scholarly journals Iodine chemistry in the chemistry-climate model SOCOL-AERv2-iodine

2021 ◽  
Author(s):  
Arseniy Karagodin-Doyennel ◽  
Eugene Rozanov ◽  
Timofei Sukhodolov ◽  
Tatiana Egorova ◽  
Alfonso Saiz-Lopez ◽  
...  
Keyword(s):  
Climate Model ◽  
Geographical Location ◽  
Lower Troposphere ◽  
Fold Increase ◽  
High Latitudes ◽  
Ozone Loss ◽  
Low Latitudes ◽  
Iodine Chemistry ◽  
Ozone Column ◽  
Good Agreement

Abstract. This paper introduces a new version of the chemistry-climate model SOCOL-AERv2, supplemented by an iodine chemistry module. We conducted three twenty-year-long ensemble experiments to assess the validity of modeled iodine and to quantify the effects of iodine on ozone. The obtained iodine distributions with SOCOL-AERv2-iodine show good agreement with the CAM-chem model simulations and AMAX-DOAS observations. For the present-day atmosphere, the model suggests the strongest influence of iodine in the lower stratosphere with an ozone loss of up to 30 ppbv at low latitudes and up to 100 ppbv at high latitudes. Globally averaged, the model suggests iodine-induced chemistry to result in an ozone column reduction of 3–4 %, maximizing at high latitudes. In the troposphere, iodine chemistry lowers tropospheric ozone concentrations by 5–10 % depending on the geographical location. We also determined the sensitivity of ozone to iodine applying a 2-fold increase of iodine emissions, which reduces the ozone column globally by an additional 1.5–2.5 %. We found that in the lower troposphere, the share of ozone loss induced by iodine originating from inorganic sources is 75 % and 25 % by iodine originating from organic sources, and contributions become similar at about 50 hPa. These results constrain the importance of atmospheric iodine chemistry for present and future conditions, even though uncertainties remain high due to the paucity of observational data of iodine species.

scholarly journals Iodine chemistry in the chemistry–climate model SOCOL-AERv2-I

2021 ◽  
Vol 14 (10) ◽  
pp. 6623-6645
Author(s):  
Arseniy Karagodin-Doyennel ◽  
Eugene Rozanov ◽  
Timofei Sukhodolov ◽  
Tatiana Egorova ◽  
Alfonso Saiz-Lopez ◽  
...  
Keyword(s):  
Lower Stratosphere ◽  
Climate Model ◽  
Geographical Location ◽  
Lower Troposphere ◽  
Fold Increase ◽  
High Latitudes ◽  
Iodine Species ◽  
Low Latitudes ◽  
Iodine Chemistry ◽  
Ozone Column

Abstract. In this paper, we present a new version of the chemistry–climate model SOCOL-AERv2 supplemented by an iodine chemistry module. We perform three 20-year ensemble experiments to assess the validity of the modeled iodine and to quantify the effects of iodine on ozone. The iodine distributions obtained with SOCOL-AERv2-I agree well with AMAX-DOAS observations and with CAM-chem model simulations. For the present-day atmosphere, the model suggests that the iodine-induced chemistry leads to a 3 %–4 % reduction in the ozone column, which is greatest at high latitudes. The model indicates the strongest influence of iodine in the lower stratosphere with 30 ppbv less ozone at low latitudes and up to 100 ppbv less at high latitudes. In the troposphere, the account of the iodine chemistry reduces the tropospheric ozone concentration by 5 %–10 % depending on geographical location. In the lower troposphere, 75 % of the modeled ozone reduction originates from inorganic sources of iodine, 25 % from organic sources of iodine. At 50 hPa, the results show that the impacts of iodine from both sources are comparable. Finally, we determine the sensitivity of ozone to iodine by applying a 2-fold increase in iodine emissions, as it might be representative for iodine by the end of this century. This reduces the ozone column globally by an additional 1.5 %–2.5 %. Our results demonstrate the sensitivity of atmospheric ozone to iodine chemistry for present and future conditions, but uncertainties remain high due to the paucity of observational data of iodine species.

The paleomagnetism of Huronian red beds and Nipissing diabase; Post-Huronian Igneous Events and apparent polar path for the interval −2300 to −1500 Ma for Laurentia

1976 ◽  
Vol 13 (6) ◽  
pp. 749-773 ◽  
Author(s):  
J. L. Roy ◽  
P. L. Lapointe
Keyword(s):  
High Stability ◽  
Vertical Axis ◽  
Time Range ◽  
High Latitudes ◽  
Red Beds ◽  
Two Stage ◽  
Low Latitudes ◽  
The Many ◽  
Age Determinations ◽  
Good Agreement

Thermal, chemical, and alternating field (and two-stage) cleaning treatments of Huronian sediments and Nipissing diabase (which intrudes the sediments) from the Cobalt area yield five directions of magnetizations (A–E) of high stability; A, B, C, and E are found in the sediments, and C, D, and E in the diabase. It is suggested that magnetization B (337°, +52°; α95 = 8°; pole 158 °E, 67 °N) was acquired shortly after deposition of the Firstbrook beds [Formula: see text]; magnetization C (259°, +82°; α95 = 5°; pole 258 °E, 42 °N), found in both the diabase and sediments in contact with the diabase, was acquired during cooling following emplacement of the diabase [Formula: see text]; and magnetizations D and E, yielding poles at 264 °E, 15 °S and 000°, 09 °N respectively, were produced during the Hudsonian orogeny (−1850 to −1700 Ma). This interpretation resolves the previous inconsistencies between poles and age determinations. Good agreement between results from the Nipissing diabase and other igneous bodies indicate that widespread igneous events occurred in the time range approximately −2200 to −2100 Ma, immediately following deposition of Huronian sediments. This is referred to as 'Post-Huronian Igneous Events'. A proposed apparent polar path relative to Laurentia shows two distinct motions; for the 2300–1850 Ma interval, a latitudinal change (roughly along longitude 250° E) from high [Formula: see text] to low [Formula: see text] latitudes and, for the 1850–1500 Ma interval, a displacement along the present-day equator with first an eastward motion to about 000° longitude followed by a westward motion to 240° E longitude; the apex of the eastward excursion is given a date of [Formula: see text]. It is possible that this reflects a rotation of Laurentia about a vertical axis at the time of and following the Hudsonian orogeny. Subsequent uplift and cooling would explain the many overprinted stable magnetizations yielding poles distributed along the equator (track 4). Latitude maps indicate that Laurentia was in high latitudes from 2200–2000 Ma and in intermediate to low latitudes from 1900–1500 Ma.

scholarly journals Estimation of Antarctic ozone loss from ground-based total column measurements

2010 ◽  
Vol 10 (14) ◽  
pp. 6569-6581 ◽  
Author(s):  
J. Kuttippurath ◽  
F. Goutail ◽  
J.-P. Pommereau ◽  
F. Lefèvre ◽  
H. K. Roscoe ◽  
...  
Keyword(s):  
Ozone Depletion ◽  
Sensitivity Study ◽  
Satellite Measurements ◽  
Macquarie Island ◽  
Ozone Loss ◽  
Antarctic Ozone ◽  
The Antarctic ◽  
Ozone Column ◽  
Total Column ◽  
Good Agreement

Abstract. The passive tracer method is used to estimate ozone loss from ground-based measurements in the Antarctic. A sensitivity study shows that the ozone depletion can be estimated within an accuracy of ~4%. The method is then applied to the ground-based observations from Arrival Heights, Belgrano, Concordia, Dumont d'Urville, Faraday, Halley, Marambio, Neumayer, Rothera, South Pole, Syowa, and Zhongshan for the diagnosis of ozone loss in the Antarctic. On average, the ten-day boxcar average of the vortex mean ozone column loss deduced from the ground-based stations was about 55±5% in 2005–2009. The ozone loss computed from the ground-based measurements is in very good agreement with those derived from satellite measurements (OMI and SCIAMACHY) and model simulations (REPROBUS and SLIMCAT), where the differences are within ±3–5%. The historical ground-based total ozone observations in October show that the depletion started in the late 1970s, reached a maximum in the early 1990s and stabilised afterwards due to saturation. There is no indication of ozone recovery yet. At southern mid-latitudes, a reduction of 20–50% is observed for a few days in October–November at the newly installed Rio Gallegos station. Similar depletion of ozone is also observed episodically during the vortex overpasses at Kerguelen in October–November and at Macquarie Island in July–August of the recent winters. This illustrates the significance of measurements at the edges of Antarctica.

RADIO STAR SCINTILLATIONS AND IONOSPHERIC DISTURBANCES

1959 ◽  
Vol 37 (10) ◽  
pp. 1137-1152 ◽  
Author(s):  
T. R. Hartz
Keyword(s):  
Geographical Location ◽  
Generation Mechanism ◽  
Upper Atmosphere ◽  
Ionospheric Disturbances ◽  
High Latitudes ◽  
General Belief ◽  
Auroral Activity ◽  
Middle Latitudes ◽  
Low Latitudes ◽  
Spread F

The generation mechanism for the ionization irregularities in the upper atmosphere which are responsible for radio star scintillations is considered. The general belief that scintillations are related to the spread-F phenomenon observed on ionosonde recordings is found to be an inadequate explanation for the scintillations at 53 Mc/s recorded at Ottawa. An examination of the Ottawa recordings shows that there is a definite association, both in time of occurrence and geographical location, with those ionospheric disturbances that are usually considered to be due to incoming solar particles. Since other workers at more southerly geomagnetic latitudes have associated their scintillation observations with the spread-F phenomenon which they consider to be independent of auroral activity, it would appear that two mechanisms, at least, are responsible for the radio star fluctuations: namely, the precipitation of solar corpuscles and a mechanism linked with the spread-F phenomenon. The former seems to predominate at high latitudes, the latter is probably predominant at low latitudes, while both mechanisms probably are operative in middle latitudes.

scholarly journals Sensitivity of remote aerosol distributions to representation of cloud-aerosol interactions in a global climate model

2013 ◽  
Vol 6 (1) ◽  
pp. 331-378 ◽  
Author(s):  
H. Wang ◽  
R. C. Easter ◽  
P. J. Rasch ◽  
M. Wang ◽  
X. Liu ◽  
...  
Keyword(s):  
Liquid Water ◽  
Climate Model ◽  
Global Climate Model ◽  
Fold Increase ◽  
Convective Transport ◽  
The Arctic ◽  
Cloud Base ◽  
High Latitudes ◽  
Upper Troposphere ◽  
Wet Removal

Abstract. Many global aerosol and climate models, including the widely used Community Atmosphere Model version 5 (CAM5), have large biases in predicting aerosols in remote regions such as upper troposphere and high latitudes. In this study, we conduct CAM5 sensitivity simulations to understand the role of key processes associated with aerosol transformation and wet removal affecting the vertical and horizontal long-range transport of aerosols to the remote regions. Improvements are made to processes that are currently not well represented in CAM5, which are guided by surface and aircraft measurements together with results from a multi-scale aerosol-climate model (PNNL-MMF) that explicitly represents convection and aerosol-cloud interactions at cloud-resolving scales. We pay particular attention to black carbon (BC) due to its importance in the Earth system and the availability of measurements. We introduce into CAM5 a new unified scheme for convective transport and aerosol wet removal with explicit aerosol activation above convective cloud base. This new implementation reduces the excessive BC aloft to better simulate observed BC profiles that show decreasing mixing ratios in the mid- to upper-troposphere. After implementing this new unified convective scheme, we examine wet removal of submicron aerosols that occurs primarily through cloud processes. The wet removal depends strongly on the sub-grid scale liquid cloud fraction and the rate of conversion of liquid water to precipitation. These processes lead to very strong wet removal of BC and other aerosols over mid- to high latitudes during winter months. With our improvements, the Arctic BC burden has a10-fold (5-fold) increase in the winter (summer) months, resulting in a much better simulation of the BC seasonal cycle as well. Arctic sulphate and other aerosol species also increase but to a lesser extent. An explicit treatment of BC aging with slower aging assumptions produces an additional 30-fold (5-fold) increase in the Arctic winter (summer) BC burden. This BC aging treatment, however, has minimal effect on other under-predicted species. Interestingly, our modifications to CAM5 that aim at improving prediction of high-latitude and upper tropospheric aerosols also produce much better aerosol optical depth over various other regions globally when compared to multi-year AERONET retrievals. The improved aerosol distributions have impacts on other aspects of CAM5, improving the simulation of global mean liquid water path and cloud forcing.

scholarly journals Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources

2012 ◽  
Vol 12 (3) ◽  
pp. 1423-1447 ◽  
Author(s):  
C. Ordóñez ◽  
J.-F. Lamarque ◽  
S. Tilmes ◽  
D. E. Kinnison ◽  
E. L. Atlas ◽  
...  
Keyword(s):  
Lower Stratosphere ◽  
Marine Boundary Layer ◽  
Climate Model ◽  
Heterogeneous Reactions ◽  
Model Description ◽  
Chl A ◽  
Tropical Oceans ◽  
Vertical Distributions ◽  
Iodine Chemistry ◽  
Good Agreement

Abstract. The global chemistry-climate model CAM-Chem has been extended to incorporate an expanded bromine and iodine chemistry scheme that includes natural oceanic sources of very short-lived (VSL) halocarbons, gas-phase photochemistry and heterogeneous reactions on aerosols. Ocean emissions of five VSL bromocarbons (CHBr3, CH2Br2, CH2BrCl, CHBrCl2, CHBr2Cl) and three VSL iodocarbons (CH2ICl, CH2IBr, CH2I2) have been parameterised by a biogenic chlorophyll-a (chl-a) dependent source in the tropical oceans (20° N–20° S). Constant oceanic fluxes with 2.5 coast-to-ocean emission ratios are separately imposed on four different latitudinal bands in the extratropics (20°–50° and above 50° in both hemispheres). Top-down emission estimates of bromocarbons have been derived using available measurements in the troposphere and lower stratosphere, while iodocarbons have been constrained with observations in the marine boundary layer (MBL). Emissions of CH3I are based on a previous inventory and the longer lived CH3Br is set to a surface mixing ratio boundary condition. The global oceanic emissions estimated for the most abundant VSL bromocarbons – 533 Gg yr−1 for CHBr3 and 67.3 Gg yr−1 for CH2Br2 – are within the range of previous estimates. Overall the latitudinal and vertical distributions of modelled bromocarbons are in good agreement with observations. Nevertheless, we identify some issues such as the reduced number of aircraft observations to validate models in the Southern Hemisphere, the overestimation of CH2Br2 in the upper troposphere – lower stratosphere and the underestimation of CH3I in the same region. Despite the difficulties involved in the global modelling of the shortest lived iodocarbons (CH2ICl, CH2IBr, CH2I2), modelled results are in good agreement with published observations in the MBL. Finally, sensitivity simulations show that knowledge of the diurnal emission cycle for these species, in particular for CH2I2, is key to assess their global source strength.

scholarly journals Stratospheric sudden warming effects on winds and temperature in the middle atmosphere at middle and low latitudes: a study using WACCM

2014 ◽  
Vol 32 (7) ◽  
pp. 859-874 ◽  
Author(s):  
A. Chandran ◽  
R. L. Collins
Keyword(s):  
Climate Model ◽  
Middle Atmosphere ◽  
Planetary Waves ◽  
Lower Latitude ◽  
High Latitudes ◽  
Mean Flow ◽  
Low Latitude ◽  
Quasi Biennial Oscillation ◽  
Stratospheric Sudden Warming ◽  
Low Latitudes

Abstract. A stratospheric sudden warming (SSW) is a dynamical phenomenon of the wintertime stratosphere caused by the interaction between planetary Rossby waves propagating from the troposphere and the stratospheric zonal-mean flow. While the effects of SSW events are seen predominantly in high latitudes, they can also produce significant changes in middle and low latitude temperature and winds. In this study we quantify the middle and low latitude effects of SSW events on temperature and zonal-mean winds using a composite of SSW events between 1988 and 2010 simulated with the specified dynamics version of the Whole Atmosphere Community Climate Model (WACCM). The temperature and wind responses seen in the tropics also extend into the low latitudes in the other hemisphere. There is variability in observed zonal-mean winds and temperature depending on the observing location within the displaced or split polar vortex and propagation direction of the planetary waves. The propagation of planetary waves show that they originate in mid–high latitudes and propagate upward and equatorward into the mid-latitude middle atmosphere where they produce westward forcing reaching peak values of ~ 60–70 m s−1 day−1. These propagation paths in the lower latitude stratosphere appear to depend on the phase of the quasi-biennial oscillation (QBO). During the easterly phase of the QBO, waves originating at high latitudes propagate across the equator, while in the westerly phase of the QBO, the planetary waves break at ~ 20–25° N and there is no propagation across the equator. The propagation of planetary waves across the equator during the easterly phase of the QBO reduces the tropical upwelling and poleward flow in the upper stratosphere.

scholarly journals Chemical contribution to future tropical ozone change in the lower stratosphere

2014 ◽  
Vol 14 (6) ◽  
pp. 2959-2971 ◽  
Author(s):  
S. Meul ◽  
U. Langematz ◽  
S. Oberländer ◽  
H. Garny ◽  
P. Jöckel
Keyword(s):  
Lower Stratosphere ◽  
Climate Model ◽  
Dominant Role ◽  
Ozone Production ◽  
Net Production ◽  
Future Evolution ◽  
Ozone Loss ◽  
The Future ◽  
Ozone Column

Abstract. The future evolution of tropical ozone in a changing climate is investigated by analysing time slice simulations made with the chemistry–climate model EMAC. Between the present and the end of the 21st century a significant increase in ozone is found globally for the upper stratosphere and the extratropical lower stratosphere, while in the tropical lower stratosphere ozone decreases significantly by up to 30%. Previous studies have shown that this decrease is connected to changes in tropical upwelling. Here the dominant role of transport for the future ozone decrease is confirmed, but it is found that in addition changes in chemical ozone production and destruction do contribute to the ozone changes in the tropical lower stratosphere. Between 50 and 30 hPa the dynamically induced ozone decrease of up to 22% is amplified by 11–19% due to a reduced ozone production. This is counteracted by a decrease in the ozone loss causing an ozone increase by 15–28%. At 70 hPa the large ozone decrease due to transport (−52%) is reduced by an enhanced photochemical ozone production (+28%) but slightly increased (−5%) due to an enhanced ozone loss. It is found that the increase in the ozone production in the lowermost stratosphere is mainly due to a transport induced decrease in the overlying ozone column while at higher altitudes the ozone production decreases as a consequence of a chemically induced increase in the overlying ozone column. The ozone increase that is attributed to changes in ozone loss between 50 and 30 hPa is mainly caused by a slowing of the ClOx and NOx loss cycles. The enhanced ozone destruction below 70 hPa can be attributed to an increased efficiency of the HOx loss cycle. The role of ozone transport in determining the ozone trend in this region is found to depend on the changes in the net production as a reduced net production also reduces the amount of ozone that can be transported within an air parcel.

scholarly journals Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources

2011 ◽  
Vol 11 (10) ◽  
pp. 27421-27474 ◽  
Author(s):  
C. Ordóñez ◽  
J.-F. Lamarque ◽  
S. Tilmes ◽  
D. E. Kinnison ◽  
E. L. Atlas ◽  
...  
Keyword(s):  
Lower Stratosphere ◽  
Marine Boundary Layer ◽  
Climate Model ◽  
Lower Boundary ◽  
Heterogeneous Reactions ◽  
Model Description ◽  
Lower Boundary Condition ◽  
Chl A ◽  
Iodine Chemistry ◽  
Good Agreement

Abstract. The global chemistry-climate model CAM-Chem has been extended to incorporate an expanded bromine and iodine chemistry scheme that includes natural oceanic sources of very short-lived (VSL) halocarbons, gas-phase photochemistry and heterogeneous reactions on aerosols. Ocean emissions of five VSL bromocarbons (CHBr3, CH2Br2, CH2BrCl, CHBrCl2, CHBr2Cl) and three VSL iodocarbons (CH2ICl, CH2IBr, CH2I2) have been parameterised by a biogenic chlorophyll-a (chl-a) dependent source in the tropical oceans (20° N–20° S) as well as constant oceanic fluxes with a 2.5 coast-to-ocean emission ratio for the extratropics (latitudinal bands 20°–50° and 50°–90° in both hemispheres). Top-down emission estimates of bromocarbons have been derived using available measurements in the troposphere and lower stratosphere, while iodocarbons have been constrained with observations in the marine boundary layer (MBL). Emissions of CH3I are based on a previous inventory and the longer lived CH3Br is set to a lower boundary condition. The global oceanic emissions estimated for the most abundant VSL bromocarbons – 533 Gg yr−1 for CHBr3 and 67.3 Gg yr−1 for CH2Br2 – are within the range of previous estimates. Overall the latitudinal and vertical distributions of modelled bromocarbons are in good agreement with observations. Nevertheless, we identify some issues such as the reduced number of aircraft observations to validate models in the Southern Hemisphere, the overestimation of CH2Br2 in the upper troposphere – lower stratosphere and the underestimation of CH3I in the same region. Despite the difficulties involved in the global modelling of the most short-lived iodocarbons (CH2ICl, CH2IBr, CH2I2), modelled results are in good agreement with published observations in the MBL. Finally, sensitivity simulations show that knowledge of the diurnal emission cycle for these species, in particular for CH2I2, is key to assess their global source strength.

scholarly journals Evaluation of ACCMIP ozone simulations using a multi-constituent chemical reanalysis

2016 ◽  
Author(s):  
Kazuyuki Miyazaki ◽  
Kevin Bowman
Keyword(s):  
Atmospheric Chemistry ◽  
Radiative Forcing ◽  
Climate Model ◽  
Lower Troposphere ◽  
Ensemble Mean ◽  
Systematic Biases ◽  
Intercomparison Project ◽  
The Tropics ◽  
Observational Record ◽  
Good Agreement

Abstract. The Atmospheric Chemistry Climate Model Intercomparison Project (ACCMIP) ensemble ozone simulations for the present-day are evaluated by a state-of-the-art multi-constituent atmospheric chemical reanalysis that ingests multiple satellite data including Tropospheric Emission Spectrometer (TES), Microwave Limb Sounder (MLS), Ozone Mapping Instrument (OMI), and the Measurements of Pollution in the Troposphere (MOPITT). Validation of the chemical reanalysis against global ozonesondes shows good agreement throughout the free troposphere and lower stratosphere for both seasonal and year-to-year variations, with an annual mean bias of less than 0.9 ppb in the middle and upper troposphere at the tropics and mid-latitudes. The model evaluation using the reanalysis reveals that the ensemble mean overestimates ozone in the northern extratropics by 6–11 ppb while underestimating by up to 18 ppb in the southern tropics over the Atlantic in the lower troposphere. Most models underestimate the spatial variability of the annual mean concentration in the extratropics of both hemispheres in the lower troposphere. The ensemble mean also underestimates the seasonal amplitude by 25–70 % in the NH extratropics and overestimates the inter-hemispheric gradient by about 30 % in the lower and middle troposphere. These differences are less evident with the current sonde network, which is shown to provide biased regional and monthly ozone statistics, especially in the tropics. These systematic biases have implications for ozone radiative forcing and the response of chemistry to climate that can be further quantified as the satellite observational record extends to multiple decades.

Sign in / Sign up

Export Citation Format

Share Document