Preparation and Characterization of Steel Slag Adsorbent

2011 ◽  
Vol 48-49 ◽  
pp. 844-847
Author(s):  
Sheng Yu Liu ◽  
Yuan Yuan Xu ◽  
Jin Gao ◽  
Cheng Wei Lu ◽  
Yi Jin Yang
Keyword(s):  
Surface Characterization ◽  
Ph Value ◽  
Steel Slag ◽  
X Ray Diffraction ◽  
Steel Making ◽  
Adsorption Capacities ◽  
Adsorption Processes ◽  
Solid Liquid ◽  
Solid Liquid Separation

Steel slag is a industry solid waste which come from steel making factory，and is easy to solid-liquid separation, so it posses some adsorption capacities and can be used as adsorbent. Adsorption phenol onto steel slag was investigated by the oscillating adsorption experiments and the effect of different operating parameters on these adsorption processes, such as initial concentration phenol and the pH value were studied. The surface characterization were gained by SEM, X-ray diffraction, IR Spectroscopy and BET.

Preparation of Steel Slag Adsorbent and its Removal Phenol Property

2011 ◽  
Vol 213 ◽  
pp. 460-464
Author(s):  
Sheng Yu Liu ◽  
Jin Gao ◽  
Yuan Yuan Xu ◽  
Cheng Wei Lu ◽  
Yi Jin Yang
Keyword(s):  
Surface Characterization ◽  
Ph Value ◽  
Steel Slag ◽  
X Ray Diffraction ◽  
X Ray ◽  
Steel Making ◽  
Adsorption Capacities ◽  
Adsorption Processes ◽  
Solid Liquid ◽  
Solid Liquid Separation

Steel slag is a industry solid waste which come from steel making factory，and is easy to solid-liquid separation, so it posses some adsorption capacities and can be used as adsorbent. Adsorption phenol onto steel slag was investigated by the oscillating adsorption experiments and the effect of different operating parameters on these adsorption processes, such as initial concentration phenol and the pH value were studied. The surface characterization were gained by SEM, X-ray diffraction, IR Spectroscopy and BET.

The Use of Advanced Analytical Techniques for Characterization of the Chemical, Physical, and Crystallographic Nature of a Surface

1973 ◽  
Vol 31 ◽  
pp. 132-133 ◽  
Author(s):  
R. E. Herfert
Keyword(s):  
Surface Characterization ◽  
Analytical Techniques ◽  
X Ray Diffraction ◽  
Depth Of Penetration ◽  
X Ray ◽  
The Past ◽  
Transmission Electron ◽  
Scanning Electron

Studies of the nature of a surface, either metallic or nonmetallic, in the past, have been limited to the instrumentation available for these measurements. In the past, optical microscopy, replica transmission electron microscopy, electron or X-ray diffraction and optical or X-ray spectroscopy have provided the means of surface characterization. Actually, some of these techniques are not purely surface; the depth of penetration may be a few thousands of an inch. Within the last five years, instrumentation has been made available which now makes it practical for use to study the outer few 100A of layers and characterize it completely from a chemical, physical, and crystallographic standpoint. The scanning electron microscope (SEM) provides a means of viewing the surface of a material in situ to magnifications as high as 250,000X.

scholarly journals Characterization of Steel Slag Filler and Its Effect on Aging Resistance of Asphalt Mastic with Various Aging Methods

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 869
Author(s):  
Minghua Wei ◽  
Shaopeng Wu ◽  
Haiqin Xu ◽  
Hechuan Li ◽  
Chao Yang
Keyword(s):  
Particle Size ◽  
Surface Characterization ◽  
Steel Slag ◽  
Self Healing ◽  
Limestone Filler ◽  
Asphalt Mastic ◽  
Pore Characterization ◽  
Asphalt Mastics ◽  
Healing Property

Steel slag is the by-product of the steelmaking industry, the negative influences of which prompt more investigation into the recycling methods of steel slag. The purpose of this study is to characterize steel slag filler and study its feasibility of replacing limestone filler in asphalt concrete by evaluating the resistance of asphalt mastic under various aging methods. Firstly, steel slag filler, limestone filler, virgin asphalt, steel slag filler asphalt mastic and limestone filler asphalt mastic were prepared. Subsequently, particle size distribution, surface characterization and pore characterization of the fillers were evaluated. Finally, rheological property, self-healing property and chemical functional groups of the asphalt mastics with various aging methods were tested via dynamic shear rheometer and Fourier transform infrared spectrometer. The results show that there are similar particle size distributions, however, different surface characterization and pore characterization in the fillers. The analysis to asphalt mastics demonstrates how the addition of steel slag filler contributes to the resistance of asphalt mastic under the environment of acid and alkaline but is harmful under UV radiation especially. In addition, the pore structure in steel slag filler should be a potential explanation for the changing resistance of the asphalt mastics. In conclusion, steel slag filler is suggested to replace limestone filler under the environment of acid and alkaline, and environmental factor should be taken into consideration when steel slag filler is applied to replace natural fillers in asphalt mastic.

Preparation and Application of Lead Dioxide Electrode for Zinc Electrolysis

2013 ◽  
Vol 785-786 ◽  
pp. 1125-1129
Author(s):  
Xiao Yong Yang ◽  
Pei Xian Zhu ◽  
Yun Sen Si
Keyword(s):  
Surface Characterization ◽  
Catalytic Properties ◽  
Lead Dioxide ◽  
Manufacturing Cost ◽  
X Ray Diffraction ◽  
Simulation Test ◽  
X Ray ◽  
Zinc Smelter ◽  
Lead Dioxide Electrode

According to the process of anodic oxygen evolution in sulfate system for zinc electrolysis,Ti-base lead dioxide electrode can be prepared to use in this case.The surface characterization of the electrode was studied by Scanning electron microscopy(SEM) and X-ray diffraction(XRD).The electrode lifetime was tested in 1mol/L H2SO4solution at 60°C,and the electro-catalytic properties was examined by polarization curves.Then these samples was enlarged and simulation test was conducted at Mengzi marriage zinc smelter in Yunnan.The results show that the electro-catalytic properties is better and the electrodes lifetime is longer compared to the traditional lead electrode.Moreover,it has a significant effect in reducing energy consumption, manufacturing cost and improving the production and grade of zinc.

scholarly journals Experimental Study on Precipitation Behavior of Spinels in Stainless Steel-Making Slag under Heating Treatment

Processes ◽  
2019 ◽  
Vol 7 (8) ◽  
pp. 487 ◽  
Author(s):  
Jianli Li ◽  
Qiqiang Mou ◽  
Qiang Zeng ◽  
Yue Yu
Keyword(s):  
Particle Size ◽  
Stainless Steel ◽  
Steel Slag ◽  
Calcium Content ◽  
Heating Time ◽  
X Ray Diffraction ◽  
Stainless Steel Slag ◽  
Steel Making ◽  
Heating Treatment ◽  
The Stability

The stability of chromium in stainless steel slag has a positive correlation with spinel particle size and a negative correlation with the calcium content of the spinel. The effect of heating time on the precipitation of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3-FeO system was investigated in the laboratory. Scanning electron microscopy with energy-dispersive and X-ray diffraction were adopted to observe the microstructure, test the chemical composition, and determine the mineral phases of synthetic slags, and FactSage7.1 was applied to calculate the crystallization process of the molten slag. The results showed that the particle size of the spinel crystals increased from 9.42 to 10.73 μm, the calcium content in the spinel crystals decreased from 1.38 at% to 0.78 at%, and the content of chromium in the spinel crystal increased from 16.55 at% to 22.78 at% with an increase in the heating time from 0 min to 120 min at 1450 °C. Furthermore, the species of spinel minerals remained constant. Therefore, an extension in the heating time is beneficial for improving the stability of chromium in stainless steel slag.

Synthesis and Characterization of Immobilized Nanometer Calcium Titanate and the Application in Speciation Analysis for Chromium

2010 ◽  
Vol 129-131 ◽  
pp. 724-727
Author(s):  
Dong Zhang
Keyword(s):  
Silica Gel ◽  
Sol Gel ◽  
Speciation Analysis ◽  
Environmental Water ◽  
Complete Separation ◽  
Calcium Titanate ◽  
X Ray Diffraction ◽  
Ph Values ◽  
Adsorption Capacities

Nanometer calcium titanate immobilized on silica gel G (SGCTO) was prepared by the sol–gel method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectrophotometry (FTIR). Its application in speciation of Cr(III) and Cr(VI) from water was studied. Adsorption and elution were investigated under different conditions. The results showed that the nanometer calcium titanate was immobilized on the silica gel G firmly, becoming a new adsorbent. At normal temperature, two forms of chromium show different adsorption capacities at different pH values, that is, Cr (III) selectively retained at pH 8–14, but Cr(Ⅵ) can’t be adsorbed. Whereas Cr (VI) retained at pH 1, but Cr(Ⅲ) can’t be adsorbed. Hence complete separation of the two forms of chromium is possible. Retained Cr(III) and Cr(VI) were eluted with 1 mol•L−1 HCl and 2 mol•L−1NaOH, respectively. The Cr(III) and Cr(VI) concentration was measured by atomic absorption spectroscopy. The method was successfully applied for the speciation of chromium in environmental water samples.

scholarly journals β-Cyclodextrin Modified Poly(Acrylonitrule-co-Acrylic Acid) Hydrogel for Thorium(IV) Adsorption

Polymers ◽  
2017 ◽  
Vol 9 (6) ◽  
pp. 201 ◽  
Author(s):  
Guojian Duan ◽  
Qiangqiang Zhong ◽  
Lei Bi ◽  
Liu Yang ◽  
Tonghuan Liu ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Contact Time ◽  
Ph Value ◽  
Water System ◽  
Maximum Adsorption Capacity ◽  
Practical Application ◽  
X Ray Diffraction ◽  
Liquid Ratio ◽  
X Ray ◽  
Solid Liquid

In this report, the β-CD(AN-co-AA) hydrogel was used to remove the thorium(IV) [Th(IV)] from the water system, and the new adsorbent was characterized through Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The influences of contact time, pH value, ionic strength, solid-liquid ratio, initial Th(IV) concentration, and temperature on Th(IV) adsorption onto the functional hydrogel were researched. The results showed that the experimental data followed the Langmuir isotherm and the maximum adsorption capacity (qmax) for Th(IV) was 692 mg/g at pH 2.95, which approached the calculated (qe) 682 mg/g. The desorption capacity of Th(IV) in different HNO3 concentrations ranging from 0.005 to 0.5 M was also studied, and the percentage of the maximum desorption was 86.85% in the condition of 0.09 M HNO3. The selectivity of β-CD(AN-co-AA) hydrogel was also be studied, the results indicated that this material retained the good adsorption capacity to Th(IV) even when the Ca2+, Mg2+, or Pb2+ existed in the system. The findings indicate that β-CD(AN-co-AA) can be used as a new candidate for the enrichment and separation of Th(IV), or its analogue actinides, from large-volume solution in practical application.

Surface Characterization of Carbon-Bearing Magnetite (CBM) and Carbon-Bearing Ni(II)-Ferrite (CBNF)

1994 ◽  
Vol 344 ◽  
Author(s):  
T. Sano ◽  
K. Akanuma ◽  
M. Tsuji ◽  
Y. Tamaura
Keyword(s):  
Photoelectron Spectroscopy ◽  
Spinel Structure ◽  
Surface Characterization ◽  
Carbon Deposition ◽  
X Ray Diffraction ◽  
Xps Spectra ◽  
X Ray ◽  
Oxygen Ions ◽  
Diffraction Patterns

AbstractOxygen-deficient magnetite (ODM; Fe3O4-δ, δ>0) synthesized by reduction of magnetite with H2 at 300°C decomposed CO2 to carbon with an efficiency of nearly 100% at 300°C. In this reaction, two oxygen ions of the CO2 were incorporated into the spinel structure of ODM and carbon was deposited on the surface of ODM with zero valence to form visible particles. The particles of carbon separated from ODM were studied by Raman, energy-dispersive X-ray and wave-dispersive X-ray spectroscopies. The carbon which had been deposited on the ODM was found to be a mixture of graphite and amorphous carbon in at least two levels of crystallization. X-ray photoelectron spectroscopy and X-ray diffraction patterns of the carbon-bearing magnetite (CBM) showed no indication of carbide (Fe3C) or metallic iron (α-Fe) phase formation. In the C 1s XPS spectra of the CBM, no peaks were observed which could be assigned to CO2 or CO. X-ray diffractometry, chemical analysis and TG-MS measurement showed that the carbon-bearing Ni(II)-ferrite (CBNF) (Ni(II)/Fetotal = 0.15) synthesized by the carbon deposition reaction from CO2 with the H2-reduced Ni(II)-ferrite was represented by (Ni0.28Fe2.72O4.00)1-δ (Ni2+06.9Fe2+2.31O3.00)δCτ (δ= 0.27, τ= 0.17). The carbon of the CBNF gave the CIOlayer-like oxide containing some Ni2+ ions.

Tribocorrosion behavior of electroless Ni-P/Ni-B duplex coating on AA7075 aluminum alloy

2019 ◽  
Vol 71 (5) ◽  
pp. 630-635 ◽  
Author(s):  
Harun Mindivan
Keyword(s):  
Aluminum Alloy ◽  
Surface Characterization ◽  
X Ray Diffraction ◽  
Electron Microscopic ◽  
Content Type ◽  
Duplex Coating ◽  
Scanning Electron Microscopic ◽  
Electroless Ni ◽  
Insight Into

Purpose This paper aims to investigate the structural, corrosion and the study of tribocorrosion features of the AA7075 aluminum alloy with and without the application of electroless Ni-P/Ni-B duplex coating with a thickness of approximately 40 microns. Design/methodology/approach Surface characterization of the samples was made by structural surveys (light optic microscope, scanning electron microscopic examinations and X-ray diffraction analyses), hardness measurements, corrosion and tribocorrosion tests. Findings Results of the experiments showed that upper Ni-B coating deposited on the surface of first Ni-P layer by duplex treatment caused remarkable increment in the hardness, corrosion resistance and tribocorrosion performance as compared to the AA7075 aluminum alloy. Originality/value This study can be a practical reference and offers insight into the effects of duplex treating on the increase of hardness, corrosion and tribocorrosion performance.

Microscopic characterization of acidic paper manuscripts

2019 ◽  
Vol 48 (2) ◽  
pp. 119-128 ◽  
Author(s):  
Safa Abd El kader Mohamed Hamed ◽  
Rushdya Rabee Ali Hassan
Keyword(s):  
Ph Value ◽  
Morphological Changes ◽  
Environmental Scanning ◽  
X Ray Diffraction ◽  
Arabic Gum ◽  
Content Type ◽  
Cellulosic Fibers ◽  
Fiber Degradation ◽  
Historical Samples

Purpose This paper aims to investigate the effect of acidity on the morphology of archeological paper, especially in the presence of colors and whether natural pigments play a role in the process of degradation. Design/methodology/approach The morphological changes in the cellulosic fibers of the manuscripts because of acidity were investigated using environmental scanning electron microscope (ESEM). Ten historical samples were collected from different manuscripts suffering from acidity. X-ray diffraction was used to identify the inks and pigments that were used in some samples. Additionally, Fourier transform infrared microscopy was used to identify the binding medium. Findings The results confirmed that carbon ink, ultramarine, cinnabar and gold pigments were applied to some manuscripts with Arabic gum. As for ESEM investigation, the results proved that acidity badly affected the integrity of the cellulosic fibers resulting in their embrittlement. The micrographs showed differences in fiber degradation according to pH value. The presence of inks and pigments increased the degradation extent resulting from acidity. Originality/value This paper addresses a specific need to study the behavior of degradation in paper manuscripts, thus helping the conservators find solutions to the phenomenon.

Sign in / Sign up

Export Citation Format

Share Document