Epidote U–Pb ages vs. fluid–mineral interaction

2021 ◽  
Author(s):  
Veronica Peverelli ◽  
Alfons Berger ◽  
Pierre Lanari ◽  
Martin Wille ◽  
Igor Maria Villa ◽  
...  
Keyword(s):  
Time Frame ◽  
Swiss Alps ◽  
Earth Planet ◽  
Concentration Data ◽  
Massif Central ◽  
Isotopic Signatures ◽  
Vein Formation ◽  
External Fluid ◽  
Wide Range ◽  
Mineral Interaction

<p>Recently, the application of LA–ICP–MS has enabled U–Pb dating of epidote minerals within the epidote–clinozoisite solid solution series (Peverelli et al., 2020). Epidote crystallization ages can provide an absolute time frame of deformation sequences when combined with detailed microstructural and metamorphic P–T analysis. Epidote deformation occurs in a brittle manner over a wide range of conditions below its closure temperature for Pb diffusion (685–750 °C; Dahl, 1997); hence, such deformation will not affect its formation U–Pb age. Nevertheless, the possibility of isotopically resetting epidote via fluid–mineral interaction has to be taken into account even at low deformation temperatures.</p><p>We investigated the geochemical and Sr–Pb isotopic characteristics of epidote in one hydrothermal vein in the Aar Massif (central Swiss Alps). The vein is associated with an Alpine shear zone and it is composed of aggregates of 0.1–1 mm anhedral to subhedral epidote grains (epidote-A) + green biotite within a quartz matrix. This quartz dynamically recrystallized by subgrain rotation at temperatures above 400 °C (Stipp et al., 2002) along with crystallization of a second epidote generation (epidote-B) made of tiny (< 0.1 mm) anhedral epidote grains in part mantling epidote-A and defining a fold. We address whether interaction with the fluid that precipitated epidote-B chemically affected epidote-A, i.e. whether the U–Pb age measured by LA–ICP–MS in epidote-A still dates its crystallization upon vein formation or displays age disturbance.</p><p>LA–ICP–MS Sr and Pb concentration data overlap between epidote-A and epidote-B, as do their REE patterns, with (La/Yb)<sub>N</sub> ratios of 0.03–0.92. Lead and Sr isotopic signatures were measured respectively by solution MC–ICP–MS and by TIMS in epidote-A and in separates mixing different proportions of epidote-A and -B (no pure mechanical separates of epidote-B possible), and they are different. This requires open-system conditions during deformation, i.e., introduction of an external fluid with higher <sup>87</sup>Sr/<sup>86</sup>Sr and <sup>208</sup>Pb/<sup>206</sup>Pb ratios during crystallization of epidote-B. Despite the presence of an external fluid and the incorporation of external Sr and Pb in epidote-B, LA–ICP–MS U–Pb isotopic data for epidote-A define a regression in a Tera–Wasserburg plot indicating an age of 19.2 ± 4.3 Ma, consistent with epidote-A crystallization during original vein opening. The preservation of the crystallization age in epidote-A indicates that interaction with the fluid that formed epidote-B did not geochemically and isotopically affect epidote-A. The consistency in trace element contents between epidote-A and -B hints that the epidote-forming cations were inherited by the fluid from epidote-A, and thus suggests dissolution-precipitation as the formation process for epidote-B.</p><p> </p><p>Dahl, Earth Planet. Sci. Lett. 150, 277–290, 1997.</p><p>Peverelli et al., Geochronology Discuss. [preprint], https://doi.org/10.5194/gchron-2020-27, in review, 2020.</p><p>Stipp et al., Geological Society, London, Special Publications, 200(1), 171-190, 2002</p>

scholarly journals U–Pb geochronology of epidote by LA–ICP–MS as a tool for dating hydrothermal-vein formation

2020 ◽  
Author(s):  
Veronica Peverelli ◽  
Tanya Ewing ◽  
Daniela Rubatto ◽  
Martin Wille ◽  
Alfons Berger ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
A Priori ◽  
Swiss Alps ◽  
Hydrothermal Vein ◽  
Isotopic Compositions ◽  
Vein Formation ◽  
Icp Ms ◽  
Wide Range ◽  
Primary Reference

Abstract. Monoclinic epidote is a low-µ (µ = 283U / 204Pb) mineral occurring in a variety of geological environments, participating in many metamorphic reactions and stable throughout a wide range of pressure–temperature conditions. Despite containing fair amounts of U, its use as a U–Pb geochronometer has been hindered by the commonly high contents of initial Pb with isotopic compositions that cannot be assumed a priori. We present U–Pb geochronology of hydrothermal-vein epidote spanning a wide range of Pb (3.9–190 µg g−1), Th (0.009–38 µg g−1) and U (2.6–530 µg g−1) contents and with µ values between 7–510 from the Albula area (eastern Swiss Alps), from the Grimsel area (central Swiss Alps) and from the Heyuan fault (Guangdong province, China). The investigated epidote samples show appreciable fractions of initial Pb that vary to different extents. A protocol has been developed for in situ U–Pb dating of epidote by spot-analysis laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) with a magmatic allanite as primary reference material. The suitability of the protocol and the reliability of the measured isotopic ratios have been ascertained by independent measurements of 238U / 206Pb and 207Pb / 206Pb ratios respectively by quadrupole and multicollector ICP–MS applied to epidote micro-separates digested and diluted in acids. For age calculation, we used the Tera–Wasserburg (207Pb / 206Pb–238U / 206Pb) diagram, which does not require corrections for initial Pb and provides the initial 207Pb / 206Pb ratio if all intra-sample analyses are co-genetic. Petrographic and microstructural data indicate that the calculated ages date the crystallization of vein epidote from a hydrothermal fluid and that the U–Pb system was not reset to younger ages by later events. Vein epidote from the Albula area formed in the Paleocene (62.7 ± 3.0 Ma) and is related to Alpine greenschist-facies metamorphism. The Miocene (19.1 ± 4.0 Ma and 16.9 ± 3.7 Ma) epidote veins from the Grimsel area formed during the Handegg phase (22–17 Ma) of the Alpine evolution of the Aar Massif. Identical initial 207Pb / 206Pb ratios reveal homogeneity in Pb isotopic compositions of the fluid across ca. 200 m. Vein epidote from the Heyuan fault is Cretaceous in age (108.1 ± 8.4 Ma) and formed during the early movements of the fault. In situ U–Pb analyses of epidote returned reliable ages of otherwise undatable epidote-quartz veins. The Tera–Wasserburg approach has proven pivotal for in situ U–Pb dating of epidote and the decisive aspect for low age uncertainties is the variability in intra-sample initial Pb fractions.

scholarly journals Design of a high-stability heterogeneous clock system for small satellites in LEO

GPS Solutions ◽  
2021 ◽  
Vol 25 (3) ◽  
Author(s):  
Damon Van Buren ◽  
Penina Axelrad ◽  
Scott Palo
Keyword(s):  
Low Power ◽  
High Stability ◽  
Time Frame ◽  
System Stability ◽  
Small Satellite ◽  
Crystal Oscillator ◽  
Small Satellites ◽  
Clock System ◽  
Wide Range

AbstractWe describe our investigation into the performance of low-power heterogeneous timing systems for small satellites, using real GPS observables from the GRACE Follow-On mission. Small satellites have become capable platforms for a wide range of commercial, scientific and defense missions, but they are still unable to meet the needs of missions that require precise timing, on the order of a few nanoseconds. Improved low-power onboard clocks would make small satellites a viable option for even more missions, enabling radio aperture interferometry, improved radio occultation measurements, high altitude GPS navigation, and GPS augmentation missions, among others. One approach for providing improved small satellite timekeeping is to combine a heterogeneous group of oscillators, each of which provides the best stability over a different time frame. A hardware architecture that uses a single-crystal oscillator, one or more Chip Scale Atomic Clocks (CSACs) and the reference time from a GPS receiver is presented. The clocks each contribute stability over a subset of timeframes, resulting in excellent overall system stability for timeframes ranging from less than a second to several days. A Kalman filter is used to estimate the long-term errors of the CSACs based on the CSAC-GPS time difference, and the improved CSAC time is used to discipline the crystal oscillator, which provides the high-stability reference clock for the small satellite. Simulations using GRACE-FO observations show time error standard deviations for the system range from 2.3 ns down to 1.3 ns for the clock system, depending on how many CSACs are used. The results provide insight into the timing performance which could be achieved on small LEO spacecraft by a low power timing system.

scholarly journals Breeding Strategies to Improve Miscanthus as a Sustainable Source of Biomass for Bioenergy and Biorenewable Products

Agronomy ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 673 ◽  
Author(s):  
John Clifton-Brown ◽  
Kai-Uwe Schwarz ◽  
Danny Awty-Carroll ◽  
Antonella Iurato ◽  
Heike Meyer ◽  
...  
Keyword(s):  
Significant Contribution ◽  
Perennial Grass ◽  
Time Frame ◽  
Eastern Asia ◽  
Germplasm Collections ◽  
Naturally Occurring ◽  
Wide Range ◽  
Yield Quality ◽  
Short Time ◽  
Commercial Expansion

Miscanthus, a C4 perennial grass native to Eastern Asia, is being bred to provide biomass for bioenergy and biorenewable products. Commercial expansion with the clonal hybrid M. × giganteus is limited by low multiplication rates, high establishment costs and drought sensitivity. These limitations can be overcome by breeding more resilient Miscanthus hybrids propagated by seed. Naturally occurring fast growing indigenous Miscanthus species are found in diverse environments across Eastern Asia. The natural diversity provides for plant breeders, the genetic resources to improve yield, quality, and resilience for a wide range of climates and adverse abiotic stresses. The challenge for Miscanthus breeding is to harness the diversity through selections of outstanding wild types, parents, and progenies over a short time frame to deploy hybrids that make a significant contribution to a world less dependent on fossil resources. Here are described the strategies taken by the Miscanthus breeding programme at Aberystwyth, UK and its partners. The programme built up one of the largest Miscanthus germplasm collections outside Asia. We describe the initial strategies to exploit the available genetic diversity to develop varieties. We illustrate the success of combining diverse Miscanthus germplasm and the selection criteria applied across different environments to identify promising hybrids and to develop these into commercial varieties. We discuss the potential for molecular selections to streamline the breeding process.

scholarly journals Reasoned Action Frameworks

Communication ◽  
2011 ◽  
Author(s):  
Marco Yzer ◽  
Brian Southwell
Keyword(s):  
Action Research ◽  
Reasoned Action ◽  
Time Frame ◽  
Situational Factors ◽  
Integrative Model ◽  
Behavioral Performance ◽  
Reasoned Action Approach ◽  
Theoretical Understanding ◽  
Wide Range ◽  
The Individual

Reasoned action frameworks, which include the Theory of Reasoned Action and its extensions, the widely used Theory of Planned Behavior and the more recent Integrative Model of Behavioral Prediction, describe that intention to perform a behavior follows reasonably (but not necessarily rationally) from specific beliefs that people hold about the behavior and that people act on their intentions when they have the required skills and when situational factors do not impede behavioral performance. Reasoned action research has two broad foci. A first seeks to advance theoretical understanding of human social behavior as based on expectancy beliefs about consequences of behavioral performance. A second applies reasoned action research to development or evaluation of interventions that seek to modify a specific behavior in a particular population. The relevance of the reasoned action approach for communication scholars lies in its direct applicability to a wide range of important communication questions, including the explanation of communication as a socially relevant behavior and intra-individual processes to explain how exposure to information leads to behavior change. Although reasoned action propositions embed belief-based processes in a multilevel system of influence, the individual is nonetheless the primary level of analysis. The range of citations included in this bibliography addresses the decades-long time frame during which scholars have explicitly employed core reasoned action concepts. Beyond the introductory works, the examples presented here are illustrative rather than exhaustive, by necessity, as few other behavioral theories have generated more citations in communication research.

scholarly journals Mycorrhizal Communities and Isotope Signatures in Two Partially Mycoheterotrophic Orchids

2021 ◽  
Vol 12 ◽  
Author(s):  
Hans Jacquemyn ◽  
Rein Brys ◽  
Michael Waud ◽  
Alexandra Evans ◽  
Tomáš Figura ◽  
...  
Keyword(s):  
Isotopic Signatures ◽  
Carbon And Nitrogen ◽  
Wide Range ◽  
Terrestrial Orchids ◽  
Significant Enrichment ◽  
Mycoheterotrophic Plants ◽  
C And N ◽  
Species Specific ◽  
Epipactis Helleborine ◽  
Isotope Analyses

Partial mycoheterotrophy, the ability of plants to obtain carbon from fungi throughout their life cycle in combination with photosynthesis, appears to be more common within the Plant Kingdom than previously anticipated. Recent studies using stable isotope analyses have indicated that isotope signatures in partially mycoheterotrophic plants vary widely among species, but the relative contributions of family- or species-specific characteristics and the identity of the fungal symbionts to the observed differences remain unclear. Here, we investigated in detail mycorrhizal communities and isotopic signatures in four co-occurring terrestrial orchids (Platanthera chlorantha, Epipactis helleborine, E. neglecta and the mycoheterotrophic Neottia nidus-avis). All investigated species were mycorrhizal generalists (i.e., associated with a large number of fungi simultaneously), but mycorrhizal communities differed significantly between species. Mycorrhizal communities associating with the two Epipactis species consisted of a wide range of fungi belonging to different families, whereas P. chlorantha and N. nidus-avis associated mainly with Ceratobasidiaceae and Sebacinaceae species, respectively. Isotopic signatures differed significantly between both Epipactis species, with E. helleborine showing near autotrophic behavior and E. neglecta showing significant enrichment in both carbon and nitrogen. No significant differences in photosynthesis and stomatal conductance were observed between the two partially mycoheterotrophic orchids, despite significant differences in isotopic signatures. Our results demonstrate that partially mycoheterotrophic orchids of the genus Epipactis formed mycorrhizas with a wide diversity of fungi from different fungal families, but variation in mycorrhizal community composition was not related to isotope signatures and thus transfer of C and N to the plant. We conclude that the observed differences in isotope signatures between E. helleborine and E. neglecta cannot solely be explained by differences in mycorrhizal communities, but most likely reflect a combination of inherent physiological differences and differences in mycorrhizal communities.

scholarly journals Evaluating seasonal hydrological extremes in mesoscale (pre-)Alpine basins at coarse 0.5° and fine hyperresolution

2019 ◽  
Vol 23 (3) ◽  
pp. 1593-1609 ◽  
Author(s):  
Joost Buitink ◽  
Remko Uijlenhoet ◽  
Adriaan J. Teuling
Keyword(s):  
High Resolution ◽  
Land Cover ◽  
Swiss Alps ◽  
Hydrological Response ◽  
Low Resolution ◽  
Continental Scale ◽  
Wide Range ◽  
Resolution Model ◽  
High Resolution Model ◽  
Basin Response

Abstract. Hydrological models are being applied for impact assessment across a wide range of resolutions. In this study, we quantify the effect of model resolution on the simulated hydrological response in five mesoscale basins in the Swiss Alps using the distributed hydrological model Spatial Processes in Hydrology (SPHY). We introduce a new metric to compare a range of values resulting from a distributed model with a single value: the density-weighted distance (DWD). Model simulations are performed at two different spatial resolutions, matching common practices in hydrology: 500 m × 500 m matching regional-scale models, and 40 km × 40 km matching global-scale modeling. We investigate both the intra-basin response in seasonal streamflow and evapotranspiration from the high-resolution model and the difference induced by the two different spatial resolutions, with a focus on four seasonal extremes, selected based on temperature and precipitation. Results from the high-resolution model show that the intra-basin response covers a surprisingly large range of anomalies and show that it is not uncommon to have both extreme positive and negative flux anomalies occurring simultaneously within a catchment. The intra-basin response was grouped by land cover, where different dominant runoff-generating processes are driving the differences between these groups. The low-resolution model failed to capture the diverse and contrasting response from the high-resolution model, since neither the complex topography nor land cover classes were properly represented. DWD values show that, locally, the hydrological response simulated with a high-resolution model can be a lot more extreme than a low-resolution model might indicate, which has important implications for global or continental scale assessments carried out at coarse grids of 0.5∘×0.5∘ or 0.25∘×0.25∘ resolution.

scholarly journals Multidisciplinary characterisation of sedimentary processes in a recent maar lake (Lake Pavin, French Massif Central) and implication for natural hazards

2010 ◽  
Vol 10 (9) ◽  
pp. 1815-1827 ◽  
Author(s):  
E. Chapron ◽  
P. Albéric ◽  
D. Jézéquel ◽  
W. Versteeg ◽  
J.-L. Bourdier ◽  
...  
Keyword(s):  
Lacustrine Sediments ◽  
French Massif Central ◽  
Mass Wasting ◽  
Data Set ◽  
Massif Central ◽  
Volcanic Material ◽  
Deep Waters ◽  
Wide Range ◽  
Maar Lake ◽  
Lake Pavin

Abstract. Sedimentation processes occurring in the most recent maar lake of the French Massif Central (Lake Pavin) are documented for the first time based on high resolution seismic reflection and multibeam bathymetric surveys and by piston coring and radiocarbon dating on a sediment depocentre developed on a narrow sub aquatic plateau. This new data set confirms the mid Holocene age of maar lake Pavin formation at 6970±60 yrs cal BP and highlights a wide range of gravity reworking phenomena affecting the basin. In particular, a slump deposit dated between AD 580–640 remoulded both mid-Holocene lacustrine sediments, terrestrial plant debris and some volcanic material from the northern crater inner walls. Between AD 1200 and AD 1300, a large slide scar mapped at 50 m depth also affected the southern edge of the sub aquatic plateau, suggesting that these gas-rich biogenic sediments (laminated diatomite) are poorly stable. Although several triggering mechanisms can be proposed for these prehistoric sub-aquatic mass wasting deposits in Lake Pavin, we argue that such large remobilisation of gas-rich sediments may affect the gas stability in deep waters of meromictic maar lakes. This study highlights the need to further document mass wasting processes in maar lakes and their impacts on the generation of waves, favouring the development of dangerous (and potentially deadly) limnic eruptions.

Improving quality of care by obtaining patient-reported outcomes (PRO)-CTCAE chemotoxicities using tablet technology in daycare (DC) waiting rooms.

2014 ◽  
Vol 32 (30_suppl) ◽  
pp. 165-165 ◽  
Author(s):  
Tian Qi Wang ◽  
Catherine Brown ◽  
Ashlee Vennettilli ◽  
Lauren Wong ◽  
Aein Zarrin ◽  
...  
Keyword(s):  
Quality Of Care ◽  
Time Frame ◽  
Patient Reported Outcome ◽  
Waiting Room ◽  
Cross Sectional ◽  
Hematologic Cancer ◽  
Wide Range ◽  
Patient Reported ◽  
Age Range

165 Background: In a busy chemo DC, any efficient means of tracking important chemotoxicities can improve quality of care. The study goal was to evaluate whether tablet technology available in a DC waiting room is able to capture prevalent and severe toxicities associated with chemotherapy using the patient reported outcome (PRO) - common toxicity criteria for adverse events (CTCAE). Methods: This cross-sectional PRO-CTCAE study of 160 adult solid/hematologic cancer outpatients of all stages, who were undergoing chemotherapy (CT), focused on common chemotoxicities captured using touchscreen tablets in the DC waiting room of Princess Margaret Cancer Centre (Toronto, CA). Individual health scores from the EQ-5D VAS tool and the prevalence of AEs experienced by cancer patients within the past seven days were captured. Symptoms that were listed as moderate to very severe were considered significant. Results: Across a wide range of tumours and patients on intravenous CT, the median age (range) was 56 (19-88) years; 38% were males.Patients reported a median (range) health score (100 = best health possible, 0 = worst) of 70 (4-100). The severity offiveprevalent, key side-effects of CT were tabulated (Table). 59% of patients felt their fatigue interfered significantly with their daily activities, and 30% felt decreased appetite interfered significantly. 32% experienced nausea occasionally to almost constantly. Conclusions: The common symptoms of CT were captured FEASIBLY, and found to be highly prevalent in this CT-treated population. Capturing additional symptom prevalence outside of the 7-day time frame may be important from a clinical standpoint. Administration of PRO-CTCAE instrument through tablet technology may be an excellent method to help collect such data systematically and reliably. Updated data on 300 patients will be presented at the meeting. [Table: see text]

Functionalization of Nanomaterials utilizing Pulse Thermal Processing

2004 ◽  
Vol 853 ◽  
Author(s):  
Puja B. Kadolkar ◽  
Ronald D. Ott ◽  
Craig A. Blue ◽  
Adrian S. Sabau
Keyword(s):  
Thermal Processing ◽  
Thin Film Transistor ◽  
Single Pulse ◽  
Time Frame ◽  
High Density ◽  
Plasma Arc ◽  
Magnetic Media ◽  
Heating Rates ◽  
Wide Range ◽  
Media Applications

ABSTRACTPulse Thermal Processing (PTP) using a High Density Infrared (HDI) Plasma Arc Lamp has been investigated as an enabling manufacturing tool for processing nanomaterials and thin-films. HDI is a single source lamp that offers unique capabilities of processing broad areas with power densities approaching those of a laser. The extremely high radiant energies delivered by the plasma arc lamp provides heating rates approaching 600, 000°C/s through a single pulse on a millisecond time frame, thus allowing controlled diffusion on nano-meter scale. The ability to design the functionality of nanomaterials offers tremendous potential to exploit this technology for a wide range of applications based on nanotechnology. This present article discusses application of PTP using high-density plasma arc lamp to perform; a) phase transformation in FePt nanoparticle system for magnetic media applications, and b) crystallization of amorphous Si (a-Si) for photovoltaic and thin-film transistor (TFT) applications.

scholarly journals Concentration-discharge relationships vary among hydrological events, reflecting differences in event characteristics

2020 ◽  
Author(s):  
Julia L. A. Knapp ◽  
Jana von Freyberg ◽  
Bjørn Studer ◽  
Leonie Kiewiet ◽  
James W. Kirchner
Keyword(s):  
Trace Metals ◽  
Major Ions ◽  
Low Frequency ◽  
Solute Concentration ◽  
Biologically Active ◽  
Concentration Data ◽  
Event Scale ◽  
Wide Range ◽  
Insight Into

Abstract. Studying the response of streamwater chemistry to changes in discharge can provide valuable insights into how catchments store and release water and solutes. Previous studies have determined concentration-discharge (cQ) relationships from long-term, low-frequency data of a wide range of solutes. These analyses, however, provide little insight into the coupling of solute concentrations and flow during individual hydrologic events. Event-scale cQ relationships have rarely been investigated across a wide range of solutes and over extended periods of time, and thus little is known about differences and similarities between event-scale and long-term cQ relationships. Differences between event-scale and long-term cQ behavior may provide useful information about the processes regulating their transport through the landscape. Here we analyze cQ relationships of 14 different solutes, ranging from major ions to trace metals, as well as electrical conductivity, in the Swiss Erlenbach catchment. From a 2-year time series of sub-hourly solute concentration data we determined long-term cQ relationships for each solute and compared them to cQ relationships of 30 individual events. The long-term cQ behavior of groundwater-sourced solutes was representative of their cQ behavior during hydrologic events. Other solutes, however, exhibited very different cQ patterns at the event and long-term scale. This was particularly true for trace metals as well as atmospheric and/or biologically active solutes, many of which exhibited highly variable cQ behavior from one event to the next. Most of this inter-event variability in cQ behavior can be explained by factors such as catchment wetness, season, event size, input concentrations, and event-water contributions. We present an overview of the processes regulating different groups of solutes, depending on their origin in and pathways through the catchment. Our analysis thus provides insight into controls on solute variations at the hydrologic event scale.

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