Streptomyces fradiae biomass was utilized as an eco-friendly sorbent for Congo Red (CR) and Methylene Blue (MB) removal from aqueous solutions. The biosorbent was characterized by Fourier transform infrared spectroscopy. Batch experiments were conducted to study the effect of pH, biosorbent dosage, initial concentration of adsorbates, contact time and temperature on the biosorption of the two dyes. The equilibrium adsorption data were analysed using Freundlich and Langmuir models. Both models fitted well the experimental data. The maximum biosorption capacity of the pretreated Streptomyces fradiae biomass was 46.64 mg g-1 for CR and 59.63 mg g-1 for MB, at a pH 6.0, with the contact time of 120 min, the biosorbent dosage of 2 g dm-3 and the temperature of 298 K. Lagergren and Ho kinetic models were used to analyse the kinetic data obtained from different batch experiments. The biosorption of both dyes followed better the pseudo-second order kinetic model. The calculated values for ?G, ?S, and ?H indicated that the biosorption of CR and MB onto the waste pretreated biomass was feasible, spontaneous, and exothermic in the selected temperature range and conditions.

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