Quantifying deposition pathways of Ozone at a rainforest site (ATTO) in the central Amazon basin

Author(s):  
Matthias Sörgel ◽  
Anywhere Tsokankunku ◽  
Stefan Wolff ◽  
Alessandro Araùjo ◽  
Pedro Assis ◽  
...  

<p>Direct eddy covariance flux measurements of O<sub>3</sub> in tropical forests are sparse and deposition velocities of O<sub>3</sub> for tropical forest have large uncertainties in models. Therefore, we measured O<sub>3</sub> fluxes at different heights ( 4 m, 12 m, 46 m and 81 m), which is 2 levels within canopy (below crown layer) and two levels above. At the same levels heat and CO<sub>2</sub> fluxes were measured by eddy covariance to differentiate upper canopy fluxes from understory and soil fluxes and to infer stomatal conductance based on the inverted Penman-Monteith equation. Further measurements include the profiles of O<sub>3</sub>, NO<sub>x</sub>, CO<sub>2</sub> and H<sub>2</sub>O which are used to calculate storage fluxes and reactions of O<sub>3</sub> with NO<sub>x</sub> within the air volume. Additionally, leaf surface temperature and leaf wetness were measured in the upper canopy (26 m) to infer their influence on the non-stomatal deposition. The measurements took place at the ATTO (Amazon Tall Tower Observatory) site that is located about 150 km northeast of the city of Manaus in the Amazon rainforest. (02°08’38.8’’S, 58°59’59.5’’W). The climate in this region is characterized by a rainy (350 mm around March) and a dry season (ca. 80 mm in September). During the wet months, the air quality is close to pristine, while strong pollution from biomass burning is evident in the dry season. Therefore, we will present results from two intensive campaigns (3- 4 flux levels) for the rainy season (March to May) and the dry season (September to December) 2018.</p><p> </p><p>The focus of the analysis is the partitioning between a) the crown layer and understory and b) stomatal and non-stomatal deposition with a further analysis of the non-stomatal pathways. Non-stomatal deposition is analyzed by quantifying gas-phase reactions of O<sub>3</sub> with NO<sub>x</sub> and an estimate of O<sub>3</sub> reactivity by VOCs. Furthermore, the remaining (surface) deposition is analyzed according to its relations with leaf surface temperature and leaf wetness.</p>

Author(s):  
P. Nwaerema ◽  
Ojeh N. Vincent ◽  
C. Amadou ◽  
Atuma, I. Morrison

The study examined Land Surface Temperature (LST) and Land Surface Emissivity (LSE) in a tropical coastal city of Port Harcourt and its environs. Satellite remote sensing of multiple-wavelength origin was employed to derive data from the Landsat Enhance Thematic Mapper (ETM+). Statistical mean and range were used to show pattern of LST and LSE. The study established the relationship and characteristics of land use land cover, built-up area and influence of population on land surfaces. With population of over 3,095,342 persons occupying surface area of approximately 458,28 Km2, rapid vegetal and water body lost have put the city area under pressure of 4.7°C heat bias at the interval of 15 years. From rural fringes to the city center, LST varies with 9.3°C in wet season and 4.8°C in the dry season. During the dry season, LSE is severe in the southern part of the city contributed by water bodies, more vegetal cover and urban pavement materials. Emissivity in the wet season varied with 0.0136 and 0.0006 during the dry season but differs with 0.0165 between the two seasons. One critical finding is that LSE decreases from the rural fringes to the city center and LST increases from the rural fringes to the city center. It is recommended that urban greening at the city center should be practiced and the rural fringes should be explored by decongesting activities at the city center to the outskirts in order to ameliorate the effects of urban heat bias without further delay.


2008 ◽  
Vol 363 (1498) ◽  
pp. 1753-1759 ◽  
Author(s):  
Phil P Harris ◽  
Chris Huntingford ◽  
Peter M Cox

The Hadley Centre coupled climate–carbon cycle model (HadCM3LC) predicts loss of the Amazon rainforest in response to future anthropogenic greenhouse gas emissions. In this study, the atmospheric component of HadCM3LC is used to assess the role of simulated changes in mid-twenty-first century sea surface temperature (SST) in Amazon Basin climate change. When the full HadCM3LC SST anomalies (SSTAs) are used, the atmosphere model reproduces the Amazon Basin climate change exhibited by HadCM3LC, including much of the reduction in Amazon Basin rainfall. This rainfall change is shown to be the combined effect of SSTAs in both the tropical Atlantic and the Pacific, with roughly equal contributions from each basin. The greatest rainfall reduction occurs from May to October, outside of the mature South American monsoon (SAM) season. This dry season response is the combined effect of a more rapid warming of the tropical North Atlantic relative to the south, and warm SSTAs in the tropical east Pacific. Conversely, a weak enhancement of mature SAM season rainfall in response to Atlantic SST change is suppressed by the atmospheric response to Pacific SST. This net wet season response is sufficient to prevent dry season soil moisture deficits from being recharged through the SAM season, leading to a perennial soil moisture reduction and an associated 30% reduction in annual Amazon Basin net primary productivity (NPP). A further 23% NPP reduction occurs in response to a 3.5°C warmer air temperature associated with a global mean SST warming.


2020 ◽  
Author(s):  
Robbie Ramsay ◽  
Chiara F. Di Marco ◽  
Matthias Sörgel ◽  
Mathew R. Heal ◽  
Samara Carbone ◽  
...  

Abstract. The Amazon rainforest presents a unique, natural laboratory for the study of surface-atmosphere interactions. Its alternation between a near-pristine, marine-influenced atmosphere during the wet season, and a vulnerable system affected by periodic intrusions of anthropogenic pollution during the dry season, provides an opportunity to investigate some fundamental aspects of boundary-layer chemical processes. This study presents the first simultaneous hourly measurements of concentrations, fluxes and deposition velocities of the inorganic trace gases NH3, HCl, HONO, HNO3 and SO2 and their water-soluble aerosol counterparts NH4+, Cl−, NO2−, NO3− and SO42− over the Amazon. Species concentrations were measured in the dry season (from 6 October to 5 November 2017), at the Amazon Tall Tower Observatory (ATTO) in Brazil, using a two-point gradient, wet-chemistry instrument (Gradient of Aerosols and Gases Online Registration, GRAEGOR) sampling at 42 m and 60 m. Fluxes and deposition velocities were derived from the concentration gradients using a modified form of the aerodynamic gradient method corrected for measurement within the roughness sub-layer. Findings from this campaign include observations of elevated concentrations of NH3 and SO2 partially driven by long-range transport (LRT) episodes of pollution, and the substantial influence of coarse Cl− and NO3− particulate on overall aerosol mass burdens. From the flux measurements, the dry season budget of total reactive nitrogen dry deposition at the ATTO site was estimated as −2.9 kg N ha−1 a−1. HNO3 and HCl were deposited continuously at a rate close to the aerodynamic limit. SO2 was deposited with an average daytime surface resistance (Rc) of 28 s m−1, whilst aerosol components showed average surface deposition velocities of 2.8 and 2.7 mm s−1 for SO42− and NH4+. Deposition rates of NO3


Author(s):  
Georgiana Grigoraș ◽  
Bogdan Urițescu

Abstract The aim of the study is to find the relationship between the land surface temperature and air temperature and to determine the hot spots in the urban area of Bucharest, the capital of Romania. The analysis was based on images from both moderate-resolution imaging spectroradiometer (MODIS), located on both Terra and Aqua platforms, as well as on data recorded by the four automatic weather stations existing in the endowment of The National Air Quality Monitoring Network, from the summer of 2017. Correlation coefficients between land surface temperature and air temperature were higher at night (0.8-0.87) and slightly lower during the day (0.71-0.77). After the validation of satellite data with in-situ temperature measurements, the hot spots in the metropolitan area of Bucharest were identified using Getis-Ord spatial statistics analysis. It has been achieved that the “very hot” areas are grouped in the center of the city and along the main traffic streets and dense residential areas. During the day the "very hot spots” represent 33.2% of the city's surface, and during the night 31.6%. The area where the mentioned spots persist, falls into the "very hot spot" category both day and night, it represents 27.1% of the city’s surface and it is mainly represented by the city center.


2021 ◽  
Vol 13 (7) ◽  
pp. 3910
Author(s):  
Michael Gräf ◽  
Markus Immitzer ◽  
Peter Hietz ◽  
Rosemarie Stangl

Urban green infrastructures offer thermal regulation to mitigate urban heat island effects. To gain a better understanding of the cooling ability of transpiring plants at the leaf level, we developed a method to measure the time series of thermal data with a miniaturized, uncalibrated thermal infrared camera. We examined the canopy temperature of four characteristic living wall plants (Heuchera x cultorum, Bergenia cordifolia, Geranium sanguineum, and Brunnera macrophylla) under increasing drought stress and compared them with a well-watered control group. The method proved suitable to evaluate differences in canopy temperature between the different treatments. Leaf temperatures of water-stressed plants were 6 to 8 °C higher than those well-watered, with differences among species. In order to cool through transpiration, vegetation in green infrastructures must be sufficiently supplied with water. Thermal cameras were found to be useful to monitor vertical greening because leaf surface temperature is closely related to drought stress. The usage of thermal cameras mounted on unmanned aerial vehicles could be a rapid and easy monitoring system to cover large façades.


2021 ◽  
Vol 13 (2) ◽  
pp. 323
Author(s):  
Liang Chen ◽  
Xuelei Wang ◽  
Xiaobin Cai ◽  
Chao Yang ◽  
Xiaorong Lu

Rapid urbanization greatly alters land surface vegetation cover and heat distribution, leading to the development of the urban heat island (UHI) effect and seriously affecting the healthy development of cities and the comfort of living. As an indicator of urban health and livability, monitoring the distribution of land surface temperature (LST) and discovering its main impacting factors are receiving increasing attention in the effort to develop cities more sustainably. In this study, we analyzed the spatial distribution patterns of LST of the city of Wuhan, China, from 2013 to 2019. We detected hot and cold poles in four seasons through clustering and outlier analysis (based on Anselin local Moran’s I) of LST. Furthermore, we introduced the geographical detector model to quantify the impact of six physical and socio-economic factors, including the digital elevation model (DEM), index-based built-up index (IBI), modified normalized difference water index (MNDWI), normalized difference vegetation index (NDVI), population, and Gross Domestic Product (GDP) on the LST distribution of Wuhan. Finally, to identify the influence of land cover on temperature, the LST of croplands, woodlands, grasslands, and built-up areas was analyzed. The results showed that low temperatures are mainly distributed over water and woodland areas, followed by grasslands; high temperatures are mainly concentrated over built-up areas. The maximum temperature difference between land covers occurs in spring and summer, while this difference can be ignored in winter. MNDWI, IBI, and NDVI are the key driving factors of the thermal values change in Wuhan, especially of their interaction. We found that the temperature of water area and urban green space (woodlands and grasslands) tends to be 5.4 °C and 2.6 °C lower than that of built-up areas. Our research results can contribute to the urban planning and urban greening of Wuhan and promote the healthy and sustainable development of the city.


2011 ◽  
Vol 8 (9) ◽  
pp. 2815-2831 ◽  
Author(s):  
W. Eugster ◽  
T. DelSontro ◽  
S. Sobek

Abstract. Greenhouse gas budgets quantified via land-surface eddy covariance (EC) flux sites differ significantly from those obtained via inverse modeling. A possible reason for the discrepancy between methods may be our gap in quantitative knowledge of methane (CH4) fluxes. In this study we carried out EC flux measurements during two intensive campaigns in summer 2008 to quantify methane flux from a hydropower reservoir and link its temporal variability to environmental driving forces: water temperature and pressure changes (atmospheric and due to changes in lake level). Methane fluxes were extremely high and highly variable, but consistently showed gas efflux from the lake when the wind was approaching the EC sensors across the open water, as confirmed by floating chamber flux measurements. The average flux was 3.8 ± 0.4 μg C m−2 s−1 (mean ± SE) with a median of 1.4 μg C m−2 s−1, which is quite high even compared to tropical reservoirs. Floating chamber fluxes from four selected days confirmed such high fluxes with 7.4 ± 1.3 μg C m−2 s−1. Fluxes increased exponentially with increasing temperatures, but were decreasing exponentially with increasing atmospheric and/or lake level pressure. A multiple regression using lake surface temperatures (0.1 m depth), temperature at depth (10 m deep in front of the dam), atmospheric pressure, and lake level was able to explain 35.4% of the overall variance. This best fit included each variable averaged over a 9-h moving window, plus the respective short-term residuals thereof. We estimate that an annual average of 3% of the particulate organic matter (POM) input via the river is sufficient to sustain these large CH4 fluxes. To compensate the global warming potential associated with the CH4 effluxes from this hydropower reservoir a 1.3 to 3.7 times larger terrestrial area with net carbon dioxide uptake is needed if a European-scale compilation of grasslands, croplands and forests is taken as reference. This indicates the potential relevance of temperate reservoirs and lakes in local and regional greenhouse gas budgets.


2021 ◽  
Author(s):  
Richard Sims ◽  
Brian Butterworth ◽  
Tim Papakyriakou ◽  
Mohamed Ahmed ◽  
Brent Else

<p>Remoteness and tough conditions have made the Arctic Ocean historically difficult to access; until recently this has resulted in an undersampling of trace gas and gas exchange measurements. The seasonal cycle of sea ice completely transforms the air sea interface and the dynamics of gas exchange. To make estimates of gas exchange in the presence of sea ice, sea ice fraction is frequently used to scale open water gas transfer parametrisations. It remains unclear whether this scaling is appropriate for all sea ice regions. Ship based eddy covariance measurements were made in Hudson Bay during the summer of 2018 from the icebreaker CCGS Amundsen. We will present fluxes of carbon dioxide (CO<sub>2</sub>), heat and momentum and will show how they change around the Hudson Bay polynya under varying sea ice conditions. We will explore how these fluxes change with wind speed and sea ice fraction. As freshwater stratification was encountered during the cruise, we will compare our measurements with other recent eddy covariance flux measurements made from icebreakers and also will compare our turbulent CO<sub>2 </sub>fluxes with bulk fluxes calculated using underway and surface bottle pCO<sub>2</sub> data. </p><p> </p>


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