scholarly journals Effect of Using Urea Formaldehyde Modified with Extracts in Plywood on Formaldehyde Emission

2021 ◽  
Vol 72 (3) ◽  
pp. 237-244
Author(s):  
Ugur Bilgin ◽  
Gursel Colakoglu
Keyword(s):  
Lung Cancer ◽  
Shear Strength ◽  
Urea Formaldehyde ◽  
Formaldehyde Emission ◽  
Corylus Avellana ◽  
Bark Extract ◽  
Advantages And Disadvantages ◽  
Ulmus Glabra ◽  
Forestry Industry ◽  
Bonding Shear Strength

Formaldehyde-based adhesives are used in the forestry industry. This is because formaldehyde is inexpensive, easy to use and resistant to moisture; it also has particular mechanical effects. Formaldehyde has both advantages and disadvantages. It is known that various diseases such as lung cancer occur in humans as a result of the release of formaldehyde into the air during and after board production. In this study, a urea formaldehyde glue mixture was prepared by using four different fillers (extract of maritime pine (Pinus pinaster) and elm (Ulmus glabra) bark, extract of hazelnut (Corylus avellana) husk and acorn tannins) at two different ratios. The bonding shear strength of pine (Pinus sylvestris) and spruce (Picea orientalis) plywood produced with urea formaldehyde adhesive was tested according to EN 314-1 standard. All plywood, except the plywood with acorn tannin, met the requirements of the standard. A formaldehyde emission test of the plywood was carried out in accordance with EN 713-3 standard. With this approach, it is possible to quickly determine formaldehyde emissions. Experimental results were obtained for subsequent measurements, including chamber tests. It was observed that the elm bark extract reduced the formaldehyde emission of pine plywood by 40 %, while other fillers reduced it by 3-37 %.

scholarly journals Urea Formaldehyde Resin Resultant Plywood with Rapid Formaldehyde Release Modified by Tunnel-Structured Sepiolite

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1286 ◽  
Author(s):  
Li ◽  
Gao ◽  
Xia ◽  
Li ◽  
Zhou
Keyword(s):  
Shear Strength ◽  
Fracture Surface ◽  
Cross Section ◽  
Urea Formaldehyde ◽  
Formaldehyde Emission ◽  
Formaldehyde Resin ◽  
Tunnel Structure ◽  
Formaldehyde Release ◽  
Uf Resin ◽  
The Cost

In order to reduce the cost of plywood and save edible resources (wheat flour), a cheap and resourceful clay, sepiolite, was used to modify urea formaldehyde (UF) resin. The performances of filler-filled UF resins were characterized by measuring the thermal behavior, cross section, and functional groups. Results showed that cured UF resin with SEP (sepiolite) formed a toughened fracture surface, and the wet shear strength of the resultant plywood was maximum improved by 31.4%. The tunnel structure of SEP was beneficial to the releasing of formaldehyde, as a result, the formaldehyde emission of the plywood bonded by UF resin with SEP declined by 43.7% compared to that without SEP. This study provided a new idea to reduce the formaldehyde emission, i.e. accelerating formaldehyde release before the product is put into use.

scholarly journals Cellulose sludge and wood bark as formaldehyde scavengers for plywood bonded with urea formaldehyde resin

2017 ◽  
Vol 6 (4) ◽  
pp. 187-193
Author(s):  
Смидракова ◽  
Mariya Smidrakova ◽  
Седлячик ◽  
Yan Sedlyachek
Keyword(s):  
Shear Strength ◽  
Urea Formaldehyde ◽  
Formaldehyde Emission ◽  
Adhesive Joints ◽  
Urea Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Spruce Bark ◽  
Wood Bark

The aim of the research was to modify urea-formaldehyde resin (UF) by cellulose sludge and wood bark in order to reduce formaldehyde emission. Wood bark powder was a mixture containing 50 % of beech bark and 50 % of spruce bark. Release of formaldehyde and shear strength of the adhesive joints was tested on five resp. three-layer alder plywood. Formaldehyde emission was determined by 24-hour desiccator method and monitored during seven weeks after gluing. After 7 weeks of the experiment the reference UF adhesive showed formaldehyde emission decreased by 39 %.

scholarly journals Effect of waste rubber powder as filler for plywood application

2015 ◽  
Vol 17 (1) ◽  
pp. 41-47 ◽  
Author(s):  
Huei Ruey Ong ◽  
Maksudur R. Khan ◽  
Abu Yousuf ◽  
Nitthiyah Jeyaratnam ◽  
D.M. Reddy Prasad
Keyword(s):  
Shear Strength ◽  
Chemical Interaction ◽  
Inorganic Compounds ◽  
Urea Formaldehyde ◽  
Chemical Properties ◽  
Formaldehyde Emission ◽  
Wood Adhesive ◽  
Rubber Powder ◽  
Waste Rubber ◽  
Waste Rubber Powder

Abstract The study investigated the suitability of waste rubber powder (WRP) use as filler in adhesive formulation for plywood application. Melamine Urea Formaldehyde (MUF) was employed as resin for formulating the wood adhesive. To improve chemical properties and bonding quality of adhesive, WRP was treated by different chemicals like 20% nitric acid, 30% hydrogen peroxide and acetone solution. The treated WRP were analysed by XRD and it showed that inorganic compounds were removed and carbon was remained as major component under the treatment of 20% HNO3. The treatment improved the mechanical properties like shear strength and formaldehyde emission of plywood (high shear strength and low formaldehyde emission). The physico-chemical interaction between the wood, resin and filler was investigated using fourier transform infrared spectroscopic (FTIR) technique and the interactions among N-H of MUF and C=O of wood and WRP were identified. The morphology of wood-adhesive interface was studied by field emission scanning electron microscope (FESEM) and light microscope (LM). It showed that the penetration of adhesives and fillers through the wood pores was responsible for mechanical interlocking. Therefore, chemically treated WRP proved its potential use as filler in MUF based adhesive for making plywood.

scholarly journals Effects of moisture content on lap-shear, bending, and tensile strength of lap-jointed and finger-jointed southern pine using phenol resorcinol formaldehyde and melamine urea formaldehyde

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 3534-3544 ◽  
Author(s):  
Jian Liu ◽  
Kong Yue ◽  
Feng Wang ◽  
Jinhao Wu ◽  
Zhongqiu Tang ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Shear Strength ◽  
Bending Strength ◽  
Urea Formaldehyde ◽  
Southern Pine ◽  
Resorcinol Formaldehyde ◽  
Bonding Performance ◽  
Lap Shear ◽  
Bonding Shear Strength ◽  
Shear Bending

The bonding performance of the phenol-resorcinol-formaldehyde adhesive (PRF) and melamine-urea-formaldehyde adhesive (MUF) with southern pine as substrates at various moisture contents (MC) was evaluated. The results showed that bonding shear strength with MUF and PRF was negatively related to wood MC, and bonding shear strength with MUF was higher than that of the PRF. The bending and tensile strengths of finger-jointed lumber decreased with wood MC. The bending strength of finger-jointed lumber was affected more by wood than adhesive. However, both wood and adhesive exhibited the same important contribution to the tensile strength.

scholarly journals Formaldehyde Emission in Micron-Sized Wollastonite-Treated Plywood Bonded with Soy Flour and Urea-Formaldehyde Resin

2020 ◽  
Vol 10 (19) ◽  
pp. 6709 ◽  
Author(s):  
Hamid R. Taghiyari ◽  
Seyed Behzad Hosseini ◽  
Saman Ghahri ◽  
Mohammad Ghofrani ◽  
Antonios N. Papadopoulos
Keyword(s):  
Shear Strength ◽  
Urea Formaldehyde ◽  
Physical And Mechanical Properties ◽  
Formaldehyde Emission ◽  
Weight Basis ◽  
Soy Flour ◽  
Formaldehyde Resin ◽  
Negative Effects ◽  
Wet Weight ◽  
Different Content

Soy flour was partly substituted for urea-formaldehyde (UF) resin with different content to investigate its effect on formaldehyde emission in three-layer plywood panels. In each square meter of panels, 300 g of resin was used (wet weight basis of resin). Micron-sized wollastonite was added to the resin mixture at 5% and 10% consumption levels (wet weight basis of resin) to determine its potential effects as a reinforcing filler to mitigate the negative effects of addition of soy flour. Results showed a decreasing trend in formaldehyde emission as soy flour content increased to 20%. The highest shear-strength values were observed in panels with 10% and 15% soy flour content. The addition of wollastonite did not have a significant effect on formaldehyde emission, but it decreased the shear strength in soy-treated panels, although the values were still higher than those of control panels. Wollastonite significantly mitigated the negative effects of soy flour on the water absorption and thickness swelling of panels. It was concluded that 10% of soy flour and 5% of wollastonite provided the lowest formaldehyde emission and the most optimum physical and mechanical properties.

scholarly journals Utilization of Birch Bark as an Eco-Friendly Filler in Urea-Formaldehyde Adhesives for Plywood Manufacturing

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 511
Author(s):  
Roman Réh ◽  
Ľuboš Krišťák ◽  
Ján Sedliačik ◽  
Pavlo Bekhta ◽  
Monika Božiková ◽  
...  
Keyword(s):  
Bending Strength ◽  
Urea Formaldehyde ◽  
Formaldehyde Emission ◽  
Birch Bark ◽  
Gravimetric Analysis ◽  
European Standard ◽  
Scanning Calorimetry ◽  
Wood Processing ◽  
Fagus Sylvatica L ◽  
Positive Effect

The potential of using ground birch (Betula verrucosa Ehrh.) bark as an eco-friendly additive in urea-formaldehyde (UF) adhesives for plywood manufacturing was investigated in this work. Five-ply plywood panels were fabricated in the laboratory from beech (Fagus sylvatica L.) veneers bonded with UF adhesive formulations comprising three addition levels of birch bark (BB) as a filler (10%, 15%, and 20%). Two UF resin formulations filled with 10% and 20% wheat flour (WF) were used as reference samples. The mechanical properties (bending strength, modulus of elasticity and shear strength) of the laboratory-fabricated plywood panels, bonded with the addition of BB in the adhesive mixture, were evaluated and compared with the European standard requirements (EN 310 and EN 314-2). The mechanical strength of the plywood with the addition of BB in the adhesive mixture is acceptable and met the European standard requirements. Markedly, the positive effect of BB in the UF adhesive mixture on the reduction of formaldehyde emission from plywood panels was also confirmed. Initially, the most significant decrease in formaldehyde release (up to 14%) was measured for the plywood sample, produced with 15% BB. After four weeks, the decrease in formaldehyde was estimated up to 51% for the sample manufactured with 20% BB. The performed differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and derivative thermogravimetry (DTG), also confirmed the findings of the study. As this research demonstrated, BB as a waste or by-product of wood processing industry, can be efficiently utilized as an environmentally friendly, inexpensive alternative to WF as a filler in UF adhesive formulations for plywood manufacturing.

scholarly journals Improved strength properties of LVL glued using PVAc adhesives with physical treatment-based Rubberwood (Hevea brasiliensis)

2020 ◽  
Vol 5 (1) ◽  
pp. 711-725
Author(s):  
Sutrisno ◽  
Eka Mulya Alamsyah ◽  
Ginanjar Gumilar ◽  
Takashi Tanaka ◽  
Masaaki Yamada
Keyword(s):  
Shear Strength ◽  
Hevea Brasiliensis ◽  
Formaldehyde Emission ◽  
Strength Properties ◽  
Modulus Of Rupture ◽  
Horizontal Shear ◽  
Physical Treatment ◽  
Cold Pressing ◽  
Laminated Veneer Lumber ◽  
Pressing Time

AbstractThe properties of the laminated veneer lumber (LVL) composed of the boiled veneer of Rubberwood (Hevea brasiliensis) using polyvinyl acetate (PVAc) adhesives in various cold-pressing time and various conditioned time with loaded and unloaded were studied. Five-ply LVL was produced by boiling veneer at 100°C for 90 min as pretreatment and cold-pressing time at 12 kgf cm−2 for 1.5, 6, 18, and 24 h then conditioned at 20°C and 65% relative humidity (RH) with loaded (12 kgf cm−2) and unloaded for 7 days as physical treatment. Especially for the delamination test, the specimens were immersed at 70 ± 3°C for 2 h and dried in the oven at 60 ± 3°C for 24 h; then, the specimens were solidified at room temperature (20°C and 65% RH) with loaded (12 kgf cm−2) and unloaded for 7, 10, 12, and 14 days. To determine the performance of LVL, the density, moisture content (MC), delamination, modulus of elasticity (MOE), modulus of rupture (MOR), horizontal shear strength, and formaldehyde emission tests were conducted according to the Japanese Agricultural Standard (JAS 2008) for structural LVL. The MOE and MOR values were significantly influenced by the physical treatment, however, neither to horizontal shear strength nor to formaldehyde emission. The best performance of LVL has resulted from unloaded LVL with cold-pressed time for 18 h; the MOE and MOR values were 9,345.05 ± 141.61 N mm−2 and 80.67 ± 1.77 N mm−2, respectively. The best value of the horizontal shear strength was obtained from the LVL with 18 h cold-pressing time and conditioned with loaded (13.10 ± 1.47 N mm−2) and unloaded (12.23 ± 1.36 N mm−2). The percentage of delamination values decreased with an increase in the cold-pressing time and conditioning time. The lowest value of delamination (19.06%) was obtained from the LVL with 24 h cold-pressing time and conditioned with loaded for 14 days. Except the delamination test, all other properties fulfilled the JAS.

Tensile shear strength of UF- and MUF-bonded veneer related to data of adhesives and cell walls measured by nanoindentation

Holzforschung ◽  
2010 ◽  
Vol 64 (3) ◽  
Author(s):  
Frank Stöckel ◽  
Johannes Konnerth ◽  
Wolfgang Kantner ◽  
Johann Moser ◽  
Wolfgang Gindl
Keyword(s):  
Mechanical Properties ◽  
Shear Strength ◽  
Bond Strength ◽  
Cell Walls ◽  
Urea Formaldehyde ◽  
Lap Joints ◽  
Tensile Shear Strength ◽  
Tensile Shear ◽  
Interphase Cell ◽  
Cure Time

Abstract The tensile shear strength of veneer lap joints was characterised. The joints were produced with an Automated Bonding Evaluation System (ABES) using urea-formaldehyde (UF) as well as melamine-urea-formaldehyde (MUF) adhesive formulated for particleboard production. At a fixed heating temperature of 110°C, a systematic increase in bond strength was observed for both adhesives with increasing cure time. The absolute bond strength was significantly higher for MUF compared to UF. Nanoindentation experiments with the same specimens used for ABES revealed a very hard, stiff and brittle character of the UF resin, whereas the MUF proved significantly less hard and stiff, and less brit-tle. Wood cell walls in contact with adhesive, i.e., where adhesive penetration into the cell wall was assumed, showed significantly altered mechanical properties. Such cell walls were harder, stiffer and more brittle than unaffected reference cell walls. These effects were slightly more pronounced for UF than for MUF. Comparing UF and MUF, the micro-mechanical properties of cured adhesive and interphase cell walls confirm earlier observations that tougher adhesives can lead to higher macroscopic bond strength. In strong contrast to that, no obvious correlation was found between micromechanical properties and the strong cure time dependence of macroscopic bond strength.

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