scholarly journals Assessment of Anions and Heavy Metals in Sediments from River Sio, Busia County, Kenya

2019 ◽  
pp. 1-18
Author(s):  
K. O. Ondoo ◽  
J. K. Kiptoo ◽  
A. O. Onditi ◽  
S. M. Shivaji ◽  
J. K. Ogilo
Keyword(s):  
Heavy Metals ◽  
Surface Runoff ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Water Source ◽  
Pollution Load Index ◽  
Dry Season ◽  
Wet Season ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

Agricultural activities, discharge of raw sewage into farms and the rise in urbanization have greatly contributed to soil pollution. During the rainy season, surface runoff from farms find their way into water bodies and deposits these contaminants into Rivers and Lakes which poses a threat to both aquatic and terrestrial organisms that depend on that water source. The objective of this research was to determine the level of anions and heavy metals from sediments in River Sio, Busia County, Kenya. Five sediment samples were taken from five sampling points and the levels of anions and heavy metals in them determined. Anions were determined using Shimadzu 1800 UV/visible spectrophotometer while heavy metals were determined using Shimadzu 6200 flame atomic absorption spectrophotometer (AAS). Copper, lead and nickel were above the allowed WHO limits while cadmium was below detection limit. The levels of nitrates, phosphates and chlorides were higher during the wet season due to surface runoff that carried these nutrients from the farms and deposited them on the bottom of the River. The levels of heavy metals were high during the dry season due to evaporation of water from the River, leading to an increase in the analyte concentration during the dry season. High levels of copper and nickel in the sediments points to the use of herbicides and pesticides in farming and washing of vehicles and motorcycles on the banks of the River. According to Igeo nickel showed moderate pollution during the dry season. The contamination factor for lead was very high during the dry season, while pollution load index confirmed pollution due to anthropogenic activities in sampling sites 1 – 4 during the dry season and no pollution due to anthropogenic activities during the wet season.  The study recommends reduced use of inorganic fertilizers in order to save the River from the danger of eutrophication. Excessive use of agrochemicals such as herbicides and pesticides should be discouraged. In addition, pesticide leaching and the level of microbes in soil and sediments should be considered for further research

scholarly journals A Study of Heavy Metals Pollution in the Coastal Marine Sediment of Ondo State, Nigeria

2019 ◽  
pp. 1-10
Author(s):  
Ayeku, P. Oluwagbemiga ◽  
Ogundele, L. Tunde ◽  
Adeniyi, I. Funsho
Keyword(s):  
Heavy Metals ◽  
Marine Sediment ◽  
Anthropogenic Activities ◽  
Sampling Site ◽  
Contamination Factor ◽  
Dry Season ◽  
Contamination Level ◽  
Pollution Indices ◽  
Wet Season ◽  
Sediment Samples

The present study was carried out to assess the pollution status of heavy metals in the marine sediment in Ondo coastal area. A total of 36 sediment samples were collected from the three locations (Awoye, Abereke and Ayetoro) once in a month in 2015 covering both dry and wet season. The sediment samples were subjected to digestion and Atomic Absorption Spectrophotometer (AAS) was used to measure the concentrations of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn. The measured concentrations data were used for evaluating the contamination level and accumulation status of heavy metals in sediment by employing several pollution indices: contamination factor (CF), degree of contamination (Cdeg), pollution load index (PLI), enrichment factor (EF) and index of geoaccumulation (Igeo). The results showed that Fe had the highest average concentration values of 248.00§ 20.00 and 324.33§ 5.80 mg/kg at Awoye sampling site for wet and dry season, respectively while the highest mean concentration of Mn were 271.77±9.50 and 295±10.06 mg/kg at Abereke and Ayetoro, respectively. The contamination factor (CF) values for As, Cd and Mn were 1 < CF < 3, indicating a moderate contamination. The results of Cdeg were ranged from 8.6 to 12.5 for both dry and wet season except in Ayetoro site that had 7.8 in the wet season. The PLI values were 0.47, 0.50 and 0.54 (<1) for Abereke, Awoye and Ayetoro sites, respectively, denoting unpolluted conditions. The EF values for Pb and Ni obtained from all the sites ranged from 20.8 to 38.9, showing their significantly enriched in sediment. The Igeo values of As, Cr, Fe, V, Zn and Cu were less than one (Igeo <1) for the three sampling locations in both seasons, implying that the sediments in the study area are practically uncontaminated by these metals. Pb had the Igeo values of 2.80 and 2.85 during dry and wet season at Awoye sampling site while Ni had 2.57 at Abereke only in the dry season. The heavy metals in sediment might be derived from the upstream rivers from the top soil, mechanically weathered rock materials and anthropogenic activities.

scholarly journals Ecological Risk Assessment of Heavy Metals in Soil of an Open Dump along Old Ikare Road Owo, Ondo State, Nigeria

2019 ◽  
pp. 1-11
Author(s):  
J. O. Olayinka-Olagunju ◽  
A. M. Olatunji-Ojo ◽  
A. Adejuyigbe ◽  
H. A. Ikuesan ◽  
S. E. Abubakar
Keyword(s):  
Heavy Metals ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Dry Season ◽  
Soil Samples ◽  
Pollution Load ◽  
Wet Season ◽  
Heavy Metal Concentrations ◽  
Regulatory Limits ◽  
Ondo State

Aims: To investigate the heavy metal concentrations in soil samples collected from an open dumpsite in a rural community (Aba Idi-Mangoro) in Owo, Ondo State and to compare the observed values with the regulatory limits. This study also aimed to determine the pollution levels using tools like contamination factor, pollution load index and geoaccumulation index. Study Design: Field study design was use in this study. Place and Duration of Study: Soil samples were collected from Aba Idi-Mangoro in Owo, Ondo State, Nigeria between July 2015 and February 2016 to represent the wet and dry seasons. Methodology: A total of 96 soil samples were collected (6 samples on each visit and the site was visited twice a month). The samples were taken to the Prof. Julius Okojie Central Research Laboratory at the Federal University of Technology, Akure, Ondo State, Nigeria. In the laboratory, samples were air dried to remove the moisture. 2 g of the sampes were digested into HNO3, HCl, HF and HClO4, and AA Spectrophotometer was used to analyse the concentrations of the heavy metals. Results: Out of the 8 heavy metals assessed, 6 were above the regulatory limits. The order of heavy metal concentrations for the wet season is: Fe>Mn>Zn>Cu>Pb>Ni>Cr>Co>Cd and the dry season is as follows: Fe>Zn>Mn>Pb>Cu>Ni>Co>Cr>Cd. When the mean concentrations of the samples for the wet season were compared to the dry season, Mn (0.009), Cd (0.035), Cr (0.044) and Co (0.014) differ significantly (p<0.05). No significant difference was found in Fe, Co, Ni and Zn. It was observed from the overall results that the concentrations of heavy metals were higher during the dry season than in the wet season. The contamination factor (CF), pollution load index and geo-accumulation index values of Fe was extremely high in the two seasons while it varies at different collection times for the other metals. Conclusion: Due to the high presence of some of the heavy metals found in the soil, the study suggests that water and sediment samples from nearby river(s) within the community should also be examined.

scholarly journals Spatial Variations in Groundwater Quality Around Dumpsite in Igando

2015 ◽  
Vol 6 (1) ◽  
pp. 179-186
Author(s):  
Akoteyon ◽  
S Isaiah
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Drinking Water ◽  
Groundwater Quality ◽  
Anthropogenic Activities ◽  
Dry Season ◽  
Spatial Variations ◽  
T Test ◽  
Drinking Water Quality ◽  
Wet Season

Water samples collected from fifteen hand dug wells in November (dry season), 2011 and July (Wet season), 2012 using random sampling technique. In situ parameters were measured for pH, electrical conductivity, total dissolved solids using portable meters. Heavy metals were analyzed for; Fe, Cu, Zn, Cd, Pb, and Cr using Atomic Absorption Spectrophotometer (AAS). The study aimed at examining the spatial variations in groundwater quality around dumpsite in Igando using paired sample T-test statistical technique. The result shows that the measured pH values were below the minimum WHO standard for drinking water quality in wet and dry seasons in about73.3% and 26.7% respectively. Also, approximately, 13.3% of EC, and 6.7% exceeded the prescribed standard limit of WHO in dry and wet seasons respectively. Concentration of Fe exceeded drinking water quality in all the sampling locations during wet season and only about 46.7% in dry season. Pb, Zn, and Cu exceeded WHO limit in about 86.7%, 80%, and 26.7% respectively in dry season. Concentration of Pb, Cd , Cu and Cr were under detection limit in all the locations except at locations G2 for Cu in wet season. The paired samples statistics and correlation revealed that the mean values of all the parameters were higher in dry season with the exception of Fe. No significant correlations exist among the paramet er for both seasons at p<0.05. The paired T-test show significant seasonal variations among four heavy metals including Fe, Cd, Pb and Zn.The study concluded that, samples in dry season are of low quality compared to wet. The study recommends public enlightenment on solid waste disposal, controlled anthropogenic activities, and treatment /recycling of waste to prevent heavy metal from leaching unto the sub-surface.DOI: http://dx.doi.org/10.3329/jesnr.v6i1.22063 J. Environ. Sci. & Natural Resources, 6(1): 179-186 2013

scholarly journals Environmental Impact of Heavy Metals from Poultry Waste Discharged into the Olosuru Stream, Ikire, Southwestern Nigeria

2019 ◽  
Vol 9 (22) ◽  
Author(s):  
Abayomi Tolulope Oyewale ◽  
Taiwo Adekanmi Adesakin ◽  
Adedeji Idowu Aduwo
Keyword(s):  
Heavy Metals ◽  
Environmental Impact ◽  
Anthropogenic Activities ◽  
Sampling Period ◽  
Dry Season ◽  
World Health ◽  
Poultry Waste ◽  
Wet Season ◽  
Southwestern Nigeria ◽  
Southwest Nigeria

Background. Water supplies can be contaminated by anthropogenic activities. The poultry industry uses a variety of heavy metals as additives in chicken feed, but excretion, runoff and dumping of heavy metals can threaten water bodies and have adverse effects on human health. Objectives. The aim of the present study was to determine the environmental impact of heavy metals from poultry waste discharged into the Olosuru stream, located in Ikire, southwest Nigeria. Methods. In order to study changes in heavy metal loads, samples were collected six times during the wet season (September, October 2014 and April 2015) and dry season (November 2014, January and February 2015). The inhabitants of Olosuru village use water for domestic and agriculture purposes from the Olosuru stream which is located only a few meters from a poultry farm discharge point. Three stations were sampled, upstream to downstream, with 500 meter distance between each point. Results. Selected heavy metals concentrations in the Olosuru stream were all above the World Health Organization (WHO) standard for drinking water. The highest mean concentrations of heavy metals were recorded at the downstream station, while arsenic, iron and lead showed significant spatial and seasonal differences. Seasonally, the highest iron concentrations were recorded in the dry season (0.104±0.401 mg/L), while the mean concentrations of other heavy metals recorded during the sampling period were higher during the wet season. Conclusions. Concentrations of heavy metals in the present study were above acceptable limits. Poultry waste discharged into the Olosuru stream, can have negative impacts on the stream and health implications for local residents. Competing Interests. The authors declare no competing financial interests.

scholarly journals The Potential of Heavy Metals Contamination in the Surface Sediments of River Nile, Egypt

2018 ◽  
Vol 3 (2) ◽  
pp. 143-159 ◽  
Author(s):  
Mohamed Nageeb Rashed ◽  
Mohamed ELSadeek Fouad Toufeek ◽  
Mahmoud Abedeldaium Eltaher ◽  
Ayman Outhman Elbadry
Keyword(s):  
Heavy Metals ◽  
Electrical Conductivity ◽  
Organic Matter ◽  
Anthropogenic Activities ◽  
Correlation Coefficients ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Indices ◽  
River Nile ◽  
Pollution Load

Electrical conductivity, pH, organic matter, carbonates and five heavy metals (Fe, Mn, Zn, Cu and Pb) were measured seasonally in the sediments of River Nile (Egypt) during 2015. Ten sectors include 30 sites were selected along River Nile from Aswan to Armant to assess the levels of the studied parameters. Heavy metals in sediments were in the order of Pb < Cu < Zn < Mn < Fe, which indicated that Pb was found to be the least concentration in sediments, whereas Fe was the most accumulated element. Pearson’s correlation coefficients among the measured parameters were tested. Zn, Cu and Pb were positively correlated with electrical conductivity and organic matter accumulation and also they were positively correlated with each other. Sediments pollution load was studied through pollution indices [geo-accumulation index, pollution load index, modified degree of contamination, contamination factor and enrichment factor]. The pollution indices confirmed that the River Nile sediments in the studied area were not contaminated with these heavy metals except for some samples collected from certain sites as a result of the anthropogenic activities at these sites.

scholarly journals Evaluation of the impact of anthropogenic activities on wetland soil qualities: A case study of Isoko South Area of Delta State, Southern Nigeria

2021 ◽  
Vol 6 (2) ◽  
pp. 58-66
Author(s):  
A. N. Ogbaran ◽  
◽  
I. E. Joseph-Akwara ◽  
Keyword(s):  
Heavy Metals ◽  
Soil Depth ◽  
Anthropogenic Activities ◽  
Cadmium Concentration ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Soil Samples ◽  
Reference Station ◽  
Wetland Soil ◽  
The Impact

This research was carried out to evaluate the impact of dumpsite and farming methods (anthropogenic Activities) on wetland soil qualities. Soil samples were collected from three strategic locations in Irri and Uzere communities at Delta State of Nigeria, and a reference station (control) about 5 km away from the study site. The sampling was done at the end of the rainy season (September, 2020), when the flood water had started rescinding, at two soil depths (5 to 10 cm and 45 to 50 cm). The concentration of iron, nickel, copper and cadmium concentration of the soil samples were determined with the Atomic Absorption Spectrophotometer (AAS), according to procedures approved by ASTM International. Results obtained from the chemical analysis revealed irregular concentration and distribution of the heavy metals within the studied area. Regardless of the sampling depth, the highest heavy metal concentrations were observed around the active dumpsite. Ranking order of the heavy metals’ concentrations in all the sampling locations was Fe ˃ Cu ˃ Ni ˃ Cd. It was observed from the results that the profile concentrations of the heavy metals increased with an increase in the soil depth. Using the contamination factor to assess the heavy metals contamination of the wetland, the results showed that the area ranged from moderate to considerable level of contamination, while pollution load index reveled that wetland soils were moderately polluted with the heavy metals. In terms of the soil pollution, the overall results revealed that area closed to the wastes dumpsite (site 1) was heavy polluted with the heavy metals

scholarly journals Determination and Contamination Assessment of Heavy Metals in Street Dust from Different Types of Land-Use in Kathmandu District, Nepal

2019 ◽  
Vol 24 (1) ◽  
pp. 6-18 ◽  
Author(s):  
Sudarshana Shakya ◽  
Samikshya Baral ◽  
Priya Belbase ◽  
Mohd Nur E Alam Siddique ◽  
Abd Naser HJ Samoh ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Land Use ◽  
Heavy Traffic ◽  
Electrical Conductance ◽  
Contamination Factor ◽  
Street Dust ◽  
Total Alkalinity ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer ◽  
Different Types

A total of forty seven street dust samples, collected from five different types of land use viz., industrial, urban, heavy traffic road, residential and undisturbed areas (control) of Kathmandu district (Nepal), were subjected to characterize the physico-chemical parameters such as pH, electrical conductance (EC), total alkalinity (T. Alk), total organic carbon (TOC) and particle size distribution. Four heavy metals of Cd, Cu, Pb and Zn were determined in dust samples using flame atomic absorption spectrophotometer (FAAS). It was found that all types of dust samples possessed alkaline nature along with variation in EC, T. Alk and TOC values. Results revealed that the dust of industrial areas contained high concentrations of Zn (143.3 mg/kg) and Cu (106.42 mg/kg), whereas the heavy traffic areas were mainly affected by Cd (0.90 mg/kg) and Pb (70.08 mg/kg). The average metal concentrations of Cd, Cu, Pb and Zn in dust of all the types of land use in Kathmandu were found to be 0.73, 68.86, 51.46 and 104.30 mg/kg and their average metal enrichment factors were 2.28, 5.50, 1.92 and 3.17, respectively. The results were also compared against heavy metals status in street dust from various cities/countries around the world. Pollution indices such as contamination factor (CF), degree of contamination (CD) and geo-accumulation index (Igeo) showed different classes of metal contamination in street dust of Kathmandu indicating traffic emission, automobiles, construction and demolition activities and other anthropogenic activities as the potential sources.

scholarly journals Contamination and Pollution Studies of Heavy Metals in Sand Filter Media Waste Dumpsite in Yenagoa, Bayelsa State, Nigeria

2020 ◽  
Vol 24 (4) ◽  
pp. 581-588
Author(s):  
I.L. Ikoko ◽  
C.I. Osu ◽  
M. Horsfall
Keyword(s):  
Heavy Metals ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Pollution Level ◽  
Pollution Indices ◽  
Filter Media ◽  
Degree Of Contamination ◽  
Sand Filter ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

The contamination and pollution level of five Heavy Metals in spent Sand Filter Media [SFM] waste dumpsite was investigated to ascertain the contamination, pollution and possible migration in that environment. Samples were collected at the surface, 0.1m depth and 100m away from the dumpsite and analysed using Flame Atomic Absorption Spectrophotometer (FAAS) for concentration of Cr, Fe, Mn. Ni and Pb ions. Geochemical Pollution Indices were used to evaluate the contamination and pollution level of the HMs comparatively using the world shale average values and the experimental control value. Results obtained showed highest concentration of 12.50mg/kg for Fe and lowest detectable concentration of 0.2mg/kg for Ni at the top of the dumpsite. All five heavy metals had low concentrations compared to WHO and national standards for soil qualityboth at the top and 0.1m depth of the dumpsite. Percentage concentrations of the heavy metals at the top showed 78.81, 12.04, 7.88, 1.26% in the order Fe >>> Cr > Mn > Ni > Pb with the values of Ni and Cr at 0.1m depth slightly higher indicating some level of migration. Contamination Factor Cf, depicts very severe contamination to slight pollution at the top with minimum of 0.714 and maximum of 1.471. Degree of Contamination Cd, of <8 and Modified Degree of Contamination mCd <1.5 showed low contamination. The pollution load index, PLI values of < 50 depicts that no drastic rectification measure was needed which concludes that the SFM dumpsite was contaminated but technically not polluted. Keywords: Surface mobility, Yenagoa, heavy metal contamination, Pollution indices, Bayelsa State

scholarly journals Heavy Metals Content in Kaolin Mined Soil and Water Body at Ohiya, Umuahia South, Abia State, Nigeria

2021 ◽  
pp. 58-68
Author(s):  
C. E. Igwe ◽  
C. M. U. Ajero ◽  
A. A. Amaechi ◽  
P. O.` Nzenwa
Keyword(s):  
Heavy Metals ◽  
Water Body ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Soil Samples ◽  
Pollution Indices ◽  
Mining Activities ◽  
Wet Season ◽  
Significant Difference ◽  
Very High

Heavy metals (HM) have been a global concern for its toxic and detrimental effect on the environment especially when it exceeds the permissible limit through anthropogenic activities like kaolin mining. Kaolin mining has improved the economic wellbeing of the local people through employment and otherwise; and at the same time attached with environmental consequences that threatens the livelihood of the community members. This study was carried out to ascertain the concentrations of selected heavy metals in kaolin mined soils and water body and its pollution density using single pollution indices such as contamination factor (CF), geo-accumulation (Igeo) and ecological risk factor (Er ). Soil sample were collected from three different kaolin mined sites labelled (A,B and C) also surface water samples were collected from upper and down streams of Iyi-ugbohoroAmaudara, both samples were digested and elemental analysis was carried out using Atomic Absorption Spectrophotometer (AAS UNICAM 919 model). The concentration of the metals in three different kaolin mined soil samples ranges from Pb(40.00, 52.00 and 55.09 mg/kg) Cr(45.01, 70.00 and 71.00 mg/kg) Ni( 32.10, 50.50 and 51.00 mg/kg) Cd( 2.16, 6.25 and 6.15 mg/kg) Co( 19.68, 57.06 and 56.00 mg/kg) Se(1.06, 0.50, and 1.00 mg/kg) Mn(0.001, 0.01 and 0.01 mg/kg) Hg( 2.01, 2.00 and 2.50 mg/kg) As( 1.07, 1.10 and 1.05 mg/kg) and Cu(33.01, 60.00 and 57.5 mg/kg). Results from single pollution indices used for the selected heavy metals from kaolin mined soil, samples (A,B and C) showed that Mn, As, Cr, Ni and Cu indicated low to moderate contamination factor while Cd, Se, Co and Hg indicated high to very high contamination factor in all the samples. The distribution trend of heavy metals concentrations in the upper and down streams of the river body during wet season, showed that there were significant difference between upper and down streams while dry season showed variations in significant differences between the upper and down streams of some of the heavy metals. The study therefore concludes that kaolin soils are contaminated with heavy metals as a result of kaolin deposit and its mining activities. The single pollution indices used for the study pointed out that Cd, Se, Co and Hg are very high in the kaolin soils. The surface waters of Iyi-ugbohoroAmaudara River at the study area are polluted with heavy metals as a result of kaolin mining activities in the area; more especially during wet season of the study. Consequently, these outcomes would pose a toxic effect to both fauna and flora and possibly threatens the aquatic lives and the local populace.

scholarly journals Integrated Characterization of Toxicity Distribution of Selected Heavy Metals in Stream Sediments Around Itakpe Iron Ore Mines, North Central Nigeria

2016 ◽  
Vol 6 (1) ◽  
pp. 109
Author(s):  
Eneojo Godwin Ameh ◽  
Ojochogwu Sunday Idakwo ◽  
Ojone Caroline Ameh ◽  
Omojo Mercy Lekdukum
Keyword(s):  
Heavy Metals ◽  
Enrichment Factor ◽  
Contamination Factor ◽  
Stream Sediments ◽  
Dry Season ◽  
Middle Level ◽  
Wet Season ◽  
Hazard Level ◽  
Very High

The results of the analysis were subjected to five (5) indices: contamination factor (CF); Ecological risk factor (Eri); Enrichment factor (EF); index of geo-accumulation (Igeo) and anthropogenic factor (AF). The CF results showed that the River PomPom dry and wet season sediments were collected in February and July respectively from 0cm to 10cm depth. Stainless steel spoon was used to collect the samples. The sediment samples were packaged, labeled and refrigerated for onward transportation to the laboratory. All samples were oven-dried (50oC) for about 24 hours, sieved through -80 mesh. About 1.0g of each sample was digested, filtered and the filtrates were ready for heavy metal analysis using Atomic sediments were most contaminated with Fe in both seasons, least contaminated with Cd at dry season and Zn in wet season. The Eri factor revealed pollution hazard level of middle during wet season and tiny in dry season. Pb and Ni showed strong and middle hazard level during wet season and Cu revealed middle level during dry season. The enrichment factor indicated extremely enriched for Fe in all locations in both seasons while most heavy metals showed depletion to minimal enrichment. The Igeo for both seasons showed that Fe was moderately to highly polluted in all locations. During dry season, other heavy metals showed moderately to unpolluted while in wet season Cd, Ni and Pb indicated moderately to very highly polluted. In both seasons, the % AF was very high for Fe, Cu, Pb. The AF% was very high for Ni and Cd in wet season. All sites in both seasons have experienced deterioration but more in the wet season. From these indices, the stream sediments have been significantly contaminated with Fe, Ni, Pb and Ni in most locations in both seasons.

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