Effect of ZrB2 Nanoparticle Addition: Nano-LPSO-Grain Structured Ultra-High Strength Mg-RE Alloy

2014 ◽  
Vol 783-786 ◽  
pp. 425-430
Author(s):  
Muralidharan Paramsothy ◽  
Manoj Gupta
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Yield Strength ◽  
Polycrystalline Material ◽  
High Strength ◽  
Tensile Yield Strength ◽  
Intermetallic Formation ◽  
Long Period ◽  
Ordered Phases ◽  
The Common

Currently, long period stacking/ordered phases (LPSO phases) are known to reinforceMg97Y2Zn1 type Mg-RE alloys. The LPSO phases are composed of a solid solution of Y and Znatoms placed orderly in long periods along the Mg basal plane. Also, an efficient way to strengthena polycrystalline material is to reduce its grain size. This increases the density of grain boundarieswhich impede the flow of dislocations. In many of the LPSO forming solidification processed Mg-RE alloys, the common practice is to solutionize the ingot, quench in warm water, hot extrude andthermally age. While this practice is suitable for obtaining high strength Mg-RE alloys, itconveniently employs the common idea in conventional metallurgy of fine intermetallicstrengthening while refining the grain size to within the micron regime. In this work, an alternativemethod involving boride nanoparticle addition to obtain a selected solidification processed ultrahighstrength (tensile yield strength > 400 MPa) Mg-RE alloy is discussed. Here, LPSO phaserather than fine intermetallic formation while retaining grain size under the micron regime ishighlighted.

Mechanical Properties and Microstructure of Mg-Zn-Y Alloys Processed by ECAE

2006 ◽  
Vol 503-504 ◽  
pp. 769-774 ◽  
Author(s):  
Shintaro Yoshimoto ◽  
Yuichi Miyahara ◽  
Z. Horita ◽  
Yoshihito Kawamura
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Yield Strength ◽  
High Strength ◽  
Mg Alloys ◽  
Tensile Yield Strength ◽  
Ordered Structure ◽  
Lpso Phase ◽  
Microstructure Refinement

Development of high strength I/M Mg alloys has been tried by ECAE processing. The mechanical properties and microstructure of ECAE-processed Mg97Zn1Y2 alloy with LPSO (long-periodic stacking ordered) structure were investigated. The tensile yield strength and elongation of as-cast Mg97Zn1Y2 were improved substantially by ECAE process. ECAE-processed with yield strength of 290 MPa and elongation of 22 % was obtained. The microstructure of ECAE-processed Mg97Zn1Y2 alloy consisted of refined α-Mg with the grain size around 6.5 μm and finely dispersed LPSO phase. Furthermore, the some texture was formed by ECAE process. The improved mechanical properties seem to be originated by the microstructure refinement and texture.

Novel hexagonal structure and ultrahigh strength of magnesium solid solution in the Mg–Zn–Y system

2001 ◽  
Vol 16 (7) ◽  
pp. 1894-1900 ◽  
Author(s):  
Akihisa Inoue ◽  
Yoshihito Kawamura ◽  
Mitsuhide Matsushita ◽  
Kentaro Hayashi ◽  
Junichi Koike
Keyword(s):  
Solid Solution ◽  
Yield Strength ◽  
High Strain ◽  
High Strength ◽  
Hexagonal Structure ◽  
Tensile Yield Strength ◽  
Specific Yield ◽  
The Novel ◽  
Fine Grain ◽  
Novel Structure

A magnesium (Mg) solid solution with a long periodic hexagonal structure was found in a Mg97Zn1Y2 (at.%) alloy in a bulk form prepared by warm extrusion of atomized powders at 573 K. The novel structure has an ABACAB-type six layered packing with lattice parameters of a = 0.322 nm and c = 3 × 0.521 nm. The Mg solid solution has fine grain sizes of 100 to 150 nm and contains 0.78 at.% Zn and 1.82 at.% Y. In addition, cubic Mg24Y5 particles with a size of about 7 nm are dispersed at small volume fractions of less than 10% in the Mg matrix. The specific density (ρ) of the extruded bulk Mg–Zn–Y alloy was 1.84 Mg/m3. The tensile yield strength (σy) and elongation (δ) are 610 MPa and 5%, respectively, at room temperature, and the specific yield strength defined by the ratio of σy to ρ is as high as 3.3 × 105 Nm/kg. High σy values exceeding 400 MPa are also maintained at temperatures up to 473 K. It is noticed that the σy levels are 2.5 to 5 times higher than those for conventional high-strength type Mg-based alloys. The Mg-based alloy also exhibits a high-strain-rate superplasticity with large δ of 700 to 800% at high strain rates of 0.1 to 0.2 s−1 and 623 K. The excellent mechanical properties are due to the combination of the fine grain size, new long periodic hexagonal solid solution containing Y and Zn, and dispersion of fine Mg24Y5 particles. The new Mg-based alloy is expected to be used in many fields.

BETHLEHEM LUKENS PLATE SPARTAN

Alloy Digest ◽  
2003 ◽  
Vol 52 (8) ◽  
Keyword(s):  
Fracture Toughness ◽  
Yield Strength ◽  
Tensile Properties ◽  
High Strength Steels ◽  
High Strength ◽  
Tensile Yield Strength ◽  
Precipitation Reactions

Abstract Bethlehem Lukens Plate (BLP) offers five grades of Spartan high-strength steels with tensile yield strength over 690 MPa (100 ksi). These alloys contain copper for precipitation reactions. They also have improved weldability and toughness compared to ASTM A 514 and A 543 grades. This datasheet provides information on composition, microstructure, hardness, and tensile properties as well as fracture toughness. It also includes information on forming and joining. Filing Code: SA-518. Producer or source: Bethlehem Lukens Plate.

scholarly journals A Study on the Damping Capacities of Mg–Zn–Y-Based Alloys with Lamellar Long Period Stacking Ordered Phases by Preparation Process

Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 79
Author(s):  
Ruopeng Lu ◽  
Kai Jiao ◽  
Yuhong Zhao ◽  
Kun Li ◽  
Keyu Yao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Solid Solution ◽  
Damping Capacity ◽  
Second Phase ◽  
Preparation Process ◽  
Obvious Effect ◽  
Lpso Phase ◽  
Long Period ◽  
Lamellar Phases ◽  
Ordered Phases

Mg alloys with fine mechanical properties and high damping capacities are essential in engineering applications. In this work, Mg–Zn–Y based alloys with lamellar long period stacking ordered (LPSO) phases were obtained by different processes. The results show that a more lamellar second phase can be obtained in the samples with more solid solution atoms. The density of the lamellar LPSO phase has an obvious effect on the damping of the magnesium alloy. The compact LPSO phase is not conducive to dislocation damping, but sparse lamellar phases can improve the damping capacity without significantly reducing the mechanical properties. The Mg95.3Zn2Y2.7 alloy with lamellar LPSO phases and ~100 μm grain size exhibited a fine damping property of 0.110 at ε = 10–3.

scholarly journals Effect of Rare Earth Ce on Deep Stamping Properties of High-Strength Interstitial-Free Steel Containing Phosphorus

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1473
Author(s):  
Hao Wang ◽  
Yanping Bao ◽  
Chengyi Duan ◽  
Lu Lu ◽  
Yan Liu ◽  
...  
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Rare Earth ◽  
High Strength ◽  
Rolling Process ◽  
P Element ◽  
Second Phase ◽  
Strengthening Effect ◽  
Interstitial Free ◽  
If Steel

The influence of rare earth Ce on the deep stamping property of high-strength interstitial-free (IF) steel containing phosphorus was analyzed. After adding 120 kg ferrocerium alloy (Ce content is 10%) in the steel, the inclusion statistics and the two-dimensional morphology of the samples in the direction of 1/4 thickness of slab and each rolling process were observed and compared by scanning electron microscope (SEM). After the samples in each rolling process were treated by acid leaching, the three-dimensional morphology and components of the second phase precipitates were observed by SEM and energy dispersive spectrometer (EDS). The microstructure of the sample was observed by optical microscope, and the grain size was compared. Meanwhile, the content and strength of the favorable texture were analyzed by X-ray diffraction (XRD). Finally, the mechanical properties of the product were analyzed. The results showed that: (1) The combination of rare earth Ce with activity O and S in steel had lower Gibbs free energy, and it was easy to generate CeAlO3, Ce2O2S, and Ce2O3. The inclusions size was obviously reduced, but the number of inclusions was increased after adding rare earth. The morphology of inclusions changed from chain and strip to spherical. The size of rare earth inclusions was mostly about 2–5 μm, distributed and dispersed, and their elastic modulus was close to that of steel matrix, which was conducive to improving the structure continuity of steel. (2) The rare earth compound had a high melting point. As a heterogeneous nucleation point, the nucleation rate was increased and the solidification structure was refined. The grade of grain size of products was increased by 1.5 grades, which is helpful to improve the strength and plasticity of metal. (3) Rare earth Ce can inhibit the segregation of P element at the grain boundary and the precipitation of Fe(Nb+Ti)P phase. It can effectively increase the solid solution amount of P element in steel, improve the solid solution strengthening effect of P element in high-strength IF steel, and obtain a large proportion of {111} favorable texture, which is conducive to improving the stamping formability index r90 value.

Effect of Long-Period Stacking Order Phase and α-Mg Phase on Strength and Ductility of Mg-Zn-Y Alloy

2012 ◽  
Vol 706-709 ◽  
pp. 1237-1242 ◽  
Author(s):  
Masafumi Noda ◽  
Yoshihito Kawamura
Keyword(s):  
Mechanical Properties ◽  
Yield Strength ◽  
High Temperatures ◽  
Mg Alloys ◽  
Tensile Yield Strength ◽  
Block Type ◽  
Lpso Phase ◽  
Long Period ◽  
Stacking Order ◽  
Type Phase

Mg alloys are lightweight structural alloys that normally have a good castability and machinability as well as an excellent specific strength and rigidity. However, the mechanical properties of Mg alloys are inferior to those of Al alloys, and their range of industrial applications is limited. Recently, Mg–Zn–Y alloy has been found to show a high tensile yield strength with a good elongation. The alloy has a long-period stacking order (LPSO) phase as the secondary phase in an α-Mg phase. In general, the tensile yield strengths of LPSO-type Mg alloy are known to be markedly enhanced by the formation of kink bands in the LPSO phase and by microstructural refinement of the α-Mg phase during plastic deformation. The separate roles of the LPSO phase and the α-Mg phase in relation to the mechanical properties of high-strength LPSO-type Mg alloy were investigated at ambient and high temperatures. For high strengths at ambient and high temperatures, it was important that the α-Mg phase consisted of a fine-grain region and a nonrecrystallized region, and that the LPSO phase remained as a block-type phase. On the other hands, it was necessary to change the LPSO phase from a block-type phase into a plate-type phase by heat treatment before tensile testing to improve the ductility of the alloy while maintaining its tensile yield strength. Microstructural control of the LPSO phase and the α-Mg phase is necessary to obtained Mg–Zn–Y alloy with superior mechanical properties at ambient-to-high temperatures.

Paradox of Strength and Ductility in Metals Processed Bysevere Plastic Deformation

2002 ◽  
Vol 17 (1) ◽  
pp. 5-8 ◽  
Author(s):  
R. Z. Valiev ◽  
I. V. Alexandrov ◽  
Y. T. Zhu ◽  
T. C. Lowe
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Grain Size ◽  
Yield Strength ◽  
Mechanical Behavior ◽  
High Strength ◽  
High Ductility ◽  
Elongation To Failure ◽  
Failure Ductility ◽  
Strength And Ductility

It is well known that plastic deformation induced by conventional forming methodssuch as rolling, drawing or extrusion can significantly increase the strength of metalsHowever, this increase is usually accompanied by a loss of ductility. For example, Fig.1 shows that with increasing plastic deformation, the yield strength of Cu and Almonotonically increases while their elongation to failure (ductility) decreases. Thesame trend is also true for other metals and alloys. Here we report an extraordinarycombination of high strength and high ductility produced in metals subject to severeplastic deformation (SPD). We believe that this unusual mechanical behavior is causedby the unique nanostructures generated by SPD processing. The combination ofultrafine grain size and high-density dislocations appears to enable deformation by newmechanisms. This work demonstrates the possibility of tailoring the microstructures ofmetals and alloys by SPD to obtain both high strength and high ductility. Materialswith such desirable mechanical properties are very attractive for advanced structuralapplications.

scholarly journals Effect of enhanced weld cooling on the mechanical properties of a structural steel with a yield strength of 700 MPa

2020 ◽  
Vol 2 (11) ◽  
Author(s):  
Juhani Laitila ◽  
Lassi Keränen ◽  
Jari Larkiola
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Fatigue Strength ◽  
Impact Toughness ◽  
Yield Strength ◽  
Uniform Elongation ◽  
High Strength ◽  
Low Alloy Steel ◽  
External Cooling ◽  
Welding Processes

AbstractIn this study, we present the effect of enhanced cooling on the mechanical properties of a high-strength low-alloy steel (having a yield strength of 700 MPa) following a single-pass weld process. The properties evaluated in this study include uniform elongation, impact toughness, yield, tensile and fatigue strengths alongside the cooling time of the weld. With the steel used in this study, the enhanced cooling resulted in a weld joint characterized with excellent cross-weld uniform elongation, yield and fatigue strength. The intensified cooling reduced the time it takes for the weld to reach 100 °C by around 190 s. Not only the fusion line of the weld was less pronounced, but also the grain size of the CGHAZ was greatly refined as a result of the enhanced cooling. The results indicate that combining external cooling to the welding processes can be beneficial for the studied high-strength steel.

scholarly journals Microstructure and Enhanced Properties of Copper-Vanadium Nanocomposites Obtained by Powder Metallurgy

Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 339 ◽  
Author(s):  
Yong Wang ◽  
Jinguo Wang ◽  
Haohao Zou ◽  
Yutong Wang ◽  
Xu Ran
Keyword(s):  
Electrical Conductivity ◽  
Grain Size ◽  
Yield Strength ◽  
Grain Boundary ◽  
High Strength ◽  
Strengthening Mechanism ◽  
Copper Matrix ◽  
Dispersion Strengthening ◽  
Annealed Copper ◽  
Grain Boundary Strengthening

Cu-2.4 wt.%V nanocomposite has been prepared by mechanical alloy and vacuum hot-pressed sintering technology. The composites were sintered at 800 °C, 850 °C, 900 °C, and 950 °C respectively. The microstructure and properties of composites were investigated. The results show that the Cu-2.4 wt.%V composite presents high strength and high electrical conductivity. The composite sintered at 900 °C has a microhardness of 205 HV, a yield strength of 404.41 MPa, and an electrical conductivity of 79.5% International Annealed Copper Standard (IACS); the microhardness and yield strength reduce gradually with the increasing consolidation temperature, which is mainly due to the growth of copper grain size. After sintering, copper grain size and V nanoparticle both maintain in nanoscale; the strengthening mechanism is related to grain boundary strengthening and dispersion strengthening, while the grain boundary strengthening mechanism plays the most important role. This study indicates that the addition of small amounts of V element could enhance the copper matrix markedly with the little sacrifice of electrical conductivity.

The Study on the Low Yield Strength for Super Fine Grain and High Strength Bearing Nb if Steel

2011 ◽  
Vol 335-336 ◽  
pp. 615-618
Author(s):  
Hong Mei Zhang ◽  
Li Feng Qiao
Keyword(s):  
Solid Solution ◽  
Yield Strength ◽  
Grain Boundary ◽  
High Strength ◽  
If Steel ◽  
Rolled Steel ◽  
Steel Sheets ◽  
Fine Grain ◽  
Cold Rolled ◽  
R Value

The cold rolling and simulative continuous annealing experiments after rolling were carried out in the laboratory on the base of super fine grain (SFG) steel sheet. The microstructure and the second-phase particles precipitated behavior were analyzed by the technology of OM, TEM and EDX. It is found that the fined Nb(C, N) can be formed by adding micro-alloy element Nb. It is noted that the yield strength is low as well as the tensile strength is high by the PFZ which is free of precipitate called precipitated free zone on the one side of the grain boundary. Contrast to the conventional IF steel, the super fine grain steel has super fine grains and gives excellent press-formability such as low yield strength, high r-value（the plastic strain ratio）. High strength cold-rolled steel sheets (HSS) with high formability have been developed in the last decade, in which the major strengthening method was solid-solution hardening with silicon, manganese and phosphorous [1-3]. When the IF steel is strengthened with the high amount of solid-solution elements, it becomes susceptible to the secondary work embrittlement because of the lack of grain boundary strength [4-6]. In this paper, High strength cold-rolled steel sheets (HSS) with high formability have been developed for the IF steel-bases. The grain refinement and precipitation hardening are achieved by means of the fine distribution of carbide under the appropriate combination of the relatively higher carbon content near 0.0070 mass% with niobium. As the result, this type of IF-HSS has been successfully developed to reach a higher r-value as compared with the conventional IF-HSS.

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