Improved glucose recovery from durian peel by alkaline-catalyzed steam pretreatment

Durian (Durio zibethinus Murr.) peel, as agricultural waste, is a potential under-utilized lignocellulosic biomass that is sufficiently available in Thailand. In this study, durian peel from monthong (D. zibethinus Murr. cv. Monthong) and chanee (D.zibethinus Murr. cv. Chanee) were subjected to pretreatment with sodium hydroxide (NaOH) under autoclaving conditions to improve glucose recovery. The effect of NaOH concentration (1%, 2%, 3%, and 4%) and autoclave temperature (110 °C, 120 °C, and 130 °C) was investigated based on the amount of glucose recovered. The optimal NaOH concentration and autoclave temperature were determined to be 2% and 110 °C, respectively, under which maximum glucose (36% and 35% in monthong and chanee peels, respectively) was recovered. Glucose recovery was improved by about 6-fold at the optimal pretreatment condition for both pretreated monthong and chanee when compared to the untreated durian peels. Scanning electron microscopy (SEM) showed great changes to the surface morphology of pretreated durian peel from the two cultivars. X-ray diffraction (XRD) analysis also revealed a rise in cellulose crystallinity index (CrIs) after pretreatment. A combination of mild NaOH concentration and autoclaving is a very effective pretreatment technique for maximum glucose recovery from durian peel.

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Development of Ternary Concrete Utilizing Agricultural Waste Material

10.21203/rs.3.rs-1107515/v1 ◽

2022 ◽

Author(s):

Sunita Kumari ◽

Dhirendra Singhal ◽

Rinku Walia ◽

Ajay Rathee

Keyword(s):

Rice Husk ◽

Rice Husk Ash ◽

Agricultural Waste ◽

Xrd Analysis ◽

Sem Analysis ◽

X Ray Diffraction ◽

X Ray ◽

Concrete Mix ◽

Maize Cob

Abstract The present project proposes to utilize rice husk and maize cob husk ash in the cement to mitigate the adverse impact of cement on environment and to enhance the disposal of waste in a sustainable manner. Ternary concrete / MR concrete was prepared by using rise husk and maize cob ash with cement. For the present project, five concrete mixes MR-0 (Control mix), MR-1 (Rice husk ash 10% and MR-2.5%), MR-2 (Rice husk ash 10% and MR-5%), MR-3 (Rice husk ash 10% and MR-2.5%), MR-4 (Rice husk ash 10% and MR-2.5%) were prepared. M35 concrete mix was designed as per IS 10262:2009 for low slump values 0-25mm. The purpose is to find the optimum replacement level of cement in M35 grade ternary concrete for I – Shaped paver blocks.In order to study the effects of these additions, micro-structural and structural properties test of concretes have been conducted. The crystalline properties of control mix and modified concrete are analyzed by Fourier Transform Infrared Spectroscope (FTIR), Scanning Electron Microscopy (SEM), and X-Ray Diffraction (XRD). The results indicated that 10% Rice husk ash and 5% maize cob ash replaced with cement produce a desirable quality of ternary concrete mix having good compressive strength. The results of SEM analysis indicated that the morphology of both concrete were different, showing porous structure at 7 days age and become unsymmetrical with the addition of ashes. After 28 day age, the control mix contained more quantity of ettringite and became denser than ternary concrete. XRD analysis revealed the presence of portlandite in large quantity in controlled mix concrete while MR concrete had the partially hydrated particle of alite.

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Utilization of Rice Husk Cellulose as a Magnetic Nanoparticle Biocomposite Fiber Source for the Absorption of Manganese (Mn2+) Ions in Peat Water

Jurnal Kimia Sains dan Aplikasi ◽

10.14710/jksa.22.6.220-226 ◽

2019 ◽

Vol 22 (6) ◽

pp. 220-226 ◽

Cited By ~ 2

Author(s):

Emil Zacky Effendi ◽

Yudhi Christian Hariady ◽

Muhammad Daffa Salaahuddin ◽

Chairul Irawan ◽

Iryanti Fatyasari Nata

Keyword(s):

Rice Husk ◽

Magnetic Nanoparticle ◽

Agricultural Waste ◽

Crystallinity Index ◽

Total Suspended Solid ◽

Xrd Analysis ◽

Suspended Solid ◽

Silica Content ◽

Amino Group ◽

X Ray Diffraction

Rice husk (RH) is an agricultural waste that contains cellulose. Rice husk fiber (RHF) can be used as a source of fiber in the manufacture of magnetic nanoparticle biocomposite. The purpose of this study is to synthesize and characterize magnetic nanoparticle biocomposite used as an adsorbent and evaluate its performance on the adsorption of Mn2+ ions and Total Suspended Solid (TSS) in peat water. Rice husk fiber was delignified to eliminate lignin levels. Furthermore, the biocomposite was made through the solvothermal method with and without the addition of hexanediamine. The products produced are two types of adsorbents, namely magnetic nanoparticle biocomposite with an amino group (RHB-MH) and rice husk fiber biocomposite without an amino group (RHB-M). These biocomposites were used to adsorb Mn2+ ions in peat water. Evaluations were carried out at pH 5, 6, 7, and 8 with an optimum adsorption time of 60 minutes. The solutions at the time of adsorption were evaluated to determine the optimum conditions of the adsorption process carried out. The observation of magnetic nanoparticle biocomposite based on the analysis of Scanning Electron Microscopy (SEM) shows magnetic nanoparticles formed on the surface of rice husk fiber with a diameter of 30-50 nm. X-Ray Diffraction (XRD) analysis showed that the delignification of rice husk increased Crystallinity Index (CrI) by 64.98% and reduced silica content by 78%. Fourier Transform Infra-Red (FT-IR) spectrometer show absorption peak at 570 cm-1 for Fe-O bonds and Fe3O4 peak around 1627 cm−1, indicating the presence of N-H bending. The optimum condition for Mn2+ adsorption was achieved at pH 5 and 60-minutes duration with an adsorption capacity of 54.7 mg/g and 190.78 mg/g for RHB-M and RHB-MH. The TSS reduction achieved the effectiveness of 60.2% and 90.3% for BSP-M and BSP-MH, respectively.

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Experimental Investigation of Surface Modified Abaca Fibre

Materials Science Forum ◽

10.4028/www.scientific.net/msf.978.291 ◽

2020 ◽

Vol 978 ◽

pp. 291-295 ◽

Cited By ~ 2

Author(s):

Agnivesh Kumar Sinha ◽

Harendra Kumar Narang ◽

Somnath Bhattacharya

Keyword(s):

Polymer Composites ◽

Amorphous Materials ◽

Crystallinity Index ◽

Surface Modifications ◽

Xrd Analysis ◽

Natural Fibres ◽

Ftir Analysis ◽

X Ray Diffraction ◽

X Ray ◽

Surface Modified

Natural fibres have gained popularity due to their use in fabrication of biodegradable polymer composites which are not only non-polluting but are also light weight and inexpensive. Abaca fibres are known for their remarkable properties for which their polymer composites are used in automotive applications. However, hydrophilicity and compatibility with polymer matrices are the two major drawbacks of natural fibres which restrict their use as reinforcements in polymer composites. Therefore, present study deals with the surface modifications of abaca fibre using potassium permanganate and sodium hydroxide solutions to enhance crystallinity and reduce hydrophilicity of abaca fibres. Further, the surfaces of untreated and treated fibre were investigated with the help of Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis. Surface treatment of abaca fibre led to the removal of unwanted wax, and other amorphous materials which was confirmed through FTIR analysis. Crystallinity index was found to be 57%, 59% and 61% for untreated, NaOH treated and KMnO4 treated abaca fibre respectively.

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An Improved Method to Extract Crystalline Cellulose from Alternatives Sources

Defect and Diffusion Forum ◽

10.4028/www.scientific.net/ddf.371.128 ◽

2017 ◽

Vol 371 ◽

pp. 128-130

Author(s):

M. Sánchez ◽

Mauro Cesar Terence ◽

Juan Alfredo Guevara Carrió

Keyword(s):

Diffraction Method ◽

Crystallinity Index ◽

Crystalline Cellulose ◽

Cellulose Crystallinity ◽

Improved Method ◽

X Ray Diffraction ◽

Waste Wood ◽

X Ray ◽

Alternative Sources ◽

High Cellulose

Crystalline cellulose can be obtained from alternative sources like waste wood by hydrolysis with hydrochloric or sulfuric acid. In this study we report a process for producing crystals with high cellulose crystallinity index of approximately 82%. We chose to work with eucalyptus FSC certified as a way to ensure the reproducibility of experiments. Said wood samples were subjected to acid hydrolysis with nitric acid. The resulting mass was dried out and measured by the X-ray diffraction method.

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SYNTHESIS OF WOUND-HEALING KERATIN HYDROGELS USING CHICKEN FEATHERS PROTEINS AND ITS PROPERTIES

International Journal of Pharmacy and Pharmaceutical Sciences ◽

10.22159/ijpps.2017v9i2.15620 ◽

2017 ◽

Vol 9 (2) ◽

pp. 171 ◽

Cited By ~ 8

Author(s):

Priyaah Kumaran ◽

Arun Gupta ◽

Swati Sharma

Keyword(s):

Wound Healing ◽

Wound Care ◽

Aloe Vera ◽

Crystallinity Index ◽

Xrd Analysis ◽

Solid Content ◽

Chicken Feather ◽

X Ray Diffraction ◽

X Ray ◽

Chicken Feathers

Objective: A novel cross-linked keratin hydrogel was prepared by integrating keratin from chicken feather into an aloe-vera, Chitosan and honey based dressing formulation separately.Methods: Keratin fibres extracted from chicken feathers are eco-friendly, non-abrasive, biodegradable, insoluble in organic solvents and having good mechanical properties, hydrophobic behaviour, low density and finally cheap. Keratin based hydrogels were prepared with five types of ingredients and studied for their wound healing properties. The analysis of keratin-based hydrogel was done by Fourier Transform Infra-red Spectroscopy (FTIR) and X-ray diffraction (XRD) analysis.Results: Keratinocytes containing keratin travel from the wound border to initiate the process of healing. The characteristics of keratin-based hydrogel derived from chicken feather made it an effective wound care therapeutic product. X-ray diffraction (XRD) analysis showed the crystallinity index in between 30-50% of the hydrogen.Conclusion: The test for swelling and solubility were carried out on the hydrogen to determine the solid content and water absorbance capacity. Overall, this product is safe to use as an effective wound healing product with appropriate properties.

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Fermentable Sugar Production from the Peels of Two Durian (Durio zibethinus Murr.) Cultivars by Phosphoric Acid Pretreatment

Resources ◽

10.3390/resources7040060 ◽

2018 ◽

Vol 7 (4) ◽

pp. 60 ◽

Cited By ~ 5

Author(s):

Abraham Obeng ◽

Duangporn Premjet ◽

Siripong Premjet

Keyword(s):

Enzymatic Hydrolysis ◽

Phosphoric Acid ◽

Glucose Concentration ◽

Crystallinity Index ◽

Xrd Analysis ◽

X Ray Diffraction ◽

Acid Pretreatment ◽

Durio Zibethinus ◽

Hydrolysis Process ◽

Acid Soluble Lignin

The potential of durian (Durio zibethinus Murr.) peel as feedstock for the production of fermentable sugars was evaluated. Durian peel biomass from two cultivars, monthong (Durio zibethinus Murr. cv. Monthong) and chanee (Durio zibethinus Murr. cv. Chanee), were pretreated with different concentrations (70%, 75%, 80%, and 85%) of phosphoric acid (H3PO4) at a moderate temperature of 60 °C for 60 min. The H3PO4-pretreated durian peel biomass was then subjected to enzymatic hydrolysis. Significantly higher glucan (44.74 ± 0.21%) content was observed in the monthong peel compared to the chanee peel (42.06 ± 0.28%). Phosphoric acid pretreatment caused the significant solubilization of the xylan and acid soluble lignin (ASL) contents. This enhanced the enzymatic hydrolysis process causing a significant increase in the hydrolysis efficiency and glucose concentration. The highest hydrolysis efficiency and glucose concentration were obtained after 72 h from the 75% H3PO4-pretreated peel biomass for both the monthong (90.33 ± 0.42% and 9.55 ± 0.11 g/L, respectively) and chanee (90.06 ± 0.40% and 8.56 ± 0.13 g/L, respectively) peels. Biomass to glucose recovery for monthong and chanee were improved by approximately 7- and 6-fold, respectively. The scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis showed destruction of the peel biomass structure and changes in the cellulose crystallinity index (CrIs).

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Use of Chènevotte, a Valuable Co-Product of Industrial Hemp Fiber, as Adsorbent for Pollutant Removal. Part I: Chemical, Microscopic, Spectroscopic and Thermogravimetric Characterization of Raw and Modified Samples

Molecules ◽

10.3390/molecules26154574 ◽

2021 ◽

Vol 26 (15) ◽

pp. 4574

Author(s):

Chiara Mongioví ◽

Dario Lacalamita ◽

Nadia Morin-Crini ◽

Xavier Gabrion ◽

Aleksandra Ivanovska ◽

...

Keyword(s):

Crystallinity Index ◽

Xrd Analysis ◽

Pollutant Removal ◽

X Ray Diffraction ◽

Hemp Fiber ◽

X Ray ◽

Agricultural Cooperative ◽

Composition And Structure ◽

Industrial Hemp ◽

The Impact

FINEAU (2021–2024) is a trans-disciplinary research project involving French, Serbian, Italian, Portuguese and Romanian colleagues, a French agricultural cooperative and two surface-treatment industries, intending to propose chènevotte, a co-product of the hemp industry, as an adsorbent for the removal of pollutants from polycontaminated wastewater. The first objective of FINEAU was to prepare and characterize chènevotte-based materials. In this study, the impact of water washing and treatments (KOH, Na2CO3 and H3PO4) on the composition and structure of chènevotte (also called hemp shives) was evaluated using chemical analysis, X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, X-ray computed nanotomography (nano-CT), attenuated total reflectance–Fourier transform infrared (ATR-FTIR) spectroscopy, solid state NMR spectroscopy and thermogravimetric analysis. The results showed that all these techniques are complementary and useful to characterize the structure and morphology of the samples. Before any chemical treatment, the presence of impurities with a compact unfibrillated structure on the surfaces of chènevotte samples was found. Data indicated an increase in the crystallinity index and significant changes in the chemical composition of each sample after treatment as well as in surface morphology and roughness. The most significant changes were observed in alkaline-treated samples, especially those treated with KOH.

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Effect of Ionic Liquids/water Pre-Treatment of Luffa ﬁbres on the Structural Properties

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.610-613.3587 ◽

2012 ◽

Vol 610-613 ◽

pp. 3587-3590

Author(s):

Li Wei ◽

Xiao Qing Shi ◽

Ying Wang ◽

Ying Chong Ma ◽

Ji Xiang Zhao ◽

...

Keyword(s):

Ionic Liquids ◽

Interfacial Adhesion ◽

Raw Materials ◽

Crystallinity Index ◽

Xrd Analysis ◽

Raw Material ◽

Water Mixture ◽

X Ray Diffraction ◽

X Ray ◽

Pre Treatment

Recently, the use of lignocellulosic ﬁbres to reinforcing composite has received an increased attention. However, lack of good interfacial adhesion makes important the treatment of raw materials. In this study, the raw material Luffa ﬁbres were treated by ionic liquids/water mixture and this treatment proved to be useful by elimination of gummy and waxy substances. The effect of the treatments on the structure of ﬁbres was showed using SEM and XRD (X-Ray Diffraction) analysis. The SEM results revealed that the treatment resulted in a removal of lignin, pectin and hemicellulose substances, and change the characteristics of the surface topography. The XRD analysis shows the increase of crystallinity index.

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Identification of acid-insoluble filter-plugging compounds and optimal acid-washing procedures for tubular backpulse pressure filters

TAPPI Journal ◽

10.32964/tj10.1.17 ◽

2011 ◽

Vol 10 (1) ◽

pp. 17-23

Author(s):

KEVIN TAYLOR ◽

RICH ADDERLY ◽

GAVIN BAXTER

Keyword(s):

Calcium Sulfate ◽

Membrane Filter ◽

Sulfamic Acid ◽

Xrd Analysis ◽

Metal Sulfides ◽

X Ray Diffraction ◽

X Ray ◽

Gypsum Formation ◽

Acid Washing ◽

Hydrolysis Of

Over time, performance of tubular backpulse pressure filters in kraft mills deteriorates, even with regular acid washing. Unscheduled filter replacement due to filter plugging results in significant costs and may result in mill downtime. We identified acid-insoluble filter-plugging materials by scanning electron microscope/energy-dispersion X-ray spectroscopy (SEM/EDS) and X-ray diffraction (XRD) analysis in both polypropylene and Gore-Tex™ membrane filter socks. The major filter-plugging components were calcium sulfate (gypsum), calcium phosphate (hydroxylapatite), aluminosilicate clays, metal sulfides, and carbon. We carried out detailed sample analysis of both the standard acid-washing procedure and a modified procedure. Filter plugging by gypsum and metal sulfides appeared to occur because of the acid-washing procedure. Gypsum formation on the filter resulted from significant hydrolysis of sulfamic acid solution at temperatures greater than 130°F. Modification of the acid-washing procedure greatly reduced the amount of gypsum and addition of a surfactant to the acid reduced wash time and mobilized some of the carbon from the filter. With surfactant, acid washing was 95% complete after 40 min.

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A study on using expanded perlite with hydroxyapatite: Reinforced bio-composites

Proceedings of the Institution of Mechanical Engineers Part H Journal of Engineering in Medicine ◽

10.1177/0954411921996565 ◽

2021 ◽

pp. 095441192199656

Author(s):

Erdoğan Karip ◽

Mehtap Muratoğlu

Keyword(s):

Body Fluid ◽

Xrd Analysis ◽

Cold Isostatic Pressing ◽

Expanded Perlite ◽

X Ray Diffraction ◽

Pressing Method ◽

X Ray ◽

Infra Red ◽

Ft Ir

People are exposed to different kinds of diseases or various accidents in life. Hydroxyapatite (HA) has been widely employed for bone treatment applications. In this study, HA was extracted from sheep bones. Bio-composites were doped with 1, 5, and 10 wt.% of expanded perlite and 5 wt.% of ZrO2–MgO-P2O5. The bio-composites were prepared by the cold isostatic pressing method (250 MPa) and sintered at 900°C for 1 h. In order to evaluate the characteristics of the bio-composites, microhardness, density, X-ray diffraction (XRD), Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) analyses were carried out on them. Additionally, the specimens whose characteristics were determined were kept in synthetic body fluid (SBF), and their in vitro behavior was examined. As a result, it was observed that microhardness increased as both the weight and the grain size of the expanded perlite were increased. Calcium silicate, tri-calcium phosphate, and hydroxyapatite were observed in the XRD analysis of all samples, and the formation of apatite structures was increased by addition of ZrO2–MgO–P2O5.

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