Microscopic Mechanism of the Diffusivity of Concrete Chloride Ion

2013 ◽  
Vol 773 ◽  
pp. 687-692 ◽  
Author(s):  
Jun Liu ◽  
Feng Xing ◽  
Bi Qing Dong

Use concrete specimens with different mix proportions to conserve them for 90d taking into account the influence of mineral admixture material---fly ash. Then adopts the RCM test method to measure the rapid diffusivity of chloride ion of concrete and observes the microstructure of the cement paste using the SEM (scanning electron microscopy), aiming to study the impact of fly ash on its hydration process. The results show that the micro-pore structure of the concrete has a great influence on the rapid diffusivity of chloride ion, while its diffusivity is closely related with the water-cement ratio of concrete; after the fly ash is added, the ettringite generation of the concrete in the early stage decreases, and the interspace of the transition zone between the hydrated particles and hydration slurry is enlarged, coupled with the increase in the intercommunicating pore; after curing for 90d, the chloride ion diffusivity decreases significantly with the increase in the dosage of fly ash. For the concrete with the fly ash dosage of 15%, its chloride ion diffusivity is only 75.4% of that with the same water-cement ratio; when its fly ash content is 30%, its chloride ion diffusivity is only 32.3% of the ordinary concrete.

2016 ◽  
Vol 847 ◽  
pp. 469-475 ◽  
Author(s):  
Hai Bo Ren ◽  
Jian Yin ◽  
Zheng Hui Sang ◽  
Ting Gao

Water-cement ratio is an important parameter of concrete quality. Rapid measurement of fresh concrete water-cement ratio can effectively monitor the on-site concrete quality management and play a great role in quality control. We study the variation of fresh concrete resistivity with the aid of electrodeless cement concrete resistivity meter, and discuss the impact of water-cement ratio under different varieties of cement, mineral admixture, chemical admixtures conditions on fresh concrete resistivity. We establish the relationships between fresh concrete resistivity and water-cement ratio based on the law of Portland cement initial hydration resistivity. The studies show that: fresh concrete resistivity is most vulnerable to the changes of water-cement ratio; there is a correlation between the law of fresh concrete resistivity and water-cement ratio; according to the fresh concrete resistivity variation, we can quickly identify water-cement ratio, cement and other parameters.


2013 ◽  
Vol 357-360 ◽  
pp. 1200-1205
Author(s):  
Chun Hui Yu ◽  
Gu Hua Li ◽  
Jin Liang Gao ◽  
Qun Wei ◽  
Da Zhen Xu

Compared with natural sand, manufactured-sand is of small porosity, poor grain shape and graded, which impacts mixes workability and the properties after hardening. In Concrete, playing the role of retaining moisture water is mainly powder, including cement, powder in the sand and fly ash etc. The amount of powder has a great influence on the properties of concrete, especially on its workability. This paper mainly discusses the influence of amount of cement, cementitious materials, fly ash, water-cement ratio and other factors on the workability, compressive strength and shrinkage of concrete. The experiments show that, in the case of the low amount of cement, workability of the manufactured-sand concrete mixture, compressive strength and shrinkage deformation of test block all meet the actual requirements.


2012 ◽  
Vol 174-177 ◽  
pp. 152-158 ◽  
Author(s):  
Jing Song Zhu ◽  
Ya Li Sun ◽  
Yue Feng Zhu ◽  
Dan Fei Chen

By means of accelerated carbonation tests, the carbonation resistance of concrete in relation to the variation of water-cement ratio, fly ash content and curing conditions is studied in this article. The results show that under the standard curing conditions, with the fly ash content of 20%, in response to different water-cement ratio, the carbonation depth of concrete and the water-cement ratio are presented more or less in a linear relationship. At the water-cement ratio of 0.40, there is hardly any carbonation effect onto the concrete. However, at the ratio of bigger than 0.60, the carbonation depth of concrete increases in a speedy way. Under the standard curing conditions, at the water-cement ratio of 0.55, with the fly ash content of lower than or equal to 30%, the carbonation resistance of concrete is good enough to fulfill the design criteria of 50~100 years for service life of important and general buildings, while the compressive strength declines by less than 10%. But under the condition of 1d curing with retention of moisture followed by curing in the air until 28d, with no fly ash content, the carbonation depth of concrete has reached 35mm, which fails to fulfill the design criteria of 50 years for service life of general buildings. It is therefore concluded that the control of water-cement ratio, the control of fly ash content, and the sufficient curing with retention of moisture in early stage are all the essential factors to ensure the durability against carbonation for the concrete with fly ash content.


2013 ◽  
Vol 405-408 ◽  
pp. 2801-2805
Author(s):  
Ji Feng Liang ◽  
Lei Lv ◽  
Feng Wang

The use of orthogonal test method, the concrete mixed with limestone power and fly ash was carried out static compressive experiment, and contrast with the experiment of single doped with limestone powder and fly ash concrete. The experimental result demonstrated that the compressive strength enhancement effect of the concrete mixed with limestone power and fly ash was obvious. The importance of each factor affecting static compressive strength as follows: water-cement ratio, the amount of fly ash, the amount of limestone powder, sand ratio. The concrete compressive strength reached the maximum when the water-cement ratio reached 0.3, the limestone powder content reached 15%, the fly ash content reached 10%, and sand ratio reached 34%.


2014 ◽  
Vol 584-586 ◽  
pp. 1176-1181 ◽  
Author(s):  
Ying Zi Yang ◽  
Mao Guang Li ◽  
Hong Wei Deng ◽  
Qi Liu

The present study investigated experimentally effects of temperature on drying shrinkage of concrete in different water cement ratio and containing mineral admixture. Concrete was exposed to a controlled environment of 20±1oC, 35±1oC, 50±1oC, and 60% ± 5 RH, respectively. The drying shrinkage of concretes with water cement ratio of 0.3, 0.4 and 0.5 were evaluated. The resuluts showed that with the increase of temperature from 20 oC to 50 oC, the influence of water cement ratio on drying shrinkage of concrete was gradually weakened. The shrinkage strain of concretes with replacement of cement by 20% of ground granulated blast-furnace slag (GGBS), 10% of silica fume (SF), and 20% of fly ash (FA) were measured, respectively. Test results showed that GGBS had a little impact on drying shrinkage of concrete; Silica fume could increase the drying shrinkage of concrete significantly in the early and later ages, especially when concrete was subjected to high temperature; Fly ash reduced drying shrinkage in early ages and increased drying shrinkage of concrete in the later ages.


2011 ◽  
Vol 261-263 ◽  
pp. 352-355
Author(s):  
Jian Jiang Ding ◽  
Jian Jun Zheng ◽  
Chun Lei Chen

The study on the penetration of chloride ions into concrete is very important for the durability assessment and design of reinforced concrete structures. A cyclic wetting and drying test is conducted to evaluate the effects of concrete mix proportions on the penetration of chloride ions. Based on the experimental results, the variations in chloride ion content at various points in concrete with the water/cement ratio, maximum aggregate diameter, aggregate gradation, fly ash content, and anticorrosion agent content are analyzed quantitatively. It is found that the water/cement ratio, aggregate gradation, maximum aggregate diameter, and fly ash all have a larger influence on the penetration of chloride ions. These conclusions can provide theoretical evidence for the design optimization of concrete properties.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3613
Author(s):  
Baohui Yang ◽  
Yangjie Zuo ◽  
Zhengping Chang

Foams are widely used in protective applications requiring high energy absorption under impact, and evaluating impact properties of foams is vital. Therefore, a novel test method based on a shock tube was developed to investigate the impact properties of closed-cell polyethylene (PE) foams at strain rates over 6000 s−1, and the test theory is presented. Based on the test method, the failure progress and final failure modes of PE foams are discussed. Moreover, energy absorption capabilities of PE foams were assessed under both quasi-static and high strain rate loading conditions. The results showed that the foam exhibited a nonuniform deformation along the specimen length under high strain rates. The energy absorption rate of PE foam increased with the increasing of strain rates. The specimen energy absorption varied linearly in the early stage and then increased rapidly, corresponding to a uniform compression process. However, in the shock wave deformation process, the energy absorption capacity of the foam maintained a good stability and exhibited the best energy absorption state when the speed was higher than 26 m/s. This stable energy absorption state disappeared until the speed was lower than 1.3 m/s. The loading speed exhibited an obvious influence on energy density.


2014 ◽  
Vol 875-877 ◽  
pp. 177-182 ◽  
Author(s):  
Xiang Li ◽  
Hua Quan Yang ◽  
Ming Xia Li

The hydration degree of fly ash and the calcium hydroxide (CH) content were measured. Combined with the equilibrium calculation of cement hydration, a new method for assessment of the hydration degree of cement in the fly ash-cement (FC) pastes based on the CH content was developed. The results reveal that as the fly ash content increase, the hydration degree of fly ash and the CH content decrease gradually; at the same time, the hydration degree of cement increase. The hydration degree of cement in the FC pastes containing a high content of fly ash (more than 35%) at 360 days is as high as 80%, even some of which hydrates nearly completely. The effect of water-cement ratio to the hydration degree of cement in the FC pastes is far less distinct than that of the content of fly ash.


2014 ◽  
Vol 584-586 ◽  
pp. 894-898
Author(s):  
Ping Zhang ◽  
Guan Guo Liu ◽  
Chao Ming Pang ◽  
Bing Du ◽  
Hong Gen Qin

The X ray computed tomography (X-CT) was applied to test the cracking resistance of cement paste, and the hydration process was monitored to study the effect of fly ash on the early age cracking performance. The results showed that the hydration heat reduced with the increase of fly ash under the same water-cement ratio. Within 24h, the porosity increased with time. The addition of fly ash increased the proportion of large holes and then changed the internal stress state. Using X-CT test method and by comparing the number of cracks, the sample with 20% FA was found to have the most serious cracks, whereas the sample with 30% FA had the best crack resistance.


2013 ◽  
Vol 4 (1) ◽  
pp. 50-55 ◽  
Author(s):  
Ong Ming Wei ◽  
Norsuzailina Mohamed Sutan

Efflorescence phenomenon on concrete is not new and found in the form of white deposits on surfaces of concrete. Incorporation of Finely Ground Mineral Admixture (FGMA) in concrete to prevent occurrence of efflorescence is based on reduction of portlandite, densified microstructure and thus enhanced watertightness. The magnitude of efflorescence in term of percentage of calcium carbonate formation of FGMA modified mortar were evaluated at water-cement ratio of 0.3, 0.4 and 0.5 with 10%, 20%, and 30% of cement replacement by weight. The samples were tested with chemical analysis at 7, 14, 21, 28, 60 and 90 days. The FGMA additions into mortar were comparing with ordinary mortar to evaluate enhanced performance of FGMA modified mortar toward efflorescence. The results of this experiment showed that addition of FGMA into mortar caused less formation of calcium carbonate as partial replacement of cement with certain w/c ratio and percentage of cement replacement.


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