scholarly journals Contamination and Pollution Risk Assessment of Heavy Metals in Rice Samples (Oryza sativa) from Nasarawa West, Nigeria

Author(s):  
Abdullahi Abubakar Mundi ◽  
Umar Ibrahim ◽  
Idris Mohammed Mustapha

Aim: This study was undertaken to assess the heavy metals contamination level in rice grains (Oryza sativa) from Nasarawa West, Nigeria. Study Design: To estimate the contamination factor, degree of Contamination and Pollution load index of rice samples from Nasarawa west using the world health organization/food and agricultural organization acceptable limits of some toxic Heavy Metals in Food as reference heavy metals concentration. Place and Duration of Study: The research was carried out in the Department of physics, Nasarawa State University, Keffi, from September 2017 to April 2018. Methodology: Fifteen (15) samples each were taken from various locations from the rice fields in Keffi, Kokona, Karu, Nasarawa, and Toto respectively. Rice grain samples were dried in an open air at an ambient temperature to constant weight. Husks were removed. Then, the grain rice samples were pulverized and were passed through a 2.00 mm sieve and stored in closed polyethylene bags for irradiation using ECLIPSE Ш Energy Dispersive X – Ray Fluorescence (EDXRF) XR–100 CR spectrometer supplied by AMTEK INC. MA; USA. Results: The values of contamination factor of rice samples from the study area were in the order of Zn < Cu < Ni < Cr < Pb and are all less than 1, indicating a ‘low risk’ of contamination with the value of Cd >> 6 presenting a very high contamination risk of Cadmium. The Pollution Load Index value observed in Nasarawa West were in the order of Nasarawa (0.0683) < Keffi (0.0773) < Toto (0.0972) < Kokona (0.0988) < Karu (0.1389) and are all less than unity (1), indicating that the rice samples were not polluted by Cd, Cu, Cr, Ni, Pb and Zn. Conclusion: Findings from this study will help in making policies and preferring solution to public health related issues and further studies may be important.

Tehnika ◽  
2020 ◽  
Vol 75 (4) ◽  
pp. 297-304
Author(s):  
Todor Serafimovski ◽  
Goran Tasev ◽  
Trajce Stafilov

The intense mineral extraction in mining areas during the last several decades has produced a large amount of waste material and tailings, which release toxic elements to the environment. The aim of the study was to determine in two vertical profiles/sections (1 and 2) the heavy metal contents of samples derived from six samples, three from each section located in the porphyry copper mine Buchim area, Republic North Macedonia. The results have been compared to new Dutchlist (DL) and Kabata-Pendias (KP) standards and the following was concluded: As values ranged 14.985÷60.131 mg kg-1 with 4 samples above the target value of the DL (29 mg kg-1 As) and 6 above standard values given in KP value (5 mg kg-1 As), in that context Co values ranged 11 ÷57 mg kg-1 with 6 values above the target value of the DL (9 mg kg-1 Co) and 5 above standard values given in KP value (12 mg kg-1 Co), Cr with range 29.32÷75.76 mg kg-1 with 6 over KP value (10 mg kg-1 Cr) and none above the target value of the DL (100 mg kg-1 Cr), Cu with range 2694÷6749 mg kg-1 with 6 samples above the target value of the DL (36 mg kg-1 Cu) and 6 above standard values given in KP value (20 mg kg-1 Cu), Ni with range 59.57÷105.98 mg kg-1 with 6 samples above the target value of the DL (35 mg kg-1 Ni) and 6 above standard values given in KP value (20 mg kg-1 Ni), Pb with range 27.06 ÷96.08 mg kg-1 with 1 sample above the target value of the DL (85 mg kg-1Pb) and 6 above standard values given in KP value (25 mg kg-1Pb), Zn with range 147÷273 mg kg-1 with 6 over target value of the DL (140 mg kg-1 Zn) and 6 above standard KP value (64 mg kg-1 Zn), V with range 34.44÷92.57 mg kg-1 with 5 over target value of the DL (42 mg kg-1 V) and one above KP value (90 mg kg-1 V).In order to compare the level of contamination, the contamination factor (𝐶𝑓 𝑖 ), degree of contamination (Cd), and pollution load index (PLI) were computed. Serious numbers were found for Cu, as, Zn, Co and Ni, which exceeded standard values at almost all samples from both vertical sections. Compared from section 1 and section 2, pollution load index increased by 13.43%, which in almost all samples was classified as heavily polluted to extremely polluted. The fact that mining activities at the Buchim Mine last for almost 40 years, the presence of heavy metals in soils at a serious level is understandable. The high level of contamination is a result of heavy metal persistence and non-biodegradability.


Author(s):  
A. Benarabi ◽  
M. S. Nili ◽  
A. Douadi

Soil is contaminated with various potentially harmful metals (PTMs). Therefore, the adequate protection of soil from contamination is imperative, as the soil is regarded as the primary cradle for living and environmental balance. Accordingly, the purpose of this study was to assess the contamination level by PTMs in Touggourt city, where soil samples have been collected randomly from 18 sites. These sites included manufacturing companies and institutions belonging to the industrial region of Touggourt city. The concentrations of six PTMs - zinc (Zn), iron (Fe), cobalt (Co), copper (Cu), lead (Pb) and manganese (Mn) were assessed using the atomic absorption spectrophotometer (AAS) instrument as well as the application of the modern pollution indices such as CF (Contamination Factor), PLI (Pollution Load Index) and EF (Enrichment Factor). The highest values of contamination factor (CF) for Zn, Fe, Co, Cu, and Pb were 0.605, 1.605, 0.277, 0.05, 0.438, and 0.01, respectively, and the highest value of pollution load index (PLI) was 0.139, while the results of enrichment factor (EF) for the Zn, Mn, Co, Cu and Pb metals were 2.608, 0.060, 0.740, 0.122, and 2.358, respectively. According to these pollution indices, the results of this study have indicated that human effects or industrial wastes and traffic, in particular, were the sources of heavy metal contaminating the studied region.


2018 ◽  
Vol 6 (1) ◽  
pp. 108 ◽  
Author(s):  
Ram Proshad ◽  
Md. Saiful Islam ◽  
Tapos Kormoker

This study was conducted to assess the ecological risk of heavy metals in soils collected from the industrial vicinity of Tangail district in Bangladesh. In this study, the levels of six heavy metals namely chromium (Cr), nickel (Ni), copper (Cu), arsenic (As), cadmium (Cd), and lead (Pb) in 15 sampling sites around the industrial vicinity of Tangail district in Bangladesh were assessed. The mean concentration of Cr, Ni, Cu, As, Cd and Pb in studied soils were 11.56, 23.92, 37.27, 6.11, 2.01, and 17.46 mg/kg, respectively. Certain indices, including the enrichment factor (EF), contamination factor (Cif), geoaccumulation index (Igeo), pollution load index (PLI), toxic unit analysis, and principal component analysis (PCA) were used to assess the ecological risk. The enrichment factor of all the studied metals for all sampling sites were in the descending order of Cd > Cu > As > Pb >Ni > Cr. The contamination factor values revealed that the studied soils were highly impacted by Cd. The pollution load index (PLI) values of Cd were higher than 1, indicating the progressive deterioration of soil due to Cd contamination. In the context of potential ecological risk (PER), soils from all sampling sites showed moderate to very high potential ecological risk.


Author(s):  
U. U. Ubong ◽  
I. O. Ekwere ◽  
E. E. Ikpe

This study evaluates the physico-chemical parameters and heavy metals in water, sediments and Tympanotonus fuscatus obtained from three sample sites along Iko River in Eastern Obolo LGA, AkwaIbom State. The heavy metal analysis results on Pb, Cd and Ni in sediments and Tympanotonus fuscatus were used to estimate the human health and ecological risk assessment of the study area. The human health risk assessment tools utilized in this study were estimated dietary intake (EDI), total hazard quotient (THQ) and hazard index (HI) while sediment pollution parameters evaluated were contamination factor (CF), contamination degree (CD), pollution load index (PLI) and geoaccumulation index (Igeo). Results obtained showed that EDI of Cd in periwinkle in the study sites ranged from 0.2 – 6.4 µg/kg-bw/day and exceeded the provisional tolerable dietary intake (PTDI), while EDI for Pb (0.0004 – 2.6 µg/kg-bw/day) and Ni (0.32 – 2 µg/kg-bw/day) was within the limit for all sites, except Ni in site II (34 µg/kg-bw/day) which was higher than the PTDI of 5 µg/kg-bw/day. The THQ of Cd in all sites was greater than 1, while Pb and Ni generally recorded THQ < 1. The hazard index (HI) was as follows: site I (2.36), sites II (24.44) and site III (6.5), highlighting a potential hazardous effect to humans as a result of the consumption of Tympanotonus fuscatus obtained from site II and III. The sediment pollution assessment revealed that the contamination factor (CF) and geoaccumulation index, Igeo of Cd were far above the permissible limits while Pb and Ni were mostly within limits. The estimated contamination degree (CD) and pollution load index (PLI) showed a high degree of pollution, which can be mainly attributed to the high degree of Cd contamination in the sediment. Therefore, the area under investigation is highly polluted and the periwinkle obtained from Iko river in the study area is unfit for human consumption.


2016 ◽  
Vol 10 (3) ◽  
pp. 41-46
Author(s):  
Soheil Sobhanardakani ◽  
◽  
Mehrnaz Ghoochian ◽  

Background: Soil and sediment serve as major reservoir for contaminants as they possess ability to bind various chemicals together. In this study the concentrations of heavy metals Cd, Cr and Cu were analyzed in surface sediments of Agh Gel Wetland in west of Iran. Methods: The sediment samples were taken from 10 stations. The samples were subjected to bulk digestion and chemical partitioning and Cd, Cr and Cu concentrations of the sediments were determined by ICP-OES. Geo-accumulation index (I-geo), Contamination factor (CF) and Pollution load index (PLI) were used to evaluate the magnitude of contaminants in the sediment profile. Results: The mean sediment concentrations (mg kg-1 dry weight) ranged within 0.20-0.29 (Cd), 58-71 (Cr) and 23-36 (Cu). According to the I-geo values, the sediments' qualities are classified as unpolluted to moderately polluted category. According to the CF values, the sediments' qualities are classified as low to moderate contamination. Furthermore, the PLI values indicated that there were no metal pollution exists for all sampling stations. Conclusion: The Agh Gel Wetland is potential to be threatened by chemical pollutants such as agricultural effluent. So to preserve the environment of the Agh Gel Wetland from deterioration, periodically monitoring of the water and sediment qualities is recommended.


2018 ◽  
Vol 3 (2) ◽  
pp. 143-159 ◽  
Author(s):  
Mohamed Nageeb Rashed ◽  
Mohamed ELSadeek Fouad Toufeek ◽  
Mahmoud Abedeldaium Eltaher ◽  
Ayman Outhman Elbadry

Electrical conductivity, pH, organic matter, carbonates and five heavy metals (Fe, Mn, Zn, Cu and Pb) were measured seasonally in the sediments of River Nile (Egypt) during 2015. Ten sectors include 30 sites were selected along River Nile from Aswan to Armant to assess the levels of the studied parameters. Heavy metals in sediments were in the order of Pb < Cu < Zn < Mn < Fe, which indicated that Pb was found to be the least concentration in sediments, whereas Fe was the most accumulated element. Pearson’s correlation coefficients among the measured parameters were tested. Zn, Cu and Pb were positively correlated with electrical conductivity and organic matter accumulation and also they were positively correlated with each other. Sediments pollution load was studied through pollution indices [geo-accumulation index, pollution load index, modified degree of contamination, contamination factor and enrichment factor]. The pollution indices confirmed that the River Nile sediments in the studied area were not contaminated with these heavy metals except for some samples collected from certain sites as a result of the anthropogenic activities at these sites.


2019 ◽  
Vol 20 (3) ◽  
pp. 1-9
Author(s):  
José Gonzalo Zapata Carbonell ◽  
Francisco Bautista Zúñiga ◽  
Jaime Rendón von Osten ◽  
Luz del Carmen Lagunes Espinoza ◽  
David de Jesús Palma López ◽  
...  

The first diagnose of heavy metal (Cd, Cr, Cu, Fe, Mn, Ni and Pb) concentrations present in Chetumal, Mexico and its spatial distribution was carried out by analyzing 86 samples of urban dust through atomic absorption spectrophotometry. The assessment of the extent of pollution was undertaken by the use of the Mexican Residential Soil Guideline Values, the calculation of the contamination factor and the pollution load index. The results showed concentrations of heavy metals below the Mexican guidelines in the city, except for chromium and lead in a few samples. However, using the contamination factor the concentrations for chromium, lead and copper are exceeded in some samples. The map of pollution load index shows the areas requiring immediate attention from the decision makers.


2021 ◽  
Vol 11 (2) ◽  
Author(s):  
Francis Chizoruo Ibe ◽  
Alexander Iheanyichukwu Opara ◽  
Collins Emeka Amaobi ◽  
Bridget Onyekachi Ibe

AbstractThe study investigated groundwater sources within reclaimed municipal waste dumpsites around Akachi road in Owerri, Southeastern Nigeria. The research evaluated the pollution and risk inherent in the consumption of groundwater in the vicinity of the reclaimed waste dumpsite using standard procedures. Results showed acidic pH values for some groundwater samples within the reclaimed waste dumpsite. Elevated nitrate (NO3−), aluminium (Al) and chromium (Cr) concentrations above the World Health Organization (WHO) limits for drinking water samples were recorded in some of the groundwater samples from the study area. The observed strong positive correlations between the metallic contaminants indicated that the distribution of the pollutants has a strong relationship with organic contaminants in the reclaimed waste dumpsite. Low contamination factor was exhibited by all metals for the individual samples except for Cr in sample A and Al in sample A and D. The pollution load index for all the samples was low, except for sample C with a pollution load index of unity. Elevated hazard quotient > 1 and hazard index > 1 were observed for both adults and children due to high Cr levels. The chronic daily intake risk assessment revealed values < 1, while carcinogenic risk values greater than 10−6 and 10−4 were observed for the samples suggesting potential health risk for children and adults. The water quality index of samples from the reclaimed waste dumpsite calls for concern due to elevated levels of Al and Cr. These findings, therefore, suggest the need to treat the groundwater from the reclaimed dumpsite before consumption to avert serious health risks. Finally, waste dumpsites should be remediated or allow to undergo natural remediation before reclamation, erecting residential structures, and sinking of boreholes for water supply within such areas.


Author(s):  
Ogunti mehin ◽  
◽  
Apata o ◽  

Ten water and ten sediment samples from both Igbokoda and Apapa in South west, Nigeria were collected between March and August, 2018 for heavy metal analysis. The study aimed at using Potential Ecological Risk (PER) index to characterize rivers sediments and waters for possible environmental impact. The sampling span industrial, domestic and recreational areas. The water and sediment grab samples were treated using standard procedures. The filtrate from sediment was made up to 50 cm3 mark with distilled water and used for seven heavy metals determination using atomic absorption spectrophotometry (AAS). Contamination factor (CF) and Pollution load index (PLI) calculated for each metal in the sediments indicate moderate contaminations. However, Cd in exception showed the highest potential ecological risk factor of 42.3 in Igbokoda. PER value of the Igbokoda sediment is 45.37 while that of Apapa sediment is 6.79. The potential risk pose by Cd alone in the sediment suggests that the Igbokoda water is unsafe for recreational and other beach activities. The recommendation from the study will suggest a proper treatment of wastewater and sewages before fluxing into both the Igbokoda and Apapa water bodies


Sign in / Sign up

Export Citation Format

Share Document