scholarly journals CHEMICAL PROPERTIES OF PELLETS OF Pinus sp. TORREFIED IN A SCREW TYPE REACTOR

FLORESTA ◽  
2018 ◽  
Vol 48 (4) ◽  
pp. 493 ◽  
Author(s):  
Mateus Alves de Magalhães ◽  
Angélica De Cássia Oliveira Carneiro ◽  
Benedito Rocha Vital ◽  
Carlos Miguel Simões da Silva ◽  
Emylle Veloso Santos Costa ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Chemical Composition ◽  
Moisture Content ◽  
Fossil Fuels ◽  
Lignin Content ◽  
Chemical Properties ◽  
Type Reactor ◽  
Proportional Increase ◽  
The Times

The combination of pelletization and torrefaction allows for obtaining pellets with higher energetic density. Thus, biomass becomes more attractive and usable for energetic purposes, and therefore, knowing the chemical properties becomes important to guarantee the quality of the torrefied pellets for fuel. The objective of this study was to evaluate the effect of torrefaction of Pinus sp. pellets on their chemical properties. The wood was previously transformed into particles and dried to 16% moisture content for further pelleting. For the torrefaction, the pellets were dried to 0% moisture content and subjected to heat treatment in a screw type reactor at the temperatures of 210, 250, and 290 °C and the times of 10, 20, and 30 minutes. In order to determine the chemical properties, the structural chemical composition, immediate chemical composition, elemental composition, and thermogravimetric analysis were performed. The torrefaction promoted significant changes in the chemical properties of Pinus sp. pellets, especially regarding the proportional increase of carbon content in detriment to oxygen reduction, increase of the thermal stability, and proportional increase of the lignin content by the reduction of the hemicelluloses. This improves the energetic quality of the biomass and turns it into a more competitive fuel when compared to fossil fuels.

scholarly journals Effect of Saturated Steam Heat Treatment on Physical and Chemical Properties of Bamboo

Molecules ◽  
2020 ◽  
Vol 25 (8) ◽  
pp. 1999 ◽  
Author(s):  
Qiuyi Wang ◽  
Xinwu Wu ◽  
Chenglong Yuan ◽  
Zhichao Lou ◽  
Yanjun Li
Keyword(s):  
Heat Treatment ◽  
Moisture Content ◽  
Treatment Time ◽  
Flexural Modulus ◽  
Initial Moisture Content ◽  
Chemical Properties ◽  
Saturated Steam ◽  
Xrd Patterns ◽  
Physical And Chemical ◽  
Steam Heat

The aim of this study was to investigate the effects of the heat treatment time and initial moisture content of bamboo on the corresponding chemical composition, crystallinity, and mechanical properties after saturated steam heat treatment at 180 °C. The mechanism of saturated steam heat treatment of bamboo was revealed on the micro-level, providing a theoretical basis for the regulation of bamboo properties and the optimization of heat treatment process parameters. XRD patterns of the treated bamboo slices were basically the same. With the increase in the initial moisture content of bamboo, the crystallinity of bamboo increased first and then decreased after treatment. Due to the saturated steam heat treatment, the content of cellulose and lignin in bamboo slices increased while the content of hemicellulose decreased, but the content of cellulose in bamboo with a 40% initial moisture content increased first and then decreased. The shear strength of treated bamboo changed little within 10 min after saturated steam heat treatment, and then decreased rapidly. During the first 20 min with saturated steam heat treatment, the compressive strength, flexural strength, and flexural modulus of elasticity of the treated bamboo increased, and then decreased.

scholarly journals The nutritional quality of feedstuffs used in dairy goat nutrition in Vojvodina

2019 ◽  
Vol 35 (2) ◽  
pp. 163-178
Author(s):  
Snezana Paskas ◽  
Jelena Miocinovic ◽  
Branislav Vejnovic ◽  
Zsolt Becskei
Keyword(s):  
Chemical Composition ◽  
Medicago Sativa ◽  
Protein Content ◽  
Nutritional Quality ◽  
Lignin Content ◽  
Dairy Goat ◽  
Crude Fibre ◽  
Significant Difference ◽  
Medicago Sativa L

The study was to conduct to evaluate the chemical composition and nutritive values of feedstuffs (forages and concentrate mixtures) used for dairy goats nutrition in Vojvodina. Samples were collected from six farms, including one organic farm. The results showed that the relative feed values of analyzed forages were in the range of good, medium to lower quality. Average protein content from lowest to highest for investigated forages was: corn silage (Zea Mays) (65.37-82.57g kg??DM), alfalfa haylage (Medicago sativa L.) (159.99-184.17g kg??DM), pasture (185.30g kg?? DM), and alfalfa hay (Medicago sativa L.) (167.48-203.60g kg??DM). The non-fibre carbohydrates and protein content most varied in organic hay samples (cv: 29.25% and 19.09%, respectively). Generally, feedstuffs used in organic nutrition, including organic concentrate, were of lower nutritional quality and moreover contained higher amounts of crude fibre and lignin. Especially, a high source of variation was observed in investigated concentrate mixtures for the crude protein content (p<0.0001), ranged from 135.32 to 209.87g kg??DM. Corn silages also varied substantially in their chemical composition and significant difference (p<0.05) was observed in regard to acid detergent fibre (ADF) and lignin content (ranged: ADF: 242.20-319.24g kg??DM; ADL: 27.98-52.54g kg??DM, respectively). Furthermore, pasture contained the most soluble materials during May and June and their content was related inversely to crude fibre amount. This survey highlights that investigated farms still pay insufficient attention to the quality of the feedstuff. For the development of intensive goat farming, greater emphasis should be placed on using higher quality feedstuffs, as well, standards for feed quality must be considered and established.

scholarly journals Development of Black Pepper Rotary Drum Dryer System

2020 ◽  
Vol 12 (7) ◽  
Author(s):  
Ana Sakura Zainal Abidin ◽  
◽  
Mohamad Zulhatta Kifli ◽  
Annisa Jamali ◽  
Rasli Muslimen ◽  
...  
Keyword(s):  
Moisture Content ◽  
Heating Temperature ◽  
Chemical Properties ◽  
Practical Method ◽  
Black Pepper ◽  
Drying Time ◽  
Final Weight ◽  
Rotary Drum ◽  
Current Weight

Rotary drum dryer has been identified as hygienic and practical method to dry black pepper. The quality of black pepper is defined based on the chemical properties and moisture content. This research aims to develop a control system for black pepper rotary drum dryer. The dried pepper should meet the specific 12% moisture content while the heating temperature must be kept below 550C. The requirement of 12% moisture content is equivalent to 30% of the remaining weight of the pepper (final weight). The developed system uses Arduino Mega 2560 REV board as a microcontroller. A type K thermocouple with MAX6675 thermocouple amplifier and S-type load cells (TAS501) with HX711 load cell amplifier are used as input sensor to microcontroller. The system keeps measuring the current weight until it hit the targeted final weight. Two set of experiments that are using 500 g and 1500 g of pre-treated pepper were conducted to verify the system. As a result, the dryer was successful to work within the desired temperature and it stop operating just after the samples reached 12% of the moisture content. The finding has proven a shorten of drying time from 4 to 7 days when using the traditional method to the current 3 – 5 hours only when using the developed system. Hence, this is an improved method achieved to a quick drying of the black pepper.

scholarly journals Characteristics and Influence to Fruit Distillates Quality of Rapid Induction of Ageing Character in the Presence of Mulberry Tree (Morus alba L.) Wooden Chips

2016 ◽  
Vol 73 (2) ◽  
pp. 165
Author(s):  
Elena MUDURA ◽  
Teodora COLDEA ◽  
Timea HORVATH ◽  
Carmen Rodica POP
Keyword(s):  
Heat Treatment ◽  
Chemical Composition ◽  
Volatile Compounds ◽  
Control Sample ◽  
Polyphenolic Compounds ◽  
Chemical Parameters ◽  
Rapid Induction ◽  
Factors Influencing ◽  
Mulberry Tree

Research on rapid induction of ageing character to double distilled traditional fruit brandies, from Transylvania region was conducted. Mulberry tree chips were used as an alternative to traditional ageing in wooden barrels. The aim of this study was to highlight the factors influencing the chemical composition of fruit brandies, both depending on the type of the wood used and the transformations occurred during the heat treatment. Fruit distillates were produced after the traditional method – double distillation in copper alambic. The evaluation of the brandies consisted in analyzing the chemical parameters and the phenolic compounds after two months of ageing with wood chips. Results were compared with a control sample (unaged distillate), and found that during the ageing process volatile and non-volatile compounds were extracted significantly. The heat treatment influenced the chemical composition of the wooden chips. The chemical composition of finished products varied due to the composition of the wooden chips used and to the heat treatment applied. Evaluation of volatile and non-volatile compounds formed was carried out by comparison with the samples of the unaged distillate. It was demonstrated the improvement of chemical characteristics and polyphenolic compounds content, by rapidly inducing of the ageing character.

scholarly journals Calorific Power Improvement of Wood by Heat Treatment and Its Relation to Chemical Composition

Energies ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 5322
Author(s):  
Idalina Domingos ◽  
Umit Ayata ◽  
José Ferreira ◽  
Luisa Cruz-Lopes ◽  
Ali Sen ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Chemical Composition ◽  
Lignin Content ◽  
Treated Wood ◽  
Untreated Wood ◽  
High Heating Value ◽  
Heat Treated ◽  
Positive Linear Correlation ◽  
Total Extractives ◽  
Calorific Power

Chemical composition influences the calorific power of wood, mainly due to the calorific power of structural compounds and extractives. Heat treatment changes the chemical composition of treated wood. This work studies the relationship between chemical composition and calorific power improvement by heat treatment. Samples were heat-treated by the ThermoWood process ® for 1 h and 2 h. High heating value (HHV) and chemical composition; lignin, cellulose, hemicelluloses and extractives in dichloromethane, ethanol, and water were determined. The HHV of untreated wood ranged between 18.54–19.92 MJ/kg and increased with heat treatment for all the tested species. A positive linear correlation was found between HHV and Klason lignin (R2 = 0.60). A negative trend was observed for holocellulose, cellulose, and hemicelluloses content against HHV, but with low determination coefficients for linear regression. The best adjust for polysaccharides was found for hemicelluloses content. A positive correlation could be found for dichloromethane extractives (R2 = 0.04). The same was obtained in relation to ethanol extractives with R2 = 0.20. For water and total extractives, no clear positive or negative trends could be achieved. The results showed that the HHV of wood increased with heat treatment and that this increase was mainly due to the increase in lignin content.

scholarly journals Heat Processing and Change of Proper Indicators of Basalts

Land Science ◽  
2020 ◽  
Vol 2 (2) ◽  
pp. p1
Author(s):  
Rashidova R K ◽  
Kurbanov Abdirakhim Ahmedovich ◽  
Aliyev T ◽  
Jiyanov A B ◽  
Turdieva O J ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Chemical Composition ◽  
Raw Materials ◽  
Practical Interest ◽  
Heat Processing ◽  
High Quality ◽  
Mineral Raw Materials ◽  
Different Color ◽  
Basalt Rock

This paper presents the results of the analysis of the quality of basalts, their heat treatment and studies of changes in the chemical composition of basalts, which leads to a change in the external color of partially processed basalt raw materials (hereinafter referred to as semi-finished product). The results of a study of purified basalt from slime, impurities and hydroxides, changes in the chemical composition of basalt rock are presented. The prospects of heat treatment of a semi-finished product and obtaining multi-colored products from mineral raw materials is shown. It was found that the optimal firing temperature of the semi-finished product, the possible options for changing the external color and the criterion points of the thermal effect at which the basalt semi-finished product changes the external shade. These statements are of great scientific and practical interest in the fact that during the heat treatment of a semifinished product, basalt easily overheats and gradually acquires a different color, which occurs to a liquids temperature and allows the future to plan to obtain high-quality multi-colored products from basalts, for example, products for design.

scholarly journals LOW-MELTING UNFRITTED GLAZE IN THE MATERIALS SYSTEM "QUARTZ SAND-ULEXIT-SODA-FELVESPATCH CONCENTRATE

2021 ◽  
Vol 6 (9) ◽  
pp. 87-96
Author(s):  
V. Onishchuk ◽  
S. Ageeva ◽  
E. Doroganov
Keyword(s):  
Chemical Composition ◽  
Quartz Sand ◽  
Raw Materials ◽  
Glassy State ◽  
Chemical Properties ◽  
Chemical Compositions ◽  
Fundamental Possibility ◽  
Feldspar Concentrate ◽  
Optimal Values

The article presents the results of studies aimed at establishing the possibility of obtaining low-melting nephritized glazes for majolica with a glass transition temperature of not more than 1000 ° C in the system of materials "quartz sand - ulexite - soda - feldspar concentrate". A rational choice of raw materials will ensure the production of slips that are able to maintain their design chemical composition during the application of majolica to the shard, therefore, provide the specified chemical composition of the glaze and contribute to obtaining the required physical, mechanical and chemical properties of the glaze layer. The design of the material compositions of the charges and the chemical compositions of the glaze coatings was carried out using the mathematical planning of the experiment, which significantly reduced the time and material costs for research. The parameters that determine the quality of slips and glaze coatings have been established, their most optimal values have been identified, which ensure the production of acceptable glaze coatings, and the ways to optimize work in the studied direction have been determined. As a result, the fundamental possibility of obtaining low-melting nephritized glazes in the system of materials "quartz sand - ulexite - soda - feldspar concentrate, capable of transforming into a glassy state at temperatures not exceeding 1000 ºC, has been proved.

scholarly journals Comparison of colors, microstructure, chemical composition and thermal properties of bamboo fibers and parenchyma cells with heat treatment

2021 ◽  
Vol 67 (1) ◽  
Author(s):  
Jieyu Wu ◽  
Tuhua Zhong ◽  
Wenfu Zhang ◽  
Jiangjing Shi ◽  
Benhua Fei ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Thermal Properties ◽  
Chemical Composition ◽  
Lignin Content ◽  
Treatment Temperature ◽  
Composition Analysis ◽  
Chemical Compositions ◽  
Cellulose Content ◽  
Parenchyma Cells ◽  
Bamboo Fibers

AbstractThe effects of heat treatment at various temperatures on mechanically separated bamboo fibers and parenchyma cells were examined in terms of color, microstructure, chemical composition, crystallinity, and thermal properties. The heat-treated parenchyma cells and fibers were characterized by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), chemical composition analysis, and thermogravimetric analysis (TGA). The results revealed that the colors of bamboo fibers and parenchyma cells were darkened as treatment temperature increased. The microstructure of the treated fibers and parenchyma cells slightly changed, yet the shape of starch granules in parenchyma cells markedly altered at a temperature of above 160 °C. The chemical compositions varied depending on the heat treatment temperature. When treated at 220 °C, the cellulose content was almost unchanged in fibers but increased by 15% in parenchyma cells; the hemicellulose content decreased and the lignin content increased regardless of fibers and parenchyma cells. The cellulose crystal structure was nearly unaffected by heat treatment, but the cellulose crystallinity of fibers changed more pronouncedly than that of parenchyma cells. The thermal stability of parenchyma cells after heat treatment was affected more substantially compared to fibers.

An Experimental Study on Temperature in Ultrasonic Vibration-Assisted Pelleting of Cellulosic Biomass

2010 ◽  
Author(s):  
Q. Feng ◽  
W. L. Cong ◽  
M. Zhang ◽  
Z. J. Pei ◽  
C. Z. Ren
Keyword(s):  
Experimental Study ◽  
Experimental Investigation ◽  
Moisture Content ◽  
Ultrasonic Vibration ◽  
Fossil Fuels ◽  
Cellulosic Biomass ◽  
Ultrasonic Power ◽  
Cellulosic Biofuels ◽  
Transportation Fuel

As one of the near-to-mid-term alternatives to fossil fuels, cellulosic biofuels can cut greenhouse gas emissions while continuing to meet liquid transportation fuel needs. By processing cellulosic biomass into pellets, density and handling efficiency of cellulosic feedstocks will be improved, resulting in a reduction in transportation and handling costs in biofuel manufacturing. Temperature of biomass during the pelleting process can affect the quality of the pellet. But effects of pelleting variables on biomass temperature during ultrasonic vibration-assisted (UV-A) pelleting are still unknown. This paper reports an experimental investigation on temperature of biomass in UV-A pelleting. It studies the effects of moisture content of the biomass and pelleting variables (ultrasonic power, tool travel distance, and feedrate). The results will be helpful in understanding the effects of ultrasonic vibration on biomass temperature, compaction mechanism, and biofuel conversion.

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