scholarly journals The Teena Zn-Pb Deposit (McArthur Basin, Australia). Part II: Carbonate Replacement Sulfide Mineralization During Burial Diagenesis—Implications for Mineral Exploration

2021 ◽  
Author(s):  
J. M. Magnall ◽  
N. Hayward ◽  
S. A. Gleeson ◽  
A. Schleicher ◽  
I. Dalrymple ◽  
...  

Abstract The Teena Zn-Pb deposit is located in the Carpentaria Zn Province (Australia), which contains some of the largest clastic dominant (CD-type) massive sulfide Zn-Pb deposits in the world. The timing of the main stage of hydrothermal sulfide mineralization in the Teena subbasin is constrained to the midstage of burial diagenesis, during a period of short-lived regional extension. To distinguish hydrothermal alteration from spatially and temporally overlapping burial diagenetic alteration, and to establish the primary controls on hydrothermal mass transfer, it is necessary to evaluate the various foot- and hanging-wall alteration assemblages that formed between early- (eogenesis) and late- (mesogenesis) stage diagenesis. To achieve this, we have statistically evaluated a large lithogeochemistry dataset (n >2,500) and selected a subset (n = 65) of representative samples for detailed mineralogical (X-ray diffraction, illite crystallinity) and petrographic (scanning electron microscopy) analyses; hyperspectral core imaging data were then used to upscale key paragenetic observations. We show that sulfide mineralization was predated by multiple diagenetic alteration assemblages, including stratiform pyrite, dolomite nodules and cement, disseminated hematite and authigenic K-feldspar. These assemblages formed during eogenesis in multiple subbasins across the broader McArthur Basin and are not part of the synmineralization alteration footprint. Whereas pyrite and dolomite formed primarily from the in situ degradation of organic matter, feldspar authigenesis was the product of K metasomatism that was focused along permeable coarse-grained volcaniclastic sandstone beds within the host-rock sequence. The immature volcaniclastic input is broadly representative of the siliciclastic compositional end member in the subbasin, which formed the protolith for phyllosilicate (illite, phengite, chlorite) formation during burial diagenesis. There is no evidence of extensive phyllosilicate alteration in any of the geochemical, mineralogical (illite crystallinity), or petrographic datasets, despite some evidence of K-feldspar replacement by sphalerite in the Lower and Main mineralized lenses. Rather, the high Zn grades formed via dolomite replacement, which is resolvable from a chemical mass balance analysis and consistent with petrographic observations. There are significant exploration implications associated with carbonate-replacement sulfide mineralization during mesogenesis: (1) the capacity for secondary porosity generation in the host rock is as important as its sulfate-reducing capacity; (2) hydrothermal mineralization has a short-range cryptic lateral and vertical synmineralization alteration footprint due to acid neutralization by a carbonate-rich protolith; and (3) the distribution and chemistry of premineralization phases (e.g., pyrite, dolomite nodules) cannot be directly related to the mineralization footprint, which is localized to the 4th-order subbasin scale. Future exploration for this deposit style should therefore be focused on identifying units that contain a mixture of organic carbon and carbonate in the protolith, at favorable stratigraphic redox boundaries, and proximal to feeder growth faults.

Solid Earth ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 211-223 ◽  
Author(s):  
Emilie Janots ◽  
Alexis Grand'Homme ◽  
Matthias Bernet ◽  
Damien Guillaume ◽  
Edwin Gnos ◽  
...  

Abstract. A multi-method investigation into Lauzière granite, located in the external Belledonne massif of the French Alps, reveals unusually hot hydrothermal conditions in vertical open fractures (Alpine-type clefts). The host-rock granite shows sub-vertical mylonitic microstructures and partial retrogression at temperatures of < 400 ∘C during Alpine tectonometamorphism. Novel zircon fission-track (ZFT) data in the granite give ages at 16.3 ± 1.9 and 14.3 ± 1.6 Ma, confirming that Alpine metamorphism was high enough to reset the pre-Alpine cooling ages and that the Lauzière granite had already cooled below 240–280 ∘C and was exhumed to < 10 km at that time. Novel microthermometric data and chemical compositions of fluid inclusions obtained on millimetric monazite and on quartz crystals from the same cleft indicate early precipitation of monazite from a hot fluid at T > 410 ∘C, followed by a main stage of quartz growth at 300–320 ∘C and 1.5–2.2 kbar. Previous Th-Pb dating of cleft monazite at 12.4 ± 0.1 Ma clearly indicates that this hot fluid infiltration took place significantly later than the peak of the Alpine metamorphism. Advective heating due to the hot fluid flow caused resetting of fission tracks in zircon in the cleft hanging wall, with a ZFT age at 10.3 ± 1.0 Ma. The results attest to the highly dynamic fluid pathways, allowing the circulation of deep mid-crustal fluids, 150–250 ∘C hotter than the host rock, which affect the thermal regime only at the wall rock of the Alpine-type cleft. Such advective heating may impact the ZFT data and represent a pitfall for exhumation rate reconstructions in areas affected by hydrothermal fluid flow.


Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 195 ◽  
Author(s):  
Wenheng Liu ◽  
Xiaodong Liu ◽  
Jiayong Pan ◽  
Kaixing Wang ◽  
Gang Wang ◽  
...  

The Qingshanbao complex, part of the uranium metallogenic belt of the Longshou-Qilian mountains, is located in the center of the Longshou Mountain next to the Jiling complex that hosts a number of U deposits. However, little research has been conducted in this area. In order to investigate the origin and formation of mafic enclaves observed in the Qingshanbao body and the implications for magmatic-tectonic dynamics, we systematically studied the mineralogy, petrography, and geochemistry of these enclaves. Our results showed that the enclaves contain plagioclase enwrapped by early dark minerals. These enclaves also showed round quartz crystals and acicular apatite in association with the plagioclase. Electron probe analyses showed that the plagioclase in the host rocks (such as K-feldspar granite, adamellite, granodiorite, etc.) show normal zoning, while the plagioclase in the mafic enclaves has a discontinuous rim composition and shows instances of reverse zoning. Major elemental geochemistry revealed that the mafic enclaves belong to the calc-alkaline rocks that are rich in titanium, iron, aluminum, and depleted in silica, while the host rocks are calc-alkaline to alkaline rocks with enrichment in silica. On Harker diagrams, SiO2 contents are negatively correlated with all major oxides but K2O. Both the mafic enclaves and host rock are rich in large ion lithophile elements such as Rb and K, as well as elements such as La, Nd, and Sm, and relatively poor in high field strength elements such as Nb, Ta, P, Ti, and U. Element ratios of Nb/La, Rb/Sr, and Nb/Ta indicate that the mafic enclaves were formed by the mixing of mafic and felsic magma. In terms of rare earth elements, both the mafic enclaves and the host rock show right-inclined trends with similar weak to medium degrees of negative Eu anomaly and with no obvious Ce anomaly. Zircon LA-ICP-MS (Laser ablation inductively coupled plasma mass spectrometry) U-Pb concordant ages of the mafic enclaves and host rock were determined to be 431.8 5.2 Ma (MSWD (mean standard weighted deviation)= 1.5, n = 14) and 432.8 4.2 Ma (MSWD = 1.7, n = 16), respectively, consistent with that for the zircon U-Pb ages of the granite and medium-coarse grained K-feldspar granites of the Qingshanbao complex. The estimated ages coincide with the timing of the late Caledonian collision of the Alashan Block. This comprehensive analysis allowed us to conclude that the mafic enclaves in the Qingshanbao complex were formed by the mixing of crust-mantle magma with mantle-derived magma due to underplating, which caused partial melting of the ancient basement crust during the collisional orogenesis between the Alashan Block and Qilian rock mass in the early Silurian Period.


2021 ◽  
Author(s):  
Bojan Otoničar

The studied palaeokarst corresponds to an uplifted peripheral foreland bulge when Upper Cretaceous diagenetically immature eugenetic carbonates were subaerially exposed, karstified and subsequently overlain by upper Paleocene/lower Eocene palustrine limestone. Among the subsurface paleokarstic features, both vadose and phreatic forms occur.  The phreatic caves/cavities include features characteristic of the mixing zone speleogenesis at the interface between freshwater (brackish water) lenses and the underlying seawater. They were found in various positions with respect to the paleokarstic surface, the deepest being about 75 m below the surface. Three indistinct horizons of cavities/caves and intermediate vugs were recognized. Subsequently, all cavities were completely filled with detrital sediments and speleothems in the phreatic and vadose zones. In general, the phreatic cavities of the lower two horizons are geopetally filled with mudstone derived from incomplete dissolution of the host rock and overlain by coarse-grained, blocky calcite. Shallower below the paleokarst surface, a large phreatic cave of the third horizon is filled with flowstone overlain by reddish micritic carbonate sediment with intercalated calcite rafts. In the upper part of the cave, sediments derived from the paleokarst surface are gradually becoming more abundant. Vadose channels, which may also intersect the cave sediments, are mainly filled with "pedogenic" material derived from the paleokarst surface. Immediately prior to marine transgression over the paleokarst surface, some cavities were filled with marine-derived microturbidites. In general, the diversity of cave fills and the amount of surface material decrease with distance from the paleokarst surface. Below the paleokarst surface, the δ13C and δ18O values of a host rock and cavity deposits show good correlation with trends significant for meteoric diagenesis. It is shown that deposits associated with phreatic caves can be of great importance for the study of the speleogenetic, geomorphological and hydrogeological evolution of certain palaeokarst regions.


2021 ◽  
Vol 91 (9) ◽  
pp. 945-968
Author(s):  
Karen E. Higgs ◽  
Stuart Munday ◽  
Anne Forbes ◽  
Karsten F. Kroeger

ABSTRACT Paleocene sandstones in the Kupe Field of Taranaki Basin, New Zealand, are subdivided into two diagenetic zones, an upper kaolinite–siderite (K-S) zone and a lower chlorite–smectite (Ch-Sm) zone. Petrographic observations show that the K-S zone has formed from diagenetic alteration of earlier-formed Ch-Sm sandstones, whereby biotite and chlorite–smectite have been altered to form kaolinite and siderite, and plagioclase has reacted to form kaolinite and quartz. These diagenetic zones can be difficult to discriminate from downhole bulk-rock geochemistry, which is largely due to a change in element-mineral affinities without a wholesale change in element abundance. However, some elements have proven useful for delimiting the diagenetic zones, particularly Ca and Na, where much lower abundances in the K-S zone are interpreted to represent removal of labile elements during diagenesis. Multivariate analysis has also proven an effective method of distinguishing the diagenetic zones by highlighting elemental affinities that are interpreted to represent the principal diagenetic phases. These include Fe-Mg-Mn (siderite) in the K-S zone, and Ca-Mn (calcite) and Fe-Mg-Ti-Y-Sc-V (biotite and chlorite–smectite) in the Ch-Sm zone. Results from this study demonstrate that the base of the K-S zone approximately corresponds to the base of the current hydrocarbon column. An assessment with 1D basin models and published stable-isotope data show that K-S diagenesis is likely to have occurred during deep-burial diagenesis in the last 4 Myr. Modeling predicts that CO2-rich fluids were generating from thermal decarboxylation of intraformational Paleocene coals at this time, and accumulation of high partial pressures of intraformational CO2 in the hydrocarbon column is considered a viable catalyst for the diagenetic reactions. Variable CO2 concentrations and residence times are interpreted to be the reason for different levels of K-S diagenesis, which is supported by a clear relationship between the presence or absence of a well-developed K-S zone and the present-day reservoir-corrected CO2 content.


2020 ◽  
Vol 191 ◽  
pp. 11
Author(s):  
Marilou de Vals ◽  
Renaldo Gastineau ◽  
Amélie Perrier ◽  
Romain Rubi ◽  
Isabelle Moretti

The choice of stones by the ancient Greeks to build edifices remains an open question. If the use of local materials seems generalized, allochthonous stones are usually also present but lead to obvious extra costs. The current work aims to have an exhaustive view of the origins of the stones used in the Sanctuary of Delphi. Located on the Parnassus zone, on the hanging wall of a large normal fault related to the Corinth Rift, this Apollo Sanctuary is mainly built of limestones, breccia, marbles, as well as more recent poorly consolidated sediments generally called pôros in the literature. To overpass this global view, the different lithologies employed in the archaeological site have been identified, as well as the local quarries, in order to find their origins. The different limestones are autochthons and come from the Upper Jurassic – Cretaceous carbonate platform of the Tethys Ocean involved in the Hellenides orogen. Those limestones of the Parnassus Massif constitute the majority of the rock volume in the site; a specific facies of Maastrichtian limestone called “Profitis Ilias limestone” has been used for the more prestigious edifices such as the Apollo Temple. The corresponding ancient quarry is located few kilometers west of the sanctuary. Then, slope breccia has been largely used in the sanctuary: it crops out in and around the site and is laying on top of the carbonates. Finally, the pôros appear to be very variable and seven different facies have been documented, including travertine, oolitic grainstone, marine carbonates and coarse-grained sandstones. All these recent facies exist in the south-east shore of the Gulf of Corinth, although – except for the grainstone – the quarries are not yet known.


Clay Minerals ◽  
2000 ◽  
Vol 35 (1) ◽  
pp. 227-237 ◽  
Author(s):  
R. E. A. Midtbø ◽  
J. M. Rykkje ◽  
M. Ramm

AbstractThe Tarbert Formation on a north±south oriented structure along the eastern flank of the Viking Graben has been studied. The reservoir in the two wells studied is buried ~100 m deeper in the northern than in the southern well. The present reservoir temperature is ~130°C. The reservoir quality is good, but due to extensive illitization of kaolin, the northern well shows lower permeability values than the southern well, for similar porosity values. The initial composition of the analysed samples in the two wells is very similar. There are no significant differences in total clay content and both wells contain K-feldspars and kaolin. However, the diagenetic alteration is more advanced in the deeper well. Total porosity is about the same in both wells but, due to illitization, the ratio of micro- vs. macro-porosity is higher in the deeper well. Petroleum emplacement in the structure occurred in two phases: oil emplacement predates, whereas gas emplacement postdates, most of the quartz cementation. In the deeper well, illitization occurred after gas emplacement.


1993 ◽  
Vol 130 (5) ◽  
pp. 613-620 ◽  
Author(s):  
R. J. Merriman ◽  
T. C. Pharaoh ◽  
N. H. Woodcock ◽  
P. Daly

AbstractWhite mica (illite) crystallinity data, derived mostly from borehole samples, have been used to generate a contoured metamorphic map of the concealed Caledonide fold belt of eastern England and the foreland formed by the Midlands Microcraton. The northern subcrop of the fold belt is characterized by epizonal phyllites and quartzites of possible Cambrian age, whereas anchizonal grades characterize Silurian to Lower Devonian strata of the Anglian Basin in the southern subcrop of the fold belt. Regional metamorphism in the Anglian Basin resulted from deep burial and Acadian deformation beneath a possible overburden of 7 km, assuming a metamorphic field gradient of 36 °C km-1. Late Proterozoic volcaniclastic rocks forming the basement of the microcraton show anchizonal to epizonal grades that probably developed during late Avalonian metamorphism. Cambrian to Tremadoc strata, showing late diagenetic alteration, rest on the basement with varying degrees of metamorphic discordance. During early Palaeozoic times, much of the microcraton was a region of slow subsidence with overburden thicknesses of 3.3–5.5 km. However, concealed Tremadoc strata in the northeast of the microcraton reach anchizonal grades and may have been buried to depths of 7 km beneath an overburden of uncertain age.


Geosites ◽  
2019 ◽  
Vol 1 ◽  
pp. 1-6
Author(s):  
Robert Biek

The Sevier fault is spectacularly displayed on the north side of Utah Highway 12 at the entrance to Red Canyon, where it offsets a 500,000-year-old basaltic lava flow. The fault is one of several active, major faults that break apart the western margin of the Colorado Plateau in southwestern Utah. The Sevier fault is a “normal” fault, a type of fault that forms during extension of the earth’s crust, where one side of the fault moves down relative to the other side. In this case, the down-dropped side (the hanging wall) is west of the fault; the upthrown side (the footwall) lies to the east. The contrasting colors of rocks across the fault make the fault stand out in vivid detail. Immediately south of Red Canyon, the 5-million-year-old Rock Canyon lava flow, which erupted on the eastern slope of the Markagunt Plateau, flowed eastward and crossed the fault (which at the time juxtaposed non-resistant fan alluvium against coarse-grained volcaniclastic deposits) (Biek and others, 2015). The flow is now offset 775 to 1130 feet (235-345 m) along the main strand of the fault, yielding an anomalously low vertical slip rate of about 0.05 mm/yr (Lund and others, 2008). However, this eastern branch of the Sevier fault accounts for only part of the total displacement on the fault zone. A concealed, down-to-the-west fault is present west of coarse-grained volcaniclastic strata at the base of the Claron cliffs. Seismic reflection data indicate that the total displacement on the fault zone in this area is about 3000 feet (900 m) (Lundin, 1987, 1989; Davis, 1999).


Clay Minerals ◽  
1986 ◽  
Vol 21 (4) ◽  
pp. 537-564 ◽  
Author(s):  
D. J. Stewart

AbstractThe diagenetic history of the Upper Jurassic Fulmar Formation of the Central North Sea is described with emphasis on the Fulmar Field. The Fulmar Formation was deposited on a variably subsiding shallow-marine shelf under the influence of halokinetic and fault movements. The sediments are extensively bio-destratified although large-scale cross-bedding is locally preserved. The dominant mechanism of deposition is thought to have been storm-generated currents. Soft-sediment deformation structures are common and are attributed to syn- and post-depositional dewatering of the sandstones. The dewatering was associated with fractures and shear zones which reflect tectonic instability resulting from periodic salt withdrawal and/or graben fault movements. The dewatering may have been initiated by repacking of the sediments during earth movements or by the gradual build-up and sudden release of overpressures due to compaction and/or clay mineral dehydration during rapid burial at the end of the Cretaceous. The formation is composed of arkosic sandstone of similar composition to Triassic sandstones from which it was probably derived. The sandstones also contain limited amounts of marine biogenic debris including sponge solenasters, bivalve shells, rare ammonites and belemnites. Initial diagenesis began with an environment-related phase during which quartz and feldspar overgrowths and chalcedony and calcite cements were precipitated. These cements appear to form concretions adjacent to local concentrations of sponge debris and shell debris, respectively, and were disturbed after their formation by fracturing and dewatering. This was followed by an early burial stage of diagenesis which resulted in extensive dolomite cementation and minor clay mineral authigenesis (illite and chlorite). The last phase of mineral growth was probably pyrite. During early burial diagenesis, secondary porosity after feldspar and/or carbonate was produced, although the exact timing is not clear. The lack of both stylolitic developments and extensive illitization indicates that the late burial diagenesis stage was never reached, although sufficient clay diagenesis occurred to destroy all traces of mixed-layer illite-smectite (present in some shallower wells). The main control on reservoir behaviour is primary depositional fabric. Diagenesis only overprints these controls. Locally-cemented fracture sets act as baffles to fluid flow, but they are not extensive and the reservoir acts as one unit.


Geology ◽  
2019 ◽  
Vol 47 (12) ◽  
pp. 1181-1184 ◽  
Author(s):  
Rosine Riera ◽  
Julien Bourget ◽  
Victorien Paumard ◽  
Moyra E.J. Wilson ◽  
Jeffrey Shragge ◽  
...  

Abstract Recognition of seismic unconformities is crucial for interpreting basin history from seismic reflection data sets in both siliciclastic and carbonate settings. While it is well established that non-erosional changes in sedimentary facies can create seismic reflections that mimic seismic unconformities (i.e., pseudo-unconformities), these features are generally considered to be localized and uncommon, and, therefore, are largely overlooked during interpretation. Diagenetic alteration of strata can also affect the morphology of seismic reflectors and mislead seismic interpreters. This study is based on a three-dimensional (3-D) seismic data set and documents a 400 km2 honeycomb structure (HS) masquerading as a regional erosional unconformity in the Oligocene–Miocene carbonate strata of Australia’s North West Shelf. This HS is located at the transition between the topsets and the foresets of clinoforms of carbonate to marly composition. The HS expression in 3-D seismic data cross sections is irregular, giving the HS the appearance of a truncated surface that could erroneously be interpreted as a regional seismic unconformity. Closer examination reveals that the HS crosscuts chronostratigraphic clinoform reflectors, and frequency extraction processing shows that the HS dominantly falls within a lower-frequency band than the clinoform reflectors. The morphology of the HS (i.e., continuous with densely packed cells) and its time-transgressive nature suggest that it has a burial diagenetic origin. This suggests that creation of pseudo-unconformities at basin scale by burial diagenesis may lead to surface misidentification, with negative consequences for paleoenvironmental studies and petroleum exploration activities.


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