Effect of Al on Corrosion Behavior in 3.5%NaCl Solution of AlxCoCrFeNi High Entropy Alloys

2021 ◽  
Vol 53 ◽  
pp. 20-30
Author(s):  
Victor Geantă ◽  
Ionelia Voiculescu ◽  
Mihai Cosmin Cotrut ◽  
Maria Diana Vrânceanu ◽  
Ion Mihai Vasile ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Polarization Resistance ◽  
Metallic Matrix ◽  
Corrosion Current ◽  
Metal Corrosion ◽  
High Entropy Alloys ◽  
Nacl Solution ◽  
High Entropy ◽  
Arc Melting

The high entropy alloys have attracted the interest of material scientists due to theirspecial mechanical properties and a very good corrosion behavior. The corrosion resistance is provided by the formation of a passive, thin and compact oxide film that prevents the chemical dissolution of the metallic matrix. The effect of aluminum in AlxCrFeCoNi high entropy alloys (with x = 1; 1.5 and 2) that were obtained by electric arc melting under argon atmosphere has been studied in the paper. In order to understand the processes involved in metal corrosion, the alloys have been tested by polarization resistance method in 3.5% NaCl solution and main corrosion parameters have been analyzed (i.e. corrosion potential; corrosion current density; corrosion rate and polarization resistance). The surfaces of the corroded samples were examined by scanning electron microscopy to estimate the effect of the chemical composition on corrosion resistance. The corrosion tests have shown that the corrosion resistance of the HEA decreases by increasing the aluminum content from about 15 at.% to 32 at. % Al and reducing the chromium content from 28 at. % to 18 at.% Cr.

scholarly journals Corrosion Behavior and Osteogenic Activity of a Biodegradable Orthopedic Implant Mg–Si Alloy with a Gradient Structure

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 781
Author(s):  
Weiyan Jiang ◽  
Wenzhou Yu
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Polarization Resistance ◽  
Corrosion Current Density ◽  
Corrosion Current ◽  
Gradient Structure ◽  
Orthopedic Implant ◽  
Biological Functions ◽  
Alloy Matrix ◽  
Osteogenic Activity

A gradient Mg-8 wt % Si alloy, which was composed of the agglomerated Mg2Si crystals coating (GMS8-1) and the eutectic Mg–Si alloy matrix (GMS8-2), was designed for biodegradable orthopedic implant materials. The bio-corrosion behavior was evaluated by the electrochemical measurements and the immersion tests. The results show that a significant improvement of bio-corrosion resistance was achieved by using the gradient Mg–Si alloy, as compared with the traditional Mg-8 wt % Si alloy (MS8), which should be attributed to the compact and insoluble Mg2Si phase distributed on the surface of the material. Especially, GMS8-1 exhibits the highest polarization resistance of 1610 Ω, the lowest corrosion current density of 1.7 × 10−6 A.cm−2, and the slowest corrosion rate of 0.10 mm/year. In addition, GMS8-1 and GMS8-2 show better osteogenic activity than MS8, with no cytotoxicity to MC3T3-E1 cells. This work provides a new way to design a gradient biodegradable Mg alloys with some certain biological functions.

scholarly journals Corrosion behavior of CoxCrCuFeMnNi high-entropy alloys prepared by hot pressing sintered in 3.5% NaCl solution

2019 ◽  
Vol 15 ◽  
pp. 102667 ◽  
Author(s):  
Rui-Feng Zhao ◽  
Bo Ren ◽  
Bin Cai ◽  
Zhong-Xia Liu ◽  
Guo-Peng Zhang ◽  
...  
Keyword(s):  
Corrosion Behavior ◽  
Hot Pressing ◽  
High Entropy Alloys ◽  
Nacl Solution ◽  
High Entropy

Corrosion Behavior of Zr53.5Cu26.5Ni5Al12Ag3 Bulk Amorphous Alloy in 3.5% NaCl Solution

2011 ◽  
Vol 299-300 ◽  
pp. 427-431
Author(s):  
Yun Li ◽  
Shi Zhi Shang ◽  
Ming Cheng ◽  
Liang Xu ◽  
Shi Hong Zhang
Keyword(s):  
Corrosion Resistance ◽  
Amorphous Alloy ◽  
Passive Film ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Bulk Amorphous Alloy ◽  
Nacl Solution ◽  
Current Densities ◽  
Resistance Decrease

The corrosion behavior of Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy in 3.5% NaCl solution was investigated by using potentiodynamic polarization experiments and electrochemical impedance spectroscopy (EIS). The results show that Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy has the better corrosion resistance than its corresponding crystal alloy. During the bath in the 3.5% NaCl solution at 25°C, Zr53.5Cu26.5Ni5Al12Ag3 alloy has the lower corrosion current density than the corresponding crystal alloy. After 100h, the corrosion current densities of Zr53.5Cu26.5Ni5Al12Ag3 and the corresponding crystal alloy are 3.8415×10-8A/cm2 and 5.2827×10-7A/cm2, respectively. The results of EIS test indicate that Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy has the excellent corrosion resistance because passive film with stable structure formed on the surface in 3.5% NaCl solution. With an increase in the immersion time, the passive film becomes thicker. It leads to impedance resistance and corrosion resistance decrease. The surface of Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy in 3.5% NaCl solution for 100h was analyzed by SEM and EDS. The results show that the corrosive pitting can be found at both the amorphous alloy and the corresponding crystal alloy. However, the amorphous alloy has the better corrosive pitting resistance than the crystal one because the corrosion products formed by selective dissolving of Zr and Al elements. Moreover, the addition of Ag element helps to improve the corrosion resistance of the amorphous alloy greatly.

Understanding the Effect of Tungsten on Corrosion Behavior of AlCuCrFeMnWx High-Entropy Alloys in 3.5 wt.% NaCl Solution

2018 ◽  
Vol 27 (9) ◽  
pp. 4481-4488 ◽  
Author(s):  
Devesh Kumar ◽  
Ornov Maulik ◽  
V. K. Sharma ◽  
Y. V. S. S. Prasad ◽  
Vinod Kumar
Keyword(s):  
Corrosion Behavior ◽  
High Entropy Alloys ◽  
Nacl Solution ◽  
High Entropy

scholarly journals Corrosion Resistance of X5CrNi18-10 Stainless Steel

2017 ◽  
Vol 62 (4) ◽  
pp. 2101-2106
Author(s):  
M. Kciuk ◽  
S. Lasok
Keyword(s):  
Heat Treatment ◽  
Corrosion Resistance ◽  
Polarization Resistance ◽  
Corrosion Potential ◽  
Electrochemical Corrosion ◽  
Corrosion Current ◽  
Nacl Solution ◽  
Corrosion Properties ◽  
Eds Microanalysis ◽  
Scanning Electron

AbstractThe paper presents the influence of heat treatment on the structure and corrosion resistance of X5CrNi18-10 steel. To determine the structure which has been obtained after heat treatment the methods of light and scanning electron microscopy with EDS microanalysis were used. The electrochemical corrosion properties of the investigated steel were studied in 3.5% NaCl solution using potentiodynamic polarization tests. Basing on the registered curves, the corrosion current, polarization resistance and corrosion potential were determined. The corrosion tests were followed by fractographic researches.

scholarly journals Wear and Corrosion Resistance Analysis of FeCoNiTiAlx High-Entropy Alloy Coatings Prepared by Laser Cladding

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 155
Author(s):  
Zhaolei Sun ◽  
Mingyuan Zhang ◽  
Gaoqi Wang ◽  
Xuefeng Yang ◽  
Shouren Wang
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Wear Rate ◽  
Laser Cladding ◽  
Dendritic Structure ◽  
Wear Test ◽  
Corrosion Current ◽  
High Entropy Alloy ◽  
Nacl Solution ◽  
High Entropy

FeCoNiTiAlx (x = 0, 0.5, 1) high-entropy alloy coatings were prepared by laser cladding technology. The phase, microstructure, hardness, wear resistance and corrosion resistance were tested and analyzed. The results showed Al element promoted the conversion from the FCC phase to the BCC phase. The coating presented dendritic structure due to the addition of the Al element, while the number of dendrites increased. And the average hardness of the coating increased from 204 to 623 HV. The addition of the Al element increases the corrosion current density of the coating from 1.270 × 10−5 to 3.489 × 10−5 A/cm2. The wear rate of the coatings decreases with the increase of Al content according to dry friction and wear, which indicates the wear resistance of the coating was improved by adding the Al element. According to the corrosion wear test in 3.5% NaCl solution, it can be found that the wear rate of the coating increases firstly and then decreases with the addition of the Al element, which indicates that the addition of the Al element intensifies the wear of the coating in 3.5% NaCl solution.

scholarly journals Effect of Recrystallization Annealing on Corrosion Behavior of Ta-4%W Alloy

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 117 ◽  
Author(s):  
Guoqiang Ma ◽  
Qiongyao He ◽  
Xuan Luo ◽  
Guilin Wu ◽  
Qiang Chen
Keyword(s):  
Corrosion Resistance ◽  
Anodic Dissolution ◽  
Corrosion Behavior ◽  
Current Density ◽  
Polarization Resistance ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Recrystallization Annealing ◽  
Site Lattice

The effect of recrystallization annealing on corrosion behavior of Ta-4%W alloy was studied. It is found that the deformed sample contains high dense dislocations and dislocation boundaries. During annealing, these dislocations and dislocation boundaries are replaced by recrystallizing grains until the alloy is fully recrystallized. Both the anodic dissolution and the cathodic activity is much more blocked. The corrosion potential gradual shift towards negative values and corrosion current density decrease, while polarization resistance increases after annealing, indicating enhanced corrosion resistance of the alloy. Such an enhancement is caused by the increase of low-Σ coincide site lattice boundaries and decrease of dislocations and dislocation boundaries.

scholarly journals Corrosion Behavior of AlFeCrCoNiZrx High-Entropy Alloys in 0.5 M Sulfuric Acid Solution

Metals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1471
Author(s):  
Yuhong Yao ◽  
Yaohua Jin ◽  
Wei Gao ◽  
Xiaoyu Liang ◽  
Jian Chen ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Rate ◽  
Corrosion Behavior ◽  
Potentiodynamic Polarization ◽  
General Corrosion ◽  
High Entropy Alloys ◽  
H2so4 Solution ◽  
High Entropy ◽  
Polarization Measurements ◽  
Selective Corrosion

AlCoCrFeNiZrx (x = 0, 0.1, 0.2, 0.3, and 0.5) high-entropy alloys (HEAs) were prepared by a non-consumable vacuum arc melting technology, and the microstructure and corrosion behavior were investigated by XRD, SEM, immersion tests, and electrochemical measurements. The results indicate that galvanic corrosion of the AlCoCrFeNiZrx alloys occurred in 0.5 M H2SO4 solution, and only 0.1 mol of the added Zr could greatly improve the corrosion resistance of the alloys. The corrosion properties of the AlCoCrFeNiZrx HEAs had similar change tendencies with the increase in the Zr content in the immersion tests, potentiodynamic polarization measurements, and electrochemical impedance analysis, that is, the corrosion resistance of the AlCoCrFeNiZrx alloys in a 0.5 M H2SO4 solution first increased and then decreased with the increase in the Zr content. The Zr0.1 alloys were found to have the best selective corrosion and general corrosion resistance with the smallest corrosion rate, whereas the Zr0.3 alloys presented the worst selective corrosion and general corrosion resistance with the highest corrosion rate from both the immersion tests and the potentiodynamic polarization measurements.

scholarly journals Experimental Study Regarding the Behavior at Different pH of Two Types of Co-Cr Alloys Used for Prosthetic Restorations

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4635
Author(s):  
Farah Bechir ◽  
Simona Maria Bataga ◽  
Elena Ungureanu ◽  
Diana Maria Vranceanu ◽  
Mariana Pacurar ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Polarization Resistance ◽  
Ph Value ◽  
Artificial Saliva ◽  
Corrosion Current ◽  
Open Circuit ◽  
Dental Alloys ◽  
Cobalt Chromium ◽  
Electrochemical Parameters

Cobalt-chromium (Co-Cr) alloys are widely utilized in dentistry. The salivary pH is a significant factor, which affects the characteristics and the behavior of dental alloys through corrosion. This study aimed to evaluate the corrosion behavior in artificial saliva with different pH values (3, 5.7, and 7.6) of two commercial Co-Cr dental alloys manufactured by casting and by milling. Corrosion resistance was determined by the polarization resistance technique, and the tests were carried out at 37 ± 1 °C, in Carter Brugirard artificial saliva. After the electrochemical parameters, it can be stated that the cast Co-Cr alloy has the lowest corrosion current density, the highest polarization resistance, and the lowest speed of corrosion in artificial saliva with pH = 7.6. In the case of milled Co-Cr alloy, the same behavior was observed, but in artificial saliva with pH = 5.7, it recorded the most electropositive values of open circuit potential and corrosion potential. Although both cast and milled Co-Cr alloys presented a poorer corrosion resistance in artificial saliva with a more acidic pH value, the milled Co-Cr alloy had better corrosion behavior, making this alloy a better option for the prosthetic treatment of patients suffering from GERD.

Corrosion Behavior of Electroless Deposited Fe-Zn Coating

2011 ◽  
Vol 117-119 ◽  
pp. 81-84
Author(s):  
Xi Ran Wang ◽  
Jing Wu ◽  
Xin Gang Hu
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Open Circuit Potential ◽  
Corrosion Current ◽  
Open Circuit ◽  
Nacl Solution ◽  
Positive Direction ◽  
Heat Treated ◽  
Heat Treated Temperature ◽  
Electronic Microscope

In this work, Fe-Zn coating on copper is obtained by electroless plating. The surface mor -phologies and composition of the coatings has been investigated using scanning electronic microscope (SEM) and energy dispersive spectroscopy(EDS). Corrosion behavior of Fe-Zn coating in3.5% NaCl solution is gaved a further insight. The impedance diagram indicates that corrosion resistance of coating is better. The open circuit potential of Fe-Zn coating is at about -1V. Self-corrosion potential of Fe-Zn coating in 3.5%NaCl solution shifts in the positive direction first and then shifts from -0.622V to -0.603V with increasing heat-treated temperature, while corresponding self-corrosion current decreases at first and then. increases Corrosion resistance of coating is the best when heat-treated temperature is 300°C.

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