Magnesium Alloy Development for Automotive Applications

2012 ◽  
Vol 706-709 ◽  
pp. 69-82 ◽  
Author(s):  
Alan A. Luo ◽  
Raja K. Mishra ◽  
Bob R. Powell ◽  
Anil K. Sachdev

This paper summarizes the development of new cast and wrought magnesium alloys using computational thermodynamics tools and experimental approach. The Mg-Al-Ca alloys show excellent creep resistance due to the formation of high-temperature (Mg,Al)2Ca phase. The Mg-Al-Sn alloys are designed for mechanical properties and corrosion resistance through the optimization of Mg17Al12and Mg2Sn phases in the microstructure. In the Mg-Zn-Ce system, Zn provides strength through solid solution strengthening while Ce increases the ductility via improved texture. Mg-Nd-Zn is a heat-treatable alloy system based on the precipitation hardening of Mg12Nd phase.

Hydrogen ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 262-272
Author(s):  
Sebastian DiMauro ◽  
Gabrielle Legall ◽  
Coleman Lubinsky ◽  
Monica Nadeau ◽  
Renee Tait ◽  
...  

Strength, hardness, and ductility characteristics were determined for a series of palladium-copper alloys that compositionally vary from 5 to 25 weight percent copper. Alloy specimens subjected to vacuum annealing showed clear evidence of solid solution strengthening. These specimens showed, as a function of increasing copper content, increased yield strength, ultimate strength, and Vickers microhardness, while their ductility was little affected by compositional differences. Annealed alloy specimens subsequently subjected to exposure to hydrogen at 323 K and PH2 = 1 atm showed evidence of hydrogen embrittlement up to a composition of ~15 wt. % Cu. The magnitude of the hydrogen embrittlement decreased with increasing copper content in the alloy.


2015 ◽  
Vol 817 ◽  
pp. 307-311 ◽  
Author(s):  
Peng Chao Zhang ◽  
Jin Chuan Jie ◽  
Yuan Gao ◽  
Tong Min Wang ◽  
Ting Ju Li

The Cu-Cr and Cu-Cr-Ti alloy plates were prepared by vacuum melting and plastic deformation. The effect of slight Ti element on microstructure and mechanical properties of Cu-Cr alloy was discussed. The result shows that Cr particles with spherical shape precipitated from Cu matrix after aging. Plenty Ti atoms dissolved in the vicinity of Cr particles and there were still parts of solid solution Ti atoms in other regions. Improvements in peak hardness and softening resistance were achieved with the addition of Ti element in Cu-Cr alloy. The addition of 0.1 wt.% Ti element makes Cu-Cr alloy possess tensile strength of 565 MPa and hardness of 185.9 HV after aging at 450 °C for 120 min, which can be attributed to multiple strengthening mechanisms, i.e. work hardening, solid solution strengthening and precipitation strengthening.


1996 ◽  
Vol 459 ◽  
Author(s):  
Yu.I. Chumlyakov ◽  
I. V. Kireeva ◽  
G. S. Kapasova ◽  
E. I. Litvinova

ABSTRACTIt was experimentally shown that the achievement of a high deforming stress level due to dispersion hardening and solid solution strengthening of FCC single crystals with a low stacking-fault energy leads to the deformation mechanism changing from slip to twinning, the dependence of mechanical properties on a crystal orientation and a sign of applied stresses. During deformation by twinning at T<150–300K effects of pseudoelasticity associated with elastic twinning is observed.


1985 ◽  
Vol 53 ◽  
Author(s):  
S. Guruswamy ◽  
J.P. Hirth ◽  
K.T. Faber

ABSTRACTSubstantial solid solution strengthening of GaAs by In acting as InAs4 units has recently been predicted. This strengthening could account for the reduction of dislocation density in GaAs single crystals grown from the melt. High temperature hardness measurements up to 700ºC have been carried out on (100) GaAs and Ga0.9975 In0.0025 As wafers. Results show a significant strengthening effect in In—doped GaAs even at concentration levels of about 0.2 wt%. A temperature independent flow stress region is observed for both these alloys. The In—doped GaAs shows ahigher plateau stress level compared to the undoped GaAs. The results are consistent with the solid solution strengthening model.


2007 ◽  
Vol 353-358 ◽  
pp. 718-721
Author(s):  
Ding Fei Zhang ◽  
Rong Shen Liu ◽  
Jian Peng ◽  
Wei Yuang ◽  
Hong Ju Zhang

With different heat treatment, the microstructure and mechanical properties of ZK60 magnesium alloy were investigated. It can be concluded that heat treatment has great effect on mechanical properties of ZK60. With artificial aging after extruding, the precipitation of the second phase from the supersaturated solid solution significantly improved mechanical properties. It can greatly increase yield strength of ZK60 alloy, while the tensile strength has little change. For the combination of solid solution strengthening and age hardening, two opposite factors must be considered. On one hand, the solid solution strengthening and the later precipitation strengthening is good for alloy’s strength; on the other hand, the properties decrease as the grains grew under high temperature for a long time during solution heating.


2019 ◽  
Vol 55 (10) ◽  
pp. 4493-4503 ◽  
Author(s):  
Arijit Lodh ◽  
Prita Pant ◽  
Gulshan Kumar ◽  
K. V. Mani Krishna ◽  
Raghvendra Tewari ◽  
...  

AbstractOrientation-dependent solid solution strengthening was explored through a combined microtexture plus nanoindentation study. Pure zirconium (6N purity crystal-bar Zr) and commercial Zircaloy-2 were investigated for comparison. Local mechanical properties were estimated through finite element (FE) simulations of the unloading part of the nanoindentation load–displacement response. Combinations of ‘averaging’ scheme and constitutive relationship were used to resolve uncertainty of FE-extracted mechanical properties. Comparing the two grades, non-basal oriented grains showed an overall hardening and increase in elastic modulus. In contrast, insignificant change was observed for basal (or near-basal) oriented grains. The strengthening of non-basal orientations appeared via elimination of the lowest hardness/stiffness values without a shift in the peak value. Such asymmetric development brought out the clear picture of orientation-dependent solid solution strengthening in zirconium.


2021 ◽  
Author(s):  
Jiquan Huang ◽  
Changliang YANG ◽  
Qiufeng HUANG ◽  
Zhonghua DENG ◽  
Yun WANG ◽  
...  

Abstract Sesquioxides such as Y2O3 and Sc2O3 are important optical materials, but the fabrication of their transparent ceramics remains a challenge due to the ultra-high melting point of over 2400 oC. In this work, a series of (Y1-xScx)2O3 transparent ceramics were successfully fabricated by a simple vacuum sintering process without any sintering additives, and the effect of Scandium (Sc) content on the crystal structure and optical/thermal/mechanical properties were evaluated. Y2O3 and Sc2O3 form a complete solid solution with a cubic bixbyite structure. The formation of (Y1-xScx)2O3 solid solution promotes the densification of ceramics, leading to the realization of high transparency close to the theoretical transmittance over a wide wavelength range of 0.35-8 mm. In particular, the in-line transmittance in the range of 0.6-6 mm remains above 80% for (Y1-xScx)2O3 with x = 0.23-0.31, while the pristine Y2O3 and Sc2O3 are opaque. Moreover, the mechanical properties including Vickers hardness (Hv), fracture toughness (KIC), and biaxial strength (δb) are evidently enhanced due to the solid solution strengthening, while the thermal conductivity is reduced due to the reduction of photon free path. This study demonstrates that forming of solid solution is a facile and universal approach for preparing sesquioxides transparent ceramics with high optical and mechanical quality.


2007 ◽  
Vol 26-28 ◽  
pp. 485-488 ◽  
Author(s):  
Kee Ahn Lee ◽  
Sung Jun Kim ◽  
Moon Chul Kim

This work sought to examine the suitability of twin roll strip casting for Ag-27%Cu- 25%Zn-3%Sn brazing alloy (BAg-7A) and to investigate the mechanical properties and microstructure of the strip. The effect of aging heat treatment on the properties was also studied. This new manufacturing process has applications in the production of the brazing alloy. XRD and microstructural analysis of the Ag-27%Cu-25%Zn-3%Sn strip represented eutectic microstructure of a Cu-rich phase and a Ag-rich matrix regardless of heat treatment. The results of mechanical tests showed tensile strength of 470MPa, a significant enhancement; and an 18% elongation of the twin roll casted strip, due mainly to the solid solution strengthening of Zn atoms (~20%) in the Cu-rich phases. Tensile results showed gradually decreasing strengths and increasing elongation with aging heat treatment. Microstructural evolution and fractography were also investigated and related to the mechanical properties.


2011 ◽  
Vol 306-307 ◽  
pp. 603-607
Author(s):  
Chong Cai Zhang ◽  
Wei Xing Wu ◽  
Quan Wang ◽  
Long Wang

The paper studied the microstructure and properties of new aluminum-based sliding bearing alloy, which Cu, Ni, Mg, Sn, Ti, B... elements were appropriately added. The as-prepared aluminum alloy was investigated using scan electron microscope (SEM). The results show that the alloy microstructure is α-Al crystalology matrix with Tin and some compounds, contribute to suitable strength, hardness and plastic level for manufacturing whole sliding bearing. All of that are mainly got credit for solid solution strengthening and precipitation hardening. Sufficient soft tin in grain boundary makes the alloy have excellent antifriction performance, anti-seizing.


1994 ◽  
Vol 364 ◽  
Author(s):  
Tohru Takahashi ◽  
Tadashi Hasegawa

AbstractTwo types of aluminum–titanium–iron–vanadium ( Al–Ti–Fe–V ) quarternary intermetallic compounds have been prepared by arc melting under argon atmosphere. Their compositions were nominally Al66Ti25Fe6V3 and Al66Ti25Fe3V6. These alloys are based on the iron–modified titanium trialuminide with L12 cubic structure. Vanadium addition up to about 6 mol% did not destroy the cubic symmetry, and L12 solid solution compounds were produced in these two Al–Ti–Fe–V quarternary alloys. Microstructure and mechanical properties have been investigated. It has been demonstrated that vanadium addition to iron–modified L12 titanium trialuminides can enhance their strength.


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