Pyroclastic rocks from Kanchanaburi and Uthai Thani Province, Inthanon Zone, Western Thailand

Author(s):  
Suwijai Jatupohnkhongchai ◽  
Sirot Salyapongse ◽  
Burapha Phajuy ◽  
Daniela Gallhofer ◽  
Christoph Hauzenberger

<p>A series of pyroclastic rocks are mapped as a Silurian-Devonian unit in the Kanchanaburi-Uthai Thani area, Western Thailand, which belongs to the Inthanon Zone. These pyroclastic rocks were discovered and described for the first time in 1977 and mentioned in the 1:250,000 Suphanburi geologic map sheet and report. Since then these rocks were poorly investigated and their formation and geotectonic setting is unclear. As a result, we report petrographic, geochemical and geochronological data of these pyroclastic rocks. Petrographically, the pyroclastic rocks can be described as a meta-quartz-K-feldspar crystal tuff, a meta-quartz crystal tuff, and a meta-lithic tuff. They are made up of mm sized clasts in a finely grained matrix. The clasts consist of potassium feldspar, rounded quartz, embayed quartz, trachytic and metasedimentary rock clasts embedded in a highly altered devitrified fine-ash matrix containing sericite.</p><p>The whole-rock composition shows enrichments in SiO<sub>2</sub> and K<sub>2</sub>O and a strong depletion in CaO and Na<sub>2</sub>O which is related to late alteration of the volcanoclastic rocks. Based on the immobile element classification plot of Pearce 1996, the tuffs can be classified as trachyandesite, trachyte, dacite and rhyolite. Their chondrite-normalized REE patterns display light REE enrichment with nearly flat heavy REE and a negative Eu anomaly, typical for calcalkaline volcanic rocks. Most samples fall in the volcanic arc granites field in the granite discrimination diagrams of Pearce 1984.</p><p>Zircons extracted from the tuffs will be used to constrain their crystallization age by U-Pb LA-MCICPMS dating. This allows us to constrain the age of formation and to place this in context with the closure of the Paleotethys.</p>

2021 ◽  
Vol 62 (6) ◽  
pp. 633-647
Author(s):  
E.V. Vetrov ◽  
A.N. Uvarov ◽  
N.I. Vetrova ◽  
F.A. Letnikov ◽  
I.A. Vishnevskaya ◽  
...  

Abstract ––We have studied the structure and composition of a volcanic unit in the valley of the Despen River, on the southern slope of the East Tannu-Ola Ridge. The unit was earlier assigned to the Lower Devonian Kendei Formation. The new geological and geochronological data show that it resulted from explosive volcanism at 460–450 Ma. The Despen volcanic rocks formed in association with granitoids of the Argolik complex at the end of the accretion–collision stage of evolution of the Altai–Sayan region, in particular, the Tannu-Ola terrane. These are predominantly felsic ferroan metaluminous and weakly peraluminous nappe volcanic rocks resulted from the differentiation of tholeiitic basalts. Their REE patterns, like those of the Argolik granitoids, are flat in the HREE, show a distinct Eu anomaly, and suggest magma generation at shallow depths in the upper crust. The magmatic source was of subduction origin, as evidenced by the negative Ta–Nb anomalies in the multielement patterns and by εNd(T) = +3.1 to +5.6, and has a Neoproterozoic model age, TNd(DM-2st) = 0.94–0.69 Ga.


2017 ◽  
Vol 34 (3) ◽  
pp. 199 ◽  
Author(s):  
Teresa Pi ◽  
Jesús Solé ◽  
Ofelia Morton-Bermea ◽  
Yuri Taran ◽  
Elizabeth Hernández-Álvarez

We present and evaluate lanthanide contents measured by inductively coupled plasma mass spectrometry (ICP-MS) in fluorite samples from the fluorite deposits in Zacualpan and Taxco mining districts in the south of Mexico. The information is used to distinguish different generations of fluorite, to establish a correlation between mineralization episodes and the wall rock nature, and to identify postdepositional processes.The total lanthanide content of the fluorites are variable, and early- stage fluorite samples are usually enriched in LREE. The concentration of REE in fluorite is low in comparison with the volcanic and metamorphic rocks (∑REE > 100 ppm) and is generally high respect the carbonates (∑REE < 30 ppm). There is host rock influence. The higher REE concentra- tions are in fluorites hosted by volcanic rocks. The fluorite that replaced carbonate is characterized by low REE to very low concentrations. Fluorite samples associated with sulfurs are typically enriched in HREE. Nearly all fluorites show a negative Eu anomaly similar to the REE anomaly observed in the volcanic rock. Only some early stage dark, uranium rich fluorites, from la Azul deposit, have a strong positive Eu anomaly. Direct correlation between color and REE patterns is observed in some samples.In the Zacualpan mining district, only an episode of mineralization has been discriminated, where fluorite presents flat to HREE- enriched chondrite-normalized REE patterns.In the Taxco mining district and particularly in the “Mina la Azul”, multiple hydrothermal events of mineralization have been determined. The first generation of fluorite is formed by replacement of carbonates and is characterized by very low contents of lanthanides, chondrite- normalized REE patterns similar to the limestone, high strontium content and primary textures (e.g. massive fluorite and rhythmites). The second generation of fluorite is related to the entry of new fluid to the system and has higher REE concentrations, chondrite-normalized REE patterns similar to volcanic rocks, low strontium content and secondary textures (i.e. breccias, nodules). Most of the samples show a genetic relationship between fluorite and fluids of magmatic origin.


2018 ◽  
Vol 37 (2) ◽  
pp. 607-625 ◽  
Author(s):  
Haitao Sun ◽  
Dakang Zhong ◽  
Weijia Zhan

To explain the strong spatial heterogeneity of volcanic reservoirs porosity in the Songliao Basin and provide new ideas for predicting good volcanic reservoirs in other similar basins, the relationship between the pore evolution process and lithology of volcanic reservoirs has been described in this article. With the description and interpretation of core, thin section, scanning electron microscope, and the results of mercury injection experiment, this article clarifies the lithology, pore types, and pore structure features of the volcanic reservoirs in the Songliao Basin. The rocks of volcanic reservoirs in study area contain pyroclastic rock and volcanic lavas. The most common lithologies are rhyolite, volcanic breccia, and volcanic tuff. The pore size, morphology, and structure vary greatly between these three lithologies, the reason of which we think is the different volcanic eruption process as well as rock composition and its structure. The digenetic evolution of rhyolite includes gas dissipation of magmatic condensation; vesicles fulfilling by hydrothermal fluid; kaolinization and sericitization of feldspar phenocrysts; carbonation, devitrification, and recrystallization of felsic matrix; and finally, the dissolution of feldspar phenocrysts and felsic matrix. As for volcanic breccia, it usually go through the compaction, quartz and calcite filling the original pores between volcanic breccias, and dissolution of mineral debris together with tuff matrix. Similar with the rhyolite, volcanic tuff also undergoes the carbonation and kaolinization of felsic matrix, the dissolution of feldspar and felsic matrix, and compaction. Due to these comprehensive processes, a comprehensive analysis of volcanic rock lithology, which can indicate lithology distribution vertically and horizontally, is very necessary during volcanic reservoirs evaluation and prediction. These detailed analyses will help explorers to find potential reservoirs by distinguishing the diagenetic evolution and pore characteristic of volcanic reservoirs.


2016 ◽  
Vol 6 (1) ◽  
pp. 43 ◽  
Author(s):  
Anthony Temidayo Bolarinwa ◽  
Adebimpe Atinuke Adepoju

Trace and Rare Earth Elements (REEs) data are used to constrain the geochemical evolution of the amphibolites from Ifewara in the Ife-Ilesha schist belt of southwestern Nigeria. The amphibolites can be grouped into banded and sheared amphibolites. Major element data show SiO2 (48.34%), Fe2O3 (11.03-17.88%), MgO (5.76-9.90%), CaO (7.76-18.6%) and TiO2 (0.44-1.77%) contents which are similar to amphibolites in other schist belts in Nigeria. The Al2O3 (2.85-15.55%) content is varied, with the higher values suggesting alkali basalt protolith. Trace and rare earth elements composition reveal Sr (160-1077ppm), Rb (0.5-22.9ppm), Ni (4.7-10.2ppm), Co (12.2-50.9 ppm) and Cr (2-7ppm). Chondrite-normalized REE patterns show that the banded amphibolites have HREE depletion and both negative and positive Eu anomalies while the sheared variety showed slight LREE enrichment with no apparent Eu anomaly. The study amphibolites plot in the Mid Oceanic Ridge Basalts (MORB) and within plate basalt fields on the Zr/Y vs Zr discriminatory diagrams. They are further classified as volcanic arc basalt and E-type MORB on the Th- Hf/3- Ta and the Zr-Nb-Y diagrams. The amphibolites precursor is considered a tholeiitic suite that suffered crustal contamination, during emplacement in a rifted crust.


Author(s):  
M. Aftalion ◽  
O. van Breemen ◽  
D. R. Bowes

ABSTRACTThe existence of a basement of granulite beneath the Midland Valley is supported by investigations of inclusions in volcanic rocks and the geophysical studies of the LISPB experiment. To establish age constraints for this basement, a compilation is presented of available Rb–Sr whole-rock, common lead, U–Pb zircon and Sm–Nd radiometrie data for crystalline rocks in Scotland from the earliest recognised crust (c. 2900 Ma) to 380 Ma (“end” of Caledonian orogeny) including xenoliths in volcanic vents and boulders in conglomerates.For rocks within the Midland Valley, isotopic data provide four lines of evidence. (1) An upper intercept U–Pb age of c. 1700 Ma for detrital zircons from a lower Palaeozoic greywacke from Dalmellington corresponds to a late stage of the Laxfordian orogenic episode (early Proterozoic) with possibly some overprinting during the Grenvillian episode (mid Proterozoic). (2) The common lead composition of the Distinkhorn granite suggests the participation of early Proterozoic basement during granite emplacement. (3) For xenoliths from the Carboniferous Partan Craig vent, one gives a Sm–Nd CHUR model age of 1180 ± 55 Ma, a second yielded a Sm–Nd garnet—potassium feldspar age of 356 ± 6 Ma and an upper intercept U–Pb age from zircons from the third is c. 2200 (± 240) Ma; for xenoliths from other vents, an Rb–Sr whole-rock isochron of 1101 ± 63 Ma and an Sm–Nd model age of c. 1100 Ma arerecorded. (4) A linear array corresponding to an apparent age of 770 ± 180 Ma on a Pb–Pb isochron diagram for Tertiary igneous rocks of Arran points to an underlying basement of late Precambrian orthogneiss.The existence of basement made of products of the Grenvillian episode, or predominantly so, similar to the basement N of the Highland Boundary fault, is not inconsistent with the available evidence. However, zircons and other rock components appear to have an ultimate Lewisian provenance. At least in parts, there is also a strong late Proterozoic imprint. Further studies are required for an unequivocal solution.


1984 ◽  
Vol 21 (6) ◽  
pp. 731-736 ◽  
Author(s):  
Nathan L. Green ◽  
Paul Henderson

A suite of hy-normative hawaiites, ne-normative mugearite, and calc-alkaline andesitic rocks from the Garibaldi Lake area exhibits fractionated, slightly concave-upward REE patterns (CeN/YbN = 4.5–15), heavy REE contents about 5–10 times the chondritic abundances, and no Eu anomalies. It is unlikely that the REE patterns provide information concerning partial melting conditions beneath southwestern British Columbia because they have probably been modified substantially by upper crustal processes including crustal contamination and (or) crystal fractionation. The REE contents of the Garibaldi Lake lavas are not incompatible with previous interpretations that (1) the hawaiites have undergone considerable fractionation of olivine, plagioclase, and clinopyroxene; and (2) the individual andesitic suites were derived from separate batches of chemically distinct magma that evolved along different high-level crystallization trends. In general, however, the andesites are characterized by lower light REE contents than the basaltic andesites. These differences in LREE abundances may reflect different amounts of LREE-rich accessory phases, such as apatite, sphene, or allanite, assimilated from the underlying quartz diorites.


Hacquetia ◽  
2019 ◽  
Vol 18 (2) ◽  
pp. 271-287
Author(s):  
Georgi Kunev ◽  
Rossen Tzonev

Abstract The study presents new data on the habitat dominated by the species complex of Genista lydia/G. rumelica in Bulgaria. It is based on 129 phytocoenological relevés and provides information on the chorology, ecology and floristic structure of these communities. This habitat type occupies substrates composed by different volcanic rocks. The floristic structure is very rich in species. The phytogeographical relationships with the East Mediterranean region are considerable, which is proved by the high occurrence of floristic elements with Mediterranean or sub-Mediterranean origin. The plant life-forms analysis demonstrates that the therophytes, geophytes and chamephytes prevail in their floristic structure, which is also typical for the shrub communities in this region. During the field study this vegetation type has been mapped and its total area of occupancy has been calculated. For a first time it is proposed this habitat to be divided into three habitat sub-types due to the established differences in the environmental factors. Some recommendations have been proposed on the conservation management and also complements on the habitat‘s descriptions in EUNIS habitat classification.


Author(s):  
A.I. Malinovsky ◽  
◽  
V.V. Golozubov ◽  

This paper studies the original results of the material composition analysis of the Early Silurian terrigenous deposits of the Kordonka formation of the Paleozoic – Early Mesozoic Laoeling-Grodekovo terrane of the South Primorye. The research is aimed at reconstructing paleogeodynamic setting of the deposition of sediments of the formation, and determining the type and mother rock composition of the feed sources based on the complex genetic interpretation of the material composition of rocks. It was established that mineralogically and geochemically formation of the rocks correspond to the typical graywackes and represent petrogenic or “first cycle” rocks formed mainly through the source rock failure. They are characterized by a low maturity, low lithodynamic recycling rate of mother rocks and their rapid burial. The interpretation of the results of the complex study of the material composition of the rocks was carried out on the basis of its comparison with the compositions of ancient rocks and modern sediments formed in the well-known geodynamic settings. The obtained data indicate that deposits of the Kordonka formation accumulated in a sedimentary basin connected with an oceanic island arc. Being built by basic and intermediate volcanic rocks as well as by igneous and sedimentary rocks that constituted its base, this island arc was the source area that supplied clastic material to the aforementioned sedimentary basin.


2004 ◽  
Vol 36 (1) ◽  
pp. 542
Author(s):  
I. Baziotis ◽  
E. Mposkos ◽  
V. Perdikatsis

In the broad area of Pentelikon Mountain, which is part of the Attic-Cycladic crystalline belt, metamigmatites and orthogneisses occur as tectonic slices within the calc-schists or between calcschists and marbles. In the metamigmatites relic of migmatitic fabrics, comprising leucosomes and melanosomes, and cross-cutting aplitic and pegmatitic dykes are still preserved. The orthogneisses have dioritic to granitic composition. They are interpreted to be probably formed in a magmatic arc setting. Granitic orthogneisses show high-K contents and are enriched in LILEs and depleted in HFSEs. They also exhibit fractionated REE patterns with slight to strong negative Eu anomaly. The exceptionally high K2O contents (>7%) and the very low Na2Û contents (0.4-0.98 wt%) of certain phengite-orthogneisses with ultramylonitic textures are attributed to metasomatic processes that occurred during ultramylonitization.


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