Hydrothermal Alteration in the Frankenstein Gabbro Martian Analogue

2020 ◽  
Author(s):  
Robert G. W. Seidel ◽  
John C. Bridges ◽  
Thomas Kirnbauer ◽  
Sarah C. Sherlock ◽  
Susanne P. Schwenzer
Keyword(s):  
Hydrothermal Alteration ◽  
Redox State ◽  
Small Scale ◽  
Secondary Mineral ◽  
Reaction Paths ◽  
Mineral Reaction ◽  
Fluid Properties ◽  
Propylitic Alteration ◽  
Mineral Replacement ◽  
Host Rocks

<p>We present results of an ongoing petrologic and modelling study of a new Martian analogue rock: The Frankenstein Gabbro (Odenwald, Germany). Our aim is to predict mineral reaction paths and fluid properties during hydrothermal alteration of basaltic host rocks on Mars – thought to be a common by-product of impact cratering – in order to assess the habitability of the fluids for the potential of Martian life, and establish a link between habitable fluid conditions and secondary mineral assemblages.</p><p>Primary minerals of the analogue are mostly plagioclase (~70 vol.%) and clinopyroxene (~20 vol.%) with lesser percentages of amphiboles and Fe-oxides. We focus on a chloritic-propylitic alteration event associated with hairline fault planes and mineral veinlets. The secondary mineralisation shows strong small-scale variability, depending on host mineral and type of fluid pathway: For plagioclase hosts, fault planes are dominated by chlorite with additional epidote and prehnite, while mineral veinlets consist of albite ± calcite ± chlorite ± epidote ± K-feldspar ± mica. For clinopyroxene hosts, fault planes consist of actinolite with additional chlorite or vermiculite, while mineral veinlets consist of prehnite and vermiculite.</p><p>We use the software CHIM-XPT to model mineral reaction paths, with published XRF bulk rock data, EMP analyses of single minerals, and a starting fluid enriched in Na, K, Mg and Si for input, the latter based on calculated element budgets of mineral replacement reactions. Our models reproduce secondary assemblages related to plagioclase-hosted fault planes (chlorite–epidote–prehnite) and veinlets (albite–chlorite–epidote–K-feldspar–mica), as well as alteration rims around clinopyroxene related to fault planes (actinolite–chlorite). Corresponding fluid conditions are ~200–250 °C, pH ~6.5–8.0, at water/rock ratios >3000, in agreement with pre-model constraints by mineralogy. The breakdown of clinopyroxene and plagioclase releases large amounts of Ca, with calcite inferred to be a late-stage product of cooling. Fluid redox state is shown to be largely controlled by host minerals, and in turn exerts strong influence on secondary mineral formation: clinopyroxene releases Fe<sup>2+</sup> during alteration, which is taken up by chlorite; in contrast, plagioclase contains up to 0.5 wt.% Fe<sup>3+</sup> substituting for Al, which is taken up by epidote. Prehnite, of the same elemental composition except for Fe, is inversely correlated with epidote. Thus, the relative percentages of chlorite, epidote and prehnite can serve as indicators of redox state in similar types of rock.</p><p>Our models match key petrological observations and provide information about the alteration process beyond what may be directly observed. They illustrate the need to account for small-scale variability, and to adjust models on a case-by-case basis. This has important implications for models of Martian habitability, where similar features may be expected. Next, we will apply these reaction pathways to Martian rocks (shergottitic basalts), focusing especially on small-scale distribution of dissolved iron species, a suggested energy source for hypothetical microbial Martian life.</p>

scholarly journals Mineralogical and Fluid Inclusions Study of Epithermal Type Veins Intruding the Volcanic Rocks of the Kornofolia Area, Evros, NE Greece.

2019 ◽  
Vol 55 (1) ◽  
pp. 202
Author(s):  
Foteini Aravani ◽  
Lambrini Papadopoulou ◽  
Vasileios Melfos ◽  
Triantafillos Soldatos ◽  
Triantafillia Zorba ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Fluid Inclusion ◽  
Hydrothermal Alteration ◽  
Fluid Inclusions ◽  
Volcanic Rocks ◽  
The Other ◽  
Calc Alkaline ◽  
Ft Ir ◽  
Host Rocks

The volcanic rocks of Kornofolia area, Evros, host a number of epithermal-type veins. The host rocks are Oligocene calc-alkaline andesites to rhyo-dacites. The andesites form hydrothermal breccias and show hydrothermal alteration. The veins comprise mainly silica polymorphs such as quartz, chalcedony and three types of opal (milky white, transparent and green). Amethyst also forms in veins at the same area. Apart from the silica polymorphs, the veins are accompanied by calcite and zeolites. The main aim of this study is the characterization of the silica polymorphs. Using FT-IR analyses, variations in the crystal structure of the three opals were recognized. The green opal is found to be more amorphous than the other two types. Fluid-inclusion measurements were performed in calcite and were compared with amethyst from previous studies. The Th is between 121-175 °C and the Te between -22.9 and -22.4 °C. The salinities range from 0.9 to 4.5 wt % NaCl equiv.

Mg-K-Fe fluid producing mineral reactions, metasomatism and microfabric development during formation of nodular sillimanite-gneiss in the middle crust

2021 ◽  
Author(s):  
Ane K. Engvik ◽  
Claudia A. Trepmann ◽  
Håkon Austrheim
Keyword(s):  
Stress Condition ◽  
White Mica ◽  
Ore Deposits ◽  
Preferred Orientation ◽  
Reaction Products ◽  
Subsequent Reaction ◽  
Crystallographic Preferred Orientation ◽  
Mineral Reaction ◽  
Metasomatic Fluid ◽  
Mineral Replacement

<p>The Proterozoic gneisses of the Bamble lithotectonic domain (south Norway) underwent intense scapolitisation caused by K- and Mg-rich fluids and extensive albitisation with formation of numerous ore deposits.</p><p>By detailed studies of mineral reaction fabrics we document release of the chemical active Mg, K and Fe-components forming the metasomatic fluid: Breakdown of biotite to muscovite releases K, Mg, Fe, Si and H<sub>2</sub>O. As reaction products tiny Fe-oxide needles are present in the transforming rock. H<sub>2</sub>O is reacting with K-feldspar to produce additional amounts of white mica and quartz. During a subsequent reaction muscovite is replaced to sillimanite again releasing quartz and a K-rich fluid. The reactions form the peculiar sillimanite-nodular quartzite, but also well-foliated sillimanite-mica gneiss.</p><p>Optical and EBSD microfabric studies reveal a shape preferred orientation for quartz, but despite of a pronounced foliation, quartz does not show a crystallographic preferred orientation. A crystallographic preferred orientation is present for mica and sillimanite. Coarse micas show sutured boundaries to quartz, implying low nucleation rates, no crystallographic or surface-energy control during growth and no obvious crystallographic relationship to quartz.</p><p>Our study illustrates the transformation of a quartzofeldspatic lithology into sillimanite-bearing quartzite. The mineral replacement and deformation show ongoing metamorphic reactions during deformation. The microfabric data indicates reaction at non-isostatic stress condition. The deduced mineral replacement reactions document a source of K-, Mg- and Fe-rich metasomatic fluids necessary to cause the pervasive scapolitisation and Fe-deposition in the area. The mineral reactions and deformation produce rocks with a new mineralogy and structure; an increased understanding of these processes is important for the modelling of crustal building and geological history.</p>

Auriferous chert, banded iron formation, and related volcanogenic hydrothermal alteration, Atik Lake, Manitoba

1989 ◽  
Vol 26 (12) ◽  
pp. 2676-2690 ◽  
Author(s):  
Louis R. Bernier ◽  
Wallace H. MacLean
Keyword(s):  
Hydrothermal Alteration ◽  
Earth Element ◽  
Massive Sulfide ◽  
Iron Formation ◽  
Small Scale ◽  
Banded Iron Formation ◽  
Sulfide Deposits ◽  
Sea Floor ◽  
Facies Metamorphism ◽  
Altered Basalt

Small-scale alteration pipes and stratiform alteration in Archean glomeroporphyritic tholeiitic basalts at Atik Lake, Manitoba, stratigraphically underlie silicate-oxide banded iron formation (BIF) and auriferous sulfide-bearing chert. The auriferous chert is locally interbedded with graphitic argillite, indicating euxinic conditions during deposition. Cordierite–gedrite rocks formed by recrystallization of alteration assemblages during the lower amphibolite-facies metamorphism (T = 550 °C, P = 2.5 kbar). Al2O3, TiO2, Zr, and Nb, which were relatively immobile during alteration, have been used to monitor igneous differentiation and alteration. Volcanogenic hydrothermal alteration resulted in depletion of Ca, Si, Mg, Na, and Sr in the altered basalt and the addition of K, Fe, Rb, and Ba. This was accompanied by mass and volume losses of up to 25%. The mineralizing fluid was reducing and somewhat acidic. Rare-earth-element (REE) profiles of BIF and graphitic argillite, normalized to Archean shale, are less steep ((La/Lu)N = 0.51 and 0.49 respectively), than those of both mineralized chert ((La/Lu)N = 0.04) and recent sea-floor, siliceous, gold-enriched massive sulfides ((La/Lu)N = 0.11). REE profiles and Boström's plot suggest that the auriferous, sulfide-bearing chert formed by mixing of hydrothermal and detrital components. The overall chemical changes in the Atik Lake alteration system are comparable to those in Noranda-type massive-sulfide deposits. The trace-metal association in the auriferous chert is similar to that at some modern sea-floor hydrothermal sites.

Alteration Mineralogy of the Zhengguang Epithermal Au-Zn Deposit, Northeast China: Interpretation of Shortwave Infrared Analyses During Mineral Exploration and Assessment

2020 ◽  
Author(s):  
Le Wang ◽  
Jeanne B. Percival ◽  
Jeffrey W. Hedenquist ◽  
Keiko Hattori ◽  
Kezhang Qin
Keyword(s):  
Northeast China ◽  
Mineral Exploration ◽  
White Mica ◽  
Absorption Feature ◽  
Hydrous Minerals ◽  
Propylitic Alteration ◽  
Identification Software ◽  
Shortwave Infrared ◽  
Host Rocks ◽  
Epithermal Au

Abstract Alteration mineralogy from shortwave infrared (SWIR) spectroscopy was compared with X-ray diffraction (XRD) analyses for samples from the Zhengguang intermediate sulfidation epithermal Au-Zn deposit, eastern Central Asian orogenic belt, northeast China. The SWIR and XRD analyses indicate that alteration minerals in the vein-adjacent halo mainly comprise quartz, illite, and locally pyrite (QIP) and chlorite, whereas samples from the pervasive propylitic alteration of host basaltic andesite lava contain epidote, chlorite, carbonate, montmorillonite, and locally illite. SWIR mineral identifications from automated mineral identification software may not always be accurate; thus, the results should be validated by the user. The wavelength position of the Al-OH (~2,200 nm; wAlOH) absorption feature can be used to approximate the composition of illite or white mica. However, caution is required when using the wAlOH value to assess paleotemperatures, as the composition of illite can be influenced by the composition of the host rocks or the hydrothermal fluid. In addition, values of the illite spectral maturity (ISM; ratio of the depth of the ~2,200 nm minima divided by the ~1,900 nm minima) can be affected by the presence of other hydrous minerals, quartz-sulfide veins, and absorption intensity (which can be a function of rock coloration). Despite these cautions, the spatial distribution and variation of the wAlOH and ISM values for illite suggest that the high paleotemperature hydrothermal upflow zones related to the Zhengguang Au-Zn deposit were located below ore zones I and IV, which are predicted to be proximal to the intrusive center of the system.

scholarly journals Geochemistry, Paragenesis, and Wall-Rock Alteration of the Qatruyeh Iron Deposits, Southwest of Iran: Implications for a Hydrothermal-Metasomatic Genetic Model

2014 ◽  
Vol 2014 ◽  
pp. 1-25 ◽  
Author(s):  
Sina Asadi ◽  
Mohammad Ali Rajabzadeh
Keyword(s):  
Genetic Model ◽  
Wall Rock ◽  
Hydrothermal Activity ◽  
Low Grade ◽  
Wall Rock Alteration ◽  
Propylitic Alteration ◽  
Iron Deposits ◽  
Geochemical Analyses ◽  
Southwest Of Iran ◽  
Host Rocks

The Qatruyeh iron deposits, located on the eastern border of the NW-SE trending Sanandaj-Sirjan metamorphic zone, southwest of Iran, are hosted by a late Proterozoic to early Paleozoic sequence dominated by metamorphosed carbonate rocks. The magnetite ores occurred as layered to massive bodies, with lesser amounts of disseminated magnetite and hematite-bearing veins. Textural evidences, along with geochemical analyses of the high field strengths (HFSEs), large ion lithophiles (LILEs), and rare earth elements (REEs), indicate that the main mineralization stage occurred as low-grade layered magnetite ores due to high-temperature hydrothermal fluids accompanied by Na-Ca alteration. Most of the main ore-stage minerals precipitated from an aqueous-carbonic fluid (3.5–15 wt.% NaCl equiv.) at temperatures ranging between 300° and 410°C during fluid mixing process, CO2 effervescence, cooling, and increasing of pH. Low-temperature hydrothermal activity subsequently produced hematite ores associated with propylitic alteration. The metacarbonate host rocks are LILE-depleted and HFSE-enriched due to metasomatic alteration.

scholarly journals Rhenium - rich molybdenites in Thracian porphyry Mo±Cu occurrences, NE - Greece

2001 ◽  
Vol 34 (3) ◽  
pp. 1015 ◽  
Author(s):  
Β. ΜΕΛΦΟΣ ◽  
Π. ΒΟΥΔΟΥΡΗΣ ◽  
Κ. ΑΡΙΚΑΣ ◽  
Μ. ΒΑΒΕΛΙΔΗΣ
Keyword(s):  
Chemical Composition ◽  
Hydrothermal Alteration ◽  
Fluid Inclusions ◽  
Mineral Chemistry ◽  
Rare Element ◽  
Alteration Zones ◽  
Porphyry Cu ◽  
Mineral Assemblages ◽  
Host Rocks

The present study correlates both the mineralogy of the hydrothermal alteration and the mineral chemistry of molybdenites from three porphyry Mo ± Cu occurrences in Thrace: Melitena, Pagoni Rachi/Kirki and Ktismata/ Maronia. The mineralisations are genetically related to calcalkaline, subvolcanic bodies of Tertiary age. According to their mineralogical and chemical composition the host rocks are characterized as dacite (Melitena), dacitic andésite (Pagoni Rachi) and porphyry microgranite (Ktismata/Maronia). The molybdenites occur in disseminated form, as fracture fillings, as well within quartz stockworks crosscuting the central alteration zones of the intrusives. They are accompanied by the following mineral assemblages: quartz, sericite, pyrophyllite, diaspore, Ca-Ba-rich alunite, pyrite (Melitena); quartz, albite/K-feldspar, biotite, actinolite, magnetite (Pagoni Rachi); and sericite, kaolinite, pyrophyllite, chlorite (Ktismata). Preliminary microthermometric results showed homogenisation temperatures from 352° to 390 °C for Pagoni Rachi area and from 295° to 363 °C for Melitena area. The salinities range between 4.5 and 6.1 wt% eq. NaCl and between 2.7 and 3.4 wt% eq. NaCl, respectively. Detailed study on over 400 fluid inclusions from the porphyry Cu-Mo deposit in Maronia area revealed formation temperatures from 300° to 420 °C, whereas salinities are distincted in two different groups from 6 to 16 wt% eq. NaCl and from 28 to 55 wt% eq. NaCl. The chemical composition of the molybdenites from the three porphyry Mo±Cu deposits in Thrace was studied with 155 microprobe analyses. The results revealed unusual high and variable Re concentrations in the studied molybdenites. Re content in molybdenite from Melitena area vary from 0.21 to 1.74 wt%, 0.79 wt% on average. The highest values were measured in samples from Pagoni Rachi (0.45-4.21 wt%, 1.98 wt% on average). Finally, microprobe analyses from molybdenite in Ktismata/Maronia showed Re content between 0.12 and 2.88 wt% (0.76 wt% on average). Rhenium is a very rare element with many definite uses, and is mainly associated with molybdenite in porphyry type deposits. According to the data published so far the Re content in molybdenite reaches up to 0.42 wt%. It is obvious therefore that such high Re concentrations (0.12 to 4.22 wt%) from the studied molybdenites in Thrace, are very ineresting for a possible future exploitation.

Inertia–gravity waves in a liquid-filled, differentially heated, rotating annulus

2015 ◽  
Vol 782 ◽  
pp. 144-177 ◽  
Author(s):  
Anthony Randriamampianina ◽  
Emilia Crespo del Arco
Keyword(s):  
Prandtl Number ◽  
Gravity Waves ◽  
Large Scale ◽  
Baroclinic Instability ◽  
Zonal Flow ◽  
Small Scale ◽  
Mean Flow ◽  
Baroclinic Waves ◽  
Fluid Properties ◽  
Spatio Temporal

Direct numerical simulations based on high-resolution pseudospectral methods are carried out for detailed investigation into the instabilities arising in a differentially heated, rotating annulus, the baroclinic cavity. Following previous works using air (Randriamampianina et al., J. Fluid Mech., vol. 561, 2006, pp. 359–389), a liquid defined by Prandtl number $Pr=16$ is considered in order to better understand, via the Prandtl number, the effects of fluid properties on the onset of gravity waves. The computations are particularly aimed at identifying and characterizing the spontaneously emitted small-scale fluctuations occurring simultaneously with the baroclinic waves. These features have been observed as soon as the baroclinic instability sets in. A three-term decomposition is introduced to isolate the fluctuation field from the large-scale baroclinic waves and the time-averaged mean flow. Even though these fluctuations are found to propagate as packets, they remain attached to the background baroclinic waves, locally triggering spatio-temporal chaos, a behaviour not observed with the air-filled cavity. The properties of these features are analysed and discussed in the context of linear theory. Based on the Richardson number criterion, the characteristics of the generation mechanism are consistent with a localized instability of the shear zonal flow, invoking resonant over-reflection.

Metasomatism in the Whin Sill of the North of England. Part II: Hydrothermal Alteration by Juvenile Solutions

1929 ◽  
Vol 66 (5) ◽  
pp. 221-238 ◽  
Author(s):  
L. R. Wager
Keyword(s):  
Thin Layer ◽  
Hydrothermal Alteration ◽  
Outer Surface ◽  
Large Scale ◽  
General Character ◽  
Small Scale ◽  
Hydrothermal Solutions ◽  
Vein Quartz ◽  
Columnar Jointing ◽  
The North

In Teesdale and Weardale, at all exposures that have been examined, the Whin Sill is cut by a system of approximately vertical, sweeping, joint planes. These are distinct in general character from, and are on a larger scale than, the columnar jointing which is conspicuous in all vertical scars of Whin Sill. The pattern of the larger scale jointing on a horizontal surface varies with the depth within the sill; Fig. 1 shows diagrammatically the appearance at a depth of about 10 feet below the top of the sill; the inset Fig. 2, of the upper surface of the sill, shows how the joints have a more irregular course in the more rapidly cooled part of the dolerite. The joints do not usually pass from the dolerite into the adjacent sediment and Fig. 2 also shows a thin layer of baked sediment, attached to the outer surface of the sill, which the joint does not penetrate. The large scale jointing is often displaced by the small scale columnar jointing in a way that proves the large scale jointing to be the earlier. For the purposes of this paper, the early, large scale, joints will be referred to simply as the early joints. The walls of the early joints, for a distance of an inch or so, have been altered by hydrothermal solutions, to a rock which, although varying in composition with the distance from the joint, consists essentially of chlorite, quartz, and carbonate. The joint walls are usually about a quarter of an inch apart, and the space between them is filled with calcite and quartz. The calcite is present in greater abundance than the quartz which occurs in well shaped crystals of vein-quartz habit.

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