Adsorption of Reactive Dye (RB 222) in Solution onto Chitosan-Rice Husk Ash Composite Beads Cross-Linked with Glutaraldehyde

2017 ◽  
Vol 751 ◽  
pp. 719-725 ◽  
Author(s):  
Ratana Sananmuang ◽  
Wipharat Chuachuad Chaiyasith ◽  
Kalayaporn Paroon
Keyword(s):  
Rice Husk ◽  
Dye Removal ◽  
Adsorption Process ◽  
Rice Husk Ash ◽  
Freundlich Isotherm ◽  
Reactive Dye ◽  
Bet Surface Area ◽  
Isotherm Study ◽  
Composite Beads ◽  
C 30

The adsorption of reactive dye (RB 222) onto cross-linked chitosan-rice husk ash composite beads was investigated. BET, SEM and FTIR methodologies were used to characterize the properties of the composite beads. The results indicated that the BET surface area values of cross-linked chitosan-rice husk ash composite beads were 4 .740 m2 /g . The effects of various parameters on the adsorption behavior of composite beads including pH (2-12), temperature (20°C, 30°C and 40°C), and initial concentration (10-850 mg/L) were studied. The dye concentrations after adsorption process were measured using a UV/VIS Spectrophotometer at 611 nm. For the effect of pH on reactive dye (RB 222) removal, the highest value of dye removal was obtained at pH 2. The isotherm study was fitted by Freundlich Isotherm. Moreover, thermodynamics of adsorption was also found that the △Go had negative values. It indicates the feasibility of adsorption process at temperature below 40°C.

scholarly journals Synthesis of zeolite L using rice husk ash silica for adsorption of methylene blue: kinetic and adsorption isotherm

2018 ◽  
Vol 197 ◽  
pp. 05002 ◽  
Author(s):  
Citra Deliana Dewi Sundari ◽  
Soni Setiadji ◽  
Yusuf Rohmatullah ◽  
Sanusi Sanusi ◽  
Denia Febby Nurbaeti ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Rice Husk ◽  
Adsorption Process ◽  
Rice Husk Ash ◽  
Freundlich Isotherm ◽  
Particle Morphology ◽  
Absorption Capacity ◽  
Molar Ratio ◽  
Blue Dye ◽  
Zeolite L

Rice husk has a high silica content, so it can be utilized as silica source for zeolite synthesis. In this research, synthesis of zeolite L has been done using silica from rice husk ash without organic template. The synthesized zeolite L is then used as an adsorbent to adsorb methylene blue dye. The steps of zeolite L synthesis include: silica extraction from rice husk ash using NaOH and zeolite L synthesis using hydrothermal method with molar ratio 10 SiO2: Al2O3: 4 K2O: 100 H2O at 170°C for 24 hours. The resulting Zeolite L was then characterized by XRD and SEM. The absorption capacity of methylene blue solution by zeolite L was observed experimentally through the effect of pH of the solution, contact time, and initial concentration of the solution, then determining the isotherm and its absorption kinetics. From XRD and SEM results of zeolite L sample, it is shown that zeolite L has been formed and its particle morphology is a hollow cylinder with cylinder diameter of 0.049 - 0.123 μm. The adsorption process refers to the Freundlich isotherm model which provides the highest correlation coefficient. The methylene blue adsorption process by zeolite L follows pseudo second-order kinetics.

scholarly journals Comparison on the Surface Structure Properties along with Fe(II) and Mn(II) Removal Characteristics of Rice Husk Ash, Inactive Saccharomyces cerevisiae Powder, and Rice Husk

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Zhao Jiang ◽  
Bo Cao ◽  
Guangxia Su ◽  
Yan Lu ◽  
Jiaying Zhao ◽  
...  
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Rice Husk ◽  
Adsorption Process ◽  
Rice Husk Ash ◽  
Structural Characteristics ◽  
Order Kinetic ◽  
Isotherm Study ◽  
Study Results ◽  
Adsorption Processes ◽  
Order Kinetic Model

This study selected solid wastes, such as rice husk ash (RHA), inactive Saccharomyces cerevisiae powder (ISP), and rice husk (RH), as the potential adsorbents for the removal of Fe(II) and Mn(II) in aqueous solution. The structural characteristics, functional groups, and elemental compositions were determined by scanning electron microscope (SEM) and Fourier translation infrared spectrum (FT-IR) analyses, respectively. Then the influence on the Fe(II) and Mn(II) removing efficiency by the factors, such as pH, adsorbent dosage, initial Fe(II) and Mn(II) concentration, and contact time, was investigated by the static batch test. The adsorption isotherm study results show that Langmuir equation can better fit the Fe(II) and Mn(II) adsorption process by the three adsorbents. The maximum adsorption amounts for Fe(II) were 6.211 mg/g, 4.464 mg/g, and 4.049 mg/g by RHA, ISP, and RH and for Mn(II) were 3.016 mg/g, 2.229 mg/g, and 1.889 mg/g, respectively. The adsorption kinetics results show that the pseudo-second-order kinetic model can better fit the Fe(II) and Mn(II) adsorption process. D-R model and thermodynamic parameters hint that the adsorption processes of Fe(II) and Mn(II) on the three adsorbents took place physically and the processes were feasible, spontaneous, and exothermic.

Removal of Telon blue AFN in solution with the crosslinked hitosan-rice husk ash composite beads using batch reactor

2019 ◽  
Vol 17 ◽  
pp. 1472-1478
Author(s):  
Wipharat Chuachuad Chaiyasith ◽  
Watchaleepron Kaewjit ◽  
Ratana Sananmuang
Keyword(s):  
Rice Husk ◽  
Rice Husk Ash ◽  
Batch Reactor ◽  
Composite Beads

scholarly journals Removal of triphenylmethane dye from aqueous solutions through an adsorption process over waste materials

2020 ◽  
Vol 10 (4) ◽  
pp. 5772-5779
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Dye Removal ◽  
Functional Group ◽  
Adsorption Process ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Pseudo Second Order ◽  
Best Fit

Water pollution is the most significant issue due to rapid growing industrial development especially textile dye industry. Therefore, the adsorption process experiment was conducted to determine the removal ability of the adsorbent chosen. The removal rate and adsorption capacity of Phenol red and Cresol were analyzed by using eggshell adsorbent in the adsorption process. The experiment was conducted with parameters of initial concentration, dosage, pH and contact time. Results indicated that the removal rate achieved more than 90% and the adsorption capacity exceeded more than 5 mg/g. The functional group before adsorption process eggshell adsorbent and after adsorption process eggshell adsorbent was analyzed by using FTIR (Fourier Transform Infrared Spectroscopy). The study of adsorption isotherm and kinetics model was carried out to identify the efficiency of the eggshell adsorbent reacting with the dye solution. The adsorption isotherm that applied in this research was Langmuir isotherm, Jovanovic isotherm and Freundlich isotherm. Moreover, Pseudo-first-order and Pseudo-second-order chosen were conducted to determine the kinetic studies. In short, eggshell adsorbent is highly effective on dye removal through adsorption capacity. The functional group of the eggshell adsorbent was found such as alcohols, phenol, alkanes, carbonyls, ester, saturated aliphatic, aldehydes, aromatics, 2°amines and phosphorus. For kinetics study, Freundlich isotherm was analyzed as the best fit isotherm model as it achieved the highest R2 value which is closed to 1 and Pseudo-second-order was analyzed as the best fit kinetic model in this experiment. Therefore, eggshell adsorbent is highly effective in dye removal.

scholarly journals Removal of Procion Red MX- 5B from aqueous solution by adsorption on Parkia speciosa (stink bean) peel powder

2019 ◽  
Vol 10 (1) ◽  
pp. 4774-4779
Keyword(s):  
Functional Groups ◽  
Dye Removal ◽  
Adsorption Process ◽  
Freundlich Isotherm ◽  
Infrared Spectrometry ◽  
Equilibrium Studies ◽  
Azo Compound ◽  
Stretch Vibration ◽  
Pseudo Second Order ◽  
Stretching Vibrations

The potential of Parkia speciosa peel (SBP) for removal of procion red mx-5B (PR) through the adsorption process was investigated. PR is a type of azo dye which is toxic to the environment especially in water. Sustainable adsorbents such as agricultural wastes have been promising to reduce the amount of pollution in wastewater due to their accessibility and more economic. The batch study was performed to examine the influence of varies exploratory conditions by fluctuating the dosage, adsorption time, and initial concentration. The main functional groups involved in the dye removal were analysed by Fourier transform infrared spectrometry (FTIR). The isotherm data were examined by the Langmuir, Freundlich and Temkin models. The result showed the equilibrium studies were perfectly associated by the Freundlich isotherm with R2= 0.9993, 0.9786 and 0.9728 for 1, 3 and 5 g of adsorbent dosage that corresponded with pseudo-second-order at a rate constant of 1x10-3/min. The FTIR spectrum of SBP after adsorption showed that changing of the functional groups of PR was presented by the stretch vibration of amine N-H and aromatic C=C, stretching vibrations for azo compound N=N. The remarkable data attained that the stink bean peel can be used as an alternative biosorbent for the removal of organic pollutants including the textile effluent industry.

scholarly journals PENGARUH pH LARUTAN DAN UKURAN PARTIKEL ABU SEKAM PADI TERHADAP PENURUNAN KADAR CONGO RED

Molekul ◽  
2007 ◽  
Vol 2 (1) ◽  
pp. 7
Author(s):  
Tien Setyaningtyas ◽  
Uyi Sulaeman
Keyword(s):  
Particle Size ◽  
Rice Husk ◽  
Congo Red ◽  
Contact Time ◽  
Adsorption Process ◽  
Rice Husk Ash ◽  
Raw Material ◽  
Particle Sizes

Rice husk used as a raw material to produce the rice husk ash. The purpose of this research were to determine the optimum contact time and maximum pH of congo red adsorption by rice husk ash, to find out the influence of particle size to adsorption The rice husk was washed, then soaked in HCl 3.84 M to remove mineral impurities, and it was dried and heated for four hours at the temperature 6000 C. The yield gained from this research is 23.44%. Optimum contact time started at after five minutes and maximum pH is six for the tree mention particle sizes 50, 100 and 140 mesh. Particle size didn’t give any significant effect to adsorption process with percent decreasing of congo red is 84.97 %, 90.39 %, 89.32 % respectively.

scholarly journals Characterization and application of orange peel as an adsorbent for cationic dye removal from aqueous solution

2021 ◽  
Vol 25 ◽  
pp. e16
Author(s):  
Aline Haas ◽  
Eliane Pereira dos Santos
Keyword(s):  
Methylene Blue ◽  
Dye Removal ◽  
Adsorption Process ◽  
Solid Medium ◽  
Orange Peel ◽  
Freundlich Isotherm ◽  
Adsorptive Capacity ◽  
Blue Dye ◽  
Maximum Adsorption Capacity ◽  
Methylene Blue Dye

 With the great generation of colored effluents, several methods for the removal of the color are used, being one of them the method of adsorption in solid medium. In this paper, the in natura orange peel was used as the alternative biomass for the adsorption process of methylene blue, which was characterized by moisture content, pH, apparent density, iodine number, and methylene blue index. To determine the adsorptive capacity of the methylene blue dye, pH 7 was obtained as favorable, the adsorption process showed an adsorption of 82% of the methylene blue dye and a 10 min equilibrium time, where the Freundlich isotherm presented a better adaptation to the adsorption process in orange peel, with its maximum adsorption capacity of 3.9630 mg g-1, for the methylene blue dye. 

scholarly journals INVESTIGATION OF THE INFLUENCE OF PARTICLE SIZE OF RICE HUSK ASH AS ADSORBENT FOR MERCURY IN COLUMN ADSORPTION SYSTEM

Konversi ◽  
2021 ◽  
Vol 10 (2) ◽  
Author(s):  
Desi Nurandini ◽  
Riani Ayu Lestari ◽  
Isna Syauqiah ◽  
Ahmad Rizalli ◽  
Ryan Rahmatullah
Keyword(s):  
Heavy Metals ◽  
Particle Size ◽  
Rice Husk ◽  
Adsorption Process ◽  
Rice Husk Ash ◽  
Liquid Waste ◽  
Silica Content ◽  
Column Adsorption ◽  
Before And After ◽  
Adsorbent Particle

The presence of heavy metal mercury (Hg2+) in liquid waste has caused serious problems to environmental pollution. One of the most effective method to reduce the levels of heavy metals mercury (Hg2+) in liquid waste is adsorption. Rice husk ash is highly potential to adsorb heavy metals in water because it is a porous material with a high silica content. Therefore, rice husk ash can be used as an adsorbent for heavy metals in liquid waste. The purpose of this study was to determine the level of mercury (Hg2+) that can be adsorbed from the column adsorption process using adsorbent of rice husk ash and to determine the optimum mass of rice husk ash as an adsorbent. The research was conducted using a series of simple adsorption column tools with a circulation time of 120 minutes. While the independent variables were adsorbent particle size of 50, 100, and 200 mesh. Measurement of mercury (Hg2+) levels was carried out on samples before and after treatment with Atomic Absorption Spectrophotometer (AAS). The results showed a significant decrease in Hg2+ levels with the optimum adsorbent particle size of 200 mesh. The value of the adsorbed Hg2+ ion content reached 101.670 mg/L in the adsorption process using adsorbent with 200 mesh particle size . 

Synthesis of MCM-41 from Rice Husk Ash and its Utilization for Lipase Immobilization

2014 ◽  
Vol 925 ◽  
pp. 23-27
Author(s):  
Nurhadijah Zainalabidin ◽  
Noor Hasyierah Mohd Salleh ◽  
Dachyar Arbain
Keyword(s):  
Surface Area ◽  
Mesoporous Materials ◽  
Rice Husk ◽  
Fine Particles ◽  
Rice Husk Ash ◽  
Enzyme Stability ◽  
Solid Particles ◽  
Bet Surface Area ◽  
Time Range ◽  
Mcm 41

Mesoporous materials are favorable for enzyme immobilization due to their unique properties of large surface area, uniform pore system and functionalizable surfaces. Immobilization on these materials enhances enzyme stability, activity and resistance towards harsh environmental conditions such as temperature and pH. The present study deals with synthesis of mesoporous materials namely MCM-41. For that purpose, the MCM-41 was synthesized using cetyltrimethylammonium bromide (CTAB) as a template and extractable silica from rice husk ash as a silica source. The synthesis was performed under alkaline conditions to produce white fine solid particles, followed by grafting with 3-aminopropyltriethoxysilane and activation with carbodiimide before it was immobilized with lipase. Characterization of those fine particles using Nitrogen physisorption gives BET surface area, as BET, and the pore diameterto be 1184 m²/g and 2.58 nm respectively. Fourier Transform Infrared spectra show peak of SiO2, NH2 and COOH functional group which confirms the existence of those compounds in covalent bonding formation between amine-grafted MCM-41 and lipase enzyme. Immobilized enzyme shows an increase in pH stability when compared to free enzyme at fixed temperature of 20°C in time range from 30 to 180 minutes.

Enhancement of CO2 Adsorption Containing Zinc-ion-exchanged Zeolite NaA Synthesized from Rice Husk Ash

2020 ◽  
Author(s):  
Patchaya Tobarameekul ◽  
Supawon Sangsuradet ◽  
Nareerat Na Chat ◽  
Patcharin Worathanakul
Keyword(s):  
Carbon Dioxide ◽  
Rice Husk ◽  
Crystallization Temperature ◽  
High Efficiency ◽  
Rice Husk Ash ◽  
Zinc Ion ◽  
Bet Surface Area ◽  
Carbon Dioxide Adsorption ◽  
Exchange Method ◽  
Zeolite Naa

Carbon dioxide is main causes the greenhouse effect and it contributes to global warming. Zeolite NaA is an excellent adsorbent among other materials but its potential as a carbon dioxide adsorption still needs to be developed. Therefore, this research was to synthesize zeolite NaA from rice husk ash under different temperatures and crystallization times. The synthesized zeolite NaA was modified with zinc by an ion exchange method. Adsorbents were tested for the carbon dioxide adsorption at different operating temperatures and flow rates. The results showed that the zeolite NaA was successfully synthesized from rice husk ash under optimal conditions of the crystallization temperature at 333.15 K and time for 2 h. The zeolite NaA can be synthesized at low crystallization temperature and time resulted in this adsorbent has low cost while achieving high efficiency. The results of zeolite NaA modification with zinc playing a key role to increase the BET surface area, micropore volume and total pore volume resulted in an increase of carbon dioxide adsorption capacity. High carbon dioxide adsorption at 89.08% with the operating temperature at 573.15 K and carbon dioxide flow rate of 1 L/h were shown with 5 wt.% zeolite NaA.

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