Smelting Reduction of Spent Catalyst Containing Nickel: A Preliminary Study

2020 ◽  
Vol 1009 ◽  
pp. 162-167
Author(s):  
Kitti Laungsakulthai ◽  
Thanapon Chandakhiaw ◽  
Natcha Wongnaree ◽  
Jirapracha Thampiriyanon ◽  
Woranittha Kritsarikun ◽  
...  

The aim of this research was to study the recycling process and the feasibility to smelt the spent nickel catalyst for the production of nickel alloy or ferronickel. The smelting process was carried out in a laboratory induction furnace. The effects of SiO2/CaO for slag forming on metal recovery and smelting time were investigated. Petroleum coke was used as reductant. Mill scale was used as an iron resource for ferro-alloy production, while CaO was used as slag forming agent. The raw materials were mixed together and put into a graphite crucible, which was then placed in the induction furnace. After the melt was completed, the melt was poured into a mold to solidify. The chemical composition of the product was analyzed by XRF and XRD. It was found that the smelting time was decreased with increasing SiO2/CaO from 1.0 to 2.3. For nickel alloy production, increasing of SiO2/CaO increased the weight of metal product. For the ferronickel production, however, the weight of metal product was found not to vary with different ratio of SiO2/CaO.

Batteries ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 29
Author(s):  
Leonard Kurz ◽  
Mojtaba Faryadras ◽  
Ines Klugius ◽  
Frederik Reichert ◽  
Andreas Scheibe ◽  
...  

Due to the increasing demand for battery electric vehicles (BEVs), the need for vehicle battery raw materials is increasing. The traction battery (TB) of an electric vehicle, usually a lithium-ion battery (LIB), represents the largest share of a BEV’s CO2 footprint. To reduce this carbon footprint sustainably and to keep the raw materials within a closed loop economy, suitable and efficient recycling processes are essential. In this life cycle assessment (LCA), the ecological performance of a waterjet-based direct recycling process with minimal use of resources and energy is evaluated; only the recycling process is considered, waste treatment and credits for by-products are not part of the analysis. Primary data from a performing recycling company were mainly used for the modelling. The study concludes that the recycling of 1 kg of TB is associated with a global warming potential (GWP) of 158 g CO2 equivalents (CO2e). Mechanical removal using a water jet was identified as the main driver of the recycling process, followed by an air purification system. Compared to conventional hydro- or pyrometallurgical processes, this waterjet-based recycling process could be attributed an 8 to 26 times lower GWP. With 10% and 20% reuse of recyclate in new cells, the GWP of TBs could be reduced by 4% and 8%, respectively. It has been shown that this recycling approach can be classified as environmentally friendly.


2021 ◽  
Vol 98 ◽  
pp. 8-13
Author(s):  
Dung Ngo Quoc ◽  
◽  
Viet Nguyen Hoang

MS1200 steel grade is now widely utilized in the automotive sector because it is a good solution for the current trend of vehicle chassis frame construction. This research presents a technology procedure for producing MS1200 steel grade from low carbon steel scrap and sponge iron – a product of MIREX Vietnam. The smelting using up to 30 % sponge iron briquettes combined with low carbon scrap, FeSi, FeMn, FeCr, FeTi,… was realized in a medium frequency induction furnace. The heat treatment for forged steel was performed to obtain required properties. The steel product has the following properties: tensile strength σb = 1280 MPa, yield strength σ0.2 = 990 MPa and impact toughness ak = 769 J/mm2, that meets the need of industrial use.


2021 ◽  
pp. 104-113
Author(s):  
O. P. Deryugina ◽  
E. A. Trapeznikov

The article discusses the issue of industrial compounding, which improves the quality of the raw materials supplied to the main pipelines. Compounding from "to compound" (English) - to mix. When mixing different types of oil obtained, "incompatibility" is possible, which is expressed in the precipitation of a solid sediment and violation of the stability of the colloidal system and due to the differing properties of oils. Attention to this problem is due to the tightening of requirements for the quality of raw materials that must comply with modern standards. The article discusses the causes of the problem of "incompatibility" of oil during compounding and effective ways of solving it, substantiates the need for a preliminary study of the properties of mixed oil in order to identify possible incompatibility of various types of oil. The standard tests for determination of incompatibility indices characterizing the ability of raw materials to mix are considered. The article substantiates the need to develop methods for diagnosing the incompatibility of oils as the most important task of modern chemical science, the solution of which will improve the quality of the raw material obtained and solve many technological problems in the compounding process.


2020 ◽  
Vol 989 ◽  
pp. 394-399
Author(s):  
Nina V. Nemchinova ◽  
Andrey A. Tyutrin ◽  
Sergei N. Fedorov

The paper considers the problem of recycling the dust waste resulting from metallurgical silicon production; such dust contains considerable amounts of valuable silica. The problem is solved by redirecting this byproduct to the silicon smelting process. We herein propose using the dust left in silicon and aluminum production as a component of pelletized charge, used for silicon smelting in ore-thermal furnaces (OTF). Mathematical (physico-chemical) modeling was applied to study the behavior of pelletized-charge components, in order to predict the chemical composition of smelting-produced silicon. We generated a model that simulated the four temperature zones of a furnace, as well as the crystalline-silicon phase (25°С). The model contained 17 elements entering the furnace, due to being contained in raw materials, electrodes, and the air. Modeling produced molten silicon, 91.73 wt% of which was the target product. Modeling showed that, when using the proposed combined charge, silicon extraction factor would amount to 69.25%, which agrees well with practical data. Results of modeling the chemical composition of crystalline silicon agreed well with the chemical analysis of actually produced silicon.


2010 ◽  
Vol 63 (2) ◽  
pp. 265-270
Author(s):  
Paulo Santos Assis ◽  
Jue Fang ◽  
Tilak R. Mankhand ◽  
Carlos Frederico Campos de Assis ◽  
Giovanni Felice Salierno

In contrast, conventional processes use coke and hematite/sinter in the blast furnace, in SR processes, other alternative fuels and iron ore sources, like charcoal and fine iron ores, can be used to produce sponge iron. The use of these alternative sources, by SR processes, can reduce environmental impacts and lower production costs. At first, the concepts of the theoretical gas utilization ratio, the smelting heat of the iron ore and the effective calorific value of coal were introduced. Then, the reason for gas utilization ratio and its performance in the shaft as a reducer in the smelting process are discussed and calculated. The relationship between coal consumption and iron ore reduction in the fluidized bed are also discussed. Finally, the influence of post-combustion on coal consumption in an iron bath furnace are calculated and discussed.


2012 ◽  
Vol 518-523 ◽  
pp. 3450-3454 ◽  
Author(s):  
Zi Qiang Zhou ◽  
Han Mo Tan ◽  
Guo Hong Dai

With rapid increasing of the vehicle population of China, The treatment of End-of-life Vehicle (ELV) becomes a serious social problem. Because the situation of ELV, labor cost and the condition of facilities of China are different from the developed countries, the technologies and the recycling process used by the developed countries can not be simply imported to China without any change. In this paper, the recycling processes of the developed counties are analyzed firstly. And then, the shortage and the advantage of the Chinese recycling factories are discussed. According to it, a scheme of ELV recycling process is presented. And three value analyzing models are illustrated which include: (1) model of ELV to raw materials; (2) model of intermediate scrap to product; (3) model of remanufacturing. In the end, the facilities used for EVL recycling factories based on this process are discussed too.


Geosciences ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 172 ◽  
Author(s):  
Michela Ricca ◽  
Giuseppe Paladini ◽  
Natalia Rovella ◽  
Silvestro Antonio Ruffolo ◽  
Luciana Randazzo ◽  
...  

This work focused on the study of decorated pottery dated back to the 16th century from the Roman archaeological site of Villa dei Quintili, a monumental complex located in the south-eastern part of Rome (Italy). A minero-petrographic and geochemical study was undertaken to analyse five archaeological samples in order to define textural features and raw materials used for their production, along with the chemical and physical composition of the superficial decorative glazed coatings. For this purpose, different analytical methods were used, such as polarising optical microscope (POM), X-ray diffraction (XRD), micro-Raman spectroscopy, X-Ray fluorescence (XRF), and electron microprobe analysis coupled with energy dispersive spectrometry (EMPA-EDS). The results of such a multidisciplinary approach allowed us to achieve important results crucial to recognise the shards as majolica of the Renaissance period, improving knowledge about manufacturing processes of these renowned painted ceramic artefacts.


2020 ◽  
Vol 24 (11) ◽  
pp. 14-18
Author(s):  
A.K. Kairakbaev ◽  
V.Z. Abdrakhimov ◽  
E.S. Abdrakhimova

The use of nanotechnogenic petrochemical raw materials-spent IM-2201 catalyst containing more than 70 % Al2O3, and as a clay binder-lowmelting clay from the Ilek Deposit in the Aktobe region allows you to get a ceramic brick that corresponds to the M150 brand. It is possible to build load-bearing walls of the lower floors of high-rise buildings (more than 10 floors) from M150 ceramic bricks. Innovative proposals for the use of waste from production and spent catalyst in the production of ceramic high-strength earthquake-resistant bricks with increased strength and frost resistance have been developed. The absolute advantage of using multi-tonnage waste and spent catalyst IM-2201 is to relieve the environmental situation.


2016 ◽  
Vol 5 ◽  
pp. 374-382
Author(s):  
F. Turco ◽  
P. Davit ◽  
A. Borghi ◽  
J. Bruno ◽  
C. Lippolis ◽  
...  

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