Utility of Air-Entraining Additive in the Development of Lightweight Alumina-Based Refractories

2020 ◽  
Vol 975 ◽  
pp. 147-152
Author(s):  
Marcel Jogl ◽  
Pavel Reiterman

The paper presents the impact of doses of an air-entraining additive on the mechanical properties of a composite based on aluminous cement. The presented data have been selected from the authors’ most recent research, which supports an economic development of a lightweight composite with the ability to withstand elevated temperatures of up to 1000 °C. The interest in the behaviour of concrete at high temperatures mainly results from the many cases of fires taking place in buildings, high-rises, tunnels, and drilling platform structures. Operation at high temperatures is also of fundamental importance to many major sectors of industry, including material production and processing, chemical engineering, power generation and more. Concrete has a great intrinsic behaviour when exposed to fire, especially when compared to other building materials. However, its fire resistance should not be taken for granted and proper structural fire protection is certainly necessary, e.g. in the form of high-temperature barriers. For the purposes of this experiment, the specimens were composed of cement paste and an air-entraining additive dosage between 2 – 10 % by weight of the cement dose. The properties of investigated specimens, dried at a temperature of 105 °C, were compared with each other. Values of compressive strength, flexural strength, and bulk density are measured in this work. The purpose was to evaluate the effects of the air-entraining agent on the workability of a fresh mixture, its bulk density, and mechanical properties after drying. In the case of a mixture with added short basalt fibres, the effects after high thermal loading were also evaluated. The proposed composites with air-entraining additive over 8 % shown the values of bulk density below 1800 kg/m3, along with the satisfactory strength results.

2014 ◽  
Vol 982 ◽  
pp. 125-129 ◽  
Author(s):  
Marcel Jogl ◽  
Pavel Reiterman ◽  
Ondřej Holčapek ◽  
Jaroslava Koťátková

This paper summarizes the results of an experimental program aimed at investigating of the mechanical properties of composites based on aluminous cement for high-temperature applications and deal with the influence of high-thermal loading on polycarboxylate superplasticizing (PCSP) additive contained in the composite. The intent of this examination was caused by the suspicion that the action of high-temperatures can lead to burnout of the PCSP additive and thus subsequently affecting the mechanical properties of the final composite. Silica composites based on Portland cement and silica aggregates are not able to resist the effects of high-temperatures [1]. For high-temperature composites was therefore used aluminous cement Secar®71 (Lafarge S.A.) in combination with crushed basalt aggregates of fraction 0/4 and 2/5 mm. The flexural strength was greatly improved thanks combinations of basalt fibers with lengths of 6.35 mm and 12.7 mm. The values ​​of flexural strength and compression strength were investigated on samples dried at temperature 105 °C or loaded for 180 minutes with high-temperature of 600 °C or 1 000 °C.


2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Pavel Reiterman ◽  
Ondřej Holčapek ◽  
Marcel Jogl ◽  
Petr Konvalinka

Present paper deals with the experimental study of the composition of refractory fiber-reinforced aluminous cement based composites and its response to gradual thermal loading. Basalt fibers were applied in doses of 0.25, 0.5, 1.0, 2.0, and 4.0% in volume. Simultaneously, binder system based on the aluminous cement was modified by fine ground ceramic powder originated from the accurate ceramic blocks production. Ceramic powder was dosed as partial replacement of used cement of 5, 10, 15, 20, and 25%. Influence of composition changes was evaluated by the results of physical and mechanical testing; compressive strength, flexural strength, bulk density, and fracture energy were determined on the different levels of temperature loading. Increased dose of basalt fibers allows reaching expected higher values of fracture energy, but with respect to results of compressive and flexural strength determination as an optimal rate of basalt fibers dose was considered 0.25% in volume. Fine ground ceramic powder application led to extensive increase of residual mechanical parameters just up to replacement of 10%. Higher replacement of aluminous cement reduced final values of bulk density but kept mechanical properties on the level of mixtures without aluminous cement replacement.


Alloy Digest ◽  
1984 ◽  
Vol 33 (8) ◽  

Abstract EASTERN STAINLESS TYPE 310S has high resistance to corrosion and oxidation at high temperatures. It also has high strength at elevated temperatures. Thus it is especially suitable for service at high temperatures. It is very ductile and can be welded readily. Among the many applications for Type 310S, a few typical uses include annealing boxes, chemical plant equipment, fire box sheets, furnace linings, heat exchangers, oil-refining equipment, kiln linings and tube hangers. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-450. Producer or source: Eastern Stainless Steel Company.


Buildings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 82
Author(s):  
Salmabanu Luhar ◽  
Demetris Nicolaides ◽  
Ismail Luhar

Even though, an innovative inorganic family of geopolymer concretes are eye-catching potential building materials, it is quite essential to comprehend the fire and thermal resistance of these structural materials at a very high temperature and also when experiencing fire with a view to make certain not only the safety and security of lives and properties but also to establish them as more sustainable edifice materials for future. The experimental and field observations of degree of cracking, spalling and loss of strength within the geopolymer concretes subsequent to exposure at elevated temperature and incidences of occurrences of disastrous fires extend an indication of their resistance against such severely catastrophic conditions. The impact of heat and fire on mechanical attributes viz., mechanical-compressive strength, flexural behavior, elastic modulus; durability—thermal shrinkage; chemical stability; the impact of thermal creep on compressive strength; and microstructure properties—XRD, FTIR, NMR, SEM as well as physico-chemical modifications of geopolymer composites subsequent to their exposures at elevated temperatures is reviewed in depth. The present scientific state-of-the-art review manuscript aimed to assess the fire and thermal resistance of geopolymer concrete along with its thermo-chemistry at a towering temperature in order to introduce this novel, most modern, user and eco-benign construction materials as potentially promising, sustainable, durable, thermal and fire-resistant building materials promoting their optimal and apposite applications for construction and infrastructure industries.


2016 ◽  
Vol 56 (1) ◽  
pp. 27 ◽  
Author(s):  
Marcel Jogl ◽  
Pavel Reiterman ◽  
Ondřej Holčapek ◽  
Jaroslava Koťátková ◽  
Petr Konvalinka

The aim of our study was to develop a composite material for industrial use that is resistant to the effect of high temperatures. The binder system based on aluminous cement was modified by adding finely-ground ceramic powder and metakaolin to reduce costs and also to reduce adverse effects on the environment due to high energy consumption for cement production. Additives were applied as a partial aluminous cement replacement in doses of 10, 20 and 30% by weight. The composites were evaluated on the basis of their mechanical properties and their bulk density after gradual temperature loading. The influence of basalt fibers and modifications to the binder system were studied at the same time. Basalt fibers were applied in doses of 0.5% and 2.0% by volume. The results confirmed the potential of the mineral additives studied here for practical applications, taking into account the residual mechanical parameters after thermal loading. The addition of ceramic powder reduced the bulk density by 5% for each 10% of cement substitution, but the residual values were very similar. The bulk density and the compressive strength were reduced when basalt fibers were applied, and the flexural strength was significantly increased in proportion to the fiber dosages. Metakaolin seems to be a more suitable additive than the ceramic powder that was applied here, because there was a significant increase in the mechanical parameters and also in the residual values of all properties that were studied.


2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Qifang Xie ◽  
Lipeng Zhang ◽  
Shenghua Yin ◽  
Baozhuang Zhang ◽  
Yaopeng Wu

Fires are always known for seriously deteriorating concrete in structures, especially for those with certain carbonation due to long-time service. In this paper, 75 prism specimens were prepared and divided into four groups (three carbonated groups and one uncarbonated group). Specimens were tested under different temperatures (20, 300, 400, 500, 600, and 700°C), exposure times (3, 4, and 6 hours), and cooling methods (water and natural cooling). Surface characteristics, weight loss rate, and residual mechanical properties (strength, initial elastic modulus, peak, and ultimate compressive strains) of carbonated concrete specimens after elevated temperatures were investigated and compared with that of the uncarbonated ones. Results show that the weight loss rates of the carbonated concrete specimens are slightly lower than that of the uncarbonated ones and that the cracks are increased with raising of temperatures. Surface colors of carbonated concrete are significantly changed, but they are not sensitive to cooling methods. Surface cracks can be evidently observed on carbonated specimens when temperature reaches 400°C. Residual compressive strength and initial elastic modulus of carbonated concrete after natural cooling are generally larger than those cooled by water. The peak and ultimate compressive strains of both carbonated and uncarbonated concrete specimens increase after heating, but the values of the latter are greater than that of the former. Finally, the constitutive equation to predict the compressive behaviors of carbonated concrete after high temperatures was established and validated by tests.


2013 ◽  
Vol 486 ◽  
pp. 406-411 ◽  
Author(s):  
Ondřej Holčapek ◽  
Pavel Reiterman ◽  
Petr Konvalinka

The following article deals with the study of mechanical properties of aluminous cement composites exposure to high temperatures. The newly designed mixtures that resist the action of high temperatures 1000 °C find their application in various fields of industrial production or in the form of fire wall for protection bearing structures. All the mechanical properties such as compressive strength and tensile strength in bending were measured on samples 160x40x40 mm. These samples were exposed to temperatures 600 °C and 1000 °C and one group of samples was reference and stayed in laboratory condition. Aluminous cement unlike the common Portland cement keeps sufficient strength even after high temperature exposure. For ensuring required ductility the basalt fibers were added to the mixture. In an effort to use of secondary raw materials as a replacement for cement as well as a suitable binder was used metakaolin and ground brick dust. Very convenient characteristics of these components are their latent hydraulic potential that makes interesting hydration products.


2014 ◽  
Vol 33 (6) ◽  
pp. 585-591 ◽  
Author(s):  
Shi Liu ◽  
Jinyu Xu

AbstractConducting experimental studies on the impact compressive mechanical properties of rock under the high temperature environment is of both theoretical value and practical significance to understanding the relationship between the rock under the effect of impact loads and the high temperature environment. Based on the Φ100 mm SHPB and the self-developed Φ100 mm high-temperature SHPB test devices, the impact compressive tests on the sandstone, whether cooling after high temperatures or under real-time high temperatures are carried out. As the test results indicate that since the two high-temperature ways of loading are different from each other, the impact compressive properties of sandstone, after as well as under high temperatures, show different variations along with changes in temperature. Under the effect of the same impact loading rate, there exists a clear critical temperature range in the impact compressive mechanical properties of sandstone after high temperature, and, near the critical temperature, there occurs a significant mutation in the impact compressive mechanical properties. Under high temperatures, however, the impact compressive mechanical properties follow an overall continuity of change except that there are slight fluctuations at individual temperatures.


2018 ◽  
Vol 9 (3) ◽  
pp. 203-221 ◽  
Author(s):  
Muhammad Masood Rafi ◽  
Abdul Basit Dahar ◽  
Tariq Aziz

Purpose The purpose of this paper is to present the results of experimental testing of steel rebars at elevated temperatures. Three types of bars available in the local market in Pakistan were used. These data are not available in Pakistan. Design/methodology/approach Three types of bars were used, which included cold-twisted ribbed (CTR), hot-rolled deformed (HRD) and thermo-mechanically treated (TMT) bars. The diameter of the bar of each type was 16 mm. The bars were heated in an electrical furnace at temperatures which were varied from 100°C to 900°C in increment of 100°C. Bars of each type were also tested at ambient temperature as control specimens. The change of strength, strain and modulus of elasticity of the bars at high temperatures were determined. Findings The mechanical properties of the bars were nearly unaffected by the temperatures up to 200°C. CTR bars did not show yield plateau and strain hardening both at ambient and high temperatures. The high temperature yield strength and elastic modulus for all the three types of bars were similar at all temperatures. The yield plateau of both the HRD and TMT bars disappeared at temperatures greater than 300°C. The ultimate strength at high temperature of the HRD and TMT bars was also similar. The behaviours of the HRD and TMT bars changed to brittle beyond 400°C as compared to their behaviours at ambient temperature. The CTR bars exhibited ductile characteristics at failure at all the exposure temperatures relative to their behaviour at ambient temperature. Research limitations/implications The parameters of the paper included the rebar type and heating temperature and the effects of temperature on strength and stiffness properties of the steel bars. Practical implications Building fire incidents have increased in Pakistan. As reinforced concrete (RC) buildings exist in the country in significant numbers, the data related to elevated temperature properties of steel is required. These data are not available in Pakistan presently. The presented paper aims at providing this information for the design engineers to enable them to assess and increase fire resistance of RC structural members. Originality/value The presented paper is unique in its nature in that there is no published contribution to date, to the best of authors’ knowledge, which has been carried out to assess the temperature-dependent mechanical properties of steel reinforcing bars available in Pakistan.


Recycling of materials has become a major interest for engineers. At present, the amount of slag deposited in storage yard adds up to millions of tons/year leading to the occupation of farm land and serious pollution to the environment, as a result of the rapid growth in the steel industry. Steel slag is made at 1500- 1650°C having a honey comp shape with high porosity. Using steel slag as the natural aggregate with a lower waste material cost can be considered as a good alternative for sustainable constructions. The objective of this study is to evaluate the performance of residual mechanical properties of concrete with steel slag as coarse aggregate partial replacement after exposing to high temperatures .This study investigates the behavior of using granulated slag as partial or fully coarse aggregate replacement with different percentages of 0%, 15%, 30%, 50% and 100% in concrete when subjected to elevated temperatures. Six groups of concrete mixes were prepared using various replacement percentages of slag exposed to different temperatures of 400 °C, 600 °C and 800 °C for different durations of 1hr, 1.5hr and 2hr. Evaluation tests were compressive strength, tensile strength, and bond strength. The steel slag concrete mixes showed week workability lower than control mix. A systematic increasing of almost up to 21.7% in compressive strength, and 66.2% in tensile strength with increasing the percentage of steel slag replacement to 50%. And the results showed improvement on concrete residual mechanical properties after subjected to elevated temperatures with the increase of steel slag content. The findings of this study give an overview of the effect of steel slag coarse aggregate replacement on concrete after exposed to high temperatures.


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