Study on the Technical Conditions of Old Newspaper(ONP)/ Recycled-Polypropylene(rPP) Composites

2012 ◽  
Vol 262 ◽  
pp. 418-421 ◽  
Author(s):  
Xiao Lin Zhang ◽  
Xiang Feng Bo

Use of resource-rich wastepaper/recycled plastics as raw materials in the production of wood-plastic composites(WPC) can alleviate the shortage of wood resources, reduce pollution and has a attractive prospect. In this paper, old newspaper fiber(ONPF)/recycled-polypropylene(rPP) Wood-Plastics Composite(WPC) was prepared by means of mixing processing and compression molding. The effects of technical conditions on the mechanical properties of WPC were investigated. The structure of composite was characterized by means of FTIR and SEM. The results show that, Wastepaper and waste-PP can be used as raw materials for preparation of WPC. The suitable preparation process for wastepaper/rPP composites was: wastepaper fiber 20%, blending temperature 175°C, blending time 15min, molding pressure 12MPa, molding temperature 175°C and molding time 10min. In these conditions, tensile strength and flexural strength of wastepaper/rPP composites are 23.6MPa and 28.8MPa respectively, increased by 20.9% and 12.6% compared to those of rPP matrix. The elongation at break of WPC is 10.6%, and the flexural modulus is 1328.9MPa,increased by 7.7% compared to those of rPP matrix. The structure analysis found that there is no chemical reaction between the fibers and the matrix. The research results have important practical significance in the field of printing and packaging waste recycling and utilization, environmental protection and energy saving.

2013 ◽  
Vol 747 ◽  
pp. 355-358 ◽  
Author(s):  
Pornsri Pakeyangkoon ◽  
Benjawan Ploydee

Mechanical properties of wood plastic composite, prepared from acrylate-styrene-acrylonitrile (ASA) and bagasse, were investigated. In this study, 10 to 50 phr of bagasse were used in order to obtain the wood plastic composite with superior mechanical properties. The wood plastic composites in the study were prepared by melt-blending technique. All materials were mixed by using a two-roll-mill, shaped into sheets by a compression molding machine and the specimens were cut with a cutting machine. Youngs modulus, flexural strength, flexural modulus, impact strength and hardness of the wood plastic composites were investigated and found to improve with increasing bagasse content. However, some composite properties, i.e., impact strength, was decreased by adding the bagasse and then become steady when the amount of bagasse added was more than 30 phr. It was concluded that wood plastic composites with the desirable mechanical properties can be formulated using ASA as the matrix polymer and 50 phr of bagasse.


2012 ◽  
Vol 32 (4-5) ◽  
pp. 291-299 ◽  
Author(s):  
Suhailah Mohd Sukri ◽  
Nor Liyana Suradi ◽  
Agus Arsad ◽  
Abdul Razak Rahmat ◽  
Azman Hassan

Abstract The objective of this work was to investigate the effect of kenaf contents on mechanical, thermal and morphological properties of recycled polyamide-6 (rPA-6)/recycled polypropylene (rPP) blends. Kenaf was used to enhance the properties of composites. Alkali treating of kenaf by sodium hydroxide (NaOH) and combination with propylene grafted maleic anhydride (PPgMA) as a compatibilizer produced good adhesion both between rPP and rPA-6, and rPA-6/rPP and kenaf. Tensile, flexural and Izod impact tests were evaluated to study the mechanical properties. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) tests were carried out to investigate thermal properties. Scanning electron microscopy (SEM) was performed for morphological analysis. Generally, the mechanical properties were successfully enhanced, especially Young’s modulus, flexural modulus, flexural strength and elongation at break, while there were some problems which caused the tensile strength and impact strength to be inferior. Thermal analysis showed that the crystallization of composites decreased as kenaf contents were increased. SEM showed a problem with kenaf and rPP/rPA-6 compatibility, which led to insufficient matrix at some places and agglomeration of kenaf at other places. Morphologically, there was unidirectional presence of kenaf in rPP main composites and random orientation in rPA-6 main composites.


2012 ◽  
Vol 630 ◽  
pp. 75-79
Author(s):  
Hua Yong Zhang ◽  
Xiao Jian Liu ◽  
Hai Yan Sun

Wood-plastic composites were produced by heating, blending and extruding with recycled plastics and wood fiber as chief raw materials and some thermoplastic resin as the additive. The compounding formula and producing craft were researched and optimized. The influence of the ratio of wood fiber and additives was examined. Wood-plastics composites with excellent performance were produced.


2020 ◽  
Vol 1015 ◽  
pp. 76-81
Author(s):  
Djoko Sihono Gabriel ◽  
Afifah Nadia Tiana

Plastic packaging that applied material value conservation paradigm will generate good quality plastic waste. It can be recycled to produce raw material for new packaging. However, repetitive recycling has impacts on lowering its mechanical properties. Recycled plastic is expected not to undergo mechanical properties degradation. This research proposed to blend recycled plastic pellets with its virgin plastic to reduce mechanical properties degradation. Mechanical properties of recycled polypropylene are compared to 100% virgin polypropylene and recycled/virgin polypropylene blends with composition 90/10, 70/30, 50/50, 30/70, and 10/90. Mechanical properties tested in this research are modulus of elasticity, tensile strength, elongation at break, and density. All were tested according to ASTM for mechanical properties testing materials. This study revealed blending 50% virgin polypropylene significantly improves mechanical properties of recycled plastics and keep improving at 70% virgin polypropylene. The optimum improvement based on four mechanical properties was found at composition 30/70 of recycled/virgin plastic. Elongation at break is the most critical property where degradation was found at 90/10. Blending 6th recycled and virgin polypropylene gives opportunities to improve the mechanical properties of recycled plastic products with careful consideration of the compositions. By implementing material value conservation, good quality plastic waste can be recycled repetitively. This will decrease accumulation of plastic waste generation and usage of non-renewable plastic’s raw material. The positive impact is not only to economic of plastic industry but also to the quality of environment.


2020 ◽  
Vol 38 (7A) ◽  
pp. 960-966
Author(s):  
Aseel M. Abdullah ◽  
Hussein Jaber ◽  
Hanaa A. Al-Kaisy

In the present study, the impact strength, flexural modulus, and wear rate of poly methyl methacrylate (PMMA) with eggshell powder (ESP) composites have been investigated. The PMMA used as a matrix material reinforced with ESP at two different states (including untreated eggshell powder (UTESP) and treated eggshell powder (TESP)). Both UTESP and TESP were mixed with PMMA at different weight fractions ranged from (1-5) wt.%. The results revealed that the mechanical properties of the PMMA/ESP composites were enhanced steadily with increasing eggshell contents. The samples with 5 wt.% of UTESP and TESP additions give the maximum values of impact strength, about twice the value of the pure PMMA sample. The calcination process of eggshells powders gives better properties of the PMMA samples compared with the UTESP at the same weight fraction due to improvements in the interface bond between the matrix and particles. The wear characteristics of the PMMA composites decrease by about 57% with increases the weight fraction of TESP up to 5 wt.%. The flexural modulus values are slightly enhanced by increasing of the ESP contents in the PMMA composites.


1999 ◽  
Vol 40 (11-12) ◽  
pp. 21-24
Author(s):  
Tapio Pento

Industrial ecology (IE) is a biological concept applied to industrial structures. The basic concepts of IE include regional, intra-firm and product-based waste recycling systems as well as the principle of upward and downward cascading. In best current examples of regional systems, several parties are in an industrial waste re-use symbiosis. Paper industry has learned to arrange the recovery and re-use of its products on distant markets, even up to a level where indications of exceeding optimal recovery and re-use rates already exist through deteriorated fibre and product quality. Such occurrences will take place in certain legislative-economic situations. Paper industry has many cascade levels, each with their internal recovery and recycling, as well as many intra-firm, regional, and life cycle ecology structures. As an example of prospects for individual cascading routes, sludges may continue to be incinerated, but the route to landfills will be closed. The main obstacles of legislative drive toward better IE systems are in many cases existing laws and political considerations rather than economic or technical aspects. The study and practice of engineering human technology systems and related elements of natural systems should develop in such a way that they provide quality of life by actively managing the dynamics of relevant systems to reduce the risk and scale of undesirable behavior and outcomes. For the paper industry, earth systems engineering offers several development routes. One of them is the further recognition of and research on the fact that the products of the industry are returned back to the carbon cycle of the natural environment. Opportunities for modifying current earth systems may also be available for the industry, e.g. genetically modified plants for raw materials or organisms for making good quality pulp out of current raw materials. It is to be recognized that earth systems engineering may become a very controversial area, and that very diverse political pressures may determine its future usefulness to the paper industry.


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1502
Author(s):  
Eliezer Velásquez ◽  
Sebastián Espinoza ◽  
Ximena Valenzuela ◽  
Luan Garrido ◽  
María José Galotto ◽  
...  

The deterioration of the physical–mechanical properties and loss of the chemical safety of plastics after consumption are topics of concern for food packaging applications. Incorporating nanoclays is an alternative to improve the performance of recycled plastics. However, properties and overall migration from polymer/clay nanocomposites to food require to be evaluated case-by-case. This work aimed to investigate the effect of organic modifier types of clays on the structural, thermal and mechanical properties and the overall migration of nanocomposites based on 50/50 virgin and recycled post-consumer polypropylene blend (VPP/RPP) and organoclays for food packaging applications. The clay with the most hydrophobic organic modifier caused higher thermal stability of the nanocomposites and greater intercalation of polypropylene between clay mineral layers but increased the overall migration to a fatty food simulant. This migration value was higher from the 50/50 VPP/RPP film than from VPP. Nonetheless, clays reduced the migration and even more when the clay had greater hydrophilicity because of lower interactions between the nanocomposite and the fatty simulant. Conversely, nanocomposites and VPP/RPP control films exhibited low migration values in the acid and non-acid food simulants. Regarding tensile parameters, elongation at break values of PP film significantly increased with RPP addition, but the incorporation of organoclays reduced its ductility to values closer to the VPP.


2021 ◽  
Vol 11 (12) ◽  
pp. 5317
Author(s):  
Rafał Malinowski ◽  
Aneta Raszkowska-Kaczor ◽  
Krzysztof Moraczewski ◽  
Wojciech Głuszewski ◽  
Volodymyr Krasinskyi ◽  
...  

The need for the development of new biodegradable materials and modification of the properties the current ones possess has essentially increased in recent years. The aim of this study was the comparison of changes occurring in poly(ε-caprolactone) (PCL) due to its modification by high-energy electron beam derived from a linear electron accelerator, as well as the addition of natural fibers in the form of cut hemp fibers. Changes to the fibers structure in the obtained composites and the geometrical surface structure of sample fractures with the use of scanning electron microscopy were investigated. Moreover, the mechanical properties were examined, including tensile strength, elongation at break, flexural modulus and impact strength of the modified PCL. It was found that PCL, modified with hemp fibers and/or electron radiation, exhibited enhanced flexural modulus but the elongation at break and impact strength decreased. Depending on the electron radiation dose and the hemp fibers content, tensile strength decreased or increased. It was also found that hemp fibers caused greater changes to the mechanical properties of PCL than electron radiation. The prepared composites exhibited uniform distribution of the dispersed phase in the polymer matrix and adequate adhesion at the interface between the two components.


2020 ◽  
Vol 10 (3) ◽  
pp. 1159 ◽  
Author(s):  
Yingmei Xie ◽  
Hiroki Kurita ◽  
Ryugo Ishigami ◽  
Fumio Narita

Epoxy resins are a widely used common polymer due to their excellent mechanical properties. On the other hand, cellulose nanofiber (CNF) is one of the new generation of fibers, and recent test results show that CNF reinforced polymers have high mechanical properties. It has also been reported that an extremely low CNF addition increases the mechanical properties of the matrix resin. In this study, we prepared extremely-low CNF (~1 wt.%) reinforced epoxy resin matrix (epoxy-CNF) composites, and tried to understand the strengthening mechanism of the epoxy-CNF composite through the three-point flexural test, finite element analysis (FEA), and discussion based on organic chemistry. The flexural modulus and strength were significantly increased by the extremely low CNF addition (less than 0.2 wt.%), although the theories for short-fiber-reinforced composites cannot explain the strengthening mechanism of the epoxy-CNF composite. Hence, we propose the possibility that CNF behaves as an auxiliary agent to enhance the structure of the epoxy molecule, and not as a reinforcing fiber in the epoxy resin matrix.


2013 ◽  
Vol 380-384 ◽  
pp. 39-42
Author(s):  
Shun Xi Gao ◽  
Shu Guo Zhao ◽  
Li Fang Zhao

This paper establishes a parametric model on the motor hanging seat structure by pro / ENGINEER software, and then optimizes the structure of the hanging seat by the weight of the hanging seat as the objective function. Taking into account the stress and displacement constraints in the optimization process, the weight of the hanging seat is greatly reduced after being optimized. It is practical significance to save a large amount of raw materials for the mass production and to reduce production costs and create higher economic efficiency.


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