On the Temperature Rate Dependent Transformation Processes

2007 ◽  
Vol 537-538 ◽  
pp. 571-578
Author(s):  
Tamás Réti ◽  
Imre Czinege ◽  
Imre Felde ◽  
Lino Costa ◽  
Rafael Colás

Kinetic models of new types are suggested which are designated primarily to predict the progress of non-isothermal transformations occurring during rapid heating and cooling in alloys. A common feature of each model outlined is that it takes into account not only the varying temperature but also the rate of temperature change on the transformation rate of the process. The two models represented by differential equations are generated by using the concept of virtual kinetic parameters, which can be determined from non-isothermal experiments only. A key property of the virtual parameter "p" involved in the transformation rate equations is that it quantitatively characterizes the temperature rate dependence of the non-isothermal reaction.

2011 ◽  
Vol 17 (2) ◽  
pp. 179-187 ◽  
Author(s):  
S.L. Gilani ◽  
G.D. Najafpour ◽  
H.D. Heydarzadeh ◽  
H. Zare

In process of xanthan gum production the effect of media temperature, agitation rate and molasses concentration on yield of fermentation were investigated. Xanthan gum was produced in batch fermentation by Xanthomonas campestris PTCC 1473 from molasses. At 32?C, 500 rpm and media with 30g/l of total sugar maximum production of xanthan gum (17.1g/l) was achieved. For the purity of the xanthan FTIR spectrum was obtained. The identified spectrum was compared with the commercial product. In batch culture, several kinetic models for the biochemical reactions were extensively studied. The growth kinetic parameters were evaluated by unstructured model and derived from the related equations. Based on Malthus and Logistic rate equations, the maximum specific growth rate, ?max, and initial cell dry weight, X0, were defined. Luedeking-Piret and Modified Luedeking-Piret models were applied for the product formation and substrate consumption rates. In batch experiments, the kinetic parameters for the growth associated (m, a) and non-growth associated (n, b) parameters were determined.


Author(s):  
Tamás Reti ◽  
Imre Czinege ◽  
Imre Felde ◽  
Lino Costa ◽  
Rafael Colás

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1429
Author(s):  
Woohyun Kim ◽  
Khaja Mohaideen Kamal ◽  
Dong Joo Seo ◽  
Wang Lai Yoon

The CO-selective methanation process is considered as a promising CO removal process for compact fuel processors producing hydrogen, since the process selectively converts the trace of CO in the hydrogen-rich gas into methane without additional reactants. Two different types of efficient nickel-based catalysts, showing high activity and selectivity to the CO methanation reaction, were developed in our previous works; therefore, the kinetic models of the reactions over these nickel-based catalysts have been investigated adopting the mechanistic kinetic models based on the Langmuir chemisorption theory. In the methanation process, the product species can react with the reactant and also affect the adsorption/desorption of the molecules at the active sites. Thus, the kinetic parameter study should be carried out by global optimization handling all the rate equations for the plausible reactions at once. To estimate the kinetic parameters, an effective optimization algorithm combining both heuristic and deterministic methods is used due to the large solution space and the nonlinearity of the objective function. As a result, 14 kinetic parameters for each catalyst have been determined and the parameter sets for the catalysts have been compared to understand the catalytic characteristics.


Author(s):  
Nicolas Scepi ◽  
Mitchell C Begelman ◽  
Jason Dexter

Abstract Dwarf novæ (DNe) and low mass X-ray binaries (LMXBs) are compact binaries showing variability on time scales from years to less than seconds. Here, we focus on explaining part of the rapid fluctuations in DNe, following the framework of recent studies on the monthly eruptions of DNe that use a hybrid disk composed of an outer standard disk and an inner magnetized disk. We show that the ionization instability, that is responsible for the monthly eruptions of DNe, is also able to operate in the inner magnetized disk. Given the low density and the fast accretion time scale of the inner magnetized disk, the ionization instability generates small, rapid heating and cooling fronts propagating back and forth in the inner disk. This leads to quasi-periodic oscillations (QPOs) with a period of the order of 1000 s. A strong prediction of our model is that these QPOs can only develop in quiescence or at the beginning/end of an outburst. We propose that these rapid fluctuations might explain a subclass of already observed QPOs in DNe as well as a, still to observe, subclass of QPOs in LMXBs. We also extrapolate to the possibility that the radiation pressure instability might be related to Type B QPOs in LMXBs.


1970 ◽  
Vol 12 (2) ◽  
pp. 156-159 ◽  
Author(s):  
V. P. Kurbatov ◽  
V. I. Murav'ev

RSC Advances ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 3286-3295 ◽  
Author(s):  
A. S. Portnyagin ◽  
A. P. Golikov ◽  
V. A. Drozd ◽  
V. A. Avramenko

Presented method of kinetic analysis of non-isothermal reaction data provides precise kinetic parameters for different materials with different morphology and particle size.


2021 ◽  
Vol 30 (3) ◽  
pp. 035030
Author(s):  
Jinsu Kim ◽  
Seung-Yeol Jeon ◽  
Seokbin Hong ◽  
Yongsan An ◽  
Haedong Park ◽  
...  

Author(s):  
Xiaojuan Zhang ◽  
Junru Zhao ◽  
Jie Zhang ◽  
Shijing Su ◽  
Luqiang Huang ◽  
...  

Abstract This paper presented a mathematical model to describe the production of fucoxanthin by alga Thalassiosira weissflogi ND-8 in photobioreactor. Our interest was focused on characterizing the effects of nitrogen and phosphorus on the growth of microalgae and on the synthesis of fucoxanthin. The rate equations of microalgal growth, fucoxanthin synthesis and substrate consumptions were formulated. Kinetic parameters of the model and their sensitivities with respect to model output were estimated. The predicted results were compared with experimental data, which showed that this model closely agrees with actual experiment and is able to reflect the growth and metabolism characteristics of microalgae. Our results also indicated that nitrogen plays a major role in the synthesis of fucoxanthin, and the synthesis of fucoxanthin is partially linearly related to the consumption of nitrogen. Phosphorus is primarily consumed in the growth and metabolism of microalgal cells, while excessive phosphorus concentration has an inhibitory effect on the growth of microalgae.


2014 ◽  
Vol 2014 (1) ◽  
pp. 000100-000106
Author(s):  
Tom Colosimo ◽  
Horst Clauberg ◽  
Evan Galipeau ◽  
Matthew B. Wasserman ◽  
Michael Schmidt-Lange ◽  
...  

Advancements in electronic packaging performance and cost have historically been driven by higher integration primarily provided by fab shrinks that has followed the well-known Moore's law. However, due to the tremendous and continuously increasing cost of building new fabs, the performance/cost improvements achieved via node shrinks are negated. This leaves packaging innovation as the vehicle to achieve future cost-performance improvements. This has initiated a More-than-Moore idea that has led to vigorous R&D in packaging. Advanced packages which employ ultra-fine pitch flip chip technology for chip-to-substrate, chip-to-chip, or chip-to-interposer for the first level interconnect have been developed as an answer to obtaining higher performance. However, the costs are too high as compared to traditional wire bonding. The status today is that the fundamental technical hurdles of manufacturing the new advanced packages have been solved, but cost reduction and yield improvements have to be addressed for large-scale adoption into high volume manufacturing. In traditional flip chip assembly silicon chips are tacked onto a substrate and then the solder joints are melted and mass reflowed in an oven. This mass reflow technique is troublesome as the pitch of the solder bumps become finer. This is due to the large differences in the thermal expansion coefficient of the die and the substrate, which creates stress at the solder joints and warpage of the package when the die and substrate are heated and cooled together. To mitigate and resolve this issue, thermo-compression bonders have been developed which locally reflow the solder without subjecting the entire substrate to the heating and cooling cycle. This requires that the bondhead undergo heating past the melting point of solder and then cooling down to a low enough temperature to pick the next die from the wafer that is mounted to tape. Machines in the market today can accomplish this temperature cycle in 7 to 15 seconds. This is substantially slower than the standard flip chip process which leads to high cost and is delaying the introduction of these new packages. This paper shows a flip chip bonder with a new heating and cooling concept that will radically improve the productivity of thermo-compression bonding. Data and productivity cycles from this new bond head with heating rates of over 200°C/sec and cooling of faster than 100°C/sec are revealed. Experimental results are shown of exceptional temperature accuracy across the die of 5°C throughout the cycle and better than 3°C at the final heating stage. The high speed thermo-compression bonds are analyzed and the efficacy of the new concept is proven. Excellent temperature uniformity while heating rapidly is an absolute necessity for enabling good solder joints in a fast process. Without good temperature uniformity, additional dwell times need to be incorporated to allow heat to flow to all of the joints, negating any benefits from rapid heating. Whereas the current state-of-that-art is often to program temperature in steps, this bonder can be commanded and accurately follows more complex temperature profiles with great accuracy. Examples of how this profiling can be used to enhance the uniformity and integrity of the joints with non-conductive pastes, film, and without underfill along with the associated productivity improvements will be shown. Tests that show portability across platforms that will lead to set up time and yield improvements and are identified and quantified. Additionally new ideas for materials and equipment development to further enhance productivity and yield are explored.


2004 ◽  
Vol 120 ◽  
pp. 405-412
Author(s):  
J. Ahlström ◽  
B. Karlsson ◽  
S. Niederhauser

A model on laser cladding of medium carbon steel, used in railway wheels and rails, is developed and implemented. When the laser beam is scanned over the surface during the cladding operation, phase transformations occur in the topmost layer of the substrate material due to rapid heating and cooling. The hardened regions may later be annealed, either during subsequent passes of the laser beam or by for example induction heating. The current model is a first step towards judging the resulting microstructure and hardness in the heat affected zone under the clad.


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