Corrosion of Co in BEOL interconnects in dilute HF solution

2018 ◽  
Vol 282 ◽  
pp. 256-262
Author(s):  
Yuya Akanishi ◽  
Els Kesters ◽  
Quoc Toan Le ◽  
Frank Holsteyns

The impact of dissolved oxygen (O2) on cobalt (Co) corrosion in dilute HF (dHF) solution was studied. It was confirmed that Co etch rate was enhanced as the amount of dissolved O2 in the HF solution increased. The Co etch rate was also found to increase radially outward when performed on a single-wafer spin process in atmospheric air due to the uptake of O2 during the dispense process. The galvanic corrosion of Co was investigated with two types of structures with a Co/Cu interface in different dissolved O2 concentrations, i.e. (1) Co bump structures on Cu and (2) Cu lines with a Co/TaN liner/barrier structure. By controlling both the dissolved and the atmospheric O2 levels, galvanic corrosion prevention at the Co/Cu interface was achieved.

1992 ◽  
Vol 26 (9-11) ◽  
pp. 2357-2360
Author(s):  
J. Zagorc-Koncan ◽  
M. Dular

A laboratory river model for the study of self-purification inhibition in a stream containing toxic substances is presented. It enables an engineering - technological prediction of the impact of toxic substances or wastewaters on dissolved oxygen (DO) profile in an organically polluted river downstream from the point of entry of toxic effluent thus providing rapidly and inexpensively significant design information to an environmental scientist or engineer. The method was applied to the toxicity evaluation of wastewaters from electroplating industry. The effects of copper, cyanide (representing two significant constituents of this type of wastewaters) and wastewater from electroplating industry on the biodegradation of organic municipal pollution in receiving stream were evaluated experimentally.


1998 ◽  
Vol 38 (10) ◽  
pp. 23-30
Author(s):  
Sarah Jubb ◽  
Philip Hulme ◽  
Ian Guymer ◽  
John Martin

This paper describes a preliminary investigation that identified factors important in the prediction of river water quality, especially regarding dissolved oxygen (DO) concentration. Intermittent discharges from combined sewer overflows (CSOs) within the sewerage, and overflows at water reclamation works (WRW) cause dynamic conditions with respect to both river hydraulics and water quality. The impact of such discharges has been investigated under both wet and dry weather flow conditions. Data collected from the River Maun, UK, has shown that an immediate, transient oxygen demand exists downstream of an outfall during storm conditions. The presence of a delayed oxygen demand has also been identified. With regard to modelling, initial investigations used a simplified channel and the Streeter-Phelps (1925) dissolved oxygen sag curve equation. Later, a model taking into account hydrodynamic, transport and dispersion processes was used. This suggested that processes other than water phase degradation of organic matter significantly affect the dissolved oxygen concentration downstream of the location of an intermittent discharge. It is proposed that the dynamic rate of reaeration and the sediment oxygen demand should be the focus of further investigation.


2021 ◽  
Vol 13 (9) ◽  
pp. 1683
Author(s):  
Nandini Menon ◽  
Grinson George ◽  
Rajamohananpillai Ranith ◽  
Velakandy Sajin ◽  
Shreya Murali ◽  
...  

Turbidity and water colour are two easily measurable properties used to monitor pollution. Here, we highlight the utility of a low-cost device—3D printed, hand-held Mini Secchi disk (3DMSD) with Forel-Ule (FU) colour scale sticker on its outer casing—in combination with a mobile phone application (‘TurbAqua’) that was provided to laymen for assessing the water quality of a shallow lake region after demolition of four high-rise buildings on the shores of the lake. The demolition of the buildings in January 2020 on the banks of a tropical estuary—Vembanad Lake (a Ramsar site) in southern India—for violation of Indian Coastal Regulation Zone norms created public uproar, owing to the consequences of subsequent air and water pollution. Measurements of Secchi depth and water colour using the 3DMSD along with measurements of other important water quality variables such as temperature, salinity, pH, and dissolved oxygen (DO) using portable instruments were taken for a duration of five weeks after the demolition to assess the changes in water quality. Paired t-test analyses of variations in water quality variables between the second week of demolition and consecutive weeks up to the fifth week showed that there were significant increases in pH, dissolved oxygen, and Secchi depth over time, i.e., the impact of demolition waste on the Vembanad Lake water quality was found to be relatively short-lived, with water clarity, colour, and DO returning to levels typical of that period of year within 4–5 weeks. With increasing duration after demolition, there was a general decrease in the FU colour index to 17 at most stations, but it did not drop to 15 or below, i.e., towards green or blue colour indicating clearer waters, during the sampling period. There was no significant change in salinity from the second week to the fifth week after demolition, suggesting little influence of other factors (e.g., precipitation or changes in tidal currents) on the inferred impact of demolition waste. Comparison with pre-demolition conditions in the previous year (2019) showed that the relative changes in DO, Secchi depth, and pH were very high in 2020, clearly depicting the impact of demolition waste on the water quality of the lake. Match-ups of the turbidity of the water column immediately before and after the demolition using Sentinel 2 data were in good agreement with the in situ data collected. Our study highlights the power of citizen science tools in monitoring lakes and managing water resources and articulates how these activities provide support to Sustainable Development Goal (SDG) targets on Health (Goal 3), Water quality (Goal 6), and Life under the water (Goal 14).


Author(s):  
Ken FURUDOI ◽  
Shigeki SAKAI ◽  
Kazuo MURAKAMI ◽  
Yoshiyuki NAKAMURA ◽  
Ikuo ABE ◽  
...  

Water ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2408
Author(s):  
Steven C. Chapra ◽  
Luis A. Camacho ◽  
Graham B. McBride

For rivers and streams, the impact of rising water temperature on biochemical oxygen demand (BOD) assimilative capacity depends on the interplay of two independent factors: the waterbody’s dissolved oxygen (DO) saturation and its self-purification rate (i.e., the balance between BOD oxidation and reaeration). Although both processes increase with rising water temperatures, oxygen depletion due to BOD oxidation increases faster than reaeration. The net result is that rising temperatures will decrease the ability of the world’s natural waters to assimilate oxygen-demanding wastes beyond the damage due to reduced saturation alone. This effect should be worse for nitrogenous BOD than for carbonaceous BOD because of the former’s higher sensitivity to rising water temperatures. Focusing on streams and rivers, the classic Streeter–Phelps model was used to determine the magnitude of the maximum or “critical” DO deficit that can be calculated analytically as a function of the mixing-point BOD concentration, DO saturation, and the self-purification rate. The results indicate that high-velocity streams will be the most sensitive to rising temperatures. This is significant because such systems typically occur in mountainous regions where they are also subject to lower oxygen saturation due to decreased oxygen partial pressure. Further, they are dominated by salmonids and other cold-water fish that require higher oxygen levels than warm-water species. Due to their high reaeration rates, such systems typically exhibit high self-purification constants and consequently have higher assimilation capacities than slower moving lowland rivers. For slow-moving rivers, the total sustainable mixing-point concentration for CBOD is primarily dictated by saturation reductions. For faster flowing streams, the sensitivity of the total sustainable load is more equally dependent on temperature-induced reductions in both saturation and self-purification.


Author(s):  
Maikanov Balgabay ◽  
Auteleeva Laura

In this study, changes in air quality were quantified before and during the introduction of COVID-19 quarantine measures in the Shchuchinsk-Borovskaya resort area. During 2020, there were only 49 resolutions "On strengthening restrictive quarantine measures in the territory of the Akmola region"on the territory of the resort zone. The maximum permissible concentration of sulfur dioxide in the atmospheric air has been exceeded. We have revealed that in the entire territory of the resort area for 2018-2019. atmospheric air pollution, according to the standard index, was elevated and high (3.38 to 6.4), according to the highest frequency (16.6 to 100%), there was a very high degree of pollution, and in 2020, the indicators of the standard index and the highest frequency were within the norm.


We made hygienic assessment of the atmospheric air quality of the observation territory and comparison according to monitoring and field observations, carried out a comparative analysis of the respiratory system diseases morbidity of the child population according to the form of federal statistical observation and actual attendance for medical care for 2014–2017, evaluated the relationship of respiratory system diseases morbidity with the effects of the studied chemical factors. Atmospheric air poor quality for a number of substances has been established in the residential development of the observation territory. An increased morbidity rate of respiratory system diseases and certain nosological forms (chronic diseases of the tonsils and adenoids and bronchial asthma) in areas with stable atmospheric air pollution by emission components of large-scale alumina production has been established as a result of a comparative analysis of morbidity rates. We proved the dependence of the occurrence probability of additional cases of respiratory system diseases on the content in the atmospheric air of suspended solids, fine PM10, PM2.5 fractions, nitrogen dioxide, aluminum, manganese, solid and gaseous fluorides, chromium.


2021 ◽  
Author(s):  
Kaveh Purkiani ◽  
Maren Walter ◽  
Matthias Haeckel ◽  
Katja Schmidt ◽  
André Paul ◽  
...  

<p><span>During RV Sonne expedition SO268 to the northeast tropical Pacific Ocean between March and May 2019, the impact of a mesoscale eddy on the seawater properties was investigated by conducting a multiple of observations. A subsequent analysis of an altimeter data revealed the formation of an anticyclonic mesoscale eddy in the Tehuantepec gulf between 15 and 20 June 2018 with a mean radius of 185 km and an average speed of 13 cm/s. This extremely long-lived eddy carried sea-water characteristics from near coastal Mexican waters westward far into the open ocean. The water mass stayed largely isolated during the 11 months of travel time due to high rotational speed.</span></p><p><span>The eddy exhibited a conical-shape vertical structure with concurrent deepening of the main thermocline. The water in the eddy core showed an extreme positive temperature anomaly of 8</span><sup><span>◦</span></sup><span>C, a negative salinity anomaly of -0.5 psu and a positive dissolved oxygen concentration anomaly of +160 μmol/kg centered at 80 m depth. The sub-surface impact of the eddy is clearly evident in the temperature and salinity profiles at a depth of 1500 m. For dissolved oxygen the eddy-induced anomaly reached even deeper to the seafloor.</span></p><p><span>This study provides new insights to the offshore transport of heat and salt driven by the long-lived anticyclonic eddy in the northeast tropical Pacific Ocean. Considering the water column trapped within the eddy, a positive heat transport anomaly of 1-3 ×10</span><sup><span>11</span></sup><span> W and a negative salt transport anomaly of -8×10</span><sup><span>3</span></sup><span> kg/s were estimated. However, due to the rare occurrence of long-lived anticyclone eddies in this region, they likely do not play a significant role in affecting the heat and salt balance of the northeastern tropical Pacific Ocean. </span></p>


2017 ◽  
Vol 2017 (1) ◽  
pp. 000046-000051 ◽  
Author(s):  
Joshua S. Petko ◽  
Philip A. Lovell ◽  
Jeremy D. Clifton ◽  
Paul H. Cohen ◽  
Karl F. Schoch

Abstract Conversion coatings are used to inhibit corrosion on aluminum structures while maintaining electrical conductivity. The most common type of conversion coatings in aerospace applications (MIL-DTL-5541 Type I), contain hexavalent chromium compounds as the corrosion-inhibiting additive. These Type I conversion coatings have a long pedigree and are highly effective in preventing corrosion; however, the hexavalent chromium compounds in these coatings are carcinogenic and water-soluble. Therefore, the use of these compounds is highly regulated in order to protect both workers and the public leading to high cost in both use and disposal. In addition to these regulations, use of these materials on new designs for DOD is prohibited by DFARS 48 CFR Parts 223 and 252, and is scheduled to be prohibited in Europe in September 2017 by REACH regulations. In response, new more environmentally friendly non-hexavalent chromium-based processes are becoming available. Coatings resulting from these types of processes are referred to as MIL-DTL-5541 Type II conversion coatings. The long term reliability and performance impacts resulting from the use of these coatings are not fully understood and there currently is an effort in the U. S. aerospace industry organized by NASA to fully define these impacts while hardware is still in the design stage. While significant work has been performed to define the corrosion performance of various Type II conversion coatings, there has been minimal work performed to quantify the impact a Type II conversion coating would have on RF electrical assemblies where plated printed wiring boards (PWBs) and aluminum structures come in intimate contact. The primary concern for these assemblies is that these junctions are inherently susceptible to galvanic corrosion; PWBs are clad with copper, which is highly cathodic while aluminum is highly anodic. In order to reduce the potential for galvanic corrosion, PWBs in DOD applications are typically plated with SnPb coating which is less cathodic than the copper. In addition, an immersion bath is used to coat the aluminum with a conversion coating that is less anodic. Changes to the conversion coating could increase the galvanic corrosion occurring at this junction. In addition, RF signals may also be negatively impacted by changes to the electrical resistivity and parasitic capacitances caused by changes to this junction. For this reason, it is highly desirable to create a RF test article that is highly sensitive to the impacts of galvanic corrosion at the junctions of passivated aluminum and plated printed wiring boards. This talk discusses a RF test article that is designed to assess the longitudinal impact of galvanic corrosion on electrical assemblies. The test article features a specialized suspended stripline/microstrip stepped impedance filter that is designed to de-tune in the presence of galvanic corrosion. The design of this filter uses a pair of machined aluminum housings to sandwich a thin two sided printed wiring board. The high-impedance sections of the filter employ cavities above and below the thin PWB to create an effective airstripline transmission line. The low-impedance sections of the filter employ a PWB ground plane to create a microstrip mode. Small aluminum feet are machined in the bottom aluminum housing to create an electrical contact between the aluminum housing and PWB ground plane. These feet are designed to function as sacrificial elements that corrode away in the presence of galvanic corrosion, creating series capacitance in the ground signal path. This talk reviews recent test results that show how the response of this specially designed filter changes in the presence of galvanic corrosion and compares these results with electrical simulations. This talk also discusses how information gained from the filter response can be used to assess the electrical impact of Type II conversion coatings. Finally, this talk will discuss the experimental design needed to quantify the impact of Type II conversion coatings with respect to the current baseline processes.


2020 ◽  
Vol 117 (10) ◽  
pp. 3018-3028 ◽  
Author(s):  
Arman Amini ◽  
Vincent Wiegmann ◽  
Hamza Patel ◽  
Farlan Veraitch ◽  
Frank Baganz

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