Influence of Niobium Oxide on the Mechanical Properties of Hydroxyapatite

2012 ◽  
Vol 529-530 ◽  
pp. 29-33 ◽  
Author(s):  
N. Demirkol ◽  
F.N. Oktar ◽  
E.S. Kayali
Keyword(s):  
Mechanical Properties ◽  
Compression Strength ◽  
Niobium Oxide ◽  
Sintering Temperature ◽  
Physical And Mechanical Properties ◽  
Oxide Content ◽  
Different Temperatures ◽  
Synthetic Hydroxyapatite ◽  
Mechanical And Microstructural Properties ◽  
Oxide Composites

The goal of this study is to produce and to investigate the mechanical and microstructural properties of composite materials made of hydroxyapatite, obtained from both natural sheep bone and commercial synthetic hydroxyapatite with niobium oxide addition ( 5 and 10 wt%). The samples were subjected to sintering at different temperatures between 1000°C and 1300°C. Microstructures and mechanical properties of sheep hydroxyapatite (SHA) and commercial synthetic hydroxyapatite (CSHA)-niobium oxide composites were investigated. The production of hydroxyapatite (HA) from natural sources is preferred due to economical reason. The aim of development of SHA and CSHA based niobium oxide composites is to improve mechanical properties of HA. The physical and mechanical properties were determined by measuring density, compression strength and Vickers microhardness (HV). Structural characterization was carried out with X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies. In all composites, density values and mechanical properties increased with increasing sintering temperature. The increase of niobium oxide content in all composites showed better mechanical properties. Both of SHA and CSHA composites with at 1300°C sintering temperature showed nearly the same compression strength value.

Comparison of Mechanical Properties of Sheep Hydroxyapatite (SHA) and Commercial Synthetic Hydroxyapatite (CSHA)-MgO Composites

2011 ◽  
Vol 493-494 ◽  
pp. 588-593 ◽  
Author(s):  
N. Demirkol ◽  
Onur Meydanoglu ◽  
Hasan Gökçe ◽  
F.N. Oktar ◽  
E.S. Kayali
Keyword(s):  
Mechanical Properties ◽  
Compression Strength ◽  
Vickers Microhardness ◽  
Sintering Temperature ◽  
Physical And Mechanical Properties ◽  
X Ray Diffraction ◽  
Time Saving ◽  
X Ray ◽  
Density Values ◽  
Synthetic Hydroxyapatite

In this study, microstructures and mechanical properties of sheep hydroxyapatite (SHA) and commercial synthetic hydroxyapatite (CSHA)-MgO composites were investigated. The production of hydroxyapatite (HA) from natural sources is preferred due to economical and time saving reasons. The goal of development of SHA and CSHA based MgO composites is to improve mechanical properties of HA. SHA and CSHA composites were prepared with the addition of different amounts of MgO and sintered at the temperature range of 1000-1300 °C. The physical and mechanical properties were determined by measuring density, compression strength and Vickers microhardness (HV). Structural characterization was carried out with X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies. In all composites, mean density values and mechanical properties increased with increasing sintering temperature. The increase of MgO content in SHA-MgO composites showed better mechanical properties in contrast to CSHA-MgO composites. Although the highest hardness and compression strength values were obtained at the SHA-10wt% MgO composite sintered at 1300°C, higher hardness and compression strength values were achieved with 5 wt% MgO addition at the CSHA-MgO composites when compared to SHA-MgO composites sintered between 1000-1200°C.

CHARACTERIZATION OF HYDROXYAPATITE/TI6AL4V COMPOSITE POWDER UNDER VARIOUS SINTERING TEMPERATURE

2015 ◽  
Vol 75 (7) ◽  
Author(s):  
Amir Arifin ◽  
Abu Bakar Sulong ◽  
Norhamidi Muhamad ◽  
Junaidi Syarif
Keyword(s):  
Mechanical Properties ◽  
Composite Powder ◽  
Sintering Temperature ◽  
Physical And Mechanical Properties ◽  
Xrd Analysis ◽  
X Ray Diffraction ◽  
Different Temperatures ◽  
Two Phases ◽  
Work Interaction

Hydroxyapatite (HA) has been widely used in biomedical applications due to its excellent biocompatibility. However, Hydroxyapatite possesses poor mechanical properties and only tolerate limited loads for implants. Titanium is well-known materials applied in implant that has advantage in mechanical properties but poor in biocompatibility. The combination of the Titanium alloy and HA is expected to produce bio-implants with good in term of mechanical properties and biocompatabilty. In this work, interaction and mechanical properties of HA/Ti6Al4V was analyzed. The physical and mechanical properties of HA/Ti6Al4V composite powder obtained from compaction (powder metallurgy) of 60 wt.% Ti6Al4V and 40 wt.% HA and sintering at different temperatures in air were investigated in this study. Interactions of the mixed powders were investigated using X-ray diffraction. The hardness and density of the HA/Ti6Al4V composites were also measured. Based on the results of XRD analysis, the oxidation of Ti began at 700 °C. At 1000 °C, two phases were formed (i.e., TiO2 and CaTiO3). The results showed that the hardness HA/Ti6Al4V composites increased by 221.6% with increasing sintering temperature from 700oC to 1000oC. In contrast, the density of the composites decreased by 1.9% with increasing sintering temperature. 

Hydroxyapatite Nano-Barium-Strontium-Titaniumoxide Composites

2011 ◽  
Vol 484 ◽  
pp. 204-209 ◽  
Author(s):  
N. Demirkol ◽  
Eyup Sabri Kayali ◽  
Mehmet Yetmez ◽  
F.N. Oktar ◽  
Simeon Agathopoulos
Keyword(s):  
Titanium Oxide ◽  
Compression Strength ◽  
Sintering Temperature ◽  
Bovine Bone ◽  
Strontium Titanium Oxide ◽  
Barium Strontium ◽  
Load Carrying ◽  
Different Temperatures ◽  
Density Values ◽  
Mechanical And Microstructural Properties

The aim of this study is to produce and to investigate the mechanical and microstructural properties of composite materials made of hydroxyapatite, obtained from natural bovine bone and nano barium strontium titanium oxide (5 and 10 wt%). Compositions were mechanical alloyed and compacted to pellets. The samples were subjected to sintering at different temperatures between 1000oC and 1300oC. Compression strength, Vickers microhardness as well as density were measured. SEM and X-ray diffraction studies were also conducted. With increasing sintering temperature, microhardness, compression strength and density of composites increased. With increasing addition of nano barium strontium titanium oxide (BST) to bovine hydroxyapatite (BHA), microhardness values of composites decreased at all sintering temperatures, but compression strength and density values of composites showed different tendency. Compression strengths of BHA-composites at low sintering temperatures were nearly the same, but their compression strengths at high sintering temperatures decreased with increasing nano BST addition. The best mechanical properties were obtained at 1300°C sintering temperature with BHA-5wt% nano BST. Microhardness and compression strengths values of these nano–oxide composites are generally higher than that BHA-composites produced by traditional methods. Adding of nano-oxides to BHA could be a valuable method to produce rigid and high load carrying ability when compared with BHA-composites produced by conventional methods. Nano-HA and nano-oxides composites could be even better. Those nano-nano studies are still in progress.

Production and Mechanical Properties of Commercial Synthetic Hydroxyapatite (CSHA) Composites

2013 ◽  
Vol 587 ◽  
pp. 147-153
Author(s):  
N. Demirkol ◽  
F.N. Oktar ◽  
E.S. Kayali
Keyword(s):  
Mechanical Properties ◽  
Bone Growth ◽  
Physical And Mechanical Properties ◽  
X Ray Diffraction ◽  
Broken Bones ◽  
Metallic Biomaterials ◽  
Different Temperatures ◽  
Density Values ◽  
Synthetic Hydroxyapatite

Hydroxyapatite (HA), one of the calcium phosphate compounds, is the most widely used bioceramic. HA materials have a common usage in bone repairing due to its ability to accelerate the bone growth around the implant. HA is a biocompatible material and used in production of various kinds of prosthesis, repairing the cracked or broken bones and coating of metallic biomaterials. This study covers production and characterization of composite materials made of commercial synthetic hydroxyapatite (CSHA) with commercial inert glass, magnesium oxide and niobium (V) oxide additions (5 and 10 wt%), seperately. These additives used as reinforcement materials to improve the mechanical properties of CSHA based composites. The composites were subjected to sintering at different temperatures between 1000oC and 1300oC, then microstructures and mechanical properties of CSHA composites were investigated. The physical and mechanical properties were determined by measuring density, compression strength and Vickers microhardness (HV). Structural characterization was carried out with X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies. In all composites, density values and mechanical properties increased with increasing sintering temperature. CSHA composite with 5 wt% CIG addition showed highest physical and mechanical properties among all CSHA composites produced in this study.

Effect of TiO2 and MgO on Microstructure of α-Alumina Ceramics and its Sintering Behavior

2015 ◽  
Vol 1112 ◽  
pp. 519-523 ◽  
Author(s):  
Jarot Raharjo ◽  
Sri Rahayu ◽  
Tika Mustika ◽  
Masmui ◽  
Dwi Budiyanto
Keyword(s):  
Mechanical Properties ◽  
Sintering Temperature ◽  
Physical And Mechanical Properties ◽  
Basic Material ◽  
Sintering Behavior ◽  
Pressureless Sintering ◽  
Alumina Ceramics ◽  
Density Measurements ◽  
Technical Alumina ◽  
Platelet Structure

Observation on the effect of adding titanium oxide (TiO2) and magnesium oxide (MgO) on the sintering of α-alumina (Al2O3) has been performed. In this study, technical alumina used as basic material in which the sample is formed by the pressureless sintering/cold press and sintered at 1500°C which is lower than alumina sintering temperature at 1700°C. Elemental analysis, observation of microstructure, hardness, fracture toughness and density measurements were carried out to determine the physical and mechanical properties of alumina. The results indicate a change in the microstructure where the content of the platelet structure are much more than the equilateral structure. At sintering temperature of 1500°C, neck growth occurs at ceramics grain, supported by the results of the density test which indicate perfect compaction has occurred in this process.

Preparation of ZrO2 Composite Ceramics with High Thermal Shock Resistance

2012 ◽  
Vol 455-456 ◽  
pp. 650-654 ◽  
Author(s):  
He Yi Ge ◽  
Jian Ye Liu ◽  
Xian Qin Hou ◽  
Dong Zhi Wang
Keyword(s):  
Mechanical Properties ◽  
Water Absorption ◽  
Thermal Shock ◽  
Thermal Shock Resistance ◽  
Sintering Temperature ◽  
Fiber Composite ◽  
Physical And Mechanical Properties ◽  
Composite Ceramics ◽  
Shock Resistance ◽  
Absorption Measurements

The physical and mechanical properties of nanometer ZrO2-ZrO2fiber composite ceramics were studied by introduction of ZrO2fiber. ZrO2composite ceramics at different sintering temperature was investigated by porosity and water absorption measurements, flexual strength and thermal shock resistance analysis. Results showed that ZrO2composite ceramics containing 15 wt% ZrO2fiber with sintering temperature of 1650°C exhibited good mechanical properties and thermal shock resistance. The porosity and the water absorption were 8.84% and 1.62%, respectively. The flexual strength was 975 MPa and the thermal shock times reached 31 times. Scanning electron microscope (SEM) was used to analyze the microstructure of ZrO2composite ceramics.

Study of the Effect of PP and LDPE Thermoplastic Binder Addition on the Mechanical Properties and Physical Properties of Particulate Composites for Building Material Application

2019 ◽  
Vol 964 ◽  
pp. 115-123
Author(s):  
Sigit Tri Wicaksono ◽  
Hosta Ardhyananta ◽  
Amaliya Rasyida ◽  
Feisha Fadila Rifki
Keyword(s):  
Mechanical Properties ◽  
Compression Strength ◽  
Building Materials ◽  
Construction Material ◽  
Construction Materials ◽  
Physical And Mechanical Properties ◽  
Waste Recycling ◽  
Plastic Waste ◽  
Particulate Composites ◽  
Water Absorbability

Plastic waste is majority an organic material that cannot easily decomposed by bacteria, so it needs to be recycled. One of the utilization of plastic waste recycling is become a mixture in the manufacture of building materials such as concrete, paving block, tiles, roof. This experiment purpose to find out the effect of addition of variation of LDPE and PP thermoplastic binder to physical and mechanical properties of LDPE/PP/Sand composite for construction material application. In this experiment are using many tests, such are SEM, FTIR, compression strength, density, water absorbability, and hardness. the result after the test are the best composition of composite PP/LDPE/sand is 70/0/30 because its have compression strength 14,2 MPa, while density value was 1.30 g/cm3, for the water absorbability is 0.073%, and for the highest hardness is 62.3 hardness of shore D. From the results obtained, composite material can be classified into construction materials for mortar application S type with average compression strength is 12.4 MPa.

scholarly journals PENENTUAN SIFAT MEKANIS DAN FISIS BATU BATA DENGAN PENAMBAHAN ARANG TEMPURUNG KELAPA ASAL ALOR

2018 ◽  
Vol 3 (1) ◽  
pp. 80-85
Author(s):  
Ernawati Kawa ◽  
Minsyahril Bukit ◽  
Albert Zicko Johannes
Keyword(s):  
Mechanical Properties ◽  
Physical Properties ◽  
Compression Strength ◽  
Physical And Mechanical Properties ◽  
Strength Test ◽  
Coconut Shell ◽  
Mechanical And Physical Properties ◽  
Maximum Limit

Abstrak Telah dilakukan penelitian tentang penentuan sifat mekanis dan fisis batu bata dengan penambahan tempurung kelapa asal alor. Penenlitian ini bertujuan mengetahui kualitas batu bata yang memenuhi standar kelayakan sebagai bahan konstruksi dengan penambahan arang tempurung kelapa aal alor dengan presentasi 0%, 5%, 10%, 15% terhadap tanah liat (lempung). Batu bata dicetak dengan prosedur pemadatan, pengringn dan pembakaran. Setelah prosedur pencetakkan selesai kemudian di lanjutkan dengan pengujian sefat mekanis dan sifat fisis, yaitu uji kuat tekan (compression strength), densitas (density), porositas (porosity) hasil  kuat tekan batu bata didapatkan berdasarkan pengujian: a) uji kuat tekan, batu bata tanpa penambahan (0%) : 4,94 meemenuhi standar kuat tekan kelas 50 (SNI 15-2094-2000), b) uji porositas, batu bata 0% dan 5% : 3,82% dan 17,93% memenuhi standar porositas dengan batas maksimum 20% (SNI 15-2094-2000) dan uji densitas, batu bata tidak ada yang memenuhi standar (SII 0021-1978) Kata kunci: sifat mekanis, sifat fisis, tempurung kelapa, densitas, porositas, kuat tekan Abstract A research had been conducted to determine physical and mechanical properties of the bricks with the addition coconut shell charcoal from alor. This research aims at the quality of the bricks to meet the standars of eligibility as a contruction material. The addition of coconut shell charcoal is variate with the presentage 0%, 5%, 10%, 15% to the clay mass. The brick being printed with procedure compaction, drying, and baking. After the printing procedure is done then next is testing the mechanical and physical properties, that is compression strength test, density test, and porosity test. The brick quality result is obtained based on the test: a) compression strength test, the brick without addition (0%) : 4,94  (SNI 15-2094-2000) is comply with the standard compression strength the class 50 , b) porosity test, the brick 0% and 5% (3,82% and 17,93%) meet the standard with the maximum limit 20% ( SNI 15-2094-2000)  , and c) density test, every bricks does not meet the standard (SII 0021- 1978). Keywords: mechanical properties, physical properties, coconut shell, density, porosity, compression strength

scholarly journals Effects of High Temperatures on the Physical and Mechanical Properties of Carbonated Ordinary Concrete

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Qifang Xie ◽  
Lipeng Zhang ◽  
Shenghua Yin ◽  
Baozhuang Zhang ◽  
Yaopeng Wu
Keyword(s):  
Mechanical Properties ◽  
Weight Loss ◽  
Elastic Modulus ◽  
High Temperatures ◽  
Elevated Temperatures ◽  
Physical And Mechanical Properties ◽  
Surface Characteristics ◽  
Time Service ◽  
Different Temperatures ◽  
Cooling Methods

Fires are always known for seriously deteriorating concrete in structures, especially for those with certain carbonation due to long-time service. In this paper, 75 prism specimens were prepared and divided into four groups (three carbonated groups and one uncarbonated group). Specimens were tested under different temperatures (20, 300, 400, 500, 600, and 700°C), exposure times (3, 4, and 6 hours), and cooling methods (water and natural cooling). Surface characteristics, weight loss rate, and residual mechanical properties (strength, initial elastic modulus, peak, and ultimate compressive strains) of carbonated concrete specimens after elevated temperatures were investigated and compared with that of the uncarbonated ones. Results show that the weight loss rates of the carbonated concrete specimens are slightly lower than that of the uncarbonated ones and that the cracks are increased with raising of temperatures. Surface colors of carbonated concrete are significantly changed, but they are not sensitive to cooling methods. Surface cracks can be evidently observed on carbonated specimens when temperature reaches 400°C. Residual compressive strength and initial elastic modulus of carbonated concrete after natural cooling are generally larger than those cooled by water. The peak and ultimate compressive strains of both carbonated and uncarbonated concrete specimens increase after heating, but the values of the latter are greater than that of the former. Finally, the constitutive equation to predict the compressive behaviors of carbonated concrete after high temperatures was established and validated by tests.

Thermal Shock Resistance of ZrO2 Fiber/Al2O3 Ceramics

2011 ◽  
Vol 306-307 ◽  
pp. 754-757 ◽  
Author(s):  
Xian Qin Hou ◽  
Jian Ye Liu ◽  
He Yi Ge
Keyword(s):  
Mechanical Properties ◽  
Electron Microscope ◽  
Water Absorption ◽  
Thermal Shock ◽  
Thermal Shock Resistance ◽  
Sintering Temperature ◽  
Physical And Mechanical Properties ◽  
Shock Resistance ◽  
Scanning Electron ◽  
Absorption Measurements

The physical and mechanical properties of alumina (Al2O3) ceramics by introduction of zirconia (ZrO2) fiber were studied. ZrO2/Al2O3ceramics at different sintering temperature was investigated by porosity and water absorption measurements, flexual strength and thermal shock resistance analysis. Results showed that Al2O3 ceramics containing 15 wt% ZrO2fiber with sintering temperature of 1650°C exhibited good mechanical properties and thermal shock resistance. The porosity and water absorption were 7.4% and 0.69%, respectively. The flexual strength was 613 MPa and the thermal shock times reached 29 times. Scanning electron microscope (SEM) was used to analyze the microstructure of Al2O3 ceramics.

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