Inertization of Mine Tailing via Cold Consolidation in Geopolymer Matrix

2018 ◽  
Vol 761 ◽  
pp. 31-34 ◽  
Author(s):  
Isabella Lancellotti ◽  
Jenni Kiventerä ◽  
Michelina Catauro ◽  
Francesco dal Poggetto ◽  
Mirja Illikainen
Keyword(s):  
Mine Tailings ◽  
Room Temperature ◽  
Gold Mining ◽  
Leaching Test ◽  
Mining Site ◽  
Granulated Blast Furnace Slag ◽  
Geopolymer Matrix ◽  
The Matrix ◽  
Naoh Solution ◽  
Furnace Slag

The consolidation via geopolymerisation is a room temperature alkaline chemical reaction of condensation between SiO2 and AlO2 monomers. Such a matrix can retain a large number of cations to compensate for the Al+3 in place of Si+4 in the tetrahedra. Arsenic-rich mine tailings from a gold mining site were activated with NaOH solution and commercial Na-Silicate (Na2O/SiO2 = 3) to produce a no-hazardous final material. Granulated blast furnace slag and metakaolin were used as co-binders to optimize the formulations. Leaching test was used to evaluate the inertization capability of the matrix after curing times of 7 and 28 days. The leaching results show that increasing curing time there is a significant decrease of As leaching due to the better consolidation of the material. Leaching of Cu, V, Ba and Zn significantly decrease, while Ni and Cr remain almost constant and Sb slightly increases.

scholarly journals Synthesis of Ambient Cured GGBFS Based Alkali Activated Binder Using a Sole Alkaline Activator: A Feasibility Study

2021 ◽  
Vol 11 (13) ◽  
pp. 5887
Author(s):  
Thandiwe Sithole ◽  
Nelson Tsotetsi ◽  
Tebogo Mashifana
Keyword(s):  
Silicate Solution ◽  
Environmental Footprint ◽  
Ambient Temperatures ◽  
Granulated Blast Furnace Slag ◽  
Naoh Solution ◽  
Alkaline Activator ◽  
Porous Morphology ◽  
Furnace Slag ◽  
Alkali Activated

Utilisation of industrial waste-based material to develop a novel binding material as an alternative to Ordinary Portland Cement (OPC) has attracted growing attention recently to reduce or eliminate the environmental footprint associated with OPC. This paper presents an experimental study on the synthesis and evaluation of alkali activated Ground granulated blast furnace slag (GGBFS) composite using a NaOH solution as an alkaline activator without addition of silicate solution. Different NaOH concentrations were used to produce varied GGBFS based alkali activated composites that were evaluated for Uncofined Compressive Strength (UCS), durability, leachability, and microstructural performance. Alkali activated GGBFS composite prepared with 15 M NaOH solution at 15% L/S ratio achieved a UCS of 61.43 MPa cured for 90 days at ambient temperatures. The microstructural results revealed the formation of zeolites, with dense and non-porous morphology. Alkali activated GGBFS based composites can be synthesized using a sole alkaline activator with potential to reduce CO2 emission. The metal leaching tests revealed that there are no potential environmental pollution threats posed by the synthesized alkali activated GGBFS composites for long-term use.

scholarly journals Phase Transformation of Kaolin-Ground Granulated Blast Furnace Slag from Geopolymerization to Sintering Process

2021 ◽  
Vol 7 (3) ◽  
pp. 32
Author(s):  
Noorina Hidayu Jamil ◽  
Mohd. Mustafa Al Bakri Abdullah ◽  
Faizul Che Pa ◽  
Mohamad Hasmaliza ◽  
Wan Mohd Arif W. Ibrahim ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Room Temperature ◽  
Curing Temperature ◽  
Curing Process ◽  
Sintering Process ◽  
Granulated Blast Furnace Slag ◽  
Fluxing Agent ◽  
Furnace Slag

The main objective of this research was to investigate the influence of curing temperature on the phase transformation, mechanical properties, and microstructure of the as-cured and sintered kaolin-ground granulated blast furnace slag (GGBS) geopolymer. The curing temperature was varied, giving four different conditions; namely: Room temperature, 40, 60, and 80 °C. The kaolin-GGBS geopolymer was prepared, with a mixture of NaOH (8 M) and sodium silicate. The samples were cured for 14 days and sintered afterwards using the same sintering profile for all of the samples. The sintered kaolin-GGBS geopolymer that underwent the curing process at the temperature of 60 °C featured the highest strength value: 8.90 MPa, and a densified microstructure, compared with the other samples. The contribution of the Na2O in the geopolymerization process was as a self-fluxing agent for the production of the geopolymer ceramic at low temperatures.

scholarly journals Microstructure Features of Ternary Alkali-activated Binder Based on Tungsten Mining Waste, Slag and Metakaolin

2020 ◽  
Author(s):  
Naim Sedira ◽  
João Castro-Gomes
Keyword(s):  
Sodium Silicate ◽  
Room Temperature ◽  
Mining Waste ◽  
Dense Matrix ◽  
Microstructural Properties ◽  
Reaction Products ◽  
Granulated Blast Furnace Slag ◽  
Alkaline Activator ◽  
Furnace Slag ◽  
Alkali Activated

This study determines the effect of ground granulated blast furnace slag (GGBFS) and metakaolin (MK) on the microstructural properties of the tungsten mining waste-based alkali-activated binder (TMWM). During this investigation, TMWM was partially replaced with 10 wt.% GGBFS and 10 wt.% MK to improve the microstructure of the binder. In order to understand the effect of the substitutions on the microstructure, two pastes were produced to make a comparative study between the sample contain 100% TMWM and the ternary precursors. Both precursors were activated using a combination of alkaline activator solutions (sodium silicate and sodium hydroxide) with the ratio of 1:3 (66.6 wt.% sodium silicate combined with 33.33 wt.% of NaOH 8M). The alkali-activated mixes were cured in oven at temperature of 60 °C in the first day and at room temperature for the next 27 days. The reaction products N-A-S-H gel and (N,M)-A-S-H gel resulted from the alkaline activation reaction process. In addition, a formation of natrite (Na2CO3) with needles shape occurred as a reaction product of the fluorescence phenomena. However, a dense matrix resulted from the alkline activation of the ternary precursors containg different gels such as N-A-S-H, C-A-S-H and (N,M)-C-A-S-H gel, these results were obtained through SEM-EDS analyses, as well FTIR tests. Keywords: Mining Waste, Alkali-activated, Microstructure, Slag, Metakaolin

scholarly journals Influence of Molarity and Chemical Composition on the Development of Compressive Strength in POFA Based Geopolymer Mortar

2015 ◽  
Vol 2015 ◽  
pp. 1-15 ◽  
Author(s):  
S. M. Alamgir Kabir ◽  
U. Johnson Alengaram ◽  
Mohd Zamin Jumaat ◽  
Afia Sharmin ◽  
Azizul Islam
Keyword(s):  
Compressive Strength ◽  
Blast Furnace Slag ◽  
Palm Oil Fuel Ash ◽  
Manufactured Sand ◽  
Granulated Blast Furnace Slag ◽  
Mix Proportion ◽  
Geopolymer Matrix ◽  
Fuel Ash ◽  
Oil Fuel ◽  
Furnace Slag

The investigation concerns the use of the optimum mix proportion of two locally available pozzolanic waste materials, namely, ground granulated blast furnace slag (GGBS) and palm oil fuel ash (POFA), together with metakaolin (MK) as binders. In addition, another local waste material, manufactured sand (M-sand), was used as a replacement for conventional sand in the development of green geopolymer mortar. Twenty-four mortar mixtures were designed with varying binder contents and alkaline activators. The oven dry curing was also kept consistent for all the mix proportions at a temperature of 65°C for 24 hours. The highest 28-day compressive strength of about 48 MPa was obtained for the mortar containing 20% of MK, 35% of GGBS, and 45% of POFA. The increment of MK beyond 20% leads to reduction of the compressive strength. The GGBS replacement beyond 35% also reduced the compressive strength. The entire specimen achieved average 80% of the 28-day strength at the age of 3 days. The density decreased with the increase of POFA percentage. The finding of this research by using the combination of MK, GGBS, and POFA as binders to wholly replace conventional ordinary Portland cement would lead to alternate eco-friendly geopolymer matrix.

scholarly journals Experimental Study on the Performance and Microstructure of Cementitious Materials Made with Dune Sand

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Chaohua Jiang ◽  
Xiaobin Zhou ◽  
Guilan Tao ◽  
Da Chen
Keyword(s):  
Raw Materials ◽  
Cementitious Materials ◽  
Dune Sand ◽  
Ordinary Concrete ◽  
Granulated Blast Furnace Slag ◽  
The Matrix ◽  
Lower Porosity ◽  
Dry Shrinkage ◽  
Hydrate Products ◽  
Furnace Slag

This paper presents the results of an investigation on the utilization of dune sand from waterway regulation engineering as the main raw materials to produce cementitious materials. The mechanical and durability properties of the cementitious materials were studied. Furthermore, a scanning electron microscope (SEM) and mercury intrusion porosimeter (MIP) were used to identify the microstructure of the specimens. The results show that the compressive and splitting tensile strength of cementitious materials can be improved due to the addition of ground granulated blast-furnace slag (GGBS) which mainly attributes to a better grain size distribution and pozzolanic effect compared to the specimen added cement alone. The specimen with the addition of suitable cement, GGBS, and gypsum shows low dry shrinkage and excellent abrasion resistance. Correspondingly the specimens present a lower porosity and total volume of pores at different curing ages. The SEM observation indicates that there are quite a lot of hydrate products such as calcium silicate hydrate gel in the matrix which verifies the formation of cementitious compounds. The results obtained suggest that there is potential in manufacturing cementitious material with dune sand in substitution of ordinary concrete to use in hydraulic engineering.

scholarly journals Evaluasi Pembuatan Prototype Package Tray Biokomposit Serat Tebu- Polypropylene untuk Kebutuhan Interior Mobil

2020 ◽  
Vol 17 (2) ◽  
pp. 42-47
Author(s):  
Patrik Permana Putra Wijaya ◽  
Juliana Anggono
Keyword(s):  
Mechanical Property ◽  
Flexural Strength ◽  
Sugarcane Bagasse ◽  
Room Temperature ◽  
Natural Fibers ◽  
Interfacial Region ◽  
Flexural Test ◽  
The Matrix ◽  
Naoh Solution ◽  
Strong Material

Natural fibers used in the fabrication of biocomposite product can support the need of the industries for lightweight yet strong material. Sugarcane bagasse is one of the available natural fibers in Indonesia. There have been some research done on these bagasse fibers as reinforcement materials for plastics and their incorporation to the matrix has improved its strength. This research aimed to evaluate the fabrication of a car package tray prototype. The composition and the bagasse were prepared in accordance with the previous research in which the bagasse were alkali treated using NaOH solution of 8 wt% for one hour at room temperature. The hotpressed prototype was evaluated by its physical outlook and the mechanical property of its preform. The flexural test shows a low flexural strength of the prototype (7.4 MPa) compared to the required strength of the current material (woodboard) used by the industry (35.58 MPa). The evaluation shows the clustering of bagasse fibers, uneven distribution of sugarcane/PP in the structure and low adhesion at the interfacial region between bagasse fibers and PP.

scholarly journals Optimizing the Acid Resistance of Concrete with Granulated Blast-Furnace Slag

2018 ◽  
Vol 199 ◽  
pp. 02001
Author(s):  
Rolf Breitenbücher ◽  
Jan Bäcker ◽  
Sebastian Kunz ◽  
Andreas Ehrenberg ◽  
Christian Gerten
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Acid Resistance ◽  
Industrial Applications ◽  
Acid Attack ◽  
Dense Microstructure ◽  
Granulated Blast Furnace Slag ◽  
Acid Type ◽  
The Matrix ◽  
Furnace Slag

Concrete for agricultural or industrial applications is often subject to intense acid attack. Most affected structures are sewage structures and biogas plants, natural draught cooling towers or silage silos. Widely independent from acid type, in most cases the acid attack on concrete runs the same way, starting with dissolution of easily soluble calcareous phases like calcium hydroxide. With ongoing attack, calcium-silicate-hydrate crystals (CSH) are also affected by acidic media. In contrast, siliceous phases like silicon-dioxide (SiO2) are widely unaffected by acid attack. While the dissolution of the matrix is increasing with ongoing attack, quarzitic aggregates remain unchanged. Beside the use of coarse SiO2-aggregates, the resistance against acid attack is mainly increased by a minimization of the porosity. For this purpose on one hand, a low water/cement-ratio has to be sought, on the other hand also the fines should be distributed with an optimized grading curve (e.g. Fuller-principle). In practice, this results in a combination of various fine and ultra-fine components, e.g. fly ash, GGBS, silica fume or metakaolin. Such binder compositions lead to a particularly dense microstructure, especially at pore sizes below 1 micron, and a higher chemical resistance due to a lower Ca(OH)2 content. This paper gives an overview on typical acid-resistant concretes, most common applications as well as the effects of the related acid attack and points out the potential of granulated blast furnace slag addition to such concretes.

Investigation on the Performance of Hybrid Fiber Reinforced Geopolymer Concrete Made of M-Sand under Heat Curing

2021 ◽  
Vol 1019 ◽  
pp. 73-81
Author(s):  
A. Chithambar Ganesh ◽  
J. Sivasubramanaian ◽  
Mahalingam Sesha Seshamahalingam ◽  
J. Millar ◽  
V. Jayanth Kumar
Keyword(s):  
Engineering Properties ◽  
Geopolymer Concrete ◽  
Hybrid Fiber ◽  
Granulated Blast Furnace Slag ◽  
Ductility Factor ◽  
Heat Curing ◽  
Mix Proportion ◽  
Naoh Solution ◽  
The Impact ◽  
Furnace Slag

Due to the elevating demand to replace the conventional cement concrete with any other building material, there has been a continuous effort to promote the properties of geopolymer concrete. The objective of this paper is to reduce the brittleness of geopolymer concrete. This research paper goes for exploring the impact of high and low young’s modulus fiber in geopolymer concrete made of M-sand. Mix proportion of various materials is based on the Rangan’s proposed Mix design. Geopolymer concrete used in this investigation is the Fly ash – Ground Granulated Blast Furnace Slag blend based. Concoction of NaOH solution and Na2SiO3 solution is used as the alkali solution. Sine 80 percent of the source material is flyash, the specimens are exposed to heat curing. Fresh property and hardened characteristics like workability, ductility factor, compressive, split tensile, flexural and impact strength are assessed in this study. Significant increase in the engineering properties is observed with respect to both the fibers. This work unveils lot of potential in the vicinity of Geopolymer concrete.

Effect of High Temperature on Properties of Bricks Using Granulated Blast-Furnace Slag as Aggregate Replacement

2014 ◽  
Vol 600 ◽  
pp. 227-239
Author(s):  
Hanan A. El Nouhy
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
High Temperature ◽  
Blast Furnace Slag ◽  
Room Temperature ◽  
Dry Weight ◽  
Fine Aggregate ◽  
Load Bearing ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

This research investigates the influence of high temperature on the properties of bricks containing non-ground granulated blast-furnace slag (GBFS) as fine aggregate replacement. Replacement percentages were 0%, 25% and 50% by dry weight of fine aggregates. The manufactured bricks were exposed to 200°С, 400°С, 600°С, and 800°С for a constant duration of two hours after 28 days of curing. Tests were conducted according to both Egyptian Standard Specifications (ESS) and American Society for Testing and Materials (ASTM) in order to determine compressive strength, absorption percentage, oven-dry weight, and ultrasound pulse velocity. Also, loss in weight was performed. Compressive strength limit regarding load-bearing units was met by mix 1 at all tested temperatures. Mixes 2 and 3, resulted in compressive strength that satisfied the requirement for load-bearing units at temperatures ranging from room temperature to 600°С.Compressive strength obtained regarding mixes 2 and 3 met the requirements of non-load bearing units at 800°С. The control mix resulted in normal weight bricks when tested at the various temperatures till 600°С. At 800°С, mixes 2 and 3 yielded light weight and medium weight bricks, respectively. There was a significant reduction in mass when comparing the mass at 800°С with the corresponding mass at room temperature concerning the three mixes. Results showed that it is feasible to partially replace fine aggregate with GBFS even when bricks are subjected to elevated temperature.

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