scholarly journals A Study of Heavy Metals Pollution in the Coastal Marine Sediment of Ondo State, Nigeria

2019 ◽  
pp. 1-10
Author(s):  
Ayeku, P. Oluwagbemiga ◽  
Ogundele, L. Tunde ◽  
Adeniyi, I. Funsho
Keyword(s):  
Heavy Metals ◽  
Marine Sediment ◽  
Anthropogenic Activities ◽  
Sampling Site ◽  
Contamination Factor ◽  
Dry Season ◽  
Contamination Level ◽  
Pollution Indices ◽  
Wet Season ◽  
Sediment Samples

The present study was carried out to assess the pollution status of heavy metals in the marine sediment in Ondo coastal area. A total of 36 sediment samples were collected from the three locations (Awoye, Abereke and Ayetoro) once in a month in 2015 covering both dry and wet season. The sediment samples were subjected to digestion and Atomic Absorption Spectrophotometer (AAS) was used to measure the concentrations of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn. The measured concentrations data were used for evaluating the contamination level and accumulation status of heavy metals in sediment by employing several pollution indices: contamination factor (CF), degree of contamination (Cdeg), pollution load index (PLI), enrichment factor (EF) and index of geoaccumulation (Igeo). The results showed that Fe had the highest average concentration values of 248.00§ 20.00 and 324.33§ 5.80 mg/kg at Awoye sampling site for wet and dry season, respectively while the highest mean concentration of Mn were 271.77±9.50 and 295±10.06 mg/kg at Abereke and Ayetoro, respectively. The contamination factor (CF) values for As, Cd and Mn were 1 < CF < 3, indicating a moderate contamination. The results of Cdeg were ranged from 8.6 to 12.5 for both dry and wet season except in Ayetoro site that had 7.8 in the wet season. The PLI values were 0.47, 0.50 and 0.54 (<1) for Abereke, Awoye and Ayetoro sites, respectively, denoting unpolluted conditions. The EF values for Pb and Ni obtained from all the sites ranged from 20.8 to 38.9, showing their significantly enriched in sediment. The Igeo values of As, Cr, Fe, V, Zn and Cu were less than one (Igeo <1) for the three sampling locations in both seasons, implying that the sediments in the study area are practically uncontaminated by these metals. Pb had the Igeo values of 2.80 and 2.85 during dry and wet season at Awoye sampling site while Ni had 2.57 at Abereke only in the dry season. The heavy metals in sediment might be derived from the upstream rivers from the top soil, mechanically weathered rock materials and anthropogenic activities.

scholarly journals Assessment of Anions and Heavy Metals in Sediments from River Sio, Busia County, Kenya

2019 ◽  
pp. 1-18
Author(s):  
K. O. Ondoo ◽  
J. K. Kiptoo ◽  
A. O. Onditi ◽  
S. M. Shivaji ◽  
J. K. Ogilo
Keyword(s):  
Heavy Metals ◽  
Surface Runoff ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Water Source ◽  
Pollution Load Index ◽  
Dry Season ◽  
Wet Season ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

Agricultural activities, discharge of raw sewage into farms and the rise in urbanization have greatly contributed to soil pollution. During the rainy season, surface runoff from farms find their way into water bodies and deposits these contaminants into Rivers and Lakes which poses a threat to both aquatic and terrestrial organisms that depend on that water source. The objective of this research was to determine the level of anions and heavy metals from sediments in River Sio, Busia County, Kenya. Five sediment samples were taken from five sampling points and the levels of anions and heavy metals in them determined. Anions were determined using Shimadzu 1800 UV/visible spectrophotometer while heavy metals were determined using Shimadzu 6200 flame atomic absorption spectrophotometer (AAS). Copper, lead and nickel were above the allowed WHO limits while cadmium was below detection limit. The levels of nitrates, phosphates and chlorides were higher during the wet season due to surface runoff that carried these nutrients from the farms and deposited them on the bottom of the River. The levels of heavy metals were high during the dry season due to evaporation of water from the River, leading to an increase in the analyte concentration during the dry season. High levels of copper and nickel in the sediments points to the use of herbicides and pesticides in farming and washing of vehicles and motorcycles on the banks of the River. According to Igeo nickel showed moderate pollution during the dry season. The contamination factor for lead was very high during the dry season, while pollution load index confirmed pollution due to anthropogenic activities in sampling sites 1 – 4 during the dry season and no pollution due to anthropogenic activities during the wet season.  The study recommends reduced use of inorganic fertilizers in order to save the River from the danger of eutrophication. Excessive use of agrochemicals such as herbicides and pesticides should be discouraged. In addition, pesticide leaching and the level of microbes in soil and sediments should be considered for further research

scholarly journals Heavy Metals Content in Kaolin Mined Soil and Water Body at Ohiya, Umuahia South, Abia State, Nigeria

2021 ◽  
pp. 58-68
Author(s):  
C. E. Igwe ◽  
C. M. U. Ajero ◽  
A. A. Amaechi ◽  
P. O.` Nzenwa
Keyword(s):  
Heavy Metals ◽  
Water Body ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Soil Samples ◽  
Pollution Indices ◽  
Mining Activities ◽  
Wet Season ◽  
Significant Difference ◽  
Very High

Heavy metals (HM) have been a global concern for its toxic and detrimental effect on the environment especially when it exceeds the permissible limit through anthropogenic activities like kaolin mining. Kaolin mining has improved the economic wellbeing of the local people through employment and otherwise; and at the same time attached with environmental consequences that threatens the livelihood of the community members. This study was carried out to ascertain the concentrations of selected heavy metals in kaolin mined soils and water body and its pollution density using single pollution indices such as contamination factor (CF), geo-accumulation (Igeo) and ecological risk factor (Er ). Soil sample were collected from three different kaolin mined sites labelled (A,B and C) also surface water samples were collected from upper and down streams of Iyi-ugbohoroAmaudara, both samples were digested and elemental analysis was carried out using Atomic Absorption Spectrophotometer (AAS UNICAM 919 model). The concentration of the metals in three different kaolin mined soil samples ranges from Pb(40.00, 52.00 and 55.09 mg/kg) Cr(45.01, 70.00 and 71.00 mg/kg) Ni( 32.10, 50.50 and 51.00 mg/kg) Cd( 2.16, 6.25 and 6.15 mg/kg) Co( 19.68, 57.06 and 56.00 mg/kg) Se(1.06, 0.50, and 1.00 mg/kg) Mn(0.001, 0.01 and 0.01 mg/kg) Hg( 2.01, 2.00 and 2.50 mg/kg) As( 1.07, 1.10 and 1.05 mg/kg) and Cu(33.01, 60.00 and 57.5 mg/kg). Results from single pollution indices used for the selected heavy metals from kaolin mined soil, samples (A,B and C) showed that Mn, As, Cr, Ni and Cu indicated low to moderate contamination factor while Cd, Se, Co and Hg indicated high to very high contamination factor in all the samples. The distribution trend of heavy metals concentrations in the upper and down streams of the river body during wet season, showed that there were significant difference between upper and down streams while dry season showed variations in significant differences between the upper and down streams of some of the heavy metals. The study therefore concludes that kaolin soils are contaminated with heavy metals as a result of kaolin deposit and its mining activities. The single pollution indices used for the study pointed out that Cd, Se, Co and Hg are very high in the kaolin soils. The surface waters of Iyi-ugbohoroAmaudara River at the study area are polluted with heavy metals as a result of kaolin mining activities in the area; more especially during wet season of the study. Consequently, these outcomes would pose a toxic effect to both fauna and flora and possibly threatens the aquatic lives and the local populace.

scholarly journals Spatial Variations in Groundwater Quality Around Dumpsite in Igando

2015 ◽  
Vol 6 (1) ◽  
pp. 179-186
Author(s):  
Akoteyon ◽  
S Isaiah
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Drinking Water ◽  
Groundwater Quality ◽  
Anthropogenic Activities ◽  
Dry Season ◽  
Spatial Variations ◽  
T Test ◽  
Drinking Water Quality ◽  
Wet Season

Water samples collected from fifteen hand dug wells in November (dry season), 2011 and July (Wet season), 2012 using random sampling technique. In situ parameters were measured for pH, electrical conductivity, total dissolved solids using portable meters. Heavy metals were analyzed for; Fe, Cu, Zn, Cd, Pb, and Cr using Atomic Absorption Spectrophotometer (AAS). The study aimed at examining the spatial variations in groundwater quality around dumpsite in Igando using paired sample T-test statistical technique. The result shows that the measured pH values were below the minimum WHO standard for drinking water quality in wet and dry seasons in about73.3% and 26.7% respectively. Also, approximately, 13.3% of EC, and 6.7% exceeded the prescribed standard limit of WHO in dry and wet seasons respectively. Concentration of Fe exceeded drinking water quality in all the sampling locations during wet season and only about 46.7% in dry season. Pb, Zn, and Cu exceeded WHO limit in about 86.7%, 80%, and 26.7% respectively in dry season. Concentration of Pb, Cd , Cu and Cr were under detection limit in all the locations except at locations G2 for Cu in wet season. The paired samples statistics and correlation revealed that the mean values of all the parameters were higher in dry season with the exception of Fe. No significant correlations exist among the paramet er for both seasons at p<0.05. The paired T-test show significant seasonal variations among four heavy metals including Fe, Cd, Pb and Zn.The study concluded that, samples in dry season are of low quality compared to wet. The study recommends public enlightenment on solid waste disposal, controlled anthropogenic activities, and treatment /recycling of waste to prevent heavy metal from leaching unto the sub-surface.DOI: http://dx.doi.org/10.3329/jesnr.v6i1.22063 J. Environ. Sci. & Natural Resources, 6(1): 179-186 2013

scholarly journals Environmental Impact of Heavy Metals from Poultry Waste Discharged into the Olosuru Stream, Ikire, Southwestern Nigeria

2019 ◽  
Vol 9 (22) ◽  
Author(s):  
Abayomi Tolulope Oyewale ◽  
Taiwo Adekanmi Adesakin ◽  
Adedeji Idowu Aduwo
Keyword(s):  
Heavy Metals ◽  
Environmental Impact ◽  
Anthropogenic Activities ◽  
Sampling Period ◽  
Dry Season ◽  
World Health ◽  
Poultry Waste ◽  
Wet Season ◽  
Southwestern Nigeria ◽  
Southwest Nigeria

Background. Water supplies can be contaminated by anthropogenic activities. The poultry industry uses a variety of heavy metals as additives in chicken feed, but excretion, runoff and dumping of heavy metals can threaten water bodies and have adverse effects on human health. Objectives. The aim of the present study was to determine the environmental impact of heavy metals from poultry waste discharged into the Olosuru stream, located in Ikire, southwest Nigeria. Methods. In order to study changes in heavy metal loads, samples were collected six times during the wet season (September, October 2014 and April 2015) and dry season (November 2014, January and February 2015). The inhabitants of Olosuru village use water for domestic and agriculture purposes from the Olosuru stream which is located only a few meters from a poultry farm discharge point. Three stations were sampled, upstream to downstream, with 500 meter distance between each point. Results. Selected heavy metals concentrations in the Olosuru stream were all above the World Health Organization (WHO) standard for drinking water. The highest mean concentrations of heavy metals were recorded at the downstream station, while arsenic, iron and lead showed significant spatial and seasonal differences. Seasonally, the highest iron concentrations were recorded in the dry season (0.104±0.401 mg/L), while the mean concentrations of other heavy metals recorded during the sampling period were higher during the wet season. Conclusions. Concentrations of heavy metals in the present study were above acceptable limits. Poultry waste discharged into the Olosuru stream, can have negative impacts on the stream and health implications for local residents. Competing Interests. The authors declare no competing financial interests.

scholarly journals The Potential of Heavy Metals Contamination in the Surface Sediments of River Nile, Egypt

2018 ◽  
Vol 3 (2) ◽  
pp. 143-159 ◽  
Author(s):  
Mohamed Nageeb Rashed ◽  
Mohamed ELSadeek Fouad Toufeek ◽  
Mahmoud Abedeldaium Eltaher ◽  
Ayman Outhman Elbadry
Keyword(s):  
Heavy Metals ◽  
Electrical Conductivity ◽  
Organic Matter ◽  
Anthropogenic Activities ◽  
Correlation Coefficients ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Indices ◽  
River Nile ◽  
Pollution Load

Electrical conductivity, pH, organic matter, carbonates and five heavy metals (Fe, Mn, Zn, Cu and Pb) were measured seasonally in the sediments of River Nile (Egypt) during 2015. Ten sectors include 30 sites were selected along River Nile from Aswan to Armant to assess the levels of the studied parameters. Heavy metals in sediments were in the order of Pb < Cu < Zn < Mn < Fe, which indicated that Pb was found to be the least concentration in sediments, whereas Fe was the most accumulated element. Pearson’s correlation coefficients among the measured parameters were tested. Zn, Cu and Pb were positively correlated with electrical conductivity and organic matter accumulation and also they were positively correlated with each other. Sediments pollution load was studied through pollution indices [geo-accumulation index, pollution load index, modified degree of contamination, contamination factor and enrichment factor]. The pollution indices confirmed that the River Nile sediments in the studied area were not contaminated with these heavy metals except for some samples collected from certain sites as a result of the anthropogenic activities at these sites.

scholarly journals Integrated Characterization of Toxicity Distribution of Selected Heavy Metals in Stream Sediments Around Itakpe Iron Ore Mines, North Central Nigeria

2016 ◽  
Vol 6 (1) ◽  
pp. 109
Author(s):  
Eneojo Godwin Ameh ◽  
Ojochogwu Sunday Idakwo ◽  
Ojone Caroline Ameh ◽  
Omojo Mercy Lekdukum
Keyword(s):  
Heavy Metals ◽  
Enrichment Factor ◽  
Contamination Factor ◽  
Stream Sediments ◽  
Dry Season ◽  
Middle Level ◽  
Wet Season ◽  
Hazard Level ◽  
Very High

The results of the analysis were subjected to five (5) indices: contamination factor (CF); Ecological risk factor (Eri); Enrichment factor (EF); index of geo-accumulation (Igeo) and anthropogenic factor (AF). The CF results showed that the River PomPom dry and wet season sediments were collected in February and July respectively from 0cm to 10cm depth. Stainless steel spoon was used to collect the samples. The sediment samples were packaged, labeled and refrigerated for onward transportation to the laboratory. All samples were oven-dried (50oC) for about 24 hours, sieved through -80 mesh. About 1.0g of each sample was digested, filtered and the filtrates were ready for heavy metal analysis using Atomic sediments were most contaminated with Fe in both seasons, least contaminated with Cd at dry season and Zn in wet season. The Eri factor revealed pollution hazard level of middle during wet season and tiny in dry season. Pb and Ni showed strong and middle hazard level during wet season and Cu revealed middle level during dry season. The enrichment factor indicated extremely enriched for Fe in all locations in both seasons while most heavy metals showed depletion to minimal enrichment. The Igeo for both seasons showed that Fe was moderately to highly polluted in all locations. During dry season, other heavy metals showed moderately to unpolluted while in wet season Cd, Ni and Pb indicated moderately to very highly polluted. In both seasons, the % AF was very high for Fe, Cu, Pb. The AF% was very high for Ni and Cd in wet season. All sites in both seasons have experienced deterioration but more in the wet season. From these indices, the stream sediments have been significantly contaminated with Fe, Ni, Pb and Ni in most locations in both seasons.

LEVELS OF HEAVY METALS IN SOME SELECTED FISH OF RIVER GONGOLA BASIN, ITS DAM AND DADINKOWA DAM, GOMBE STATE NIGERIA

2021 ◽  
Vol 5 (2) ◽  
pp. 498-510
Author(s):  
A. H. Santuraki ◽  
A. U. Babayo ◽  
Abdu Zakari ◽  
A. G. Abdulkadir
Keyword(s):  
Heavy Metals ◽  
Physicochemical Properties ◽  
Suspended Solids ◽  
Anthropogenic Activities ◽  
Clarias Gariepinus ◽  
Dry Season ◽  
Wet Season ◽  
Fish Samples ◽  
The Mean ◽  
Mean Concentration

This study was carried out in ten (10) different locations within River Gongola, its Dam, and Dadinkowa Dam, Gombe State, Nigeria during the wet and dry season to study the water quality in terms of physicochemical properties to ascertain the levels of contaminants due to flooding and anthropogenic activities and the levels of heavy metals (Cr, Cd, Pb, and Ni) in the two species of fish (Clarias gariepinus and Bagrus docmak). A total of 200 water and 360 fish samples comprising two different species were collected in the month of March-June 2017 (Dry season) and July-October 2017 (Wet Season). The results of physicochemical properties obtained ranges between Temperature 29.0-30 0C and 30-32 0C, pH 5.4-7.8 and 6.0-6.9, Conductivity 93.3-161 μS/cm3 and 104.9-128 μS/cm3, Dissolved oxygen 1.2-3.98 mg/l and 0.4-3.1 mg/l, Total Suspended Solids 10-860 mg/l and 13-1180 mg/l, Total Dissolved Solids 46.5-80.5 mg/l and 54.2-76.5 mg/l, Turbidity 424.7-783.5 NTU and 11.15-442.1 NTU, Phosphate 1.82-7.23 mg/l and 0.00-0.11 mg/l, and Nitrate 2.25-8.82 mg/l and 2.68-6.81 mg/l during wet and dry season respectively. The result reveals that turbidity, PO43, DO, TSS, and TDS were above the acceptable permissible limits of WHO While the mean concentration levels of heavy metals in Clarias gariepinus and Bagrus docmak revealed that Cr was below the detectable limit while Cd ranges between 0.5-7.75 µg/g, Pb rangesbetween 3.9-35.6 µg/g during the wet and dry season. The mean concentrations of all the studied metals were above the permissible limit of WHO with a higher concentration during the dry season.

scholarly journals Assessment Of Labile Metals In Effluents From Lubricating Oil Company In Osogbo Osun State, Nigeria

1970 ◽  
Vol 10 (5) ◽  
pp. 675-690
Author(s):  
A.O Adeniji ◽  
I.O. Olabanji ◽  
E.A. Oluyemi
Keyword(s):  
Heavy Metals ◽  
Metal Ion ◽  
Dry Season ◽  
Lubricating Oil ◽  
Residual Fraction ◽  
Wet Season ◽  
Sediment Samples ◽  
Mn Oxide ◽  
Exchangeable Fraction ◽  
Oil Company

Effluent and sediment samples were collected on seasonal basis, comprising of three months (August to October) in the wet season and three months (December to February) in the dry season from five points around a lubricating oil company in Osogbo - Nigeria. The sequential extraction method was used to respectively fractionate the sediment and effluent samples, then analyzed by Atomic Absorption Spectrophotometry (AAS) to determine concentrations of five heavy metals: Mn, Ni Co, Cd and Pb. Results showed that in wet season, higher concentration of Mn was found in exchangeable fraction, Ni  and Pb were more pronounced in carbonate bound fraction, Cd in Fe-Mn oxide fraction, while Co was more in residual fraction. In dry season, Pb was more concentrated in exchangeable fraction, Coin residual fraction, Mn in Fe-Mn oxide fraction, Cd in organic matter bound, while Ni was more concentrated in the carbonate fraction. In both seasons for sediment samples, Cd concentrations were found above the set limit by WHO. The speciation study of the effluent showed that, Mn, Co and Ni concentration were found more in Organic substances fraction in both seasons, Pb was more concentrated in free metal ion fraction in wet season while it was high in organic fraction in the dry season. Concentrations of all metals in the effluent samples in both seasons were above the maximum permissible limit for effluent. The high mobility factors of heavy metals in the sediment indicated that the metals were labile and bioavailable thereby making the soil and the living organisms vulnerable to possibility of high heavy metal bioaccumulation.Key Words: Heavy Metals, Speciation, Effluents, Sediment

scholarly journals An index approach to heavy metal pollution assessment of Eme River, Umuahia, Nigeria

2020 ◽  
Author(s):  
Emeka Donald Anyanwu
Keyword(s):  
Water Quality ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Heavy Metal Pollution ◽  
Anthropogenic Activities ◽  
Dry Season ◽  
Human Consumption ◽  
Pollution Indices ◽  
Sand Mining ◽  
Wet Season

Rivers are subjected to various kinds of natural and anthropogenic activities among which, indiscriminate and illegal sand mining is a major factor. The heavy metal content of a Nigerian river was studied between December 2017 and November 2018 in 6 stations in relation to suitability for human consumption using pollution indices. The indices used were Heavy Metal Pollution Index (HPI) and Contamination Index (Cd). Eight metals were evaluated using standard methods and compared with Nigerian Drinking Water Quality Standard. Some metals like iron, cadmium and lead exceeded limits; manganese, chromium and nickel exceeded limits in the dry season in some stations while copper and zinc were all within limits. The dry season values were significantly (P<0.05) higher than the wet season values. NPI showed all the stations exceeded the threshold (100) especially stations 1, 4 – 6 while Cd showed that stations 3 and 2 had low and medium contamination potential risks respectively and stations 1, 4 – 6 had high contamination potential risk. The indices effectively captured the effect of the anthropogenic activities (sand mining, swimming, washing, etc) in the river and showed that the water quality was not suitable for human consumption.

scholarly journals Ecological Risk Assessment of Heavy Metals in Soil of an Open Dump along Old Ikare Road Owo, Ondo State, Nigeria

2019 ◽  
pp. 1-11
Author(s):  
J. O. Olayinka-Olagunju ◽  
A. M. Olatunji-Ojo ◽  
A. Adejuyigbe ◽  
H. A. Ikuesan ◽  
S. E. Abubakar
Keyword(s):  
Heavy Metals ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Dry Season ◽  
Soil Samples ◽  
Pollution Load ◽  
Wet Season ◽  
Heavy Metal Concentrations ◽  
Regulatory Limits ◽  
Ondo State

Aims: To investigate the heavy metal concentrations in soil samples collected from an open dumpsite in a rural community (Aba Idi-Mangoro) in Owo, Ondo State and to compare the observed values with the regulatory limits. This study also aimed to determine the pollution levels using tools like contamination factor, pollution load index and geoaccumulation index. Study Design: Field study design was use in this study. Place and Duration of Study: Soil samples were collected from Aba Idi-Mangoro in Owo, Ondo State, Nigeria between July 2015 and February 2016 to represent the wet and dry seasons. Methodology: A total of 96 soil samples were collected (6 samples on each visit and the site was visited twice a month). The samples were taken to the Prof. Julius Okojie Central Research Laboratory at the Federal University of Technology, Akure, Ondo State, Nigeria. In the laboratory, samples were air dried to remove the moisture. 2 g of the sampes were digested into HNO3, HCl, HF and HClO4, and AA Spectrophotometer was used to analyse the concentrations of the heavy metals. Results: Out of the 8 heavy metals assessed, 6 were above the regulatory limits. The order of heavy metal concentrations for the wet season is: Fe>Mn>Zn>Cu>Pb>Ni>Cr>Co>Cd and the dry season is as follows: Fe>Zn>Mn>Pb>Cu>Ni>Co>Cr>Cd. When the mean concentrations of the samples for the wet season were compared to the dry season, Mn (0.009), Cd (0.035), Cr (0.044) and Co (0.014) differ significantly (p<0.05). No significant difference was found in Fe, Co, Ni and Zn. It was observed from the overall results that the concentrations of heavy metals were higher during the dry season than in the wet season. The contamination factor (CF), pollution load index and geo-accumulation index values of Fe was extremely high in the two seasons while it varies at different collection times for the other metals. Conclusion: Due to the high presence of some of the heavy metals found in the soil, the study suggests that water and sediment samples from nearby river(s) within the community should also be examined.

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