Thermal Aging Analysis of Rubber Used for Fabric Expansion Joints

2013 ◽  
Vol 807-809 ◽  
pp. 2718-2721
Author(s):  
Li Na Ma ◽  
Yu Zeng Zhao ◽  
Hong Hua Ge ◽  
Kuai Ying Liu
Keyword(s):  
Thermal Stability ◽  
Thermal Aging ◽  
Inert Atmosphere ◽  
Expansion Joints ◽  
Chemical Structures ◽  
Before And After ◽  
The Difference ◽  
Ethylene Propylene Diene Terpolymer ◽  
Thermal Stability Of ◽  
Accelerated Thermal Aging

Several kinds of rubbers used for fabric expansion joints were studied by Thermogravimetric analysis under inert atmosphere before and after artificial accelerated thermal aging. The results showed that because of the difference of the chemical structures, the rubber aging is different. And the thermal stability of Polytetrafluoroethylene (PTFE) was obviously higher than that of other two kinds of rubbers, ethylene-propylene-diene-terpolymer rubber (EPDM) and fluororubber.

Thermal Aging Behavior of Ethylene Propylene Diene Monomer (EPDM) Rubber

2015 ◽  
Vol 727-728 ◽  
pp. 47-50 ◽  
Author(s):  
Jie Liu ◽  
Bin Wang ◽  
Lun Wu Zhang ◽  
Lei Zhu ◽  
Tian Yuan Luo
Keyword(s):  
Thermal Stability ◽  
Thermal Aging ◽  
Thermo Gravimetric Analysis ◽  
Attenuated Total Reflection ◽  
Gravimetric Analysis ◽  
Ethylene Propylene Diene Monomer ◽  
Epdm Rubber ◽  
Ethylene Propylene ◽  
Chemical Structures ◽  
Accelerated Thermal Aging

Ethylene propylene diene monomer (EPDM) rubber was exposed to an accelerated thermal aging environment produced by an air-circulating oven for different time periods. The changes of thermal stability and chemical structures of EPDM were monitored by thermo-gravimetric analysis (TGA), Attenuated total reflection-fourier transform infrared spectroscopy (ATR-FTIR) and X-ray Photoelectron Spectroscopy (XPS). The results showed that the accelerated thermal aging environment did not obviously affect the thermal stability of EPDM. FTIR and XPS confirmed the formation of hydroxyl, carbonyl and ester groups in the test environment.

scholarly journals Cross-Linked Chitosan/Multi-Walled Carbon Nanotubes Composite as Ecofriendly Biocatalyst for Synthesis of Some Novel Benzil Bis-Thiazoles

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1728
Author(s):  
Latifah A. Alshabanah ◽  
Sobhi M. Gomha ◽  
Laila A. Al-Mutabagani ◽  
Tariq Z. Abolibda ◽  
Nahed A. Abd El-Ghany ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Alternative Methods ◽  
Reaction Conditions ◽  
Chemical Structures ◽  
Weight Losses ◽  
Recyclable Catalysts ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Thermal Stability Of ◽  
Heterogeneous Biocatalyst

Aminohydrazide cross-linked chitosan (CLCS) and its MWCNTs (CLCS/MWCNTs) were formulated and utilized as a potent ecofriendly basic heterogeneous biocatalyst under ultrasonic irradiation for synthesis of two novel series of benzil bis-aryldiazenylthiazoles and benzil bis-arylhydrazonothiazolones from the reaction of benzil bis-thiosemicarbazone with 2-oxo-N′-arylpropanehydrazonoyl chlorides and ethyl 2-chloro-2-(2-phenylhydrazono) acetates, respectively. The chemical structures of the newly synthesized derivatives were elucidated by spectral data and alternative methods, where available. Additionally, their yield % was estimated using a traditional catalyst as TEA and green recyclable catalysts as CLCS and CLCS/MWCNTs composite in a comparative study. We observed that, under the same reaction conditions, the yield % of the desired products increased by changing TEA to CLCS then to CLCS/MWCNT from 72–78% to 79–83% to 84–87%, respectively. The thermal stability of the investigated samples could be arranged as CLCS/MWCNTs composite > CLCS > chitosan, where the weight losses of chitosan, CLCS and CLCS/MWCNTs composite at 500 °C were 65.46%, 57.95% and 53.29%, respectively.

scholarly journals Polystyrene/Montmorillonite Nanocomposites: Study of the Morphology and Effects of Sonication Time on Thermal Stability

2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
Mashael Alshabanat ◽  
Amal Al-Arrash ◽  
Waffa Mekhamer
Keyword(s):  
Electron Microscopy ◽  
Thermal Stability ◽  
Solution Method ◽  
Sonication Time ◽  
X Ray Diffraction ◽  
Transmission Electron ◽  
Polystyrene Matrix ◽  
Before And After ◽  
Silicate Layers ◽  
Thermal Stability Of

Polymer nanocomposites of polystyrene matrix containing 10% wt of organo-montmorillonite (organo-MMT) were prepared using the solution method with sonication times of 0.5, 1, 1.5, and 2 hours. Cetyltrimethylammonium bromide (CTAB) is used to modify the montmorillonite clay after saturating its surface with Na+ions. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were used to characterize the montmorillonite before and after modification by CTAB. The prepared nanocomposites were characterized using the same analysis methods. These results confirm the intercalation of PS in the interlamellar spaces of organo-MMT with a very small quantity of exfoliation of the silicate layers within the PS matrix of all samples at all studied times of sonication. The thermal stability of the nanocomposites was measured using thermogravimetric analysis (TGA). The results show clear improvement, and the effects of sonication time are noted.

Synthesis and Characterization of Some Functional Luminol Derivatives with Aromatic Substituted Groups

2011 ◽  
Vol 197-198 ◽  
pp. 606-609 ◽  
Author(s):  
Ti Feng Jiao ◽  
Yuan Yuan Xing ◽  
Jing Xin Zhou ◽  
Wei Wang
Keyword(s):  
Molecular Structure ◽  
Thermal Stability ◽  
Molecular Structures ◽  
Synthesis And Characterization ◽  
Functional Material ◽  
Aromatic Substituent ◽  
The Difference ◽  
Imide Group ◽  
Thermal Stability Of

Some functional luminol derivatives with aromatic substituted groups have been designed and synthesized from the reaction of the corresponding aromatic acyl chloride precursors with luminol. It has been found that depending on the size of aromatic groups, the formed luminol derivatives showed different properties, indicating distinct regulation of molecular skeletons. UV and IR data confirmed commonly the formation of imide group as well as aromatic segment in molecular structures. Thermal analysis showed that the thermal stability of luminol derivatives with p-phthaloyl segment was the highest in those derivatives. The difference of thermal stability is mainly attributed to the formation of imide group and aromatic substituent groups in molecular structure. The present results have demonstrated that the special properties of luminol derivatives can be turned by modifying molecular structures of objective compounds with proper substituted groups, which show potential application in functional material field and ECL sensor.

Characterization of Ni- and Ni(Pt)-Silicide Formation on Narrow Polycrystalline Si Lines by Raman Spectroscopy

1999 ◽  
Vol 591 ◽  
Author(s):  
P. S. Lee ◽  
D. Mangelinck ◽  
K. L. Pey ◽  
J. Ding ◽  
T. Osipowicz ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Raman Spectroscopy ◽  
Raman Mapping ◽  
Silicide Formation ◽  
Nucleation Sites ◽  
The Difference ◽  
The Stability ◽  
Non Destructive ◽  
Thermal Stability Of

ABSTRACTThe formation and thermal stability of Ni- and Ni(Pt) silicide on narrow polycrystalline Si (poly-Si) lines have been investigated using the non-destructive micro-Raman technique. The presence of Ni or Ni(Pt)Si on poly-Si lines with linewidths ranging from 0.5 gtm to 0.25 μm has been monitored by a distinct Raman peak at around 215 cm−1. Ni(Pt)Si was clearly identified to be present up to a RTA temperature of 900°C on narrow poly-Si lines as compared to pure NiSi which was found only up to 750°C. Raman scattering from the 100×100 μm2 poly-Si pads showed the formation of NiSi2 at 750°C for pure Ni-salicidation and 900°C for Ni(Pt)-salicidation respectively. The difference in the stability of NiSi on the poly-Si pads and lines is discussed in terms of agglomeration, inversion and/or nucleation of NiSi2that could be due to difference in nucleation sites and/or stress. In addition, a correlation between the line sheet resistance and the presence of Ni silicide was found using micro-Raman mapping along single poly-Si lines.

scholarly journals Synthesis and Properties of Bulk Metallic Glasses in Pd-Ni-P and Pd-Cu-P Alloys

1996 ◽  
Vol 455 ◽  
Author(s):  
Y. He ◽  
R. B. Schwarz
Keyword(s):  
Thermal Stability ◽  
Glass Transition ◽  
Metallic Glasses ◽  
Amorphous Alloys ◽  
Composition Range ◽  
Wide Composition Range ◽  
Upper Limit ◽  
Ternary Alloy Systems ◽  
The Difference ◽  
Thermal Stability Of

ABSTRACTBulk amorphous Pd-Ni-P and Pd-Cu-P alloy rods with diameters ranging from 7 to 25 mm have been synthesized over a wide composition range using a fluxing technique. For most bulk amorphous Pd-Ni-P alloys, the difference ΔT = Tx - Tg between the crystallization temperature Tx and the glass transition temperature Tg is larger than 90 K, while for bulk amorphous Pd-Cu-P alloys, ΔT varies from 27 to 73 K. Pd40Ni40P20 has the highest glass formability, and 300-gram bulk amorphous cylinders, 25 mm in diameter and 50 mm in length, can be easily produced. This size, however, is not an upper limit. The paper presents the glass formation ranges for both ternary alloy systems and data on the thermal stability of the amorphous alloys, as well as their specific heat, density, and elastic properties.

Properties and Effects of Hydrogen in GaN

1999 ◽  
Vol 595 ◽  
Author(s):  
S.J. Pearton ◽  
H. Cho ◽  
F. Ren ◽  
J.-I. Chyi ◽  
J. Han ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Heterojunction Bipolar Transistors ◽  
Bipolar Transistors ◽  
Residual Hydrogen ◽  
Diffusion Characteristics ◽  
Significant Difference ◽  
Device Structures ◽  
The Status ◽  
The Difference ◽  
Thermal Stability Of

AbstractThe status of understanding of the behavior of hydrogen in GaN and related materials is reviewed. In particular, we discuss the amount of residual hydrogen in MOCVD-grown device structures such as heterojunction bipolar transistors, thyristors and p-i-n diodes intended for high power, high temperature applications. In these structures, the residual hydrogen originating from the growth precursors decorates Mgdoped layers and AlGaN/GaN interfaces. There is a significant difference in the diffusion characteristics and thermal stability of implanted hydrogen between n- and p-GaN, due to the stronger affinity of hydrogen to pair with acceptor dopants and possibly to the difference in H2 formation probability.

scholarly journals Influence of ZrO2 Addition on Structural and Biological Activity of Phosphate Glasses for Bone Regeneration

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4058
Author(s):  
M. Mohan Babu ◽  
P. Syam Prasad ◽  
P. Venkateswara Rao ◽  
S. Hima Bindu ◽  
A. Prasad ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Biological Activity ◽  
Incubation Time ◽  
Sample Surface ◽  
Glass Forming Ability ◽  
Phosphate Glasses ◽  
Bioactive Materials ◽  
Glass Forming ◽  
Before And After ◽  
Thermal Stability Of

Zirconium doped calcium phosphate-based bioglasses are the most prominent bioactive materials for bone and dental repair and regeneration implants. In the present study, a 8ZnO–22Na2O–(24 − x)CaO–46P2O5–xZrO2 (0.1 ≤ x ≤ 0.7, all are in mol%) bioglass system was synthesized by the conventional melt-quenching process at 1100 °C. The glass-forming ability and thermal stability of the glasses were determined by measuring the glass transition temperature (Tg), crystallization temperature (Tc), and melting temperature (Tm), using differential thermal analysis (DTA). The biological activity of the prepared samples was identified by analyzing X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy-energy dispersive spectra (SEM-EDS), before and after immersion in simulated body fluid (SBF) for various intervals of 0, 1 and 5 days, along with the magnitude of pH and the degradation of glasses also evaluated. The obtained results revealed that the glass-forming ability and thermal stability of glasses increased with the increase in zirconia mol%. The XRD, FTIR, and SEM-EDS data confirmed a thin hydroxyapatite (HAp) layer over the sample surface after incubation in SBF for 1 and 5 days. Furthermore, the development of layer found to be increased with the increase of incubation time. The degradation of the glasses in SBF increased with incubation time and decreased gradually with the increase content of ZrO2 mol% in the host glass matrix. A sudden rise in initial pH values of residual SBF for 1 day owing to ion leaching and increase of Ca2+ and PO43− ions and then decreased. These findings confirmed the suitability of choosing material for bone-related applications.

High thermal stability of SiO2–ZrO2 aerogels using solvent-thermal aging

2020 ◽  
Vol 291 ◽  
pp. 121624
Author(s):  
Huijun Yu ◽  
Zongwei Tong ◽  
Yingchen Qiao ◽  
Zhuchao Yang ◽  
Sheng Yue ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Thermal Aging ◽  
High Thermal Stability ◽  
Thermal Stability Of

Thermal Stability of PALF-PP and PALF-PLA for Natural Fiber Honeycomb Core Materials

2021 ◽  
Vol 87 (1) ◽  
pp. 20-29
Author(s):  
Amira Syuhada Zainudin ◽  
Abdul Rahim Othman
Keyword(s):  
Thermal Stability ◽  
Natural Fiber ◽  
Thermal Characteristic ◽  
Inert Atmosphere ◽  
Filler Loading ◽  
Differential Scanning Calorimetric ◽  
Dsc Analysis ◽  
Honeycomb Core ◽  
Nitrogen Gas ◽  
Thermal Stability Of

This paper studied the thermal behaviour of pineapple leaf fiber (PALF) reinforced with polypropylene (PP) and polylactic acid (PLA) composite, used for natural fiber honeycomb core. Thermogravimetric analysis (TGA) and differential scanning calorimetric (DSC) analysis were used to measure the thermal characteristic of PALF-PP/PLA composites. In particular, the TGA analysis was utilized to measure the degradation and decomposition of materials in different composition (NF-PP/PLA (0%, 15%, 30% and 50%). The measurements were carried out in the temperature of 0oC- 900oC, at a heating rate of 10oCmin-1 and under an inert atmosphere (nitrogen gas). The temperature of DSC analysis was programmed to between 25oC- 500oC. The result shows the thermal stability of PALF-PP/PLA decreased as the PALF filler-loading increased. While from the DSC analysis this study clearly shows in the graph plot, the sample have glass transition temperature, crystallization and melting temperature. So that means the sample in this study is crystalline and amorphous domains.

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