Improvement on Dyeing Performance of Different Bifunctional Reactive Dyes for Soybean Protein Fibers

2012 ◽  
Vol 502 ◽  
pp. 306-311 ◽  
Author(s):  
Jing Chun Lv ◽  
Hong Qin Lin ◽  
Qing Qing Zhou ◽  
Jing Li
Keyword(s):  
Mechanical Strength ◽  
Ph Value ◽  
Soybean Protein ◽  
Reactive Dyes ◽  
Dyeing Performance ◽  
Dyeing Process ◽  
Protein Fibers ◽  
Reactive Groups ◽  
Dyeing Effluent ◽  
Dyed Fabrics

This study assesses dyeing performance of reactive dyes with monofluorotriazine and modified cvinyl-sulfone bifunctional reactive groups in alkaline/acid denaturalization bath to the soybean fibers. It has been shown that 3~4 of the dyeing pH value, 60 minutes and 70°C of dyeing time and temperature were selected for denatured bath. The denaturalization bath can dramatically improve exhaustion and fixation and significantly decrease the chromaticity of the dyeing effluent. Besides, colorimetric properties, fastness and mechanical strength of the dyed fabrics were evaluated to indicate applicability of this dyeing process of soybean protein fibers.

Union Dyeing of Soybean Protein Fiber/Wool Blends

2011 ◽  
Vol 332-334 ◽  
pp. 1421-1424 ◽  
Author(s):  
Lei Zhu ◽  
Jun Li Chen ◽  
Qiu Bao Zhou ◽  
Jin Huan Zheng ◽  
Wei Guo Chen
Keyword(s):  
Smooth Surface ◽  
Soybean Protein ◽  
Reactive Dyes ◽  
Wool Fiber ◽  
Bleaching Process ◽  
Bursting Strength ◽  
The Past ◽  
Dyeing Process ◽  
Protein Fibers ◽  
Protein Fiber

Protein fibers are attractive topics in the past decades. Among them, soybean protein fiber, the regenerated protein-base fiber, is very popular due to its luster, smooth surface, breathability, and comfort. In order to blend with wool and reach union dyeing, soybean protein fiber was first bleached due to its yellow appearance. Various bleaching processes were introduced in this paper. Reactive dyes for cellulose and for wool, such as Unisol or Megafix dyes, together with proper dyeing process were selected and compared. The results showed that one-time oxidation bleaching is confirmed as the bleaching process due to its compromise of high whiteness and bursting strength. It is unable to reach union dyeing for soybean protein fiber/wool fiber with Unisol or Megafix dyes respectively while it is feasible to reach union dyeing of soybean protein fiber/wool fiber dyeing with Unisol dyes followed by Megafix dyes.

scholarly journals Natural Dyeing of Cellulose and Protein Fibers with the Flower Extract of Spartium junceum L. Plant

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4091
Author(s):  
Zorana Kovačević ◽  
Ana Sutlović ◽  
Ana Matin ◽  
Sandra Bischof
Keyword(s):  
Negative Impact ◽  
Environmentally Friendly ◽  
Future Research ◽  
Wool Fabric ◽  
Dyeing Process ◽  
Protein Fibers ◽  
Wool Sample ◽  
C Value ◽  
Total Difference ◽  
Spartium Junceum

In this study, the natural dye was extracted from Spartium junceum L. (SJL) flowers and applied on cellulose (cotton) and protein (wool) fabric. Fabrics were pre-mordant with alum prior to the dyeing process. Considering the global requirements on zero waste and green policy, the dyeing process was intended to be as much as possible environmentally friendly but still effective. Therefore, mordant concentration was optimized due to the reduction of the negative impact. The efficiency of the dyeing process was investigated by examination of fabrics’ color characteristics and colorfastness to washing properties. In this paper, we have proved that the extracted dye from Spartium junceum L. is an acidic dye (mordant dye) which is more applicable for the treatment of wool fabrics. In this paper, it was proved that phytochemicals responsible for coloring are part of the flavonoids group. The UV absorption spectra of extracted dye show 4 bands in the region of λmax 224, 268, 308 and 346 nm which are ascribed to bands characteristic for flavonoids. Wool fabric pre-mordant with 3% alum and dyed shows great chromatic (C*) properties where C* value is in a range from 47.76 for unwashed samples to 47.50 for samples after 5 washing cycles and color hue (h°) is in a range 82.13 for unwashed samples to 81.52 for samples after 5 washing cycles. The best result regarding the colorfastness properties is shown by the wool sample treated with 3% alum after 5 washing cycles (total difference in color (Delta E*) = 0.87). These results confirm that metal (Al) from alum mordant make strong chemical bonds with wool substrate and dye since Delta E* values decrease in comparison to Delta E* values of the cotton samples treated the same way. The results revealed it is possible to reduce the concentration of mordant up to 3% and obtain satisfactory results regarding the colorfastness. Nevertheless, future research will go in the direction of replacing synthetic mordant with a more environmentally friendly one.

scholarly journals Renovation and Reuse of Reactive Dyeing Effluent by a Novel Heterogeneous Fenton System Based on Metal Modified PTFE Fibrous Catalyst/H2O2

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Bing Li ◽  
Yongchun Dong ◽  
Zhizhong Ding ◽  
Yiming Xu ◽  
Chi Zou
Keyword(s):  
Reactive Dyes ◽  
Cotton Fabrics ◽  
Molar Ratio ◽  
The Novel ◽  
Heterogeneous Fenton ◽  
Reactive Dyeing ◽  
Toc Removal ◽  
Dyeing Effluent ◽  
Fenton System

Cu-Fe bimetallic grafted polytetrafluoroethylene (PTFE) fiber complexes were prepared and optimized as the novel heterogeneous Fenton catalysts for the degradation of reactive dyes under UV irradiation. Cotton fabrics were dyed with three reactive dyes, namely, Reactive Red 195, Reactive Yellow 145, and Reactive Blue 222, in tap fresh water using exhaustion process. The spent dyeing effluents were then collected and degraded with the optimized Cu-Fe bimetallic grafted PTFE fiber complex/H2O2system. The treated dyeing effluents were characterized and reused for the dyeing of cotton fabrics through the same process. The effect of reuse process number on quality of the dyed cotton fabrics was examined. The results indicated that the Cu-Fe bimetallic modified PTFE fiber complex with a Cu/Fe molar ratio of 2.87 was found to be the most effective fibrous catalyst, which enhanced complete decolorization of the treated dyeing effluents with H2O2in 4 h. However, the TOC removal for the treated dyeing effluents was below 80%. The dyeing quality was not affected for three successive cycles. The increase in residual TOC value influences fourth dyeing cycle. Further TOC reduction of the treated effluents is needed for its repeated reuse in more than three dyeing cycles.

scholarly journals Dyeing of Polyester with 4-Fluorosulfonylphenylazo-5-pyrazolone Disperse Dyes and Application of Environment-Friendly Aftertreatment for Their High Color Fastness

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4209 ◽  
Author(s):  
Sanghyun Yoon ◽  
Byunghun Choi ◽  
Md Morshedur Rahman ◽  
Santosh Kumar ◽  
Shekh Md Mamun Kabir ◽  
...  
Keyword(s):  
Nitro Group ◽  
Oxygen Demand ◽  
Biological Oxygen Demand ◽  
Disperse Dyes ◽  
Color Fastness ◽  
Fastness Properties ◽  
Environment Friendly ◽  
Dyeing Process ◽  
Pyrazolone Derivatives ◽  
Dyeing Effluent

Dyeing and fastness properties of a series of 4-fluorosulfonylphenylazo-5-pyrazolone dyes on polyester were investigated in this study. The 4-nitrophenylazo-5-pyrazolone dyes were also synthesized to compare their dyeing and fastness properties on polyester with those of fluorosulfonyl-substituted analogues. The substantivity of 4-arylazo-5-pyrazolone derivatives containing a p-fluorosulfonyl group in the diazo component was lower than that of their nitro analogues which have a higher extinction coefficient and higher affinity because of the polar nitro group. They showed relatively hypsochromic color and lower chroma on polyester compared with their nitro analogues because of the relatively weaker electron-accepting power of the fluorosulfonyl group compared to the nitro group. Disperse dyeing of polyester with 4-fluorosulfonylphenylazo-5-pyrazolone disperse dyes achieved high color fastness and reduces the adverse environmental impact of the dyeing process by providing the option of performing alkali clearing instead of reductive clearing, which has high biological oxygen demand when discharged into the dyeing effluent and generates carcinogenic aromatic amines.

scholarly journals Preparation of hydroxyapatite-based porous materials for absorption of lead ions

2019 ◽  
Vol 80 (7) ◽  
pp. 1266-1275
Author(s):  
Zejun Wang ◽  
Kangqi Sun ◽  
Yufeng He ◽  
Pengfei Song ◽  
Dawei Zhang ◽  
...  
Keyword(s):  
Porous Materials ◽  
Metal Ion ◽  
Ph Value ◽  
Soybean Protein ◽  
Protein Isolate ◽  
Soybean Protein Isolate ◽  
Bet Analysis ◽  
Initial Ph ◽  
Infrared Spectrometer ◽  
Composition Structure

Abstract In this paper, soybean protein isolate (SPI) was used as template, hydroxyapatite was crystallized on protein chains of SPI by in-situ synthesis, then the obtained inorganic HA/biopolymer SPI composite (HA@SPI) was calcined at suitable temperature, which afforded a novel hydroxyapatite-based porous materials (HApM). The results indicated that the product showed a porous morphology structure and excellent absorption performance for Pb2+. HApM maximum removal of lead was attained (96.25%) at an initial pH value of 7.4, temperature of 25 °C and contact time of 30 min with an initial metal concentration of 60 mg/L. In order to identify composition, structure and functional groups involved in the uptake of Pb2+, Fourier transform infrared spectrometer (FTIR), thermogravimetric analysis (TG), X-ray diffraction (XRD) scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Brunauer–Emmett–Teller (BET) analysis were carried out. Therefore, the hydroxyapatite-based porous materials (HApM) is a promising candidate for the treatment of liquid wastes containing toxic Pb2+ metal ion, heavy metal ion antidotes and other related fields.

Study on Dyeing Properties of Black Rice Pigment on Tussah Silk

2013 ◽  
Vol 821-822 ◽  
pp. 626-629 ◽  
Author(s):  
Yan Mei Jia
Keyword(s):  
Ph Value ◽  
Visible Spectrum ◽  
Black Rice ◽  
Natural Pigment ◽  
Dyeing Properties ◽  
Dyeing Process ◽  
The Stability ◽  
Dyed Fabric ◽  
Mordant Dyeing ◽  
Color Depth

To enrich the color of natural dyes, a natural pigment was extracted from black rice and used to dye tussah silk. The stability of the extract to mordant ions was investigated by Visible Spectrum and the effect of the dyeing pH, dyeing temperature, dyeing time as well as mordant process on dyeing properties (K/S value) were studied, the optimum dyeing process was obtained. The results show that the optimized direct dyeing process is pH value 4. 5, dyeing at 90 °C for 60 min, the color of dyed fabric various with metal ions. In comparison, the fabric post-mordant dyeing with ferrous sulfate exhibits the higher color depth and better color fastness.

A novel approach for dyeing of polyester using non-aqueous deep eutectic solvent as a dyeing medium

2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Sushant S. Pawar ◽  
Ravindra Adivarekar
Keyword(s):  
Water Conservation ◽  
Textile Industry ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Content Type ◽  
Dyeing Performance ◽  
Novel Approach ◽  
Wet Processing ◽  
Dyed Fabrics ◽  
Dyeing Parameters

Purpose Textile industry is considered to be one of the largest consumers of water. There needs to be an alternative for water in textile wet processing. Solvent dyeing can be an approach to replace the use of water in dyeing for water conservation. Design/methodology/approach In this study, the dyeing of polyester was carried out using conventional and solvent dyeing methods. The solvent used was non-aqueous, deep eutectic solvent (DES) prepared using choline chloride and urea. Dyeing parameters such as time, temperature and pH were optimized for a concentration of dye using the solvent and were compared with the conventional dyeing. Findings The prepared solvent was characterized in terms of Fourier-transform infrared resonance and 1H and 13C nuclear magnetic resonance to analyze the reaction between choline chloride and urea. Dyeing performance in terms of K/S and fastness properties of dyed fabrics were evaluated and found to be at par against conventional dyeing. Originality/value Use of DES as a dyeing medium is a novel approach in the textile industry.

Degradation of Reactive Red K-2G by a Photoassisted Fenton Reaction Using a Novel Loading Phthalocyanine Sulfonic Iron Fibers as a Catalyst

2011 ◽  
Vol 175-176 ◽  
pp. 712-716
Author(s):  
Hai Ning Lv ◽  
Li Ping Xu ◽  
Cheng Qian
Keyword(s):  
Fenton Reaction ◽  
Ph Value ◽  
Dye Degradation ◽  
Reactive Dyes ◽  
Cellulose Fibers ◽  
Catalyst Loading ◽  
Solution Ph ◽  
Catalyst Dosage ◽  
Silk Fabrics ◽  
Modified Cellulose

Reactive dyes have been widely used in the dyeing of bright colourful silk fabrics. The discoloration and degradation of Reactive Red K-2G in waste water were discussed in this paper. A new heterogeneous photocatalyst named loading phthalocyanine sulfonic iron fibers (FePcS-F) was prepared by phthalocyanine sulfonic Iron supported by modified cellulose fibers in acidic condition. The photocatalytic degradation of Reactive Red K-2G was characterized by discoloration rate to evaluate the effect of catalyst dosage, catalyst loading (CFePcS-F) and solution pH. The results proved that increasing catalyst dosage and CFePcS-F significantly accelerated the dye degradation. FePcS-F catalyst showed higher photocatalytic activity when the solution’s pH value is equal to or less than 6.0, compared to alkaline medium.

Investigation into Acceleration Efficiency of Ultrasound in Dyeing Process

2013 ◽  
Vol 734-737 ◽  
pp. 2222-2225
Author(s):  
De Shuai Sun ◽  
Long Fang ◽  
Tao Liu
Keyword(s):  
Reactive Dyes ◽  
Dyeing Wastewater ◽  
Dyeing Process ◽  
Ultrasound Energy ◽  
Remazol Red ◽  
Experimental Findings

Ultrasound energy could strengthen the adsorption of dyes on fiber. The acceleration efficiency of ultrasound was investigated by dyeing cotton with reactive dyes. The experimental findings showed the accelerative efficiency of ultrasound decreased with the prolongation of dyeing time and increment of dyeing temperature. Ultrasound exhibited a better acceleration effect in high dye concentration. The use of ultrasound reduced about 27.2% Remazol red RGB and 50.3% Remazol yellow 3RS in dyeing wastewater.

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